Layered injection technology for chemical flooding of Class-Ⅲ oil reservoirs in the Daqing Oil Fields complex,Songliao Basin,Northeast China

The Class-Ⅲ oil reservoirs of Lasaxing oilfield in the Daqing Oil Fields complex have geological oil reserves of 1.86 billion tonnes,an oil recovery of 39%,with remaining reserves accounting for more than 45%of the total geological reserves of the oilfield.Therefore,they have considerable potential for future oil production.The current layered injection technologies fail to achieve effective control over the low single-layer injection rates since they can only produce low throttle differential pressure under low injection rates(5-20 m^(3)/d).In this study,a symmetrically-structured double-offset-hole injection allocator and a novel throttling component were developed.Their spatial layout was constructed and mechanical parameters were optimized using finite element analysis,which allows for expanding the flow rate range at low injection rates.According to experimental results,the throttle differential pressure increased from 0.2 MPa to 0.8 MPa at an injection rate of 5 m^(3)/d,and the range of the single-layer flow rates expanded from 20-70 m^(3)/d to 5-70 m3/d.The field test results show that the effective production of oil layers with medium and low permeability was achieved and that the ratio of producing oil layer thickness to the total reservoir thickness increased by 9.7%on average.Therefore,this study provides valuable technical support for the effective chemical-flooding-based development of Class-Ⅲ oil reservoirs.

Frequency-dependent viscoelasticity effects on the wave attenuation performance of multi-layered periodic foundations

In this paper,layered periodic foundations(LPFs)are numerically examined for their responses to longitudinal and transverse modes in the time and frequency domains.Three different unit-cells,i.e.,2-layer,4-layer,and 6-layer unit-cells,comprising concrete/rubber,concrete/rubber/steel/rubber,and concrete/rubber/steel/rubber/lead/rubber materials,respectively,are taken into account.Also,the viscoelasticity behavior of the rubber is modeled with two factors,i.e.,a frequency-independent(FI)loss factor and a linear frequency-dependent(FD)loss factor.Following the extraction of the complex dispersion curves and the identification of the band gaps(BGs),the simulations of wave transmission in the time and frequency domains are performed using the COMSOL software.Subsequent parametric studies evaluate the effects of the rubber viscoelasticity models on the dispersion curves and the wave transmission for the longitudinal and transverse modes.The results show that considering the rubber viscoelasticity enhances the wave attenuation performance.Moreover,the transverse-mode damping is more sensitive to the viscoelasticity model than its longitudinal counterpart.The 6-layer unit-cell LPF exhibits the lowest BG,ranging from 4.8 Hz to 6.5 Hz.

Self-Assembled Film of Tb^(3+) and Poly(3- Thiophene Acetic Acid) via Layer-by-Layer Complexation Technique and Its Photoluminescence

The layer by layer complexation technique of polymer and metal ion was successfully utilized to fabricate the ultrathin multilayer film of poly(3 thiophene acetic acid (PTAA) and Tb 3+ ion by dipping the substrates alternatively in polymer and Tb 3+ ion aqueous solutions. UV-vis measurement revealed that the absorbance has linearity with the bilayer number from layer to layer and the X ray photoelectron spectrum (XPS) confirmed the existence of Tb 3+ ion. The pH of both the polymer and TbCl 3 solutions influence the thickness dramatically while the concentration of the solutions is not so sensitive. The luminescent spectrum of the complex film shows the characteristic emission of Tb 3+ ion as well as the ligand indicating the formation of the complex.

Synergistic Optimization of Buried Interface by Multifunctional Organic-Inorganic Complexes for Highly Efficient Planar Perovskite Solar Cells

For the further improvement of the power conversion efficiency(PCE)and stability of perovskite solar cells(PSCs),the buried interface between the perovskite and the electron transport layer is crucial.However,it is challenging to effectively optimize this interface as it is buried beneath the perovskite film.Herein,we have designed and synthesized a series of multifunctional organic-inorganic(OI)complexes as buried interfacial material to promote electron extraction,as well as the crystal growth of the perovskite.The OI complex with BF4−group not only eliminates oxygen vacancies on the SnO_(2) surface but also balances energy level alignment between SnO_(2) and perovskite,providing a favorable environment for charge carrier extraction.Moreover,OI complex with amine(−NH_(2))functional group can regulate the crystallization of the perovskite film via interaction with PbI2,resulting in highly crystallized perovskite film with large grains and low defect density.Consequently,with rational molecular design,the PSCs with optimal OI complex buried interface layer which contains both BF4−and−NH_(2) functional groups yield a champion device efficiency of 23.69%.More importantly,the resulting unencapsulated device performs excellent ambient stability,maintaining over 90%of its initial efficiency after 2000 h storage,and excellent light stability of 91.5%remaining PCE in the maximum power point tracking measurement(under continuous 100 mW cm−2 light illumination in N2 atmosphere)after 500 h.

Preparation and Characterization of Layered Compound Zirconium Bis(monohydrogenphosphate) Intercalated with Rare Earth Complex

Layered compound zirconium bis(monohydrogenphosphate)(alpha-ZrP) intercalated with rare earth complex Eu(DBM)(3)phen was prepared. The pre-intercalation of p-methoxyaniline into alpha-ZrP makes the interlayer separation large enough to exchange PMA with europium complex, thus, the luminescent assembly was prepared. This was confirmed by X-ray diffraction, UV-visible spectra and elemental analysis. The fluorescence spectra and lifetime of the assembly were also presented.

A Layered Vanadium Oxide with Cobalt(Ⅱ) Coordination Complex: Hydrothermal Synthesis and Crystal Structure of (py)_5Co_2(H_2O)_3[V_4O_(12)]

A novel layered mixed metal vanadium-cobadt complex, （py）5Co2（H2O）3[V4O12] 1 （py = pyridine）, was hydro（solvo）thermally synthesized and characterized by single-crystal X-ray diffraction. It crystallizes in orthorhombic, space group Pca21 with a = 17.473（4）, b = 11.447（2）, c = 17.509（4）A^°, V = 5005.3（7）A^°3, Z = 4, Mr = 3502.1（12）, Z = 4, Dc = 1.827 g/cm^3,μ（MoKα） = 2.023 mm^-1, F（000） = 1928, S = 1.020, the final R = 0.0400 and wR= 0.1063 for 6035 observed reflections with I 〉 2σ（I） and 460 variables. Complex 1 consists of tetrahedral VO4 groups to form the large layers which are alternately bonded by two cobalt complex species Co（py）2（H2O）2 and Co（py）3（H2O）.

Weak Interactions and 2D Layer Structure of a New Ion-pair Complex Bis(1-benzyl-4-methylquinolinium)-bis(maleonitriledithiolato)nickel(Ⅱ)

A new ion-pair complex, [BzMeQ1]2[Ni（nmt）2]1（[BzMeQ1]^＋ = 1-benzyl-4-ntethylquino- linium, mnta- -- maleonitriledithiolate） has been synthesized and structurally characterized by IR, ESI-MS and X-ray diffraction methods. Complex 1 is of triclinic, space group PI, with a = 9.079（2）, b = 10.154（2）, c = 11.243（2）A, α= 81.58（1）, β= 69.63（1）, γ = 68.02（1）°, V= 940.1（3）A3, Dc = 1.427 g/cm^3, Z = 1, F（000） = 418 and R = 0.0442. A 2D layer structure is formed via the cation-cation π…π and C-H…π interactions observed in the solid state of the complex.

Aqueous Sn-S Complex Derived Electron Selective Layer for Perovskite Solar Cells

A novel aqueous Sn-S complex solution was applied as precursor to fabricate SnO2 electron selective layers (ESLs) for the hybrid perovskite solar cells (PSCs).The tin and sulfur powder were directly dissolved in a (NH4)2S water solution to form Sn-S precursor.After depositon and annealing,the SnO2 film was formed,presenting as a low cost and enviromental friendly method for preparation of ESL.The films showed excellent transmittance at visible wavelength range.Moreover,the method exhibited high compatibility for doping using Cu,Cd,Li,and Zn elements.Zn doping (0.05 M) in the as-prepared SnO2 ESL significantly improved perovskite solar cells (PSCs) performance.The highest PCE of 13.17% was achived with 15% enhancement compared to that of undoped SnO2 ESL samples.TiCl4 modifications on SnO2 film improved photovoltaic performance to 14.45%,but resulted in the poor long-term stability,around 80% more degredation than that of PSCs based on Zn-doped SnO2 films.

Quantum Theory of Disturbance and Delay of GPS Signals in <i>D</i>and <i>E</i>Atmospheric Layers: An Introduction

GPS signals play a very important role in the modern industry, science, tourism, military and domestic operations. However, GPS signals are not free from some mistakes caused by disturbances appearing in D and E layers of the atmosphere. A quantum approach is proposed to the theory of propagation of a satellite GPS signal through the D and E layers of the atmosphere, which reduces to the problem of scattering of photons moving in the electromagnetic field of a signal in Rydberg complexes formed in a two-temperature non-equilibrium plasma. The processes of creation of additional photons as a result of stimulated emission and resonance scattering of photons are considered. It is shown that the first process leads to a direct increase in the power of the received signal, and the second to a shift in the signal carrier frequency and the time delay of its propagation. This occurs because of the scattering of the Rydberg electron by the ion core and the neutral medium molecule in the intermediate autoionization states of the composite system populated by the strong non-adiabatic coupling of electron and nuclear motions.

U-Pb SHRIMP-II Baddeleyite and Zircon Dating of the Early Proterozoic Monchegorsk Layered Mafite-Ultramafite Complex(Kola Peninsula): Evidence of Synchronous Magmatism

The Early Paleoproterozoic Monchegorsk Complex is exposed over an area of 550 km;and comprises two layered mafite–ultramafite intrusions:the Monchepluton of ultramafic and mafic rocks and the predominantly gabbroid

Simple Preparation of Halogen-Substituted <i>α</i>-Diimine Nickel Complexes Immobilized into Clay Interlayer as Catalysts for Ethylene Oligo-/Polymerization

In the practical use for the production of the α-olefins, it is highly desired to develop a novel heterogeneous catalyst system. The metal complexes immobilized into the clay interlayers show a great potential as heterogeneous catalysts due to their excellent processability. In this study, nine types of heterogeneous procatalyst Ln/Ni2+-micas were synthesized via a one-pot preparation method, which includes both the condensation reaction of the ligand derivatives and the intercalation of the ligands into the Ni2+ ion-exchanged fluorotetrasilicic mica interlayer. The ligand structures of the prepared procatalysts were [Ln: R-N = C(Nap)-C(Nap) = N-R] [(Nap = 1,8-naphthdiyl) (L1, R = 2-MePh;L2, R = 2-FPh;L3, R = 2-BrPh;L4, R = 4-MePh;L5, R = 4-FPh;L6, R = 4-BrPh;L7, R = 2,4-F2Ph;L8, R = 2,4-Br2Ph;L9, R = 2,6-F2Ph). At 50℃ and 0.7 MPaethylene pressure, the triisobutylaluminum-activated L1-L6/Ni2+-mica showed a catalytic activity for the ethylene oligo-/polymerization in the range of 334 - 549 g-ethylene&bull;g-cat–1&bull;h–1. A high catalyst activity was obtained when the substituent having a larger steric bulk than that of a methyl substituent was introduced at the ortho-position of the aryl rings. The introduction of the fluorine substituent as a strong electron-withdrawing group to the para-position also increased the catalytic activity. The L2, L4, L5, and L6/Ni2+-micas showed moderate selectivities to oligomers consisting of C4-C20 in the range of 19.9 - 41.6 wt% at 50℃. The calculated Schulz-Flory constants α based on the mole fraction of C12 and C14 were within 0.61 - 0.78.

Solvatochromic Probe Based on Nanocellulose Membrane Coated with Zn-terpyridine Complex in a Layer-by-Layer Manner

Solvatochromic materials have recently attracted increasing attention owing to their great significance in the security and sensor fields.In this study,ultrafast explicit and implicit information was collected regarding a fluorescent nanocellulose membrane produced from nanocellulose membranes coated with a Zn-terpyridine complex(Zn-tpy)in a layer-by-layer manner.The fluorescent emissions of the nanocellulose membrane changed from yellow(CIE:x=0.37,y=0.45)to green(CIE:x=0.32,y=0.47)under a dichloromethane environment and 365-nm irradiation.Due to the ease of dichloromethane volatilization,fluorescent emissions quickly returned to the original state.These solvatochromic nanocellulose membranes,with ultrafast explicit and implicit information,exhibited valuable application prospects in anti-counterfeiting techniques.

Petrography of Bethampudi Anorthosites Layered Complex from the Khammam Schist Belt, Telangana, India

The Bethampudi layered anorthosite complex at the border zone of Archaean supracrustal rocks of Khammam district, Eastern Ghats shows normal stratification predominantly in the form of rhythmic layering and often exhibits of zebra layering. Graded bedding and cumulate structures are also noticed. The rocks of the study area are classified based on petrography into anorthositic rocks, gabbroic rocks and ultramafic rocks and amphibolites. The field relations and major element composition suggest that these anorthosite rocks are of calc-alkaline in nature and petrogenitically related to the gabbroic rocks by the fractional crystallization at ℃.

Cooperation influenced by the correlation degree of two-layered complex networks in evolutionary prisoner’s dilemma games

An evolutionary prisoner＇s dilemma game is investigated on two-layered complex networks respectively representing interaction and learning networks in one and two dimensions. A parameter q is introduced to denote the correlation degree between the two-layered networks. Using Monte Carlo simulations we studied the effects of the correlation degree on cooperative behaviour and found that the cooperator density nontrivially changes with q for different payoff parameter values depending on the detailed strategy updating and network dimension. An explanation for the obtained results is provided.

Large eddy simulation of supersonic flow in ducts with complex cross-sections

Large Eddy Simulation(LES)has been employed for the investigation of supersonic flow characteristics in five ducts with varying cross-sectional geometries.The numerical results reveal that flow channel configurations exert a considerable influence on the mainstream flow and the near-wall flow behavior.In contrast to straight ducts,square-to-circular and rectangular-to-circular ducts exhibit thicker boundary layers and a greater presence of vortex structures.Given the same inlet area,rectangular-to-circular ducts lead to higher flow drag force and total pressure loss than square-to-circular ducts.Characterized by the substantial flow separation and shock waves,the"S-shaped duct shows significant vertically-asymmetric characteristics.

高含水复杂断块油藏单层系边外注水开发模式

复杂断块油藏在开发后期面临综合含水率高、地层能量不足、剩余油分布复杂、井网适应性差等问题。以济阳坳陷沾化凹陷中部垦71断块油藏为例,基于水驱油藏的油包水和水包油2种油水分布状态,利用理论模型推导和数值模拟方法,开展了单层系边外注水开发模式研究。结果表明:从采液端和注水端的受力分析可获得单层系开发的合理注水量、合理采液量和合理注采井距,单层系开发的合理注水压差、合理注水量、合理采液量是影响其剩余油饱和度、含水饱和度的关键因素,对油层合理地层压力水平及剩余油二次富集起主要控制作用。通过加大注采井距至油水边界外围,以2.9倍含油条带宽度为合理注采井距的临界值,采用短注长静置的非对称周期注采方式,建立单层系边外注水开发模式,有利于保持单层系的压力系统稳定和提高剩余油波及率,从而提高原油采收率。矿场实践表明,采用单层系边外注水开发模式后,垦71断块油藏日产油量提高至254 t/d,含水率控制在93.7%,采收率提高至31.53%,采油速率提高4.9%,显示出良好的增产效果。单层系边外注水开发模式解决了高含水复杂断块油藏开发中的剩余油分布分散、水驱波及率低和井网适应性差等难题,可为复杂断块油藏开发提供指导和借鉴。

复杂地形对风速廓线的影响

随着风电利用的发展,越来越多的风电场建立在复杂地形的山区,为了更好地进行风能评估和风电预报,就需要了解复杂地形对风速廓线的影响。本文基于薄翼理论和湍流边界层扰动的线性化理论,采用两层模型对坡度较小的山地在其二维横截面上的风廓线进行了预测,该模型能够较为准确地预报地形、压力、稳定度对风速增速的影响,但对于三维地形或其他因素产生的风速的复杂变化,需要进一步将其扩展至三维,并结合数值模拟进行研究。

隐蔽层面产状的综合勘察方法研究

为研究隐蔽层面产状的综合勘察方法,本文以洋溪水利枢纽坝址为例,针对该坝址南沱组层理不发育,劈理、节理发育及风化复杂等难点,采用工程地质测绘、钻探、钻孔电视、平硐及竖井等相结合的方法,在查清所有结构面和区域构造的基础上,通过对标志层进行三维建模并面概化,以及根据结构面的发育情况、延伸长度及区域构造产状对比进行层面与节理的辨别,最终查明了洋溪水利枢纽坝址南沱组地层产状为N12~19°E,SE∠32~45°。

考虑大气稳定度的典型复杂地形风场CFD模式

为评估中国典型复杂山地风资源,实现风资源的高效利用,结合雷诺时均的k-ε两方程模型、大气粗糙度壁面函数和热浮力作用,提出能模拟不稳定、中性和稳定状态复杂地形风场特性的大气CFD模式,并针对湍流参数、大气粗糙度对风速廓线的影响进行参数化研究。采用两种方式驱动CFD模式:一种是通过来流上游的实测风速廓线驱动CFD模式,一种是通过WRF模式输出风速廓线和温度廓线驱动CFD模式。利用山西神池南桦山丘陵山地测风数据进行大气CFD模式验证,通过WRF-CFD耦合仿真研究山地公里级范围热浮力作用对风场的影响,详细对比不同热浮力作用下的大气CFD模式仿真精度。结果表明大气CFD模式能准确地模拟不同稳定度状态下的山区大气风环境,但对于不稳定状态下山后风场的模拟能力稍差。

基于磁异探测的侵彻复杂工况磁响应仿真分析

针对目前基于地磁场磁异探测在复杂侵彻工况下的引信磁异响应研究不足的情况,利用COMSOL有限元分析软件建立了弹体复杂工况下的侵彻模型,探究了弹体在平射或垂直正侵6层钢筋混凝土靶板、不同方向与不同距离的铁磁干扰作用、侵彻带有横梁结构钢筋混凝土靶板、偏转不同角度斜侵命中竖直墙体4种不同复杂工况条件下的侵彻过程引信磁异响应特征。经过仿真分析发现,不论是平射或是垂直正侵都可以得到清晰的穿靶特征信号,相对地磁方向偏转不同角度平射只会影响穿靶时磁信号的变化量而不影响穿靶特征的识别;放置于不同方向的铁磁干扰会对该轴与Z轴的磁异信号产生影响,放置距离超过3 m时影响微弱;弹体侵彻带横梁结构靶板,在横梁放置方向与Z轴方向上穿靶信号的变化量与脉宽均有所增加,不影响穿靶特征识别;弹体绕某轴发生偏转后带有攻角侵彻带竖直墙体钢筋混凝土靶板,攻角越小,侵彻竖直墙体及相邻2层靶板时产生的磁异信号变化越剧烈,攻角为10°时,失去穿靶特征。