An active control methodology is presented for suppressing the vibratoryresponse of flexible redundant manipulators with bonded piezoceramic actuators and strain gagesensors. Firstly, the dynamic equation of the manip...An active control methodology is presented for suppressing the vibratoryresponse of flexible redundant manipulators with bonded piezoceramic actuators and strain gagesensors. Firstly, the dynamic equation of the manipulator is decoupled by means of the complex modetheory and the state-space expression of the controlled system is developed. Secondly, a continuouslinear quadratic regulator (LQR) state feedback controller is designed based on the minimumprinciple. Thirdly, a full-order Luenberger state observer featuring an assigned degree of stabilityis determined via the duality between control and estimation. Finally, a numerical simulation iscarried out on a planar 3R flexible redundant manipulator. The simulation results reveal that thedynamic performance of the system is improved rapidly and significantly.展开更多
Complex modes and traveling waves in axially moving Timoshenko beams are studied. Due to the axially moving velocity, complex modes emerge instead of real value modes. Correspondingly, traveling waves are present for ...Complex modes and traveling waves in axially moving Timoshenko beams are studied. Due to the axially moving velocity, complex modes emerge instead of real value modes. Correspondingly, traveling waves are present for the axially moving material while standing waves dominate in the traditional static structures. The analytical results obtained in this study are verified with a numerical differential quadrature method.展开更多
A universal matrix perturbation technique for complex modes is presented. This technique is applicable to all the three cases of complex eigenvalues: distinct, repeated and closely spaced eigenvalues. The lower order ...A universal matrix perturbation technique for complex modes is presented. This technique is applicable to all the three cases of complex eigenvalues: distinct, repeated and closely spaced eigenvalues. The lower order perturbation formulas are obtained hy performing two complex eigensubspace condensations, and the higher order perturbation formulas are derived hy a successive approximation process. Three illustrative examples are given to verify the proposed method and satisfactory results are observed.展开更多
For a vibration system with 2 DOF of bend and torsion, its critical flutter wind speed can be calculated by using complex mode frequency iteration (CMFI) method based on MatLab 5.2, the results of which are in agree ...For a vibration system with 2 DOF of bend and torsion, its critical flutter wind speed can be calculated by using complex mode frequency iteration (CMFI) method based on MatLab 5.2, the results of which are in agree with those acquired by wind tunnel test. Not only critical flutter wind speed, but also vibration characteristic of a system under different wind speeds can be determined. CMFI method is suitable for both of separated flow torsional flutter and classic coupling flutter analysis, which is presented by flutter analysis of an ideal thin plate and a bluff bridge deck. Furthermore, it is proved through the investigation of the relationship between flutter derivatives and its critical flutter wind speed that coupling aerodynamic derivatives are necessary for classic coupling flutter to occur.]展开更多
The frequency–space(f–x) empirical mode decomposition(EMD) denoising method has two limitations when applied to nonstationary seismic data. First, subtracting the first intrinsic mode function(IMF) results in ...The frequency–space(f–x) empirical mode decomposition(EMD) denoising method has two limitations when applied to nonstationary seismic data. First, subtracting the first intrinsic mode function(IMF) results in signal damage and limited denoising. Second, decomposing the real and imaginary parts of complex data may lead to inconsistent decomposition numbers. Thus, we propose a new method named f–x spatial projection-based complex empirical mode decomposition(CEMD) prediction filtering. The proposed approach directly decomposes complex seismic data into a series of complex IMFs(CIMFs) using the spatial projection-based CEMD algorithm and then applies f–x predictive filtering to the stationary CIMFs to improve the signal-to-noise ratio. Synthetic and real data examples were used to demonstrate the performance of the new method in random noise attenuation and seismic signal preservation.展开更多
In the study of finite element model updating or damage detection,most papers are devoted to undamped systems.Thus,their objective has been exclusively restricted to the correction of the mass and stiffness matrices.I...In the study of finite element model updating or damage detection,most papers are devoted to undamped systems.Thus,their objective has been exclusively restricted to the correction of the mass and stiffness matrices.In contrast,this paper performs the model updating and damage detection for damped structures.A theoretical contribution of this paper is to extend the cross-model cross-mode(CMCM) method to simultaneously update the mass,damping and stiffness matrices of a finite element model when only few spatially incomplete,complex-valued modes are available.Numerical studies are conducted for a 30-DOF(degree-of-freedom) cantilever beam with multiple damaged elements,as the measured modes are synthesized from finite element models.The numerical results reveal that applying the CMCM method,together with an iterative Guyan reduction scheme,can yield good damage detection in general.When the measured modes utilized in the CMCM method are corrupted with irregular errors,assessing damage at the location that possesses larger modal strain energy is less sensitive to the corrupted modes.展开更多
Under the consideration of harmonic fluctuations of initial tension and axially velocity, a nonlinear governing equation for transverse vibration of an axially accelerating string is set up by using the equation of mo...Under the consideration of harmonic fluctuations of initial tension and axially velocity, a nonlinear governing equation for transverse vibration of an axially accelerating string is set up by using the equation of motion for a 3-dimensional deformable body with initial stresses. The Kelvin model is used to describe viscoelastic behaviors of the material. The basis function of the complex-mode Galerkin method for axially accelerating nonlinear strings is constructed by using the modal function of linear moving strings with constant axially transport velocity. By the constructed basis functions, the application of the complex-mode Galerkin method in nonlinear vibration analysis of an axially accelerating viscoelastic string is investigated. Numerical results show that the convergence velocity of the complex-mode Galerkin method is higher than that of the real-mode Galerkin method for a variable coefficient gyroscopic system.展开更多
The variable block-size motion estimation(ME) and disparity estimation(DE) are adopted in multi-view video coding(MVC) to achieve high coding efficiency. However, much higher computational complexity is also introduce...The variable block-size motion estimation(ME) and disparity estimation(DE) are adopted in multi-view video coding(MVC) to achieve high coding efficiency. However, much higher computational complexity is also introduced in coding system, which hinders practical application of MVC. An efficient fast mode decision method using mode complexity is proposed to reduce the computational complexity. In the proposed method, mode complexity is firstly computed by using the spatial, temporal and inter-view correlation between the current macroblock(MB) and its neighboring MBs. Based on the observation that direct mode is highly possible to be the optimal mode, mode complexity is always checked in advance whether it is below a predefined threshold for providing an efficient early termination opportunity. If this early termination condition is not met, three mode types for the MBs are classified according to the value of mode complexity, i.e., simple mode, medium mode and complex mode, to speed up the encoding process by reducing the number of the variable block modes required to be checked. Furthermore, for simple and medium mode region, the rate distortion(RD) cost of mode 16×16 in the temporal prediction direction is compared with that of the disparity prediction direction, to determine in advance whether the optimal prediction direction is in the temporal prediction direction or not, for skipping unnecessary disparity estimation. Experimental results show that the proposed method is able to significantly reduce the computational load by 78.79% and the total bit rate by 0.07% on average, while only incurring a negligible loss of PSNR(about 0.04 d B on average), compared with the full mode decision(FMD) in the reference software of MVC.展开更多
A complex number mode analysis approach is proposed for vibration reducing of structural flexible redundant manipulators by utilizing self motion. In the proposed approach, the self motion is evaluated to nullify th...A complex number mode analysis approach is proposed for vibration reducing of structural flexible redundant manipulators by utilizing self motion. In the proposed approach, the self motion is evaluated to nullify the modal exciting force of flexural motion, and the approach can be freely used when the degree of freedom of flexural motion is much greater than the available degree of reundancy. The availability and effectiveness of the proposed approach are demonstrated through numerical simulation with a four link spatial robotic manipulator possessing an end flexible link.展开更多
In this paper, the problem of exponential synchronization of complex dynamical networks with Markovian jumping parameters using sampled-data and Mode-dependent probabilistic time-varying coupling delays is investigate...In this paper, the problem of exponential synchronization of complex dynamical networks with Markovian jumping parameters using sampled-data and Mode-dependent probabilistic time-varying coupling delays is investigated. The sam- pling period is assumed to be time-varying and bounded. The information of probability distribution of the time-varying delay is considered and transformed into parameter matrices of the transferred complex dynamical network model. Based on the condition, the design method of the desired sampled data controller is proposed. By constructing a new Lyapunov functional with triple integral terms, delay-distribution-dependent exponential synchronization criteria are derived in the form of linear matrix inequalities. Finally, two numerical examples are given to illustrate the effectiveness of the proposed methods.展开更多
In this article, a synchronization problem for master-slave Markovian switching complex dynamical networks with time-varying delays in nonlinear function via sliding mode control is investigated. On the basis of the a...In this article, a synchronization problem for master-slave Markovian switching complex dynamical networks with time-varying delays in nonlinear function via sliding mode control is investigated. On the basis of the appropriate Lyapunov-Krasovskii functional, introducing some free weighting matrices, new synchronization criteria are derived in terms of linear matrix inequalities (LMIs). Then, an integral sliding surface is designed to guarantee synchronization of master-slave Markovian switching complex dynamical networks, and the suitable controller is synthesized to ensure that the trajectory of the closed-loop error system can be driven onto the prescribed sliding mode surface. By using Dynkin's formula, we established the stochastic stablity of master-slave system. Finally, numerical example is provided to demonstrate the effectiveness of the obtained theoretical results.展开更多
A new copper(Ⅱ) compound with imino nitroxide radicals [Cu(IM-MeImz)2].(SCN)2 (IM-meImz =2-(5-methylimidazol-4-yl)-4,4,5,5-tetramethyl-2-imidazoline- 1-oxyl) has been synthesized and characterized structura...A new copper(Ⅱ) compound with imino nitroxide radicals [Cu(IM-MeImz)2].(SCN)2 (IM-meImz =2-(5-methylimidazol-4-yl)-4,4,5,5-tetramethyl-2-imidazoline- 1-oxyl) has been synthesized and characterized structurally and magnetically. It crystallizes in monoclinic, space group P21/c with a = 9.3604(7), b = 10.3012(7), c = 16.6684(12)A, β = 105.0290(10)^o, V = 1552.25(19)A3, C24H34CUN10O2S2, Mr = 622.27, Z = 2, Dc = 1.331 g/cm^3,μ(MoKα) = 0.876 mm^-1, F(000) = 650, the final R = 0.0374 and wR = 0.1079. X-ray analysis demonstrates that the IM-MeImz ligand is coordinated to the copper(Ⅱ) ion as an unusual didentate chelate with a k-2 N(MeImz),O(IM) mode in the complex. The square-planar coordination sites at Cu(Ⅱ) are occupied by two 0 and two N atoms from the imino nitroxide radicals. The complex molecules are connected as a onedimensional polymer structure by intermolecular interactions. Magnetic measurements show that there are intramolecular antiferromagnetic interactions between the Cu(Ⅱ) ion and radicals.展开更多
A technique to extract real modes from the identified complex modes is presented in this paper, which enables the normalized real mode shapes, modal masses, and full or reduced mass and stiffness matrices to be obtain...A technique to extract real modes from the identified complex modes is presented in this paper, which enables the normalized real mode shapes, modal masses, and full or reduced mass and stiffness matrices to be obtained. The theoretical derivation of the method is provided in detail. An 11-DOF vibration system is used to validate the algorithm, and to analyze the effects of the number of modes utilized and measurement DOFs on the extraction results. Finally, the method is used to extract real modes from both experimental modal analysis and operational modal analysis.展开更多
A new matrix perturbation analysis method is presented for efficient approximate solution of the complex modal quadratic generalized eigenvalue problem of viscously damped linear vibration systems. First, the damping ...A new matrix perturbation analysis method is presented for efficient approximate solution of the complex modal quadratic generalized eigenvalue problem of viscously damped linear vibration systems. First, the damping matrix is decomposed into the sum of a proportional-and a nonproportional-damping parts, and the solutions of the real modal eigenproblem with the proportional dampings are determined, which are a set of initial approximate solutions of the complex modal eigenproblem. Second, by taking the nonproportional-damping part as a small modification to the proportional one and using the matrix perturbation analysis method, a set of approximate solutions of the complex modal eigenvalue problem can be obtained analytically. The result is quite simple. The new method is applicable to the systems with viscous dampings-which do not deviate far away from the proportional-damping case. It is particularly important that the solution technique be also effective to the systems with heavy, but not over, dampings. The solution formulas of complex modal eigenvlaues and eigenvectors are derived up to second-order perturbation terms. The effectiveness of the perturbation algorithm is illustrated by an exemplar numerical problem with heavy dampings. In addition, the practicability of approximately estimating the complex modal eigenvalues, under the proportional-damping hypothesis, of damped vibration systems is discussed by several numerical examples.展开更多
An industrial building is a non-classically damped system due to the different damping properties of the primary structure and equipment.The objective of this paper is to quantify the range of applicability of the rea...An industrial building is a non-classically damped system due to the different damping properties of the primary structure and equipment.The objective of this paper is to quantify the range of applicability of the real model superposition approximation method to the seismic response calculation of industrial buildings.The analysis using lumped mass-and-shear spring models indicates that for the equipment-to-structure frequency ratiosγf>1.1 orγf<0.9,the non-classical damping effect is limited,and the real mode superposition approximation method provides accurate estimates.For 0.9<γf<1.1,the system may have a pair of closely spaced frequency modes,and the non-zero off-diagonal damping terms have a non-negligible effect on the damping ratios and mode shape vectors of these modes.For 0.9<γf<1.1 and the equipment-to-structure mass ratiosγm<0.07,the real mode superposition approximation method results in large errors,while the approximation method can provide an accurate estimation for 0.9<γf<1.1 andγm>0.07.Furthermore,extensive parametric analyses are conducted,where both steel structures and reinforced concrete structures with equipment with various damping ratios are considered.Finally,the finite element analysis of a five-story industrial building is adopted to validate the proposed range of applicability.展开更多
From the awakening and the development of feminism, to the formation of the Cinderella complex, much attention has been paid. As we know the reason of the popularity of Cinderella complex is patriarchal rule forces th...From the awakening and the development of feminism, to the formation of the Cinderella complex, much attention has been paid. As we know the reason of the popularity of Cinderella complex is patriarchal rule forces that reigns the world, the only way to remove this psychological problem is the reconstruction of the concept of gender relationship. This essay tries to find some reasons for the popularity of the Cinderella complex by some analysis of the developing of Cinderella mode and Cinderella complex, thus giving some measures.展开更多
Two novel mixed-ligand complexes, [M(phen)2(ans)2]·H2O (M = Cd(Ⅱ) 1, Zn(Ⅱ) 2; phen is 1, 10-phenanthroline, and ans is 4-aminonaphthalene-1-sulfonate), were obtained from the reaction of 1, 10-phenant...Two novel mixed-ligand complexes, [M(phen)2(ans)2]·H2O (M = Cd(Ⅱ) 1, Zn(Ⅱ) 2; phen is 1, 10-phenanthroline, and ans is 4-aminonaphthalene-1-sulfonate), were obtained from the reaction of 1, 10-phenanthroline, sodium 4-aminonaphthalene-1-sulfonate tetrahydrate and acetate in mixed solvents. Interaction of the complexes with calf thymus DNA (ctDNA) were investigated using UV-vis absorption spectra, luminescence titrations, steady-state emission quenching by [Fe(CN)6]4 , DNA competitive binding with ethidium bromide (EB) and viscosity measurements. The experimental results indicate that there exist two interaction modes between the complexes and DNA, namely the electrostatic interaction and intercalation, with the binding constants of 1.82 × 10^5 M-1 for 1 and 4.78 ×10^4 M^- 1 for 2 in buffer of 50 mM NaCl and 5 mM Tris-HCI (pH 7.0).展开更多
文摘An active control methodology is presented for suppressing the vibratoryresponse of flexible redundant manipulators with bonded piezoceramic actuators and strain gagesensors. Firstly, the dynamic equation of the manipulator is decoupled by means of the complex modetheory and the state-space expression of the controlled system is developed. Secondly, a continuouslinear quadratic regulator (LQR) state feedback controller is designed based on the minimumprinciple. Thirdly, a full-order Luenberger state observer featuring an assigned degree of stabilityis determined via the duality between control and estimation. Finally, a numerical simulation iscarried out on a planar 3R flexible redundant manipulator. The simulation results reveal that thedynamic performance of the system is improved rapidly and significantly.
基金Project supported by the National Natural Science Foundation of China(Nos.11672007 and11672186)the Training Scheme for the Youth Teachers of Higher Education of Shanghai(No.ZZyyy12035)the "Chen Guang" Project(No.14CG57)
文摘Complex modes and traveling waves in axially moving Timoshenko beams are studied. Due to the axially moving velocity, complex modes emerge instead of real value modes. Correspondingly, traveling waves are present for the axially moving material while standing waves dominate in the traditional static structures. The analytical results obtained in this study are verified with a numerical differential quadrature method.
文摘A universal matrix perturbation technique for complex modes is presented. This technique is applicable to all the three cases of complex eigenvalues: distinct, repeated and closely spaced eigenvalues. The lower order perturbation formulas are obtained hy performing two complex eigensubspace condensations, and the higher order perturbation formulas are derived hy a successive approximation process. Three illustrative examples are given to verify the proposed method and satisfactory results are observed.
文摘For a vibration system with 2 DOF of bend and torsion, its critical flutter wind speed can be calculated by using complex mode frequency iteration (CMFI) method based on MatLab 5.2, the results of which are in agree with those acquired by wind tunnel test. Not only critical flutter wind speed, but also vibration characteristic of a system under different wind speeds can be determined. CMFI method is suitable for both of separated flow torsional flutter and classic coupling flutter analysis, which is presented by flutter analysis of an ideal thin plate and a bluff bridge deck. Furthermore, it is proved through the investigation of the relationship between flutter derivatives and its critical flutter wind speed that coupling aerodynamic derivatives are necessary for classic coupling flutter to occur.]
基金supported financially by the National Natural Science Foundation(No.41174117)the Major National Science and Technology Projects(No.2011ZX05031–001)
文摘The frequency–space(f–x) empirical mode decomposition(EMD) denoising method has two limitations when applied to nonstationary seismic data. First, subtracting the first intrinsic mode function(IMF) results in signal damage and limited denoising. Second, decomposing the real and imaginary parts of complex data may lead to inconsistent decomposition numbers. Thus, we propose a new method named f–x spatial projection-based complex empirical mode decomposition(CEMD) prediction filtering. The proposed approach directly decomposes complex seismic data into a series of complex IMFs(CIMFs) using the spatial projection-based CEMD algorithm and then applies f–x predictive filtering to the stationary CIMFs to improve the signal-to-noise ratio. Synthetic and real data examples were used to demonstrate the performance of the new method in random noise attenuation and seismic signal preservation.
基金the National High-Tech Research and Development Program of China("863")(Grant No.2006AA09Z331)the China National Science Fund for Distinguished Young Scholars(Grant No.50325927)the National Natural Science Foundation of China(Grant No.50739004)
文摘In the study of finite element model updating or damage detection,most papers are devoted to undamped systems.Thus,their objective has been exclusively restricted to the correction of the mass and stiffness matrices.In contrast,this paper performs the model updating and damage detection for damped structures.A theoretical contribution of this paper is to extend the cross-model cross-mode(CMCM) method to simultaneously update the mass,damping and stiffness matrices of a finite element model when only few spatially incomplete,complex-valued modes are available.Numerical studies are conducted for a 30-DOF(degree-of-freedom) cantilever beam with multiple damaged elements,as the measured modes are synthesized from finite element models.The numerical results reveal that applying the CMCM method,together with an iterative Guyan reduction scheme,can yield good damage detection in general.When the measured modes utilized in the CMCM method are corrupted with irregular errors,assessing damage at the location that possesses larger modal strain energy is less sensitive to the corrupted modes.
基金Project supported by the National Natural Science Foundation of China (No. 10472060)Shanghai Leading Academic Discipline Project (No.Y0103)the Natural Science Foundation of Shanghai (No.04ZR14058)the Outstanding Youth Program of Shanghai Municipal Commission of Educatio(No.04YQHB088)
文摘Under the consideration of harmonic fluctuations of initial tension and axially velocity, a nonlinear governing equation for transverse vibration of an axially accelerating string is set up by using the equation of motion for a 3-dimensional deformable body with initial stresses. The Kelvin model is used to describe viscoelastic behaviors of the material. The basis function of the complex-mode Galerkin method for axially accelerating nonlinear strings is constructed by using the modal function of linear moving strings with constant axially transport velocity. By the constructed basis functions, the application of the complex-mode Galerkin method in nonlinear vibration analysis of an axially accelerating viscoelastic string is investigated. Numerical results show that the convergence velocity of the complex-mode Galerkin method is higher than that of the real-mode Galerkin method for a variable coefficient gyroscopic system.
基金Project(08Y29-7)supported by the Transportation Science and Research Program of Jiangsu Province,ChinaProject(201103051)supported by the Major Infrastructure Program of the Health Monitoring System Hardware Platform Based on Sensor Network Node,China+1 种基金Project(61100111)supported by the National Natural Science Foundation of ChinaProject(BE2011169)supported by the Scientific and Technical Supporting Program of Jiangsu Province,China
文摘The variable block-size motion estimation(ME) and disparity estimation(DE) are adopted in multi-view video coding(MVC) to achieve high coding efficiency. However, much higher computational complexity is also introduced in coding system, which hinders practical application of MVC. An efficient fast mode decision method using mode complexity is proposed to reduce the computational complexity. In the proposed method, mode complexity is firstly computed by using the spatial, temporal and inter-view correlation between the current macroblock(MB) and its neighboring MBs. Based on the observation that direct mode is highly possible to be the optimal mode, mode complexity is always checked in advance whether it is below a predefined threshold for providing an efficient early termination opportunity. If this early termination condition is not met, three mode types for the MBs are classified according to the value of mode complexity, i.e., simple mode, medium mode and complex mode, to speed up the encoding process by reducing the number of the variable block modes required to be checked. Furthermore, for simple and medium mode region, the rate distortion(RD) cost of mode 16×16 in the temporal prediction direction is compared with that of the disparity prediction direction, to determine in advance whether the optimal prediction direction is in the temporal prediction direction or not, for skipping unnecessary disparity estimation. Experimental results show that the proposed method is able to significantly reduce the computational load by 78.79% and the total bit rate by 0.07% on average, while only incurring a negligible loss of PSNR(about 0.04 d B on average), compared with the full mode decision(FMD) in the reference software of MVC.
文摘A complex number mode analysis approach is proposed for vibration reducing of structural flexible redundant manipulators by utilizing self motion. In the proposed approach, the self motion is evaluated to nullify the modal exciting force of flexural motion, and the approach can be freely used when the degree of freedom of flexural motion is much greater than the available degree of reundancy. The availability and effectiveness of the proposed approach are demonstrated through numerical simulation with a four link spatial robotic manipulator possessing an end flexible link.
基金Project supported by the NBHM Research Project (Grant Nos.2/48(7)/2012/NBHM(R.P.)/R and D II/12669)
文摘In this paper, the problem of exponential synchronization of complex dynamical networks with Markovian jumping parameters using sampled-data and Mode-dependent probabilistic time-varying coupling delays is investigated. The sam- pling period is assumed to be time-varying and bounded. The information of probability distribution of the time-varying delay is considered and transformed into parameter matrices of the transferred complex dynamical network model. Based on the condition, the design method of the desired sampled data controller is proposed. By constructing a new Lyapunov functional with triple integral terms, delay-distribution-dependent exponential synchronization criteria are derived in the form of linear matrix inequalities. Finally, two numerical examples are given to illustrate the effectiveness of the proposed methods.
文摘In this article, a synchronization problem for master-slave Markovian switching complex dynamical networks with time-varying delays in nonlinear function via sliding mode control is investigated. On the basis of the appropriate Lyapunov-Krasovskii functional, introducing some free weighting matrices, new synchronization criteria are derived in terms of linear matrix inequalities (LMIs). Then, an integral sliding surface is designed to guarantee synchronization of master-slave Markovian switching complex dynamical networks, and the suitable controller is synthesized to ensure that the trajectory of the closed-loop error system can be driven onto the prescribed sliding mode surface. By using Dynkin's formula, we established the stochastic stablity of master-slave system. Finally, numerical example is provided to demonstrate the effectiveness of the obtained theoretical results.
基金This work was supported by the N N S F of China (No. 20471026)the Natural Science Foundation of Henan Province (No. 0311021200)
文摘A new copper(Ⅱ) compound with imino nitroxide radicals [Cu(IM-MeImz)2].(SCN)2 (IM-meImz =2-(5-methylimidazol-4-yl)-4,4,5,5-tetramethyl-2-imidazoline- 1-oxyl) has been synthesized and characterized structurally and magnetically. It crystallizes in monoclinic, space group P21/c with a = 9.3604(7), b = 10.3012(7), c = 16.6684(12)A, β = 105.0290(10)^o, V = 1552.25(19)A3, C24H34CUN10O2S2, Mr = 622.27, Z = 2, Dc = 1.331 g/cm^3,μ(MoKα) = 0.876 mm^-1, F(000) = 650, the final R = 0.0374 and wR = 0.1079. X-ray analysis demonstrates that the IM-MeImz ligand is coordinated to the copper(Ⅱ) ion as an unusual didentate chelate with a k-2 N(MeImz),O(IM) mode in the complex. The square-planar coordination sites at Cu(Ⅱ) are occupied by two 0 and two N atoms from the imino nitroxide radicals. The complex molecules are connected as a onedimensional polymer structure by intermolecular interactions. Magnetic measurements show that there are intramolecular antiferromagnetic interactions between the Cu(Ⅱ) ion and radicals.
文摘A technique to extract real modes from the identified complex modes is presented in this paper, which enables the normalized real mode shapes, modal masses, and full or reduced mass and stiffness matrices to be obtained. The theoretical derivation of the method is provided in detail. An 11-DOF vibration system is used to validate the algorithm, and to analyze the effects of the number of modes utilized and measurement DOFs on the extraction results. Finally, the method is used to extract real modes from both experimental modal analysis and operational modal analysis.
文摘A new matrix perturbation analysis method is presented for efficient approximate solution of the complex modal quadratic generalized eigenvalue problem of viscously damped linear vibration systems. First, the damping matrix is decomposed into the sum of a proportional-and a nonproportional-damping parts, and the solutions of the real modal eigenproblem with the proportional dampings are determined, which are a set of initial approximate solutions of the complex modal eigenproblem. Second, by taking the nonproportional-damping part as a small modification to the proportional one and using the matrix perturbation analysis method, a set of approximate solutions of the complex modal eigenvalue problem can be obtained analytically. The result is quite simple. The new method is applicable to the systems with viscous dampings-which do not deviate far away from the proportional-damping case. It is particularly important that the solution technique be also effective to the systems with heavy, but not over, dampings. The solution formulas of complex modal eigenvlaues and eigenvectors are derived up to second-order perturbation terms. The effectiveness of the perturbation algorithm is illustrated by an exemplar numerical problem with heavy dampings. In addition, the practicability of approximately estimating the complex modal eigenvalues, under the proportional-damping hypothesis, of damped vibration systems is discussed by several numerical examples.
基金Fund of China National Industrial Building Diagnosis and Reconstruction Engineering Technology Research Center under Grant No.YZA2017Ky03the Beijing Natural Science Foundation under Grant No.JQ18029the National Natural Science Foundation of China under Grant No.52078277。
文摘An industrial building is a non-classically damped system due to the different damping properties of the primary structure and equipment.The objective of this paper is to quantify the range of applicability of the real model superposition approximation method to the seismic response calculation of industrial buildings.The analysis using lumped mass-and-shear spring models indicates that for the equipment-to-structure frequency ratiosγf>1.1 orγf<0.9,the non-classical damping effect is limited,and the real mode superposition approximation method provides accurate estimates.For 0.9<γf<1.1,the system may have a pair of closely spaced frequency modes,and the non-zero off-diagonal damping terms have a non-negligible effect on the damping ratios and mode shape vectors of these modes.For 0.9<γf<1.1 and the equipment-to-structure mass ratiosγm<0.07,the real mode superposition approximation method results in large errors,while the approximation method can provide an accurate estimation for 0.9<γf<1.1 andγm>0.07.Furthermore,extensive parametric analyses are conducted,where both steel structures and reinforced concrete structures with equipment with various damping ratios are considered.Finally,the finite element analysis of a five-story industrial building is adopted to validate the proposed range of applicability.
文摘From the awakening and the development of feminism, to the formation of the Cinderella complex, much attention has been paid. As we know the reason of the popularity of Cinderella complex is patriarchal rule forces that reigns the world, the only way to remove this psychological problem is the reconstruction of the concept of gender relationship. This essay tries to find some reasons for the popularity of the Cinderella complex by some analysis of the developing of Cinderella mode and Cinderella complex, thus giving some measures.
基金Funded by Key Project of the National Natural Science Foundation of China (No. 60537050)
文摘Two novel mixed-ligand complexes, [M(phen)2(ans)2]·H2O (M = Cd(Ⅱ) 1, Zn(Ⅱ) 2; phen is 1, 10-phenanthroline, and ans is 4-aminonaphthalene-1-sulfonate), were obtained from the reaction of 1, 10-phenanthroline, sodium 4-aminonaphthalene-1-sulfonate tetrahydrate and acetate in mixed solvents. Interaction of the complexes with calf thymus DNA (ctDNA) were investigated using UV-vis absorption spectra, luminescence titrations, steady-state emission quenching by [Fe(CN)6]4 , DNA competitive binding with ethidium bromide (EB) and viscosity measurements. The experimental results indicate that there exist two interaction modes between the complexes and DNA, namely the electrostatic interaction and intercalation, with the binding constants of 1.82 × 10^5 M-1 for 1 and 4.78 ×10^4 M^- 1 for 2 in buffer of 50 mM NaCl and 5 mM Tris-HCI (pH 7.0).