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Smart Material Based Complex Mode Active Control of Flexible Manipulators with Kinematic Redundancy 被引量:1
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作者 宋轶民 张策 余跃庆 《Chinese Journal of Aeronautics》 SCIE EI CAS CSCD 2004年第4期240-245,共6页
An active control methodology is presented for suppressing the vibratoryresponse of flexible redundant manipulators with bonded piezoceramic actuators and strain gagesensors. Firstly, the dynamic equation of the manip... An active control methodology is presented for suppressing the vibratoryresponse of flexible redundant manipulators with bonded piezoceramic actuators and strain gagesensors. Firstly, the dynamic equation of the manipulator is decoupled by means of the complex modetheory and the state-space expression of the controlled system is developed. Secondly, a continuouslinear quadratic regulator (LQR) state feedback controller is designed based on the minimumprinciple. Thirdly, a full-order Luenberger state observer featuring an assigned degree of stabilityis determined via the duality between control and estimation. Finally, a numerical simulation iscarried out on a planar 3R flexible redundant manipulator. The simulation results reveal that thedynamic performance of the system is improved rapidly and significantly. 展开更多
关键词 flexible manipulator kinematic redundancy active control smart material complex mode
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Complex modes and traveling waves in axially moving Timoshenko beams 被引量:1
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作者 Youqi TANG Erbao LUO Xiaodong YANG 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI CSCD 2018年第4期597-608,共12页
Complex modes and traveling waves in axially moving Timoshenko beams are studied. Due to the axially moving velocity, complex modes emerge instead of real value modes. Correspondingly, traveling waves are present for ... Complex modes and traveling waves in axially moving Timoshenko beams are studied. Due to the axially moving velocity, complex modes emerge instead of real value modes. Correspondingly, traveling waves are present for the axially moving material while standing waves dominate in the traditional static structures. The analytical results obtained in this study are verified with a numerical differential quadrature method. 展开更多
关键词 axially moving Timoshenko beam complex mode traveling wave
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A UNIVERSAL MATRIX PERTURBATION TECHNIQUE FOR COMPLEX MODES
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作者 刘济科 徐伟华 蔡承武 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI 2001年第3期361-367,共7页
A universal matrix perturbation technique for complex modes is presented. This technique is applicable to all the three cases of complex eigenvalues: distinct, repeated and closely spaced eigenvalues. The lower order ... A universal matrix perturbation technique for complex modes is presented. This technique is applicable to all the three cases of complex eigenvalues: distinct, repeated and closely spaced eigenvalues. The lower order perturbation formulas are obtained hy performing two complex eigensubspace condensations, and the higher order perturbation formulas are derived hy a successive approximation process. Three illustrative examples are given to verify the proposed method and satisfactory results are observed. 展开更多
关键词 perturbation method complex modes repeated eigenvalues closely spaced eigenvalues
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Complex Mode Frequency Iteration Method for Flutter Analysis of 2-DOF Systems
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作者 何向东 奚绍中 廖海黎 《Journal of Modern Transportation》 2001年第1期35-41,共7页
For a vibration system with 2 DOF of bend and torsion, its critical flutter wind speed can be calculated by using complex mode frequency iteration (CMFI) method based on MatLab 5.2, the results of which are in agree ... For a vibration system with 2 DOF of bend and torsion, its critical flutter wind speed can be calculated by using complex mode frequency iteration (CMFI) method based on MatLab 5.2, the results of which are in agree with those acquired by wind tunnel test. Not only critical flutter wind speed, but also vibration characteristic of a system under different wind speeds can be determined. CMFI method is suitable for both of separated flow torsional flutter and classic coupling flutter analysis, which is presented by flutter analysis of an ideal thin plate and a bluff bridge deck. Furthermore, it is proved through the investigation of the relationship between flutter derivatives and its critical flutter wind speed that coupling aerodynamic derivatives are necessary for classic coupling flutter to occur.] 展开更多
关键词 FLUTTER complex mode frequency iteration wind tunnel test
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Random noise attenuation by f–x spatial projection-based complex empirical mode decomposition predictive filtering 被引量:7
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作者 马彦彦 李国发 +2 位作者 王钧 周辉 张保江 《Applied Geophysics》 SCIE CSCD 2015年第1期47-54,121,共9页
The frequency–space(f–x) empirical mode decomposition(EMD) denoising method has two limitations when applied to nonstationary seismic data. First, subtracting the first intrinsic mode function(IMF) results in ... The frequency–space(f–x) empirical mode decomposition(EMD) denoising method has two limitations when applied to nonstationary seismic data. First, subtracting the first intrinsic mode function(IMF) results in signal damage and limited denoising. Second, decomposing the real and imaginary parts of complex data may lead to inconsistent decomposition numbers. Thus, we propose a new method named f–x spatial projection-based complex empirical mode decomposition(CEMD) prediction filtering. The proposed approach directly decomposes complex seismic data into a series of complex IMFs(CIMFs) using the spatial projection-based CEMD algorithm and then applies f–x predictive filtering to the stationary CIMFs to improve the signal-to-noise ratio. Synthetic and real data examples were used to demonstrate the performance of the new method in random noise attenuation and seismic signal preservation. 展开更多
关键词 complex empirical mode decomposition complex intrinsic mode functions f–x predictive filtering random noise attenuation
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Employing incomplete complex modes for model updating and damage detection of damped structures 被引量:4
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作者 HU Sau-Lon James 《Science China(Technological Sciences)》 SCIE EI CAS 2008年第12期2244-2258,共15页
In the study of finite element model updating or damage detection,most papers are devoted to undamped systems.Thus,their objective has been exclusively restricted to the correction of the mass and stiffness matrices.I... In the study of finite element model updating or damage detection,most papers are devoted to undamped systems.Thus,their objective has been exclusively restricted to the correction of the mass and stiffness matrices.In contrast,this paper performs the model updating and damage detection for damped structures.A theoretical contribution of this paper is to extend the cross-model cross-mode(CMCM) method to simultaneously update the mass,damping and stiffness matrices of a finite element model when only few spatially incomplete,complex-valued modes are available.Numerical studies are conducted for a 30-DOF(degree-of-freedom) cantilever beam with multiple damaged elements,as the measured modes are synthesized from finite element models.The numerical results reveal that applying the CMCM method,together with an iterative Guyan reduction scheme,can yield good damage detection in general.When the measured modes utilized in the CMCM method are corrupted with irregular errors,assessing damage at the location that possesses larger modal strain energy is less sensitive to the corrupted modes. 展开更多
关键词 INCOMPLETE complex modeS model updating DAMAGE detection CMCM DAMPED STRUCTURES
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Complex-mode Galerkin approach in transverse vibration of an axially accelerating viscoelastic string 被引量:1
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作者 张能辉 王建军 程昌钧 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI 2007年第1期1-9,共9页
Under the consideration of harmonic fluctuations of initial tension and axially velocity, a nonlinear governing equation for transverse vibration of an axially accelerating string is set up by using the equation of mo... Under the consideration of harmonic fluctuations of initial tension and axially velocity, a nonlinear governing equation for transverse vibration of an axially accelerating string is set up by using the equation of motion for a 3-dimensional deformable body with initial stresses. The Kelvin model is used to describe viscoelastic behaviors of the material. The basis function of the complex-mode Galerkin method for axially accelerating nonlinear strings is constructed by using the modal function of linear moving strings with constant axially transport velocity. By the constructed basis functions, the application of the complex-mode Galerkin method in nonlinear vibration analysis of an axially accelerating viscoelastic string is investigated. Numerical results show that the convergence velocity of the complex-mode Galerkin method is higher than that of the real-mode Galerkin method for a variable coefficient gyroscopic system. 展开更多
关键词 axially accelerating string viscoelasticity transverse nonlinear vibration complex-mode Galerkin method geometry nonlinearity
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Efficient fast mode decision using mode complexity for multi-view video coding 被引量:1
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作者 王凤随 沈庆宏 都思丹 《Journal of Central South University》 SCIE EI CAS 2014年第11期4244-4253,共10页
The variable block-size motion estimation(ME) and disparity estimation(DE) are adopted in multi-view video coding(MVC) to achieve high coding efficiency. However, much higher computational complexity is also introduce... The variable block-size motion estimation(ME) and disparity estimation(DE) are adopted in multi-view video coding(MVC) to achieve high coding efficiency. However, much higher computational complexity is also introduced in coding system, which hinders practical application of MVC. An efficient fast mode decision method using mode complexity is proposed to reduce the computational complexity. In the proposed method, mode complexity is firstly computed by using the spatial, temporal and inter-view correlation between the current macroblock(MB) and its neighboring MBs. Based on the observation that direct mode is highly possible to be the optimal mode, mode complexity is always checked in advance whether it is below a predefined threshold for providing an efficient early termination opportunity. If this early termination condition is not met, three mode types for the MBs are classified according to the value of mode complexity, i.e., simple mode, medium mode and complex mode, to speed up the encoding process by reducing the number of the variable block modes required to be checked. Furthermore, for simple and medium mode region, the rate distortion(RD) cost of mode 16×16 in the temporal prediction direction is compared with that of the disparity prediction direction, to determine in advance whether the optimal prediction direction is in the temporal prediction direction or not, for skipping unnecessary disparity estimation. Experimental results show that the proposed method is able to significantly reduce the computational load by 78.79% and the total bit rate by 0.07% on average, while only incurring a negligible loss of PSNR(about 0.04 d B on average), compared with the full mode decision(FMD) in the reference software of MVC. 展开更多
关键词 multi-view video coding mode decision mode complexity computational complexity
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COMPLEX NUMBER MODE APPROACH FOR REDUCING VIBRATION OF STRUCTURAL FLEXIBLE REDUNDANT ROBOT MANIPULATORS
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作者 Wu Licheng Sun Zengqi Sun Fuchun Department of Computer Science and Technology, Qinghua University Lu Zhen Yu Shouqian Zheng Hong Beijing University of Aeronautics and Astronautics 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2001年第2期102-105,共4页
A complex number mode analysis approach is proposed for vibration reducing of structural flexible redundant manipulators by utilizing self motion. In the proposed approach, the self motion is evaluated to nullify th... A complex number mode analysis approach is proposed for vibration reducing of structural flexible redundant manipulators by utilizing self motion. In the proposed approach, the self motion is evaluated to nullify the modal exciting force of flexural motion, and the approach can be freely used when the degree of freedom of flexural motion is much greater than the available degree of reundancy. The availability and effectiveness of the proposed approach are demonstrated through numerical simulation with a four link spatial robotic manipulator possessing an end flexible link. 展开更多
关键词 Redundant manipulators SELF MOTION Vibration reducing complex number mode analysis
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Exponential synchronization of complex dynamical networks with Markovian jumping parameters using sampled-data and mode-dependent probabilistic time-varying delays 被引量:2
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作者 R.Rakkiyappan N.Sakthivel S.Lakshmanan 《Chinese Physics B》 SCIE EI CAS CSCD 2014年第2期49-63,共15页
In this paper, the problem of exponential synchronization of complex dynamical networks with Markovian jumping parameters using sampled-data and Mode-dependent probabilistic time-varying coupling delays is investigate... In this paper, the problem of exponential synchronization of complex dynamical networks with Markovian jumping parameters using sampled-data and Mode-dependent probabilistic time-varying coupling delays is investigated. The sam- pling period is assumed to be time-varying and bounded. The information of probability distribution of the time-varying delay is considered and transformed into parameter matrices of the transferred complex dynamical network model. Based on the condition, the design method of the desired sampled data controller is proposed. By constructing a new Lyapunov functional with triple integral terms, delay-distribution-dependent exponential synchronization criteria are derived in the form of linear matrix inequalities. Finally, two numerical examples are given to illustrate the effectiveness of the proposed methods. 展开更多
关键词 complex networks exponential synchronization mode-dependent time-varying delays linear ma- trix inequalities sampled-data control
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SYNCHRONIZATION OF MASTER-SLAVE MARKOVIAN SWITCHING COMPLEX DYNAMICAL NETWORKS WITH TIME-VARYING DELAYS IN NONLINEAR FUNCTION VIA SLIDING MODE CONTROL 被引量:4
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作者 M.Syed ALI J.YOGAMBIGAI 曹进德 《Acta Mathematica Scientia》 SCIE CSCD 2017年第2期368-384,共17页
In this article, a synchronization problem for master-slave Markovian switching complex dynamical networks with time-varying delays in nonlinear function via sliding mode control is investigated. On the basis of the a... In this article, a synchronization problem for master-slave Markovian switching complex dynamical networks with time-varying delays in nonlinear function via sliding mode control is investigated. On the basis of the appropriate Lyapunov-Krasovskii functional, introducing some free weighting matrices, new synchronization criteria are derived in terms of linear matrix inequalities (LMIs). Then, an integral sliding surface is designed to guarantee synchronization of master-slave Markovian switching complex dynamical networks, and the suitable controller is synthesized to ensure that the trajectory of the closed-loop error system can be driven onto the prescribed sliding mode surface. By using Dynkin's formula, we established the stochastic stablity of master-slave system. Finally, numerical example is provided to demonstrate the effectiveness of the obtained theoretical results. 展开更多
关键词 Markovian switching complex dynamical networks Lyapunov-Krasovskii method sliding mode control Linear Matrix Inequality
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A Cu(II) Complex with IM-MeImz-κ~2 N,O Mode in [Cu(IM-MeImz)_2]·(SCN)_2: Synthesis, Crystal Structure and Magnetic Properties 被引量:1
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作者 王玉芳 王利亚 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 北大核心 2007年第12期1461-1465,共5页
A new copper(Ⅱ) compound with imino nitroxide radicals [Cu(IM-MeImz)2].(SCN)2 (IM-meImz =2-(5-methylimidazol-4-yl)-4,4,5,5-tetramethyl-2-imidazoline- 1-oxyl) has been synthesized and characterized structura... A new copper(Ⅱ) compound with imino nitroxide radicals [Cu(IM-MeImz)2].(SCN)2 (IM-meImz =2-(5-methylimidazol-4-yl)-4,4,5,5-tetramethyl-2-imidazoline- 1-oxyl) has been synthesized and characterized structurally and magnetically. It crystallizes in monoclinic, space group P21/c with a = 9.3604(7), b = 10.3012(7), c = 16.6684(12)A, β = 105.0290(10)^o, V = 1552.25(19)A3, C24H34CUN10O2S2, Mr = 622.27, Z = 2, Dc = 1.331 g/cm^3,μ(MoKα) = 0.876 mm^-1, F(000) = 650, the final R = 0.0374 and wR = 0.1079. X-ray analysis demonstrates that the IM-MeImz ligand is coordinated to the copper(Ⅱ) ion as an unusual didentate chelate with a k-2 N(MeImz),O(IM) mode in the complex. The square-planar coordination sites at Cu(Ⅱ) are occupied by two 0 and two N atoms from the imino nitroxide radicals. The complex molecules are connected as a onedimensional polymer structure by intermolecular interactions. Magnetic measurements show that there are intramolecular antiferromagnetic interactions between the Cu(Ⅱ) ion and radicals. 展开更多
关键词 copper(Ⅱ) complex nitronyl nitroxide radical k^2-N O unusual mode antiferromagnetic interactions
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复杂联围内涝防治规划中雨洪模拟精度提升研究
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作者 刘曾美 曹钰帆 +2 位作者 黎智良 阎苗渊 赵平 《水资源保护》 北大核心 2025年第1期64-75,共12页
针对雨洪模型结构应与实际物理现象较好吻合,以保障内涝防治规划中雨洪模拟结果的准确性,提出了一套提升复杂联围雨洪模拟精度的方法。通过剖析复杂联围的排涝模式,揭示复杂联围的排涝特点及联围内部片区涝水排除特点,分析片区不同地形... 针对雨洪模型结构应与实际物理现象较好吻合,以保障内涝防治规划中雨洪模拟结果的准确性,提出了一套提升复杂联围雨洪模拟精度的方法。通过剖析复杂联围的排涝模式,揭示复杂联围的排涝特点及联围内部片区涝水排除特点,分析片区不同地形的产汇流特性及其适宜的模拟方法,并提出了复杂联围的雨洪模型构建方法和建模步骤。以粤港澳大湾区的中(山)珠(海)联围为例,开展复杂联围雨洪模型构建的实证研究。结果表明:构建的模型结构与实际雨洪过程相吻合,模型精度较高,并在率定测试中表现稳定,平均纳什效率系数比其他未遵循联围排涝过程的模型结构高出0.05~0.61。 展开更多
关键词 复杂联围 雨洪模拟 排涝模式 水文模型 水动力模型 中珠联围
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代码覆盖测试技术在MODE-S应答机中的应用 被引量:4
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作者 浦云明 张杰敏 林颖贤 《计算机应用与软件》 CSCD 北大核心 2008年第7期131-133,148,共4页
代码覆盖测试技术可用于结构覆盖测试和程序复杂度分析,代码覆盖测试技术可用于测试用例设计,提高软件测试效率,指导编写高质量的程序代码,代码覆盖是软件测试的底线。代码覆盖测试技术及方法的研究,为软件覆盖测试提供了理论依据。在Mo... 代码覆盖测试技术可用于结构覆盖测试和程序复杂度分析,代码覆盖测试技术可用于测试用例设计,提高软件测试效率,指导编写高质量的程序代码,代码覆盖是软件测试的底线。代码覆盖测试技术及方法的研究,为软件覆盖测试提供了理论依据。在Mode-S应答机项目中应用TRACE覆盖测试技术,确保了产品满足适航软件标准RTCA/DO-178BLEVELB的要求。 展开更多
关键词 代码覆盖 测试技术 DD-路径 mode-S应答机 程序复杂度
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Extraction of real modes and physical matrices from modal testing
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作者 Wang Tong Zhang Lingmi Tee Kong Fah 《Earthquake Engineering and Engineering Vibration》 SCIE EI CSCD 2011年第2期219-227,共9页
A technique to extract real modes from the identified complex modes is presented in this paper, which enables the normalized real mode shapes, modal masses, and full or reduced mass and stiffness matrices to be obtain... A technique to extract real modes from the identified complex modes is presented in this paper, which enables the normalized real mode shapes, modal masses, and full or reduced mass and stiffness matrices to be obtained. The theoretical derivation of the method is provided in detail. An 11-DOF vibration system is used to validate the algorithm, and to analyze the effects of the number of modes utilized and measurement DOFs on the extraction results. Finally, the method is used to extract real modes from both experimental modal analysis and operational modal analysis. 展开更多
关键词 modal analysis complex mode real mode normalized mode shape modal mass
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A NEW MATRIX PERTURBATION METHOD FOR ANALYTICAL SOLUTION OF THE COMPLEX MODAL EIGENVALUE PROBLEM OF VISCOUSLY DAMPED LINEAR VIBRATION SYSTEMS
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作者 吕振华 冯振东 方传流 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI 1991年第8期767-776,共10页
A new matrix perturbation analysis method is presented for efficient approximate solution of the complex modal quadratic generalized eigenvalue problem of viscously damped linear vibration systems. First, the damping ... A new matrix perturbation analysis method is presented for efficient approximate solution of the complex modal quadratic generalized eigenvalue problem of viscously damped linear vibration systems. First, the damping matrix is decomposed into the sum of a proportional-and a nonproportional-damping parts, and the solutions of the real modal eigenproblem with the proportional dampings are determined, which are a set of initial approximate solutions of the complex modal eigenproblem. Second, by taking the nonproportional-damping part as a small modification to the proportional one and using the matrix perturbation analysis method, a set of approximate solutions of the complex modal eigenvalue problem can be obtained analytically. The result is quite simple. The new method is applicable to the systems with viscous dampings-which do not deviate far away from the proportional-damping case. It is particularly important that the solution technique be also effective to the systems with heavy, but not over, dampings. The solution formulas of complex modal eigenvlaues and eigenvectors are derived up to second-order perturbation terms. The effectiveness of the perturbation algorithm is illustrated by an exemplar numerical problem with heavy dampings. In addition, the practicability of approximately estimating the complex modal eigenvalues, under the proportional-damping hypothesis, of damped vibration systems is discussed by several numerical examples. 展开更多
关键词 vibration analysis damped system complex mode quadratic eigenvalue problem matrix perturbation method
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Range of applicability of real mode superposition approximation method for seismic response calculation of non-classically damped industrial buildings
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作者 Li Xiaodong Sun Hongyang +2 位作者 Ji Xiaodong Sanjukta Chakraborty Wang Lijun 《Earthquake Engineering and Engineering Vibration》 SCIE EI CSCD 2022年第2期475-488,共14页
An industrial building is a non-classically damped system due to the different damping properties of the primary structure and equipment.The objective of this paper is to quantify the range of applicability of the rea... An industrial building is a non-classically damped system due to the different damping properties of the primary structure and equipment.The objective of this paper is to quantify the range of applicability of the real model superposition approximation method to the seismic response calculation of industrial buildings.The analysis using lumped mass-and-shear spring models indicates that for the equipment-to-structure frequency ratiosγf>1.1 orγf<0.9,the non-classical damping effect is limited,and the real mode superposition approximation method provides accurate estimates.For 0.9<γf<1.1,the system may have a pair of closely spaced frequency modes,and the non-zero off-diagonal damping terms have a non-negligible effect on the damping ratios and mode shape vectors of these modes.For 0.9<γf<1.1 and the equipment-to-structure mass ratiosγm<0.07,the real mode superposition approximation method results in large errors,while the approximation method can provide an accurate estimation for 0.9<γf<1.1 andγm>0.07.Furthermore,extensive parametric analyses are conducted,where both steel structures and reinforced concrete structures with equipment with various damping ratios are considered.Finally,the finite element analysis of a five-story industrial building is adopted to validate the proposed range of applicability. 展开更多
关键词 non-classical damping structure-equipment interaction real mode superposition approximation method complex mode superposition method seismic response calculation
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3R踝关节康复机器人工作空间研究
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作者 王鑫 唐小强 +3 位作者 张化平 孙鑫 周阳 刘杰 《科学技术创新》 2025年第2期217-220,共4页
本文首先对3R踝关节康复训练机器人的工作原理和拓扑构型进行了分析。建立了以D-H法为基础的3R踝关节康复训练器机器人运动学模型。在Inventor软件中完成了3R踝关节康复机器人的初步方案设计工作,借助MATLAB软件仿真分析了脚踏板上一点... 本文首先对3R踝关节康复训练机器人的工作原理和拓扑构型进行了分析。建立了以D-H法为基础的3R踝关节康复训练器机器人运动学模型。在Inventor软件中完成了3R踝关节康复机器人的初步方案设计工作,借助MATLAB软件仿真分析了脚踏板上一点P在单一康复训练模式和复合康复训练模式下的运动轨迹,进而验证了3R踝关节康复机器人运动学模型的正确性。最后,借助工作原理动画,分析了3R踝关节康复训练机器人在内翻/外翻、背伸/跖屈、内旋/外旋极限位置的工作空间,验证了3R踝关节康复训练机器人初步方案设计的合理性。 展开更多
关键词 3R踝关节康复机器人 拓扑构型 复合康复训练模式 初步方案设计
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Times Variations of Cinderella——on Evaluation of the Cinderella Complex
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作者 何晓丽 《海外英语》 2014年第16期185-186,共2页
From the awakening and the development of feminism, to the formation of the Cinderella complex, much attention has been paid. As we know the reason of the popularity of Cinderella complex is patriarchal rule forces th... From the awakening and the development of feminism, to the formation of the Cinderella complex, much attention has been paid. As we know the reason of the popularity of Cinderella complex is patriarchal rule forces that reigns the world, the only way to remove this psychological problem is the reconstruction of the concept of gender relationship. This essay tries to find some reasons for the popularity of the Cinderella complex by some analysis of the developing of Cinderella mode and Cinderella complex, thus giving some measures. 展开更多
关键词 CINDERELLA mode complex PATRIARCHAL GENDER
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Spectra and DNA-binding Properties of Two Novel Mixed-ligand Complexes Containing Organosulfonate
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作者 李明田 黄俊 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2009年第2期181-185,共5页
Two novel mixed-ligand complexes, [M(phen)2(ans)2]·H2O (M = Cd(Ⅱ) 1, Zn(Ⅱ) 2; phen is 1, 10-phenanthroline, and ans is 4-aminonaphthalene-1-sulfonate), were obtained from the reaction of 1, 10-phenant... Two novel mixed-ligand complexes, [M(phen)2(ans)2]·H2O (M = Cd(Ⅱ) 1, Zn(Ⅱ) 2; phen is 1, 10-phenanthroline, and ans is 4-aminonaphthalene-1-sulfonate), were obtained from the reaction of 1, 10-phenanthroline, sodium 4-aminonaphthalene-1-sulfonate tetrahydrate and acetate in mixed solvents. Interaction of the complexes with calf thymus DNA (ctDNA) were investigated using UV-vis absorption spectra, luminescence titrations, steady-state emission quenching by [Fe(CN)6]4 , DNA competitive binding with ethidium bromide (EB) and viscosity measurements. The experimental results indicate that there exist two interaction modes between the complexes and DNA, namely the electrostatic interaction and intercalation, with the binding constants of 1.82 × 10^5 M-1 for 1 and 4.78 ×10^4 M^- 1 for 2 in buffer of 50 mM NaCl and 5 mM Tris-HCI (pH 7.0). 展开更多
关键词 CTDNA mixed-ligand complex interaction mode
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