The aerospace community widely uses difficult-to-cut materials,such as titanium alloys,high-temperature alloys,metal/ceramic/polymer matrix composites,hard and brittle materials,and geometrically complex components,su...The aerospace community widely uses difficult-to-cut materials,such as titanium alloys,high-temperature alloys,metal/ceramic/polymer matrix composites,hard and brittle materials,and geometrically complex components,such as thin-walled structures,microchannels,and complex surfaces.Mechanical machining is the main material removal process for the vast majority of aerospace components.However,many problems exist,including severe and rapid tool wear,low machining efficiency,and poor surface integrity.Nontraditional energy-assisted mechanical machining is a hybrid process that uses nontraditional energies(vibration,laser,electricity,etc)to improve the machinability of local materials and decrease the burden of mechanical machining.This provides a feasible and promising method to improve the material removal rate and surface quality,reduce process forces,and prolong tool life.However,systematic reviews of this technology are lacking with respect to the current research status and development direction.This paper reviews the recent progress in the nontraditional energy-assisted mechanical machining of difficult-to-cut materials and components in the aerospace community.In addition,this paper focuses on the processing principles,material responses under nontraditional energy,resultant forces and temperatures,material removal mechanisms,and applications of these processes,including vibration-,laser-,electric-,magnetic-,chemical-,advanced coolant-,and hybrid nontraditional energy-assisted mechanical machining.Finally,a comprehensive summary of the principles,advantages,and limitations of each hybrid process is provided,and future perspectives on forward design,device development,and sustainability of nontraditional energy-assisted mechanical machining processes are discussed.展开更多
Two kinds of Tb( Ⅲ ) complexes with tetrapodal ligand, [TbL(NO3)]^3+ and [TbL]^3+ (L: 1,1, 1', 1'-tera ( 2-pyridinecarboxylester )-di ( trimethylpropane)) were intercalated into the interlayer space of...Two kinds of Tb( Ⅲ ) complexes with tetrapodal ligand, [TbL(NO3)]^3+ and [TbL]^3+ (L: 1,1, 1', 1'-tera ( 2-pyridinecarboxylester )-di ( trimethylpropane)) were intercalated into the interlayer space of montmorillonite (MT) by ion exchange and coordination reaction of L with the Tb^3+ ion existing in the interlayer space of Tb-MT respectively. The obtained luminescent supramolecular composite materials, [ TbL (NO3) ]^2+-MT and [TbL]^3+-MT were characterized by elemental analysis, XRD, FT-IR, UV-vis and thermal analysis. At the same time, the luminescent properties of the materials were also studied. The results show that the intercalated materials with regular layered structure, good thermal stability and the interlayer spacing (d001) approximates to the size of the complex ions which are located in the interlayer space of MT in the form of a monolayer.展开更多
Ethyl methacrylate (EMA) doped with luminescent ternary terbium complex (Tb(acac) 3·dam) with acetylacetone (Hacac) and diantipylmethane (dam) was incorporated into the microporous silica gel. With the polymeriz...Ethyl methacrylate (EMA) doped with luminescent ternary terbium complex (Tb(acac) 3·dam) with acetylacetone (Hacac) and diantipylmethane (dam) was incorporated into the microporous silica gel. With the polymerization of EMA, the hybrid material containing Tb(acac) 3·dam was obtained. The hybrid material exhibited good toughness and transparency and higher thermal stability than that of the pure complex and pure polymer matrix. In the range of doping concentration of Tb(acac) 3·dam (0.05%, 0.1%, 0.2%, 0.5%, 1.0%, 2.0% and 5.0%), emission intensity increases with the increasing of corresponding doping concentration and concentration quenching effect has not taken place.展开更多
The reactions of the four-coordinated macrocyclic copper complex [CuL](ClO4)2(L = 1,4,8,11-tetraazacyclotetradecane) with NH4VO3 under different conditions gave three inorganic-organic hybrid materials of [CuL][VO...The reactions of the four-coordinated macrocyclic copper complex [CuL](ClO4)2(L = 1,4,8,11-tetraazacyclotetradecane) with NH4VO3 under different conditions gave three inorganic-organic hybrid materials of [CuL][VO3]2·2.33H2O(1), [CuL]3[V(10)O(28)]·8H2O(2) and [Cu L]3[V6O(18)]·8H2O(3). Single-crystal X-ray diffraction analyses reveal that three diverse vanadium polyoxoanions, [V6O(18)]6- ring, [V(10)O(28)]6- cluster, and [V(12)O(35)]^10- ring, were isolated from the same reactant NH4VO3 under different conditions. The [CuL]^2+ bridges the [V10O28]6- clusters to form a two-dimensional sheet in 2, and link the [V6O(18)]^6- rings in 1 and [V(12)O(35)]^10- rings in 3 into three-dimensional frameworks, respectively.展开更多
Hybrid materials incorporating Eu-(TTA)3·2H20 (hereafter designated as Eu-TTA, with TTA: thenoyltrifluoroacetone) in unmodified or modified MCM-41 by 3-aminopropyl-triethoxysilane (APTES) were prepared by impregn...Hybrid materials incorporating Eu-(TTA)3·2H20 (hereafter designated as Eu-TTA, with TTA: thenoyltrifluoroacetone) in unmodified or modified MCM-41 by 3-aminopropyl-triethoxysilane (APTES) were prepared by impregnation method. The obtained materials were characterized using X-ray diffraction (XRD), IR and diffuse reflectance spectroscopy and luminescence spectra. All the hybrid samples exhibited the characteristic emission bands of Eu3+ under UV light exci-tation at room temperature, and the excitation spectra showed significant blue-shifts compared to the pure rare-earth complex. Although the red emission intensity in the modified hybrid was almost the half of the red emission intensity in the pure Eu-TTA complex at room temperature, the hybrid showed a much higher thermal stability due to the shielding character of the MCM-41 host.展开更多
In this paper, the basic formulae for the semi-analytical graded FEM on FGM members are derived. Since FGM parameters vary along three space coordinates, the parameters can be integrated in mechanical equations. There...In this paper, the basic formulae for the semi-analytical graded FEM on FGM members are derived. Since FGM parameters vary along three space coordinates, the parameters can be integrated in mechanical equations. Therefore with the parameters of a given FGM plate, problems of FGM plate under various conditions can be solved. The approach uses 1D discretization to obtain 3D solutions, which is proven to be an effective numerical method for the mechanical analyses of FGM structures. Examples of FGM plates with complex shapes and various holes are presented.展开更多
Soluble Poly(propargyl benzoate) (PPBT) with pi -conjugated structure was synthesized using a novel bis(triphenylphosphine)-bisacetylide palladium complex catalyst [Pd(PPh3)(2)(C equivalent to CCH2OOCPh)(2)] (PPB). An...Soluble Poly(propargyl benzoate) (PPBT) with pi -conjugated structure was synthesized using a novel bis(triphenylphosphine)-bisacetylide palladium complex catalyst [Pd(PPh3)(2)(C equivalent to CCH2OOCPh)(2)] (PPB). An interdigital gold electrode was covered by screen printing films of doped PPBT (DPPBT) to prepare a resistance-type humidity sensor, which exhibits electrical response towards relative humidity (RH%) variations in the range 11%-96%. PPBT shows promise as a new humidity-sensitive material.展开更多
In the industrial engineering, the maintenance and logistics support process is one of the key factors for the performance of equipment. Bill of materials( BOM) describes all the components in product and internal hie...In the industrial engineering, the maintenance and logistics support process is one of the key factors for the performance of equipment. Bill of materials( BOM) describes all the components in product and internal hierarchal relationships as a structured tree.In order to gain all required maintenance information for complex equipment which is complex,the modeling and the application of maintenance BOM are introduced in this paper. Because of the simple structure and the wide function,IDEF0 is presented to build the model of maintenance BOM. The modeling approach can gather the maintenance information conveniently based on other BOMs,and applications of maintenance BOM are widely,particularly,in maintenance and inventory management.展开更多
Hole-transporting material(HTM)plays a paramount role in enhancing the photovltaic performance of perovskite solar cells(PSCs).Currently,the vast majority of these HTMs employed in PSCs are organic small molecules and...Hole-transporting material(HTM)plays a paramount role in enhancing the photovltaic performance of perovskite solar cells(PSCs).Currently,the vast majority of these HTMs employed in PSCs are organic small molecules and polymers,yet the use of organic metal complexes in PSCs applications remains less explored.To date,most of reported HTMs require additional chemical additives(e.g.Li-TFSI,t-TBP)towards high performance,however,the introduction of additives decrease the PSCs device stability.Herein,an organic metal complex(Ni-TPA)is first developed as a dopant-free HTM applied in PSCs for its facile synthesis and efficient hole extract/transfer ability.Consequently,the dopant-free Ni-TPAbased device achieves a champion efficiency of 17.89%,which is superior to that of pristine Spiro-OMeTAD(14.25%).Furthermore,we introduce a double HTM layer with a graded energy bandgap containing a Ni-TPA layer and a CuSCN layer into PSCs,the non-encapsulated PSCs based on the Ni-TPA/CuSCN layers affords impressive efficiency up to 20.39%and maintains 96%of the initial PCE after 1000 h at a relative humidity around 40%.The results have demonstrated that metal organic complexes represent a great promise for designing new dopant-free HTMs towards highly stable PSCs.展开更多
In this paper,sine trigonometry operational laws(ST-OLs)have been extended to neutrosophic sets(NSs)and the operations and functionality of these laws are studied.Then,extending these ST-OLs to complex neutrosophic se...In this paper,sine trigonometry operational laws(ST-OLs)have been extended to neutrosophic sets(NSs)and the operations and functionality of these laws are studied.Then,extending these ST-OLs to complex neutrosophic sets(CNSs)forms the core of thiswork.Some of themathematical properties are proved based on ST-OLs.Fundamental operations and the distance measures between complex neutrosophic numbers(CNNs)based on the ST-OLs are discussed with numerical illustrations.Further the arithmetic and geometric aggregation operators are established and their properties are verified with numerical data.The general properties of the developed sine trigonometry weighted averaging/geometric aggregation operators for CNNs(ST-WAAO-CNN&ST-WGAO-CNN)are proved.A decision making technique based on these operators has been developed with the help of unsupervised criteria weighting approach called Entropy-ST-OLs-CNDM(complex neutrosophic decision making)method.A case study for material selection has been chosen to demonstrate the ST-OLs of CNDM method.To check the validity of the proposed method,entropy based complex neutrosophic CODAS approach with ST-OLs has been executed numerically and a comparative analysis with the discussion of their outcomes has been conducted.The proposed approach proves to be salient and effective for decision making with complex information.展开更多
The generalized two_dimensional problem of a dielectric rigid line inclusion, at the interface between two dissimilar piezoelectric media subjected to piecewise uniform loads at infinity, is studied by means of the St...The generalized two_dimensional problem of a dielectric rigid line inclusion, at the interface between two dissimilar piezoelectric media subjected to piecewise uniform loads at infinity, is studied by means of the Stroh theory. The problem was reduced to a Hilbert problem, and then closed_form expressions were obtained, respectively, for the complex potentials in piezoelectric media, the electric field inside the inclusion and the tip fields near the inclusion. It is shown that in the media, all field variables near the inclusion_tip show square root singularity and oscillatory singularity, the intensity of which is dependent on the material constants and the strains at infinity. In addition, it is found that the electric field inside the inclusion is singular and oscillatory too, when approaching the inclusion_tips from inside the inclusion.展开更多
At present, research into optical properties of bio-smoke materials mostly concentrates on single band or single germplasm. Herein, we measured the spectral reflectance of three eukaryotic bio-smoke materials and thre...At present, research into optical properties of bio-smoke materials mostly concentrates on single band or single germplasm. Herein, we measured the spectral reflectance of three eukaryotic bio-smoke materials and three prokaryotic bio-smoke materials in the waveband from 0.25 μm to 14μm. Based on the Kramers-Kroning algorithm, the complex refractive index m(λ) was calculated and the Fourier-transform infrared(FTIR) spectra of materials were analyzed. The results show that n(λ) of bio-smoke materials varies between 1.1-2, and n(λ) values in the visible light to near-infrared wavebands are significantly larger than those in other wavebands. The k(λ) of bio-smoke materials varies between 0-0.4.At 6-6.5 μm, k(λ) of prokaryotic materials is 3 times that of eukaryotic materials, which is caused by C=O stretching vibration of amide I and C-N stretching vibration of amide Ⅱ in proteins. At 2.5-3 μm and 9.75 μm, k(λ) values of eukaryotic bio-smoke materials are nearly 2 times that of prokaryotic ones. The absorption peak at 2.5-3 μm is mainly triggered by C-H stretching vibration in lipid and O-H stretching vibration in bound water. The absorption peak at 9.75 μm is mainly caused by symmetric stretching vibration of PO2-in nucleic acids.展开更多
The contact problem for thermoelectric materials with functionally graded properties is considered.The material properties,such as the electric conductivity,the thermal conductivity,the shear modulus,and the thermal e...The contact problem for thermoelectric materials with functionally graded properties is considered.The material properties,such as the electric conductivity,the thermal conductivity,the shear modulus,and the thermal expansion coefficient,vary in an exponential function.Using the Fourier transform technique,the electro-thermoelastic problems are transformed into three sets of singular integral equations which are solved numerically in terms of the unknown normal electric current density,the normal energy flux,and the contact pressure.Meanwhile,the complex homogeneous solutions of the displacement fields caused by the gradient parameters are simplified with the help of Euler’s formula.After addressing the non-linearity excited by thermoelectric effects,the particular solutions of the displacement fields can be assessed.The effects of various combinations of material gradient parameters and thermoelectric loads on the contact behaviors of thermoelectric materials are presented.The results give a deep insight into the contact damage mechanism of functionally graded thermoelectric materials(FGTEMs).展开更多
The electromagnetic parameters of microwave absorbing materials are important criteria when appraising the properties of absorbents. For reconstruction of parameters which belongs to the inverse scattering problem, th...The electromagnetic parameters of microwave absorbing materials are important criteria when appraising the properties of absorbents. For reconstruction of parameters which belongs to the inverse scattering problem, the test data in requirement of traditional impedance method are "just enough" and not "redundant" to comprehensively evaluate the electromagnetic properties of materials. A novel optimization approach involving multiple impedance measurements is introduced in this paper to implement automatic measurement for electromagnetic parameters on microwave slot-line. Some results for standard samples and microwave absorbing materials are given.展开更多
The generalized two-dimensional problem of a dielectric rigid line inclusion, at the interface between two dissimilar piezoelectric media subjected to piecewise uniform loads at infinity, is studied by means of the St...The generalized two-dimensional problem of a dielectric rigid line inclusion, at the interface between two dissimilar piezoelectric media subjected to piecewise uniform loads at infinity, is studied by means of the Stroh theory. The problem was reduced to a Hilbert problem, and then closed-form expressions were obtained, respectively, far the complex potentials in piezoelectric media, the electric field inside the inclusion and the tip fields near the inclusion. it is shown that in the media, all field variables near the inclusion-tip show square root singularity and oscillatory singularity, the intensity of which is dependent on the material constants and the strains at infinity. In addition, it is found that the electric field inside the inclusion is singular and oscillatory too, when approaching the inclusion-tips from inside the inclusion.展开更多
By using a complex function method in this paper, the complex form of J-integral of mixed mode crack tip for unidirectional plate of linear-elastic orthotropic composites is obtained first by substituting crack tip st...By using a complex function method in this paper, the complex form of J-integral of mixed mode crack tip for unidirectional plate of linear-elastic orthotropic composites is obtained first by substituting crack tip stresses and displacements into general formula of J-integral. And then, the path-independence of this J-integral is proved. Finally, the computing formula of this J-integral is derived. As special examples, the complex forms, path-independence and computing formulae of J-integrals of mode I and mode II crack tips for unidirectional plate of linear-elastic orthotropic composites are given.展开更多
Nanocrystalline powder of LaF3 was synthesized by a method of direct precipitation from water solution. Particle size and shape of LaF3 nanocrystalline powder was analysed with TEM. Particles were mainly spherical wit...Nanocrystalline powder of LaF3 was synthesized by a method of direct precipitation from water solution. Particle size and shape of LaF3 nanocrystalline powder was analysed with TEM. Particles were mainly spherical with narrow particle size distribution (10 20 nm). The average particle size analysed with XRD is 16.7 nm. Nano-LaF3 bulk material was prepared by compacting the powder to 1 GPa at room temperature and a vacuum of 10^-4 Pa. The ionic conductivity of nano-LaF3 bulk material was studied with complex impedance spectra at room temperature. The ionic conductivity of nano-LaF3 bulk material (1 × 10^-5 S·cm^-1 ) at room temperature is significantly increased compared to that of single crystal LaF3 (1 × 10^-6 S·cm^-1). A special phenomenon was observed firstly time that the ionic conductivity increased gradually with multiple testing in result of relaxation.展开更多
Due to a viscoelastic damping middle layer,sandwich structures have the capacity of energy consumption.In this paper,we describe the frequency-dependent property of viscoelastic materials using complex modulus model,a...Due to a viscoelastic damping middle layer,sandwich structures have the capacity of energy consumption.In this paper,we describe the frequency-dependent property of viscoelastic materials using complex modulus model,and iterative modal strain energy method and iterative complex eigenvalue method are presented to obtain frequency and loss factor of sandwich structures.The two methods are effective and exact for the large-scale complex composite sandwich structures.Then an optimum analysis method is suggested to apply to sandwich structures.Finally,as an example,an optimum analysis of a clamped-clamped sandwich beams is conducted,theoretical closed-form solution and numerical predictions are studied comparatively,and the results agree well.展开更多
This paper deals with the electro-elastic coupling interaction between a piezoelectric screw dislocation which is located inside the elliptical inhomogeneity and an electrically conductive confocal rigid line under re...This paper deals with the electro-elastic coupling interaction between a piezoelectric screw dislocation which is located inside the elliptical inhomogeneity and an electrically conductive confocal rigid line under remote anti-plane shear stresses and in-plane electrical loads in piezoelectric composite material. The analytical-functions of the complex potentials, stress fields and the image force acting on the piezoelectric screw dislocation are obtained based on the principle of conformal mapping, the method of series expansion, the technical of analytic continuation and the analysis of singularity of complex potentials. The rigid line and the piezoelectric material property combinations upon the image force and the equilibrium position of the dislocation are discussed in detail by the numerical computation.展开更多
For the further improvement of the power conversion efficiency(PCE)and stability of perovskite solar cells(PSCs),the buried interface between the perovskite and the electron transport layer is crucial.However,it is ch...For the further improvement of the power conversion efficiency(PCE)and stability of perovskite solar cells(PSCs),the buried interface between the perovskite and the electron transport layer is crucial.However,it is challenging to effectively optimize this interface as it is buried beneath the perovskite film.Herein,we have designed and synthesized a series of multifunctional organic-inorganic(OI)complexes as buried interfacial material to promote electron extraction,as well as the crystal growth of the perovskite.The OI complex with BF4−group not only eliminates oxygen vacancies on the SnO_(2) surface but also balances energy level alignment between SnO_(2) and perovskite,providing a favorable environment for charge carrier extraction.Moreover,OI complex with amine(−NH_(2))functional group can regulate the crystallization of the perovskite film via interaction with PbI2,resulting in highly crystallized perovskite film with large grains and low defect density.Consequently,with rational molecular design,the PSCs with optimal OI complex buried interface layer which contains both BF4−and−NH_(2) functional groups yield a champion device efficiency of 23.69%.More importantly,the resulting unencapsulated device performs excellent ambient stability,maintaining over 90%of its initial efficiency after 2000 h storage,and excellent light stability of 91.5%remaining PCE in the maximum power point tracking measurement(under continuous 100 mW cm−2 light illumination in N2 atmosphere)after 500 h.展开更多
基金supported by the National Natural Science Foundation of China(Nos.52075255,92160301,52175415,52205475,and 92060203)。
文摘The aerospace community widely uses difficult-to-cut materials,such as titanium alloys,high-temperature alloys,metal/ceramic/polymer matrix composites,hard and brittle materials,and geometrically complex components,such as thin-walled structures,microchannels,and complex surfaces.Mechanical machining is the main material removal process for the vast majority of aerospace components.However,many problems exist,including severe and rapid tool wear,low machining efficiency,and poor surface integrity.Nontraditional energy-assisted mechanical machining is a hybrid process that uses nontraditional energies(vibration,laser,electricity,etc)to improve the machinability of local materials and decrease the burden of mechanical machining.This provides a feasible and promising method to improve the material removal rate and surface quality,reduce process forces,and prolong tool life.However,systematic reviews of this technology are lacking with respect to the current research status and development direction.This paper reviews the recent progress in the nontraditional energy-assisted mechanical machining of difficult-to-cut materials and components in the aerospace community.In addition,this paper focuses on the processing principles,material responses under nontraditional energy,resultant forces and temperatures,material removal mechanisms,and applications of these processes,including vibration-,laser-,electric-,magnetic-,chemical-,advanced coolant-,and hybrid nontraditional energy-assisted mechanical machining.Finally,a comprehensive summary of the principles,advantages,and limitations of each hybrid process is provided,and future perspectives on forward design,device development,and sustainability of nontraditional energy-assisted mechanical machining processes are discussed.
文摘Two kinds of Tb( Ⅲ ) complexes with tetrapodal ligand, [TbL(NO3)]^3+ and [TbL]^3+ (L: 1,1, 1', 1'-tera ( 2-pyridinecarboxylester )-di ( trimethylpropane)) were intercalated into the interlayer space of montmorillonite (MT) by ion exchange and coordination reaction of L with the Tb^3+ ion existing in the interlayer space of Tb-MT respectively. The obtained luminescent supramolecular composite materials, [ TbL (NO3) ]^2+-MT and [TbL]^3+-MT were characterized by elemental analysis, XRD, FT-IR, UV-vis and thermal analysis. At the same time, the luminescent properties of the materials were also studied. The results show that the intercalated materials with regular layered structure, good thermal stability and the interlayer spacing (d001) approximates to the size of the complex ions which are located in the interlayer space of MT in the form of a monolayer.
文摘Ethyl methacrylate (EMA) doped with luminescent ternary terbium complex (Tb(acac) 3·dam) with acetylacetone (Hacac) and diantipylmethane (dam) was incorporated into the microporous silica gel. With the polymerization of EMA, the hybrid material containing Tb(acac) 3·dam was obtained. The hybrid material exhibited good toughness and transparency and higher thermal stability than that of the pure complex and pure polymer matrix. In the range of doping concentration of Tb(acac) 3·dam (0.05%, 0.1%, 0.2%, 0.5%, 1.0%, 2.0% and 5.0%), emission intensity increases with the increasing of corresponding doping concentration and concentration quenching effect has not taken place.
基金Supported by the Opening Project of Key Laboratory of Comprehensive Utilization of Advantage Plants Resources in Hunan South(XNZW14C08)the NSF of Hunan Province(2015JJ2072)+2 种基金the Construct Program of the Key Discipline in Hunan Provincethe Science and Technology Innovative Research Team in Higher Educational Institutions of Hunan Provincethe Project for Undergraduate Research Study and Innovative Experiment of Hunan Provincial(2016-283)
文摘The reactions of the four-coordinated macrocyclic copper complex [CuL](ClO4)2(L = 1,4,8,11-tetraazacyclotetradecane) with NH4VO3 under different conditions gave three inorganic-organic hybrid materials of [CuL][VO3]2·2.33H2O(1), [CuL]3[V(10)O(28)]·8H2O(2) and [Cu L]3[V6O(18)]·8H2O(3). Single-crystal X-ray diffraction analyses reveal that three diverse vanadium polyoxoanions, [V6O(18)]6- ring, [V(10)O(28)]6- cluster, and [V(12)O(35)]^10- ring, were isolated from the same reactant NH4VO3 under different conditions. The [CuL]^2+ bridges the [V10O28]6- clusters to form a two-dimensional sheet in 2, and link the [V6O(18)]^6- rings in 1 and [V(12)O(35)]^10- rings in 3 into three-dimensional frameworks, respectively.
基金financial supportfrom PRAMX 98-05 and helpful discussion with Dr.A.C.Franville.
文摘Hybrid materials incorporating Eu-(TTA)3·2H20 (hereafter designated as Eu-TTA, with TTA: thenoyltrifluoroacetone) in unmodified or modified MCM-41 by 3-aminopropyl-triethoxysilane (APTES) were prepared by impregnation method. The obtained materials were characterized using X-ray diffraction (XRD), IR and diffuse reflectance spectroscopy and luminescence spectra. All the hybrid samples exhibited the characteristic emission bands of Eu3+ under UV light exci-tation at room temperature, and the excitation spectra showed significant blue-shifts compared to the pure rare-earth complex. Although the red emission intensity in the modified hybrid was almost the half of the red emission intensity in the pure Eu-TTA complex at room temperature, the hybrid showed a much higher thermal stability due to the shielding character of the MCM-41 host.
基金Project supported by the National Natural Science Foundation of China (No. 10432030)
文摘In this paper, the basic formulae for the semi-analytical graded FEM on FGM members are derived. Since FGM parameters vary along three space coordinates, the parameters can be integrated in mechanical equations. Therefore with the parameters of a given FGM plate, problems of FGM plate under various conditions can be solved. The approach uses 1D discretization to obtain 3D solutions, which is proven to be an effective numerical method for the mechanical analyses of FGM structures. Examples of FGM plates with complex shapes and various holes are presented.
文摘Soluble Poly(propargyl benzoate) (PPBT) with pi -conjugated structure was synthesized using a novel bis(triphenylphosphine)-bisacetylide palladium complex catalyst [Pd(PPh3)(2)(C equivalent to CCH2OOCPh)(2)] (PPB). An interdigital gold electrode was covered by screen printing films of doped PPBT (DPPBT) to prepare a resistance-type humidity sensor, which exhibits electrical response towards relative humidity (RH%) variations in the range 11%-96%. PPBT shows promise as a new humidity-sensitive material.
基金National Natural Science Foundation of China(No.71471147)the Basic Research Project of Natural Science in Shaanxi Province of China(No.2015JQ7273)the 111 Project of China(No.B13044)
文摘In the industrial engineering, the maintenance and logistics support process is one of the key factors for the performance of equipment. Bill of materials( BOM) describes all the components in product and internal hierarchal relationships as a structured tree.In order to gain all required maintenance information for complex equipment which is complex,the modeling and the application of maintenance BOM are introduced in this paper. Because of the simple structure and the wide function,IDEF0 is presented to build the model of maintenance BOM. The modeling approach can gather the maintenance information conveniently based on other BOMs,and applications of maintenance BOM are widely,particularly,in maintenance and inventory management.
基金the National Natural Science Foundation of China(22065038)the Key Project of Natural Science Foundation of Yunnan(KC10110419)+4 种基金the High-Level Talents Introduction in Yunnan Province(C619300A010)the Fund for Excellent Young Scholars of Yunnan(K264202006820)the Program for Excellent Young Talents of Yunnan University and Major Science(C176220200)the International Joint Research Center for Advanced Energy Materials of Yunnan Province(202003AE140001)the Technology Project of Precious Metal Materials Genetic Engineering in Yunnan Province(No.2019Z E001-1202002AB080001)for financial support。
文摘Hole-transporting material(HTM)plays a paramount role in enhancing the photovltaic performance of perovskite solar cells(PSCs).Currently,the vast majority of these HTMs employed in PSCs are organic small molecules and polymers,yet the use of organic metal complexes in PSCs applications remains less explored.To date,most of reported HTMs require additional chemical additives(e.g.Li-TFSI,t-TBP)towards high performance,however,the introduction of additives decrease the PSCs device stability.Herein,an organic metal complex(Ni-TPA)is first developed as a dopant-free HTM applied in PSCs for its facile synthesis and efficient hole extract/transfer ability.Consequently,the dopant-free Ni-TPAbased device achieves a champion efficiency of 17.89%,which is superior to that of pristine Spiro-OMeTAD(14.25%).Furthermore,we introduce a double HTM layer with a graded energy bandgap containing a Ni-TPA layer and a CuSCN layer into PSCs,the non-encapsulated PSCs based on the Ni-TPA/CuSCN layers affords impressive efficiency up to 20.39%and maintains 96%of the initial PCE after 1000 h at a relative humidity around 40%.The results have demonstrated that metal organic complexes represent a great promise for designing new dopant-free HTMs towards highly stable PSCs.
基金the Rajamangala University of Technology Suvarnabhumi.
文摘In this paper,sine trigonometry operational laws(ST-OLs)have been extended to neutrosophic sets(NSs)and the operations and functionality of these laws are studied.Then,extending these ST-OLs to complex neutrosophic sets(CNSs)forms the core of thiswork.Some of themathematical properties are proved based on ST-OLs.Fundamental operations and the distance measures between complex neutrosophic numbers(CNNs)based on the ST-OLs are discussed with numerical illustrations.Further the arithmetic and geometric aggregation operators are established and their properties are verified with numerical data.The general properties of the developed sine trigonometry weighted averaging/geometric aggregation operators for CNNs(ST-WAAO-CNN&ST-WGAO-CNN)are proved.A decision making technique based on these operators has been developed with the help of unsupervised criteria weighting approach called Entropy-ST-OLs-CNDM(complex neutrosophic decision making)method.A case study for material selection has been chosen to demonstrate the ST-OLs of CNDM method.To check the validity of the proposed method,entropy based complex neutrosophic CODAS approach with ST-OLs has been executed numerically and a comparative analysis with the discussion of their outcomes has been conducted.The proposed approach proves to be salient and effective for decision making with complex information.
文摘The generalized two_dimensional problem of a dielectric rigid line inclusion, at the interface between two dissimilar piezoelectric media subjected to piecewise uniform loads at infinity, is studied by means of the Stroh theory. The problem was reduced to a Hilbert problem, and then closed_form expressions were obtained, respectively, for the complex potentials in piezoelectric media, the electric field inside the inclusion and the tip fields near the inclusion. It is shown that in the media, all field variables near the inclusion_tip show square root singularity and oscillatory singularity, the intensity of which is dependent on the material constants and the strains at infinity. In addition, it is found that the electric field inside the inclusion is singular and oscillatory too, when approaching the inclusion_tips from inside the inclusion.
基金supported by the National Natural Science Foundation of China(Grant Nos.61271353 and 60908033)the Natural Science Foundation of Anhui Province,China(Grant No.1408085MKL47)
文摘At present, research into optical properties of bio-smoke materials mostly concentrates on single band or single germplasm. Herein, we measured the spectral reflectance of three eukaryotic bio-smoke materials and three prokaryotic bio-smoke materials in the waveband from 0.25 μm to 14μm. Based on the Kramers-Kroning algorithm, the complex refractive index m(λ) was calculated and the Fourier-transform infrared(FTIR) spectra of materials were analyzed. The results show that n(λ) of bio-smoke materials varies between 1.1-2, and n(λ) values in the visible light to near-infrared wavebands are significantly larger than those in other wavebands. The k(λ) of bio-smoke materials varies between 0-0.4.At 6-6.5 μm, k(λ) of prokaryotic materials is 3 times that of eukaryotic materials, which is caused by C=O stretching vibration of amide I and C-N stretching vibration of amide Ⅱ in proteins. At 2.5-3 μm and 9.75 μm, k(λ) values of eukaryotic bio-smoke materials are nearly 2 times that of prokaryotic ones. The absorption peak at 2.5-3 μm is mainly triggered by C-H stretching vibration in lipid and O-H stretching vibration in bound water. The absorption peak at 9.75 μm is mainly caused by symmetric stretching vibration of PO2-in nucleic acids.
基金supported by the National Natural Science Foundation of China(Nos.11972257,11832014,11762016,11472193)the Fundamental Research Funds for the Central Universities(No.22120180223)。
文摘The contact problem for thermoelectric materials with functionally graded properties is considered.The material properties,such as the electric conductivity,the thermal conductivity,the shear modulus,and the thermal expansion coefficient,vary in an exponential function.Using the Fourier transform technique,the electro-thermoelastic problems are transformed into three sets of singular integral equations which are solved numerically in terms of the unknown normal electric current density,the normal energy flux,and the contact pressure.Meanwhile,the complex homogeneous solutions of the displacement fields caused by the gradient parameters are simplified with the help of Euler’s formula.After addressing the non-linearity excited by thermoelectric effects,the particular solutions of the displacement fields can be assessed.The effects of various combinations of material gradient parameters and thermoelectric loads on the contact behaviors of thermoelectric materials are presented.The results give a deep insight into the contact damage mechanism of functionally graded thermoelectric materials(FGTEMs).
文摘The electromagnetic parameters of microwave absorbing materials are important criteria when appraising the properties of absorbents. For reconstruction of parameters which belongs to the inverse scattering problem, the test data in requirement of traditional impedance method are "just enough" and not "redundant" to comprehensively evaluate the electromagnetic properties of materials. A novel optimization approach involving multiple impedance measurements is introduced in this paper to implement automatic measurement for electromagnetic parameters on microwave slot-line. Some results for standard samples and microwave absorbing materials are given.
文摘The generalized two-dimensional problem of a dielectric rigid line inclusion, at the interface between two dissimilar piezoelectric media subjected to piecewise uniform loads at infinity, is studied by means of the Stroh theory. The problem was reduced to a Hilbert problem, and then closed-form expressions were obtained, respectively, far the complex potentials in piezoelectric media, the electric field inside the inclusion and the tip fields near the inclusion. it is shown that in the media, all field variables near the inclusion-tip show square root singularity and oscillatory singularity, the intensity of which is dependent on the material constants and the strains at infinity. In addition, it is found that the electric field inside the inclusion is singular and oscillatory too, when approaching the inclusion-tips from inside the inclusion.
文摘By using a complex function method in this paper, the complex form of J-integral of mixed mode crack tip for unidirectional plate of linear-elastic orthotropic composites is obtained first by substituting crack tip stresses and displacements into general formula of J-integral. And then, the path-independence of this J-integral is proved. Finally, the computing formula of this J-integral is derived. As special examples, the complex forms, path-independence and computing formulae of J-integrals of mode I and mode II crack tips for unidirectional plate of linear-elastic orthotropic composites are given.
文摘Nanocrystalline powder of LaF3 was synthesized by a method of direct precipitation from water solution. Particle size and shape of LaF3 nanocrystalline powder was analysed with TEM. Particles were mainly spherical with narrow particle size distribution (10 20 nm). The average particle size analysed with XRD is 16.7 nm. Nano-LaF3 bulk material was prepared by compacting the powder to 1 GPa at room temperature and a vacuum of 10^-4 Pa. The ionic conductivity of nano-LaF3 bulk material was studied with complex impedance spectra at room temperature. The ionic conductivity of nano-LaF3 bulk material (1 × 10^-5 S·cm^-1 ) at room temperature is significantly increased compared to that of single crystal LaF3 (1 × 10^-6 S·cm^-1). A special phenomenon was observed firstly time that the ionic conductivity increased gradually with multiple testing in result of relaxation.
文摘Due to a viscoelastic damping middle layer,sandwich structures have the capacity of energy consumption.In this paper,we describe the frequency-dependent property of viscoelastic materials using complex modulus model,and iterative modal strain energy method and iterative complex eigenvalue method are presented to obtain frequency and loss factor of sandwich structures.The two methods are effective and exact for the large-scale complex composite sandwich structures.Then an optimum analysis method is suggested to apply to sandwich structures.Finally,as an example,an optimum analysis of a clamped-clamped sandwich beams is conducted,theoretical closed-form solution and numerical predictions are studied comparatively,and the results agree well.
基金supported by the Science Fund of State Key Laboratory of Advanced Design and Manufacturing for Vehicle Body (60870005)the National Natural Science Foundation of China (10872065)
文摘This paper deals with the electro-elastic coupling interaction between a piezoelectric screw dislocation which is located inside the elliptical inhomogeneity and an electrically conductive confocal rigid line under remote anti-plane shear stresses and in-plane electrical loads in piezoelectric composite material. The analytical-functions of the complex potentials, stress fields and the image force acting on the piezoelectric screw dislocation are obtained based on the principle of conformal mapping, the method of series expansion, the technical of analytic continuation and the analysis of singularity of complex potentials. The rigid line and the piezoelectric material property combinations upon the image force and the equilibrium position of the dislocation are discussed in detail by the numerical computation.
基金The authors acknowledge the financial support from the Natural Science Foundation of China(Nos.21931002 and 22101123)the National Key Research and Development Program of China(2018YFB0704100)+4 种基金the Shenzhen Science and Technology Innovation Committee(no.JCYJ20200109140812302)the Leading talents of Guangdong province program(2016LJ06N507)the Guangdong Provincial Key Laboratory of Energy Materials for Electric Power(no.2018B030322001)the Guangdong Provincial Key Laboratory of Catalysis(no.2020B121201002)Outstanding Talents Training Fund in Shenzhen.
文摘For the further improvement of the power conversion efficiency(PCE)and stability of perovskite solar cells(PSCs),the buried interface between the perovskite and the electron transport layer is crucial.However,it is challenging to effectively optimize this interface as it is buried beneath the perovskite film.Herein,we have designed and synthesized a series of multifunctional organic-inorganic(OI)complexes as buried interfacial material to promote electron extraction,as well as the crystal growth of the perovskite.The OI complex with BF4−group not only eliminates oxygen vacancies on the SnO_(2) surface but also balances energy level alignment between SnO_(2) and perovskite,providing a favorable environment for charge carrier extraction.Moreover,OI complex with amine(−NH_(2))functional group can regulate the crystallization of the perovskite film via interaction with PbI2,resulting in highly crystallized perovskite film with large grains and low defect density.Consequently,with rational molecular design,the PSCs with optimal OI complex buried interface layer which contains both BF4−and−NH_(2) functional groups yield a champion device efficiency of 23.69%.More importantly,the resulting unencapsulated device performs excellent ambient stability,maintaining over 90%of its initial efficiency after 2000 h storage,and excellent light stability of 91.5%remaining PCE in the maximum power point tracking measurement(under continuous 100 mW cm−2 light illumination in N2 atmosphere)after 500 h.