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Multiresolution method for bending of plates with complex shapes
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作者 Jizeng WANG Yonggu FENG +2 位作者 Cong XU Xiaojing LIU Youhe ZHOU 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI CSCD 2023年第4期561-582,共22页
A high-accuracy multiresolution method is proposed to solve mechanics problems subject to complex shapes or irregular domains.To realize this method,we design a new wavelet basis function,by which we construct a fifth... A high-accuracy multiresolution method is proposed to solve mechanics problems subject to complex shapes or irregular domains.To realize this method,we design a new wavelet basis function,by which we construct a fifth-order numerical scheme for the approximation of multi-dimensional functions and their multiple integrals defined in complex domains.In the solution of differential equations,various derivatives of the unknown function are denoted as new functions.Then,the integral relations between these functions are applied in terms of wavelet approximation of multiple integrals.Therefore,the original equation with derivatives of various orders can be converted to a system of algebraic equations with discrete nodal values of the highest-order derivative.During the application of the proposed method,boundary conditions can be automatically included in the integration operations,and relevant matrices can be assured to exhibit perfect sparse patterns.As examples,we consider several second-order mathematics problems defined on regular and irregular domains and the fourth-order bending problems of plates with various shapes.By comparing the solutions obtained by the proposed method with the exact solutions,the new multiresolution method is found to have a convergence rate of fifth order.The solution accuracy of this method with only a few hundreds of nodes can be much higher than that of the finite element method(FEM)with tens of thousands of elements.In addition,because the accuracy order for direct approximation of a function using the proposed basis function is also fifth order,we may conclude that the accuracy of the proposed method is almost independent of the equation order and domain complexity. 展开更多
关键词 MULTIRESOLUTION generalized Coiflet wavelet integral collocation method irregular domain complex shape high accuracy plate bending
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Study on Isoparametric Finite-Element Integral Algorithm of Gravity and Magnetic Anomaly for Body with Complex Shape
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作者 Kim Kangsop Hu Xiang-yun +4 位作者 Cho Gyonglae Nam Myonggun Kang Jongnam Kim Gyongchil and Liu Hui 《石油地球物理勘探》 EI CSCD 北大核心 2009年第A02期125-134,共10页
关键词 等参有限元 复杂形状 重磁异常 积分算法 数值积分公式 积分计算 身体 磁法勘探
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3D analysis of functionally graded material plates with complex shapes and various holes
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作者 曹志远 唐寿高 程国华 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI 2009年第1期13-18,共6页
In this paper, the basic formulae for the semi-analytical graded FEM on FGM members are derived. Since FGM parameters vary along three space coordinates, the parameters can be integrated in mechanical equations. There... In this paper, the basic formulae for the semi-analytical graded FEM on FGM members are derived. Since FGM parameters vary along three space coordinates, the parameters can be integrated in mechanical equations. Therefore with the parameters of a given FGM plate, problems of FGM plate under various conditions can be solved. The approach uses 1D discretization to obtain 3D solutions, which is proven to be an effective numerical method for the mechanical analyses of FGM structures. Examples of FGM plates with complex shapes and various holes are presented. 展开更多
关键词 各向异性弹性力学 FEM FGM 分析法
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Structural Dimension Optimization of Robotic Belt Grinding System for Grinding Workpieces with Complex Shaped Surfaces Based on Dexterity Grinding Space 被引量:9
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作者 GAO Zhihui LAN Xiaodong BIAN Yushu 《Chinese Journal of Aeronautics》 SCIE EI CAS CSCD 2011年第3期346-354,共9页
为了改进机器的带磨擦的磨擦质量,为有建筑群的细工品的系统塑造了表面,磨点的灵巧的新概念和磨空格的灵巧被建议,他们的数学描述被定义。影响磨空间的灵巧的因素被分析。并且决定磨空间的必要灵巧的一个方法被建议。把方法基于粒子... 为了改进机器的带磨擦的磨擦质量,为有建筑群的细工品的系统塑造了表面,磨点的灵巧的新概念和磨空格的灵巧被建议,他们的数学描述被定义。影响磨空间的灵巧的因素被分析。并且决定磨空间的必要灵巧的一个方法被建议。把方法基于粒子群优化(PSO ) ,优化磨擦机器人的策略关于磨擦车轮的结构的尺寸和位置被提出获得磨空间的必要灵巧。最后,磨天线引擎片,奉献 PPPRRR (P:棱柱的 R:旋转) 磨擦机器人关于磨擦车轮的结构的尺寸和位置用上述策略被优化。根据模拟结果,如果片被放在磨空间的灵巧以内,仅仅一 gripper 和一磨擦机器被需要磨它的建筑群塑造的表面。 展开更多
关键词 空间机器人 尺寸优化 结构尺寸 磨削工件 复杂形状 磨削系统 研磨机 砂带
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Influence of shape anisotropy on microwave complex permeability in carbonyl iron flakes/epoxy resin composites 被引量:7
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作者 温福昇 乔亮 +3 位作者 周栋 左文亮 伊海波 李发伸 《Chinese Physics B》 SCIE EI CAS CSCD 2008年第6期2263-2267,共5页
To explore the mechanism of carbonyl iron flake composites for microwave complex permeability, this paper investigates the feature of the flakes. The shape anisotropy was certified by the results of the magnetization ... To explore the mechanism of carbonyl iron flake composites for microwave complex permeability, this paper investigates the feature of the flakes. The shape anisotropy was certified by the results of the magnetization hysteresis loops and the Mssbauer spectra. Furthermore, the shape anisotropy was used to explain the origin of composite microwave performance, and the calculated results agree with the experiment. It is believed that the shape anisotropy dominates microwave complex permeability, and the natural resonance plays main role in flake. 展开更多
关键词 羰基离子薄片 复合物稳定性 型状 各向异性 光谱学
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POLYMER NETWORK-POLY(ETHYLENE GLYCOL)COMPLEXES WITH SHAPE MEMORY EFFECT
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作者 Yi-ping Cao +1 位作者 C.W.Yip 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 2003年第1期29-33,共5页
The complexes of poly(methacrylic acid-co-methyl methacrylate) network with poly(ethylene glycol) stabilized by hydrogen bonds were prepared. By introducing the poly(ethylene glycol), a large difference in storage mod... The complexes of poly(methacrylic acid-co-methyl methacrylate) network with poly(ethylene glycol) stabilized by hydrogen bonds were prepared. By introducing the poly(ethylene glycol), a large difference in storage modulus below and above the glass transition temperature occurred and the complexes exhibited shape memory behaviors. The morphology of complexes was studied by using DSC, WAXD, and DMA. The results indicate that the fixed phase of this kind of novel shape memory materials is the network, and the reversible phase is the amorphous state of PEG:PMAA complex phase. The shape recoverability almost reaches 100%. This type of complexes can be regarded as a novel shape memory network. 展开更多
关键词 聚合物网络 氢键配合物 聚甲基丙烯酸 聚亚乙烯基甘醇 PMAA PEG 形状记忆功能
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PREPARATION AND CHARACTERIZATION OF INCLUSION COMPLEXES OF TWO-ARM LINEAR AND FOUR-ARM STAR-SHAPED POLY(ε-CAPROLACTONE)S WITHα-CYCLODEXTRIN 被引量:1
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作者 Lu Wang Jing-liang Wang 董常明 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 2006年第3期245-252,共8页
Both four-arm star-shaped poly(ε-caprolactone) (4sPCL) and two-arm linear PCL (2LPCL) were synthesized and their inclusion complexation withα-cyclodextrin (α-CD) were studied. The inclusion complexes (ICs) formed b... Both four-arm star-shaped poly(ε-caprolactone) (4sPCL) and two-arm linear PCL (2LPCL) were synthesized and their inclusion complexation withα-cyclodextrin (α-CD) were studied. The inclusion complexes (ICs) formed between the PCL polymers andα-CD were characterized by 1H-NMR, DSC, TGA, WAXD, and FT-IR, respectively. Both branch arm number and molecular weight of the PCL polymers have apparent effect on the stoichiometry (CL:CD, mol:mol) of these ICs. All these analytical results indicate that the branch arms of the PCL polymers are incorporated into the hydrophobicα-CD cavities and their original crystalline properties are completely suppressed. Moreover, the inclusion complexation between two-arm linear or four-arm star-shaped PCL polymers andα-CD not only enhances the thermal stability of the guest PCL polymers but also improves that ofα-CD. 展开更多
关键词 包合配合物 线性聚(ε-己内酯) 星形聚(ε-己内酯) 热稳定性 α-环式糊精
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高地应力缓斜半煤岩巷道断面形状优化研究
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作者 王志强 尹安然 +2 位作者 李敬凯 柴虎虎 王燕飞 《煤炭工程》 北大核心 2024年第1期105-112,共8页
为了优化高地应力缓斜半煤岩巷道的断面形状,以东欢坨矿3018工作面运道为工程背景展开研究。通过复变函数理论推导得出了倾斜煤层中不同断面形状的应力解析解,然后运用FLAC3D数值模拟求解了不同断面形状巷道的应力集中和塑性区情况,并... 为了优化高地应力缓斜半煤岩巷道的断面形状,以东欢坨矿3018工作面运道为工程背景展开研究。通过复变函数理论推导得出了倾斜煤层中不同断面形状的应力解析解,然后运用FLAC3D数值模拟求解了不同断面形状巷道的应力集中和塑性区情况,并以此为基础确定了巷道最优断面形状,最后结合现场工业性试验对研究结果的可靠性进行了验证。研究结果表明:高地应力作用下缓斜半煤岩巷道破坏呈现非对称形式;不管断面形状如何,巷道均在左、右两底角处呈现高应力集中,且应力集中程度矩形>梯形>直墙拱形;直墙拱形巷道稳定性最佳,梯形巷道次之,矩形稳定性最差,确定直墙拱形为最终巷道断面形状;现场巷道表面位移量监测结果表明,直墙拱形巷道更能满足现场安全生产要求。 展开更多
关键词 高地应力 缓斜半煤岩巷道 巷道断面形状 复变函数
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复杂异型建筑立面测绘轮廓提取方法设计
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作者 于淮 张燕 《自动化仪表》 CAS 2024年第2期91-95,共5页
为解决点云数据密度异常时复杂异型建筑立面测绘轮廓提取精度变差的问题,提出基于局部点云密度的复杂异型建筑立面测绘轮廓提取方法。引入基于平面投影和双边滤波的测绘点云数据平滑方法,对测绘数据进行去噪和平滑处理,并通过点云分割... 为解决点云数据密度异常时复杂异型建筑立面测绘轮廓提取精度变差的问题,提出基于局部点云密度的复杂异型建筑立面测绘轮廓提取方法。引入基于平面投影和双边滤波的测绘点云数据平滑方法,对测绘数据进行去噪和平滑处理,并通过点云分割方法提取目标点云区域。通过基于改进Alpha Shapes算法的立面测绘轮廓提取方法,以边界网格筛选的方式,去除目标点云区域冗余点云数据后,使用滚动圆半径自适应调节方法提取轮廓数据。试验结果表明,所提取轮廓匹配度高达95.08%,具有良好的精度和可行性。该方法可在有效平滑点云数据、分割获取目标点云区域的同时,高精度提取复杂异型建筑立面测绘轮廓。 展开更多
关键词 复杂异形建筑 立面测绘 轮廓提取 局部点云密度 点云数据平滑 改进Alpha shapes算法
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基于数控加工技术的建构研究
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作者 杨帆 褚作勇 《中外建筑》 2024年第4期109-113,共5页
数控加工(Computer Numerical Control)技术正在改变建筑行业的设计和建造方式,它使得建筑能够以更高的精确度和更自由的形态实现。本研究结合上海松山自然社区建筑改造、忻州华美咖啡馆、北京睡眠研究所民宿改造、南京欢乐谷东侧大门... 数控加工(Computer Numerical Control)技术正在改变建筑行业的设计和建造方式,它使得建筑能够以更高的精确度和更自由的形态实现。本研究结合上海松山自然社区建筑改造、忻州华美咖啡馆、北京睡眠研究所民宿改造、南京欢乐谷东侧大门等项目的设计与建造过程,在建筑构件形态生成、加工制造和施工安装等环节深度探索数控加工技术应用。旨在为今后数控加工技术在建筑设计与建造领域的应用提供理论和实践参考。 展开更多
关键词 数控加工技术 复杂形体建筑 数字化建构 案例研究
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自体肋软骨移植构建鼻尖支架复合体的鼻尖成形术
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作者 韩飞 张淼 《中国医疗美容》 2024年第2期19-22,共4页
目的探究自体肋软骨移植构建鼻尖支架复合体鼻整形术对鼻尖肥大患者鼻部创口愈合及鼻尖部外形的影响。方法选择我院2022年1月-2023年6月收治的鼻尖肥大患者30例作为研究对象。均采用自体肋软骨移植构建鼻尖支架复合体鼻整形术治疗。分... 目的探究自体肋软骨移植构建鼻尖支架复合体鼻整形术对鼻尖肥大患者鼻部创口愈合及鼻尖部外形的影响。方法选择我院2022年1月-2023年6月收治的鼻尖肥大患者30例作为研究对象。均采用自体肋软骨移植构建鼻尖支架复合体鼻整形术治疗。分析术后相关指标,对比手术前后鼻尖部外形,分析并发症发生情况。结果患者手术时间为(62.97±4.92)min,创口愈合时间为(8.34±1.28)d。术后鼻长、鼻尖高度大于术前,鼻尖两顶间距离小于术前(P<0.05)。30例患者出现肿胀及感染各1例,发生率为6.67%(2/30)。结论自体肋软骨移植构建鼻尖支架复合体鼻整形术均可有效治疗鼻尖肥大,且均获得理想的鼻尖部外形,预后情况良好,安全可靠,值得推广应用。 展开更多
关键词 鼻尖肥大 自体肋软骨移植 鼻尖支架复合体 鼻尖成形术 并发症
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运用GeoGebra软件实现复变函数可视化教学的探索与实践
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作者 程旭 艾小川 张恒 《科教导刊》 2024年第5期41-44,共4页
为推动技术与教育教学精准融合,探讨可视化方法在工科复变函数课程教学中的意义与实施效果是重要且必要的。文章根据复分析可视化资源库的建立步骤,利用GeoGebra软件制作可视化文件;再将可视化资源有机融入教学设计中,遵循“观察―发现... 为推动技术与教育教学精准融合,探讨可视化方法在工科复变函数课程教学中的意义与实施效果是重要且必要的。文章根据复分析可视化资源库的建立步骤,利用GeoGebra软件制作可视化文件;再将可视化资源有机融入教学设计中,遵循“观察―发现―讨论―归纳”的学习过程;最后通过教学实践结果,反映出复变函数可视化教学收效显著。数形结合思想的贯穿使教学过程高效,使学生思路开阔,有利于高技术应用型人才的培养。 展开更多
关键词 GeoGebra 可视化 复变函数 数形结合
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屋面及外立面异形条件下吊篮非常规安装方法探析
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作者 于海祥 李治强 《重庆建筑》 2024年第2期69-71,77,共4页
随着经济社会快速发展,各类高层及超高层建筑的美学设计要求越来越高,建筑物屋面和外立面趋于异形和复杂。建筑外立面常采用高处作业吊篮进行装修施工,传统的吊篮标准安装方式已无法满足现代复杂屋面及外立面的施工作业要求,由此带来了... 随着经济社会快速发展,各类高层及超高层建筑的美学设计要求越来越高,建筑物屋面和外立面趋于异形和复杂。建筑外立面常采用高处作业吊篮进行装修施工,传统的吊篮标准安装方式已无法满足现代复杂屋面及外立面的施工作业要求,由此带来了不同建筑条件下高处作业吊篮的各类非标准安装方式。为确保非标安装条件下吊篮的施工安全、便捷,促进建筑业新技术的发展,该文系统探讨了各类非标准条件下,吊篮的安装方法及安全技术要点,并提出了相关构造要求,以期提高非标条件下吊篮使用的安全技术水平。 展开更多
关键词 异形屋面 复杂外立面 高处作业吊篮
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新型H型钢前撑在复杂边界条件下深基坑的应用研究
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作者 何林南 《山西建筑》 2024年第10期80-84,共5页
前撑注浆钢管支护体系是近几年应用的一种新型基坑支护技术,已在长三角地区地下一层广泛应用与实践。与传统钢斜撑相比具有施工便捷、节省工期和对周边环境影响小等明显优势。以某杭州地区某复杂边界条件下深大基坑工程为例,从方案选型... 前撑注浆钢管支护体系是近几年应用的一种新型基坑支护技术,已在长三角地区地下一层广泛应用与实践。与传统钢斜撑相比具有施工便捷、节省工期和对周边环境影响小等明显优势。以某杭州地区某复杂边界条件下深大基坑工程为例,从方案选型、施工技术要点、支护效果等方面对新型H型钢前撑体系进行了详细的分析和介绍,通过现场试验、数值模拟分析和现场监测等手段,进一步分析验证了H型钢前撑体系使用的可行性,为类似地质和边界条件下深大基坑工程设计提供参考。 展开更多
关键词 复杂边界条件 深大基坑工程 H型钢前撑
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INTEGRAL EQUATION METHOD'S APPLICATION IN HOLE-EDGE STRESS OF COMPOSITE MATERIAL PLATE WITH DIFFERENT SHAPED HOLES 被引量:3
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作者 LI Cheng ZHENG Yanping 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2008年第6期115-118,共4页
The strength of composite plate with different hole-shapes is always one of the most important but complicated issues in the application of the composite material.The holes will lead to mutations and discontinuity to ... The strength of composite plate with different hole-shapes is always one of the most important but complicated issues in the application of the composite material.The holes will lead to mutations and discontinuity to the structure.So the hole-edge stress concentration is always a serious phenomenon.And the phenomenon makes the structure strength decrease very quickly to form dangerous weak points.Most partial damage begins from these weak points.According to the complex variable functions theory,the accurate boundary condition of composite plate with different hole-shapes is founded by conformal mapping method to settle the boundary condition problem of complex hole-shapes.Composite plate with commonly hole-shapes in engineering is studied by several complex variable stress function.The boundary integral equations are founded based on exact boundary conditions.Then the exact hole-edge stress analytic solution of composite plate with rectangle holes and wing manholes is resolved.Both of offset axis loadings and its influences on the stress concentration coefficient of the hole-edge are discussed.And comparisons of different loads along various offset axis on the hole-edge stress distribution of orthotropic plate with rectangle hole or wing manhole arc madc.It can bc concluded that hole-edge with continuous variable curvatures might help to decrease the stress concentration coefficient;and smaller angle of outer load and fiber can decrease the stress peak value. 展开更多
关键词 负载 共形映射 孔径问题 积分方程 应力函数 多重复合变量
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SOLUTION OF DIFFERENT HOLES SHAPE BORDERS OF FIBRE REINFORCED COMPOSITE PLATES BY INTEGRAL EQUATIONS 被引量:3
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作者 LI Cheng ZHENG Yanping CHEN Zhongzhong 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2007年第5期23-27,共5页
有不同的洞的合成材料盘子的精确边界条件被成立在非同类的各向异性的有弹性、复杂的功能理论之上由保角的印射的方法解决复杂的洞的边界条件问题。然后要求的二压力功能基于由边界条件不可分的 Cauchy。用矩形洞和翅膀出入孔在合成材... 有不同的洞的合成材料盘子的精确边界条件被成立在非同类的各向异性的有弹性、复杂的功能理论之上由保角的印射的方法解决复杂的洞的边界条件问题。然后要求的二压力功能基于由边界条件不可分的 Cauchy。用矩形洞和翅膀出入孔在合成材料板上打开结构和分析答案的最后的压力分布被完成。对洞边压力集中因素的影响在不同负担和纤维方向盒子下面被讨论,然后对比计算被完成女性。 展开更多
关键词 纤维加强材料 边界条件 功能复合物 技术性能
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大壁厚差复杂形状铝合金飞轮壳挤压铸造数值模拟 被引量:2
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作者 姜巨福 葛宁 +4 位作者 黄敏杰 李明星 王迎 丁长杰 邹德超 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2023年第5期1345-1360,共16页
利用ProCAST软件对大壁厚差复杂形状ZL104铝合金飞轮壳挤压铸造过程进行数值模拟。结果表明:充型过程稳定且可分为4个阶段:流道连通、水平区域填充、竖直方向填充和难充填区填充。凝固过程中存在6个凝固滞后的特征区域,特征区域的缩孔... 利用ProCAST软件对大壁厚差复杂形状ZL104铝合金飞轮壳挤压铸造过程进行数值模拟。结果表明:充型过程稳定且可分为4个阶段:流道连通、水平区域填充、竖直方向填充和难充填区填充。凝固过程中存在6个凝固滞后的特征区域,特征区域的缩孔缩松缺陷明显。缺陷位置预测准确,对预测的缺陷体积进行极差分析,确定最佳工艺参数为浇注温度650℃、比压48 MPa、模具温度220℃、补压比压800 MPa、补压延时10 s(A侧)和12 s(B侧)。最大铸造应力出现在凝固速度快、曲率大的薄壁结构中。仿真结果得到了实际工艺验证。 展开更多
关键词 数值模拟 挤压铸造 大壁厚差 复杂形状 定域补压
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Cambering of Four High Cold Mill with the View of Reducing Roller Ends Contact and Preventing Complex Waves 被引量:1
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作者 Zhenhua Bai Hongxin Si +1 位作者 Xiaodong Shi Qingtian Zhou 《Engineering(科研)》 2011年第4期359-363,共5页
Based on lots of field experiments and theoretical research, fully thinking the equipment and production craft characters of four high cold mill, a new cambering scheme for four high cold mill is advanced in this pape... Based on lots of field experiments and theoretical research, fully thinking the equipment and production craft characters of four high cold mill, a new cambering scheme for four high cold mill is advanced in this paper. This scheme considered the need of production of multi-specification products, as well as the control of roller ends contact. The most homogeneous transverse distribution of front tension is the control target and the homogeneous pressure distribution between rollers is the constraint condition. In this technology, working roll curve adapt the combination of cosine curve and high order curve, backup roll adapt the combination of cosine curve, straight line and high order curve. The cosine subentry of working roll and the high order curve subentry are used to control edge wave, the high order curve subentry of working roll is used to control the roll contact, the cosine subentry of backup roll is used to reduce the center wave. That’s the features of this technology. On-site testing shows that the new cambering and combination can not only manage the complex waves of normal four high cold mill effectively, but also will reduce the contact between roller ends and minish roll consumption. This technology has created economic benefits for enterprises. 展开更多
关键词 complex WAVES Strip shape ROLL Contour ROLL CONTACT ROLL Consumption
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Hydrodynamic Analysis and Shape Optimization for Vertical Axisymmetric Wave Energy Converters 被引量:8
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作者 张万超 刘恒序 +1 位作者 张亮 张学伟 《China Ocean Engineering》 SCIE EI CSCD 2016年第6期954-966,共13页
The absorber is known to be vertical axisymmetric for a single-point wave energy converter(WEC). The shape of the wetted surface usually has a great influence on the absorber's hydrodynamic characteristics which a... The absorber is known to be vertical axisymmetric for a single-point wave energy converter(WEC). The shape of the wetted surface usually has a great influence on the absorber's hydrodynamic characteristics which are closely linked with the wave power conversion ability. For complex wetted surface, the hydrodynamic coefficients have been predicted traditionally by hydrodynamic software based on the BEM. However, for a systematic study of various parameters and geometries, they are too multifarious to generate so many models and data grids. This paper examines a semi-analytical method of decomposing the complex axisymmetric boundary into several ring-shaped and stepped surfaces based on the boundary discretization method(BDM) which overcomes the previous difficulties. In such case, by using the linear wave theory based on eigenfunction expansion matching method, the expressions of velocity potential in each domain, the added mass, radiation damping and wave excitation forces of the oscillating absorbers are obtained. The good astringency of the hydrodynamic coefficients and wave forces are obtained for various geometries when the discrete number reaches a certain value. The captured wave power for a same given draught and displacement for various geometries are calculated and compared. Numerical results show that the geometrical shape has great effect on the wave conversion performance of the absorber. For absorbers with the same outer radius and draught or displacement, the cylindrical type shows fantastic wave energy conversion ability at some given frequencies, while in the random sea wave, the parabolic and conical ones have better stabilization and applicability in wave power conversion. 展开更多
关键词 垂直 axisymmetric 复杂弄湿的表面 半分析的方法 收敛性 几何形状
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Catalytic Oxidative Coupling of 1-Phenyl-lH-tetrazole-5-thiol(HL)and Complex[Cu(I)6L6]with a Chair Configuration
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作者 TAN Di YANG Jun-wei +1 位作者 TONG Shan-ling YAN Yan 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 2010年第1期8-10,共3页
Both a persulfide crystal of L-L(1), the oxidative coupling product of 1-phenyl-1H-tetrazole-5-thiol(HL), and a neutral copper(I) complex of Cu6L6(2) were self-assembled and their crystal architectures were characteri... Both a persulfide crystal of L-L(1), the oxidative coupling product of 1-phenyl-1H-tetrazole-5-thiol(HL), and a neutral copper(I) complex of Cu6L6(2) were self-assembled and their crystal architectures were characterized by CCD method. HL was converted into the persulfide L-L(1) over a metalloporphyrin catalyst with enzymatic characters under ambient conditions. Whlie in the crystal architecture of Cu6L6(2), 6 copper(I) ions were ligated by 6L-anions to construct a Cu6 ring, which just resembled the chair configuration of cyclohexane. Notably, both compounds 1 and 2 exhibit strong photoluminescence in solid state. 展开更多
关键词 氧化偶联 HL型 催化剂 苯基 配置 巯基 四唑 LH
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