False data injection attack(FDIA)can affect the state estimation of the power grid by tampering with the measured value of the power grid data,and then destroying the stable operation of the smart grid.Existing work u...False data injection attack(FDIA)can affect the state estimation of the power grid by tampering with the measured value of the power grid data,and then destroying the stable operation of the smart grid.Existing work usually trains a detection model by fusing the data-driven features from diverse power data streams.Data-driven features,however,cannot effectively capture the differences between noisy data and attack samples.As a result,slight noise disturbances in the power grid may cause a large number of false detections for FDIA attacks.To address this problem,this paper designs a deep collaborative self-attention network to achieve robust FDIA detection,in which the spatio-temporal features of cascaded FDIA attacks are fully integrated.Firstly,a high-order Chebyshev polynomials-based graph convolution module is designed to effectively aggregate the spatio information between grid nodes,and the spatial self-attention mechanism is involved to dynamically assign attention weights to each node,which guides the network to pay more attention to the node information that is conducive to FDIA detection.Furthermore,the bi-directional Long Short-Term Memory(LSTM)network is introduced to conduct time series modeling and long-term dependence analysis for power grid data and utilizes the temporal selfattention mechanism to describe the time correlation of data and assign different weights to different time steps.Our designed deep collaborative network can effectively mine subtle perturbations from spatiotemporal feature information,efficiently distinguish power grid noise from FDIA attacks,and adapt to diverse attack intensities.Extensive experiments demonstrate that our method can obtain an efficient detection performance over actual load data from New York Independent System Operator(NYISO)in IEEE 14,IEEE 39,and IEEE 118 bus systems,and outperforms state-of-the-art FDIA detection schemes in terms of detection accuracy and robustness.展开更多
Under the policy background and advocacy of carbon capture,utilization,and storage(CCUS),CO_(2)-EOR has become a promising direction in the shale oil reservoir industry.The multi-scale pore structure distribution and ...Under the policy background and advocacy of carbon capture,utilization,and storage(CCUS),CO_(2)-EOR has become a promising direction in the shale oil reservoir industry.The multi-scale pore structure distribution and fracture structure lead to complex multiphase flow,comprehensively considering multiple mechanisms is crucial for development and CO_(2) storage in fractured shale reservoirs.In this paper,a multi-mechanism coupled model is developed by MATLAB.Compared to the traditional Eclipse300 and MATLAB Reservoir Simulation Toolbox(MRST),this model considers the impact of pore structure on fluid phase behavior by the modified Peng—Robinson equation of state(PR-EOS),and the effect simultaneously radiate to Maxwell—Stefan(M—S)diffusion,stress sensitivity,the nano-confinement(NC)effect.Moreover,a modified embedded discrete fracture model(EDFM)is used to model the complex fractures,which optimizes connection types and half-transmissibility calculation approaches between non-neighboring connections(NNCs).The full implicit equation adopts the finite volume method(FVM)and Newton—Raphson iteration for discretization and solution.The model verification with the Eclipse300 and MRST is satisfactory.The results show that the interaction between the mechanisms significantly affects the production performance and storage characteristics.The effect of molecular diffusion may be overestimated in oil-dominated(liquid-dominated)shale reservoirs.The well spacing and injection gas rate are the most crucial factors affecting the production by sensitivity analysis.Moreover,the potential gas invasion risk is mentioned.This model provides a reliable theoretical basis for CO_(2)-EOR and sequestration in shale oil reservoirs.展开更多
This study delves into the effects of shield tunneling in complex coastal strata, focusing on how this constructionmethod impacts surface settlement, the mechanical properties of adjacent rock, and the deformation of ...This study delves into the effects of shield tunneling in complex coastal strata, focusing on how this constructionmethod impacts surface settlement, the mechanical properties of adjacent rock, and the deformation of tunnelsegments. It investigates the impact of shield construction on surface settlement, mechanical characteristics ofnearby rock, and segment deformation in complex coastal strata susceptible to construction disturbances. Utilizingthe Fuzhou Binhai express line as a case study, we developed a comprehensive numerical model using theABAQUS finite element software. The model incorporates factors such as face force, grouting pressure, jack force,and cutterhead torque. Its accuracy is validated against field monitoring data from engineering projects. Simulationswere conducted to analyze ground settlement and mechanical changes in adjacent rock and segments acrossfive soil layers. The results indicate that disturbances are most significant near the excavation zone of the shieldmachine, with a prominent settlement trough forming and stabilizing around 2.0–3.0 D from the excavation. Theexcavation face compresses the soil, inducing lateral expansion. As grouting pressure decreases, the segmentexperiences upward buoyancy. In mixed strata, softer layers witness increased cutting, intensifying disturbancesbut reducing segment floatation. These findings offer valuable insights for predicting settlements, ensuring segmentand rock safety, and optimizing tunneling parameters.展开更多
The electromagnetic force, strong nuclear force, weak nuclear force, and gravitational force are the four fundamental forces of nature. The Standard Model (SM) succeeded in combining the first three forces to describe...The electromagnetic force, strong nuclear force, weak nuclear force, and gravitational force are the four fundamental forces of nature. The Standard Model (SM) succeeded in combining the first three forces to describe the most basic building blocks of matter and govern the universe. Despite the model’s great success in resolving many issues in particle physics but still has several setbacks and limitations. The model failed to incorporate the fourth force of gravity. It infers that all fermions and bosons are massless contrary to experimental facts. In addition, the model addresses neither the 95% of the universe’s energy of Dark Matter (DM) and Dark Energy (DE) nor the universe’s expansion. The Complex Field Theory (CFT) identifies DM and DE as complex fields of complex masses and charges that encompasses the whole universe, and pervade all matter. This presumption resolves the issue of failing to detect DM and DE for the last five decades. The theory also presents a model for the universe’s expansion and presumes that every material object carries a fraction of this complex field proportional to its mass. These premises clearly explain the physical nature of the gravitational force and its complex field and pave the way for gravity into the SM. On the other hand, to solve the issue of massless bosons and fermions in the SM, Higgs mechanism introduces a pure and abstractive theoretical model of unimaginable four potentials to generate fictitious bosons as mass donors to fermions and W± and Z bosons. The CFT in this paper introduces, for the first time, a physical explanation to the mystery of the mass formation of particles rather than Higgs’ pure mathematical derivations. The analyses lead to uncovering the mystery of electron-positron production near heavy nuclei and never in a vacuum. In addition, it puts a constraint on Einstein’s mass-energy equation that energy can never be converted to mass without the presence of dense dark matter and cannot be true in a vacuum. Furthermore, CFT provides different perspectives and resolves real-world physics concepts such as the nuclear force, Casimir force, Lamb’s shift, and the anomalous magnetic moment to be published elsewhere.展开更多
According to calculation results of ocean chlorophyll concentration based on SeaWiFS data by SeaBAM model and synchronous ship-measured data, this research set up an improved model for CaseⅠand CaseⅡwater bodies...According to calculation results of ocean chlorophyll concentration based on SeaWiFS data by SeaBAM model and synchronous ship-measured data, this research set up an improved model for CaseⅠand CaseⅡwater bodies respectively. The monthly chlorophyll distribution in the East China Sea in 1998 was obtained from this improved model on calculation results of SeaBAM. The euphotic depth distribution in 1998 in the East China Sea is calculated by using remote sensing data of K 490 from SeaWiFS according to the relation between the euphotic depth and the oceanic diffuse attenuation coefficient. With data of ocean chlorophyll concentration, euphotic depth, ocean surface photosynthetic available radiation (PAR), daily photoperiod and optimal rate of daily carbon fixation within a water column, the monthly and annual primary productivity spatio-temporal distributions in the East China Sea in 1998 were obtained based on VGPM model. Based on analysis of those distributions, the conclusion can be drawn that there is a clear bimodality character of primary productivity in the monthly distribution in the East China Sea. In detail, the monthly distribution of primary productivity stays the lowest level in winter and rises rapidly to the peak in spring. It gets down a little in summer, and gets up a little in autumn. The daily average of primary productivity in the whole East China Sea is 560.03 mg/m 2 /d, which is far higher than the average of subtropical ocean areas. The annual average of primary productivity is 236.95 g/m 2 /a. The research on the seasonal variety mechanism of primary productivity shows that several factors that affect the spatio-temporal distribution may include the chlorophyll concentration distribution, temperature condition, the Yangtze River diluted water variety, the euphotic depth, ocean current variety, etc. But the main influencing factors may be different in each local sea area.展开更多
Based on abundant aftershock sequence data of the Wenchuan Ms8.0 earthquake on May 12, 2008, we studied the spatio-temporal variation process and segmentation rupture characteristic. Dense aftershocks distribute along...Based on abundant aftershock sequence data of the Wenchuan Ms8.0 earthquake on May 12, 2008, we studied the spatio-temporal variation process and segmentation rupture characteristic. Dense aftershocks distribute along Longmenshan central fault zone of NE direction and form a narrow strip with the length of 325 krn and the depth between several and 40 km. The depth profile (section of NW direction) vertical to the strike of aftershock zone (NE direction) shows anisomerous wedgy distribution characteristic of afiershock concentrated regions; it is related to the force form of the Longmenshan nappe tectonic belt. The stronger aftershocks could be divided into northern segment and southern segment apparently and the focal depths of strong aftershocks in the 50 km area between northern segment and southern segment are shallower. It seems like 'to be going to rupture' segment. We also study focal mechanisms and segmentation of strong aftershocks. The principal compressive stress azimuth of aftershock area is WNW direction and the faulting types of aftershocks at southern and northern segment have the same proportion. Because afiershocks distribute on different secondary faults, their focal mechanisms present complex local tectonic stress field. The faulting of seven strong earthquakes on the Longmenshan central fault is mainly characterized by thrust with the component of right-lateral strike-slip. Meantime six strong aftershocks on the Longmenshan back-range fault and Qingchuan fault present strike-slip faulting. At last we discuss the complex segmentation rupture mechanism of the Wenchuan earthquake.展开更多
With the advent of the era of big data and artificial intelligence, new infrastructure construction(NIC) has attracted the attention of many countries. The development of NIC provides an opportunity to bridge the digi...With the advent of the era of big data and artificial intelligence, new infrastructure construction(NIC) has attracted the attention of many countries. The development of NIC provides an opportunity to bridge the digital divide and narrow the regional gap,providing continuous impetus to further promote economic development. Here, we considered 31 provincial-level administrative units in China(not including Hong Kong, Macao, and Taiwan of China due to data unavailable) and established comprehensive evaluation indicators for the development potential of NIC. Afterward, we used the entropy-weight TOPSIS model to determine the development potential of NIC and analyze its spatio-temporal evolution characteristics. Furthermore, the GeoDetector model was applied to explore the driving mechanism of the NIC development potential. The conclusions were as follows: (1) The Chinese NIC development potential is generally low. The eastern China was the region with the highest development potential year by year, while the development potential in the central China was found to be in an accelerating phase. (2) The evolution of the Chinese NIC development potential’s spatial pattern has been characterized by an inland extension and coastal agglomeration. Moreover, we identified a superior development zone, a rising development zone, an inferior development zone, and a declining development zone. (3) The scope of Chinese NIC development potential agglomeration areas has gradually expanded and its degree has gradually deepened. The range of high-value agglomeration in eastern area gradually expanded and its degree gradually deepened. (4) Investment in innovative talents appears as the core factor affecting the Chinese NIC development potential. Whether acting alone or synergistically with other factors, its promoting effect on Chinese NIC development potential is the strongest.展开更多
The application of the parallel mechanism is still limited in the humanoid robot fields, and the existing parallel humanoid robot joint has not yet been reflected the characteristics of the parallel mechanism complete...The application of the parallel mechanism is still limited in the humanoid robot fields, and the existing parallel humanoid robot joint has not yet been reflected the characteristics of the parallel mechanism completely, also failed to solve the problem, such as small workspace, effectively. From the structural and functional bionic point of view, a three degrees of freedom(DOFs) spherical parallel mechanism for the shoulder complex of the humanoid robot is presented. According to the structure and kinetic characteristics analysis of the human shoulder complex, 3-PSS/S(P for prismatic pair, S for spherical pair) is chosen as the original configuration for the shouder complex. Using genetic algorithm, the optimization of the 3-PSS/S spherical parallel mechanism is performed, and the orientation workspace of the prototype mechanism is enlarged obviously. Combining the practical structure characteristics of the human shouder complex, an offset output mode, which means the output rod of the mechanism turn to any direction at the point a certain distance from the rotation center of the mechanism, is put forward, which provide possibility for the consistent of the workspace of the mechanism and the actual motion space of the human body shoulder joint. The relationship of the attitude angles between different coordinate system is derived, which establishs the foundation for the motion descriptions under different conditions and control development. The 3-PSS/S spherical parallel mechanism is proposed for the shoulder complex, and the consistence of the workspace of the mechanism and the human shoulder complex is realized by the stuctural parameter optimization and the offset output design.展开更多
: The kinematic vorticity number and strain of the mylonitic zone related to the detachment fault increase from ESE to WNW along the moving direction of the upper plate of the Xiaoqinling metamorphic core complex (XMC...: The kinematic vorticity number and strain of the mylonitic zone related to the detachment fault increase from ESE to WNW along the moving direction of the upper plate of the Xiaoqinling metamorphic core complex (XMCC) and the geometry of quartz c-axis fabrics changes progressively from crossed girdles to single girdles in the same direction. Therefore, pure shear is dominant in the ESE part of the XMCC while simple shear becomes increasingly important towards WNW. However, the shear type does not change with the strain across the shear zone, thus the variation of shear type is of significance in indicating the formation mechanism. The granitic plutons within the XMCC came from the deep source and their emplacement was an active and forceful upwelling prior to the detachment faulting. The PTt path demonstrates that magmatism is an important cause for the formation of the XMCC. The formation mechanism of the XMCC is supposed to be active plutonism and passive detachment. Crustal thickening and magmatic doming caused necking extension with pure shear, and magmatic heating and doming resulted in detachment extension with simple shear and formed the XMCC.展开更多
The aerospace community widely uses difficult-to-cut materials,such as titanium alloys,high-temperature alloys,metal/ceramic/polymer matrix composites,hard and brittle materials,and geometrically complex components,su...The aerospace community widely uses difficult-to-cut materials,such as titanium alloys,high-temperature alloys,metal/ceramic/polymer matrix composites,hard and brittle materials,and geometrically complex components,such as thin-walled structures,microchannels,and complex surfaces.Mechanical machining is the main material removal process for the vast majority of aerospace components.However,many problems exist,including severe and rapid tool wear,low machining efficiency,and poor surface integrity.Nontraditional energy-assisted mechanical machining is a hybrid process that uses nontraditional energies(vibration,laser,electricity,etc)to improve the machinability of local materials and decrease the burden of mechanical machining.This provides a feasible and promising method to improve the material removal rate and surface quality,reduce process forces,and prolong tool life.However,systematic reviews of this technology are lacking with respect to the current research status and development direction.This paper reviews the recent progress in the nontraditional energy-assisted mechanical machining of difficult-to-cut materials and components in the aerospace community.In addition,this paper focuses on the processing principles,material responses under nontraditional energy,resultant forces and temperatures,material removal mechanisms,and applications of these processes,including vibration-,laser-,electric-,magnetic-,chemical-,advanced coolant-,and hybrid nontraditional energy-assisted mechanical machining.Finally,a comprehensive summary of the principles,advantages,and limitations of each hybrid process is provided,and future perspectives on forward design,device development,and sustainability of nontraditional energy-assisted mechanical machining processes are discussed.展开更多
The inclusion-complex of CD-MCP (β-cyclodextrin (β-CD) including 1-methylcyclopropene (1-MCP)) was prepared and characterized. Basing on programmed-heating procedure and weight-temperature analysis, as well as...The inclusion-complex of CD-MCP (β-cyclodextrin (β-CD) including 1-methylcyclopropene (1-MCP)) was prepared and characterized. Basing on programmed-heating procedure and weight-temperature analysis, as well as the application of Satava-Sestak's, Ozawa's and Kissinger's methods, the mechanism and kinetics of thermal dissociation of this inclusion complex were studied. An additional mass loss is found at 170-180℃. The mechanism of thermal dissociation of CD-MCP is dominated by a one-dimensional random nucleation and subsequent growth process (A2/3). The activation energy Es and the pre-exponential factor AS for the process are 102.14 kJ/mol and 3.63×10^10s^-1, respectively. This ES value shows that there is no strong chemical intere, ctions between β-CD and 1-MC;P,展开更多
The Tangba high slope is mainly composed of coarse soils and supplies core wall materials for the construction of the Changheba dam. Since the filling intensity of the Changheba dam is high, the Tangba high slope suff...The Tangba high slope is mainly composed of coarse soils and supplies core wall materials for the construction of the Changheba dam. Since the filling intensity of the Changheba dam is high, the Tangba high slope suffers from a high-intensity excavation process, and reinforcement measures are usually not implemented immediately. Moreover, the distribution of useful materials is uneven and insufficient, and the mixing of different soil materials is necessary; thus, multiple simultaneous excavations and secondary excavation are inevitable. In the construction period from 2012 to 2016, large deformations occurred in this area, and one of the largest monitored horizontal deformations whose direction points to the opposite side of the valley even reached more than 8000 mm. According to field investigation, site monitoring and theoretical analysis, the large deformation in the Tangba high slope can be divided into two phases. In the first phase, the excavation construction breaks the original stress equilibrium state; in the second phase, the precipitation infiltration accelerates the deformation. Thus, the excavation construction and precipitation infiltration are the two major factors promoting the deformation, and the high-intensity and complex excavation process is the fundamental cause. Notably, rate of slope deformation significantly accelerated in rainy seasons due to precipitation infiltration; the rate also accelerated in early 2016 due to the high-intensity, complex excavation process. Comprehensively considering the above factors, timely and effective reinforcement measures are essential.展开更多
Soft rocks, such as coal, are afected by sedimentary efects, and the surrounding rock mass of underground coal mines is generally soft and rich in joints and cracks. A clear and deep understanding of the relationship ...Soft rocks, such as coal, are afected by sedimentary efects, and the surrounding rock mass of underground coal mines is generally soft and rich in joints and cracks. A clear and deep understanding of the relationship between crack geometric parameters and rock mechanics properties in cracked rock is greatly important to the design of engineering rock mass struc‑tures. In this study, computed tomography (CT) scanning was used to extract the internal crack network of coal specimens. Based on the crack size and dominant crack number, the parameters of crack area, volume, length, width, and angle were statistically analyzed by diferent sampling thresholds. In addition, the Pearson correlation coefcients between the crack parameters and uniaxial compression rock mechanics properties (uniaxial compressive strength UCS, elasticity modulus E) were calculated to quantitatively analyze the impact of each parameter. Furthermore, a method based on Pearson coefcients was used to grade the correlation between crack geometric parameters and rock mechanical properties to determine threshold values. The results indicated that the UCS and E of the specimens changed with the varied internal crack structures of the specimens, the crack parameters of area, volume, length and width all showed negative correlations with UCS and E, and the dominant crack played an important role both in weakening strength and stifness. The crack parameters of the angle are all positively correlated with the UCS and E. More crack statistics can signifcantly improve the correlation between the parameters of the crack angle and the rock mechanics properties, and the statistics of the geometric parameters of at least 16 cracks or the area larger than 5 mm2 are suggested for the analysis of complex cracked rock masses or physical reproduction using 3D printing. The results are validated and further analyzed with triaxial tests. The fndings of this study have important reference value for future research regarding the accurate and efcient selection of a few cracks with a signifcant infuence on the rock mechanical properties of surrounding rock mass structures in coal engineering.展开更多
The inclusion complex of β-cyclodextrin (β-CD) and sulfurized isobutylene (T321) was prepared with a co-precipitation method. The tribological properties of the complex with different concentrations were investigate...The inclusion complex of β-cyclodextrin (β-CD) and sulfurized isobutylene (T321) was prepared with a co-precipitation method. The tribological properties of the complex with different concentrations were investigated by a four-ball tester in the solution of polyethylene glycol-600 (PEG-600). The experimental results suggest that the complex exhibits better anti-friction and anti-wear properties than β-CD under different load conditions. The tribo-system shows the least friction coefficient when the concentration of the complex is 0.8%. During the friction process, the complex was decomposed into various molecular fragments and the T321 molecules were released onto the friction interface to provide effective lubrication. The XPS analytical results on the worn surfaces reveal that sulfide film formed by the released T321 plays a major role, and the iron alkoxide and carbon deposition films formed by the β-CD fragments have better anti-friction effect on the sulfide film surface. The interactions of different films result in the formation of a mixed boundary lubrication film.展开更多
The title complex, Zn(C24H13NO)2Cl21, has been synthesized by the reaction of zinc chloride with Schiff base ligand N-salicylidene-p-toluidine and its structure was determined by single-crystal X-ray diffraction. Th...The title complex, Zn(C24H13NO)2Cl21, has been synthesized by the reaction of zinc chloride with Schiff base ligand N-salicylidene-p-toluidine and its structure was determined by single-crystal X-ray diffraction. The crystal is of monoclinic, space group Cc with a = 14.896(3), b = 12.506(2), c = 15.352(3) A,β = 114.711 (4)°, V = 2598.0(8) A^3, C28H26ZnCl2N2O2, Mr = 558.80, Z = 4, Dc = 1 .429 g/cm^3,μ = 1.179 mm^-1, Flack parameter = 0.027(19), F(000) = 1152, R = 0.0709 and wR = 0.1041 for 3117 observed reflections (Ⅰ 〉 2σ(Ⅰ)). In complex 1, the center Zn ion is four-coordinated by two O atoms from two Schiff base ligands and two Cl atoms in a distorted tetrahedral geometry. Additionally, the thermal decomposition of complex 1 as well as its kinetic mechanisms and equations is studied under the non-isothermal integral and differential methods in air by TG-DTG curves.展开更多
The inclusion complex of fl-cyclodextrin (β-CD) and sulfurized isobutylene (T321) was prepared with a co-precipitation method. The tribological properties of the complex with different concentrations were investi...The inclusion complex of fl-cyclodextrin (β-CD) and sulfurized isobutylene (T321) was prepared with a co-precipitation method. The tribological properties of the complex with different concentrations were investigated by a four-ball tester in the solution of polyethylene glycol-600 (PEG-600). The experimental results suggest that the complex exhibits better anti-friction and anti-wear properties than fl-CD under different load conditions. The tribo-system shows the least friction coefficient when the concentration of the complex is 0.8%. During the friction process, the complex was decomposed into various molecular fragments and the T321 molecules were released onto the friction interface to provide effective lubrication. The XPS analytical results on the worn surfaces reveal that sulfide film formed by the released T321 plays a major role, and the iron alkoxide and carbon deposition films formed by the β-CD fragments have better anti-friction effect on the sulfide film surface. The interactions of different films result in the formation of a mixed boundary lubrication film.展开更多
The present study addresses the problem of fault estimation for a specific class of nonlinear time-varying complex networks,utilizing an unknown-input-observer approach within the framework of dynamic event-triggered ...The present study addresses the problem of fault estimation for a specific class of nonlinear time-varying complex networks,utilizing an unknown-input-observer approach within the framework of dynamic event-triggered mechanism(DETM).In order to optimize communication resource utilization,the DETM is employed to determine whether the current measurement data should be transmitted to the estimator or not.To guarantee a satisfactory estimation performance for the fault signal,an unknown-input-observer-based estimator is constructed to decouple the estimation error dynamics from the influence of fault signals.The aim of this paper is to find the suitable estimator parameters under the effects of DETM such that both the state estimates and fault estimates are confined within two sets of closed ellipsoid domains.The techniques of recursive matrix inequality are applied to derive sufficient conditions for the existence of the desired estimator,ensuring that the specified performance requirements are met under certain conditions.Then,the estimator gains are derived by minimizing the ellipsoid domain in the sense of trace and a recursive estimator parameter design algorithm is then provided.Finally,a numerical example is conducted to demonstrate the effectiveness of the designed estimator.展开更多
On the basis of the detailed field work, compositions and contents of plagioclase and K - feldspar,determination of ordering degree, statistical analysis of plagioclase elongation index, mass-balance calculation and m...On the basis of the detailed field work, compositions and contents of plagioclase and K - feldspar,determination of ordering degree, statistical analysis of plagioclase elongation index, mass-balance calculation and mineral spatial distribution and geochemistry, it is concluded that the migmatites in the Dabie complex are characterized by the presence of thermocenters. There are regular changes in mineral character in the migmatites from the centers outwards. The dominant genetic mechanism is anatexis and metasomatism, whose intensities decrease from the centers outwards. Finally, according to the simulated experiment on Liesegang' s rings and non-linear dynamics (dissipative structure theory), the dynamic mechanism of migmatization is profoundly expouded as consisting of the early-stage metasomatism induced by the thermal anomaly, the cardinal-stage anatexis induced by the early-stage matasomatism and finally the last-stage post-anatexis metasomatism.展开更多
The general-linear-complex singularity of Stewart mechanism is a veryimportant problem in the parallel manipulator. Its general regularity is not found yet during thepast two decades. St-Onge and Gosselin pointed Out ...The general-linear-complex singularity of Stewart mechanism is a veryimportant problem in the parallel manipulator. Its general regularity is not found yet during thepast two decades. St-Onge and Gosselin pointed Out that the singularity locus of the Stewartmechanism at some given orientations of the moving platform should be polynomial expressions withvaried degrees in 2000, but they didn't formulate the expression. Based on the kinematicssingularity principle and the geometry condition proposed by Huang Zhen in 1999, firstly thesingularity equation in degree two is derived. It is a hyperbola when the orientation of the movingplatform is given. This result is also proved using screw theory. Then some singularity surfaces aregotten in three-dimensional space. This result is of important significance.展开更多
The salicylaldehyde salicylhydrazone and its complex of Er(Ⅲ) were synthesized. The formulae K·4H_2O(HL=[C_(14)H_(10)N_2O_3]^(2-), the bivalent form of the salicylaldehyde salicylhydrazone) were determined by el...The salicylaldehyde salicylhydrazone and its complex of Er(Ⅲ) were synthesized. The formulae K·4H_2O(HL=[C_(14)H_(10)N_2O_3]^(2-), the bivalent form of the salicylaldehyde salicylhydrazone) were determined by elemental analysis and EDTA volumetric analysis. Molar conductance, IR, UV and X-ray power diffraction were carried out for the characterizations of the complex and the ligand. There are two stable five-numbered and six-numbered circles in the complex. The thermal decompositions of the ligand and the complex with the kinetic study are carried out by non-isothermal thermogravimetry. The stages of the decompositions were identified by TG-DTG curve. The non-isothermal kinetic data were analyzed by means of integral and differential methods. The possible reaction mechanism and the kinetic equation were investigated by the corresponding kinetic parameters.The activation energy value of the main step decomposition are also calculated by Kissinger′s method and Ozawa′s method.展开更多
基金supported in part by the Research Fund of Guangxi Key Lab of Multi-Source Information Mining&Security(MIMS21-M-02).
文摘False data injection attack(FDIA)can affect the state estimation of the power grid by tampering with the measured value of the power grid data,and then destroying the stable operation of the smart grid.Existing work usually trains a detection model by fusing the data-driven features from diverse power data streams.Data-driven features,however,cannot effectively capture the differences between noisy data and attack samples.As a result,slight noise disturbances in the power grid may cause a large number of false detections for FDIA attacks.To address this problem,this paper designs a deep collaborative self-attention network to achieve robust FDIA detection,in which the spatio-temporal features of cascaded FDIA attacks are fully integrated.Firstly,a high-order Chebyshev polynomials-based graph convolution module is designed to effectively aggregate the spatio information between grid nodes,and the spatial self-attention mechanism is involved to dynamically assign attention weights to each node,which guides the network to pay more attention to the node information that is conducive to FDIA detection.Furthermore,the bi-directional Long Short-Term Memory(LSTM)network is introduced to conduct time series modeling and long-term dependence analysis for power grid data and utilizes the temporal selfattention mechanism to describe the time correlation of data and assign different weights to different time steps.Our designed deep collaborative network can effectively mine subtle perturbations from spatiotemporal feature information,efficiently distinguish power grid noise from FDIA attacks,and adapt to diverse attack intensities.Extensive experiments demonstrate that our method can obtain an efficient detection performance over actual load data from New York Independent System Operator(NYISO)in IEEE 14,IEEE 39,and IEEE 118 bus systems,and outperforms state-of-the-art FDIA detection schemes in terms of detection accuracy and robustness.
基金supported by the National Natural Science Foundation of China(No.52174038 and No.52004307)China Petroleum Science and Technology Project-Major Project-Research on Tight Oil-Shale Oil Reservoir Engineering Methods and Key Technologies in Ordos Basin(No.ZLZX2020-02-04)Science Foundation of China University of Petroleum,Beijing(No.2462018YJRC015)。
文摘Under the policy background and advocacy of carbon capture,utilization,and storage(CCUS),CO_(2)-EOR has become a promising direction in the shale oil reservoir industry.The multi-scale pore structure distribution and fracture structure lead to complex multiphase flow,comprehensively considering multiple mechanisms is crucial for development and CO_(2) storage in fractured shale reservoirs.In this paper,a multi-mechanism coupled model is developed by MATLAB.Compared to the traditional Eclipse300 and MATLAB Reservoir Simulation Toolbox(MRST),this model considers the impact of pore structure on fluid phase behavior by the modified Peng—Robinson equation of state(PR-EOS),and the effect simultaneously radiate to Maxwell—Stefan(M—S)diffusion,stress sensitivity,the nano-confinement(NC)effect.Moreover,a modified embedded discrete fracture model(EDFM)is used to model the complex fractures,which optimizes connection types and half-transmissibility calculation approaches between non-neighboring connections(NNCs).The full implicit equation adopts the finite volume method(FVM)and Newton—Raphson iteration for discretization and solution.The model verification with the Eclipse300 and MRST is satisfactory.The results show that the interaction between the mechanisms significantly affects the production performance and storage characteristics.The effect of molecular diffusion may be overestimated in oil-dominated(liquid-dominated)shale reservoirs.The well spacing and injection gas rate are the most crucial factors affecting the production by sensitivity analysis.Moreover,the potential gas invasion risk is mentioned.This model provides a reliable theoretical basis for CO_(2)-EOR and sequestration in shale oil reservoirs.
文摘This study delves into the effects of shield tunneling in complex coastal strata, focusing on how this constructionmethod impacts surface settlement, the mechanical properties of adjacent rock, and the deformation of tunnelsegments. It investigates the impact of shield construction on surface settlement, mechanical characteristics ofnearby rock, and segment deformation in complex coastal strata susceptible to construction disturbances. Utilizingthe Fuzhou Binhai express line as a case study, we developed a comprehensive numerical model using theABAQUS finite element software. The model incorporates factors such as face force, grouting pressure, jack force,and cutterhead torque. Its accuracy is validated against field monitoring data from engineering projects. Simulationswere conducted to analyze ground settlement and mechanical changes in adjacent rock and segments acrossfive soil layers. The results indicate that disturbances are most significant near the excavation zone of the shieldmachine, with a prominent settlement trough forming and stabilizing around 2.0–3.0 D from the excavation. Theexcavation face compresses the soil, inducing lateral expansion. As grouting pressure decreases, the segmentexperiences upward buoyancy. In mixed strata, softer layers witness increased cutting, intensifying disturbancesbut reducing segment floatation. These findings offer valuable insights for predicting settlements, ensuring segmentand rock safety, and optimizing tunneling parameters.
文摘The electromagnetic force, strong nuclear force, weak nuclear force, and gravitational force are the four fundamental forces of nature. The Standard Model (SM) succeeded in combining the first three forces to describe the most basic building blocks of matter and govern the universe. Despite the model’s great success in resolving many issues in particle physics but still has several setbacks and limitations. The model failed to incorporate the fourth force of gravity. It infers that all fermions and bosons are massless contrary to experimental facts. In addition, the model addresses neither the 95% of the universe’s energy of Dark Matter (DM) and Dark Energy (DE) nor the universe’s expansion. The Complex Field Theory (CFT) identifies DM and DE as complex fields of complex masses and charges that encompasses the whole universe, and pervade all matter. This presumption resolves the issue of failing to detect DM and DE for the last five decades. The theory also presents a model for the universe’s expansion and presumes that every material object carries a fraction of this complex field proportional to its mass. These premises clearly explain the physical nature of the gravitational force and its complex field and pave the way for gravity into the SM. On the other hand, to solve the issue of massless bosons and fermions in the SM, Higgs mechanism introduces a pure and abstractive theoretical model of unimaginable four potentials to generate fictitious bosons as mass donors to fermions and W± and Z bosons. The CFT in this paper introduces, for the first time, a physical explanation to the mystery of the mass formation of particles rather than Higgs’ pure mathematical derivations. The analyses lead to uncovering the mystery of electron-positron production near heavy nuclei and never in a vacuum. In addition, it puts a constraint on Einstein’s mass-energy equation that energy can never be converted to mass without the presence of dense dark matter and cannot be true in a vacuum. Furthermore, CFT provides different perspectives and resolves real-world physics concepts such as the nuclear force, Casimir force, Lamb’s shift, and the anomalous magnetic moment to be published elsewhere.
基金The Key National Project for the Ninth Five-Year PlanNo.HY126-06-04-04
文摘According to calculation results of ocean chlorophyll concentration based on SeaWiFS data by SeaBAM model and synchronous ship-measured data, this research set up an improved model for CaseⅠand CaseⅡwater bodies respectively. The monthly chlorophyll distribution in the East China Sea in 1998 was obtained from this improved model on calculation results of SeaBAM. The euphotic depth distribution in 1998 in the East China Sea is calculated by using remote sensing data of K 490 from SeaWiFS according to the relation between the euphotic depth and the oceanic diffuse attenuation coefficient. With data of ocean chlorophyll concentration, euphotic depth, ocean surface photosynthetic available radiation (PAR), daily photoperiod and optimal rate of daily carbon fixation within a water column, the monthly and annual primary productivity spatio-temporal distributions in the East China Sea in 1998 were obtained based on VGPM model. Based on analysis of those distributions, the conclusion can be drawn that there is a clear bimodality character of primary productivity in the monthly distribution in the East China Sea. In detail, the monthly distribution of primary productivity stays the lowest level in winter and rises rapidly to the peak in spring. It gets down a little in summer, and gets up a little in autumn. The daily average of primary productivity in the whole East China Sea is 560.03 mg/m 2 /d, which is far higher than the average of subtropical ocean areas. The annual average of primary productivity is 236.95 g/m 2 /a. The research on the seasonal variety mechanism of primary productivity shows that several factors that affect the spatio-temporal distribution may include the chlorophyll concentration distribution, temperature condition, the Yangtze River diluted water variety, the euphotic depth, ocean current variety, etc. But the main influencing factors may be different in each local sea area.
基金supported by National Key Basic Research 973bNational Scientific Technology Support Plan (2006BAC01B02-01-01).
文摘Based on abundant aftershock sequence data of the Wenchuan Ms8.0 earthquake on May 12, 2008, we studied the spatio-temporal variation process and segmentation rupture characteristic. Dense aftershocks distribute along Longmenshan central fault zone of NE direction and form a narrow strip with the length of 325 krn and the depth between several and 40 km. The depth profile (section of NW direction) vertical to the strike of aftershock zone (NE direction) shows anisomerous wedgy distribution characteristic of afiershock concentrated regions; it is related to the force form of the Longmenshan nappe tectonic belt. The stronger aftershocks could be divided into northern segment and southern segment apparently and the focal depths of strong aftershocks in the 50 km area between northern segment and southern segment are shallower. It seems like 'to be going to rupture' segment. We also study focal mechanisms and segmentation of strong aftershocks. The principal compressive stress azimuth of aftershock area is WNW direction and the faulting types of aftershocks at southern and northern segment have the same proportion. Because afiershocks distribute on different secondary faults, their focal mechanisms present complex local tectonic stress field. The faulting of seven strong earthquakes on the Longmenshan central fault is mainly characterized by thrust with the component of right-lateral strike-slip. Meantime six strong aftershocks on the Longmenshan back-range fault and Qingchuan fault present strike-slip faulting. At last we discuss the complex segmentation rupture mechanism of the Wenchuan earthquake.
文摘With the advent of the era of big data and artificial intelligence, new infrastructure construction(NIC) has attracted the attention of many countries. The development of NIC provides an opportunity to bridge the digital divide and narrow the regional gap,providing continuous impetus to further promote economic development. Here, we considered 31 provincial-level administrative units in China(not including Hong Kong, Macao, and Taiwan of China due to data unavailable) and established comprehensive evaluation indicators for the development potential of NIC. Afterward, we used the entropy-weight TOPSIS model to determine the development potential of NIC and analyze its spatio-temporal evolution characteristics. Furthermore, the GeoDetector model was applied to explore the driving mechanism of the NIC development potential. The conclusions were as follows: (1) The Chinese NIC development potential is generally low. The eastern China was the region with the highest development potential year by year, while the development potential in the central China was found to be in an accelerating phase. (2) The evolution of the Chinese NIC development potential’s spatial pattern has been characterized by an inland extension and coastal agglomeration. Moreover, we identified a superior development zone, a rising development zone, an inferior development zone, and a declining development zone. (3) The scope of Chinese NIC development potential agglomeration areas has gradually expanded and its degree has gradually deepened. The range of high-value agglomeration in eastern area gradually expanded and its degree gradually deepened. (4) Investment in innovative talents appears as the core factor affecting the Chinese NIC development potential. Whether acting alone or synergistically with other factors, its promoting effect on Chinese NIC development potential is the strongest.
基金Supported by National Natural Science Foundation of China(Grant No.51275443)Key Project of Ministry of Education of China(Grant No.212012)+2 种基金Hebei Provincial Natural Science Foundation of China(Grant No.E2012203034)Specialized Research Fund for the Doctoral Program of Higher Education of China(Grant No.20111333120004)Research Fund for Outstanding Youth in Higher Education Institutions of Hebei Province,China(Grant No.Y2011114)
文摘The application of the parallel mechanism is still limited in the humanoid robot fields, and the existing parallel humanoid robot joint has not yet been reflected the characteristics of the parallel mechanism completely, also failed to solve the problem, such as small workspace, effectively. From the structural and functional bionic point of view, a three degrees of freedom(DOFs) spherical parallel mechanism for the shoulder complex of the humanoid robot is presented. According to the structure and kinetic characteristics analysis of the human shoulder complex, 3-PSS/S(P for prismatic pair, S for spherical pair) is chosen as the original configuration for the shouder complex. Using genetic algorithm, the optimization of the 3-PSS/S spherical parallel mechanism is performed, and the orientation workspace of the prototype mechanism is enlarged obviously. Combining the practical structure characteristics of the human shouder complex, an offset output mode, which means the output rod of the mechanism turn to any direction at the point a certain distance from the rotation center of the mechanism, is put forward, which provide possibility for the consistent of the workspace of the mechanism and the actual motion space of the human body shoulder joint. The relationship of the attitude angles between different coordinate system is derived, which establishs the foundation for the motion descriptions under different conditions and control development. The 3-PSS/S spherical parallel mechanism is proposed for the shoulder complex, and the consistence of the workspace of the mechanism and the human shoulder complex is realized by the stuctural parameter optimization and the offset output design.
文摘: The kinematic vorticity number and strain of the mylonitic zone related to the detachment fault increase from ESE to WNW along the moving direction of the upper plate of the Xiaoqinling metamorphic core complex (XMCC) and the geometry of quartz c-axis fabrics changes progressively from crossed girdles to single girdles in the same direction. Therefore, pure shear is dominant in the ESE part of the XMCC while simple shear becomes increasingly important towards WNW. However, the shear type does not change with the strain across the shear zone, thus the variation of shear type is of significance in indicating the formation mechanism. The granitic plutons within the XMCC came from the deep source and their emplacement was an active and forceful upwelling prior to the detachment faulting. The PTt path demonstrates that magmatism is an important cause for the formation of the XMCC. The formation mechanism of the XMCC is supposed to be active plutonism and passive detachment. Crustal thickening and magmatic doming caused necking extension with pure shear, and magmatic heating and doming resulted in detachment extension with simple shear and formed the XMCC.
基金supported by the National Natural Science Foundation of China(Nos.52075255,92160301,52175415,52205475,and 92060203)。
文摘The aerospace community widely uses difficult-to-cut materials,such as titanium alloys,high-temperature alloys,metal/ceramic/polymer matrix composites,hard and brittle materials,and geometrically complex components,such as thin-walled structures,microchannels,and complex surfaces.Mechanical machining is the main material removal process for the vast majority of aerospace components.However,many problems exist,including severe and rapid tool wear,low machining efficiency,and poor surface integrity.Nontraditional energy-assisted mechanical machining is a hybrid process that uses nontraditional energies(vibration,laser,electricity,etc)to improve the machinability of local materials and decrease the burden of mechanical machining.This provides a feasible and promising method to improve the material removal rate and surface quality,reduce process forces,and prolong tool life.However,systematic reviews of this technology are lacking with respect to the current research status and development direction.This paper reviews the recent progress in the nontraditional energy-assisted mechanical machining of difficult-to-cut materials and components in the aerospace community.In addition,this paper focuses on the processing principles,material responses under nontraditional energy,resultant forces and temperatures,material removal mechanisms,and applications of these processes,including vibration-,laser-,electric-,magnetic-,chemical-,advanced coolant-,and hybrid nontraditional energy-assisted mechanical machining.Finally,a comprehensive summary of the principles,advantages,and limitations of each hybrid process is provided,and future perspectives on forward design,device development,and sustainability of nontraditional energy-assisted mechanical machining processes are discussed.
文摘The inclusion-complex of CD-MCP (β-cyclodextrin (β-CD) including 1-methylcyclopropene (1-MCP)) was prepared and characterized. Basing on programmed-heating procedure and weight-temperature analysis, as well as the application of Satava-Sestak's, Ozawa's and Kissinger's methods, the mechanism and kinetics of thermal dissociation of this inclusion complex were studied. An additional mass loss is found at 170-180℃. The mechanism of thermal dissociation of CD-MCP is dominated by a one-dimensional random nucleation and subsequent growth process (A2/3). The activation energy Es and the pre-exponential factor AS for the process are 102.14 kJ/mol and 3.63×10^10s^-1, respectively. This ES value shows that there is no strong chemical intere, ctions between β-CD and 1-MC;P,
基金the support of the National Key R&D Program of China(2017YFC1501102)the Youth Science and Technology Fund of Sichuan Province(2016JQ0011)the Key Project of the Power Construction Corporation of China(ZDZX-5)
文摘The Tangba high slope is mainly composed of coarse soils and supplies core wall materials for the construction of the Changheba dam. Since the filling intensity of the Changheba dam is high, the Tangba high slope suffers from a high-intensity excavation process, and reinforcement measures are usually not implemented immediately. Moreover, the distribution of useful materials is uneven and insufficient, and the mixing of different soil materials is necessary; thus, multiple simultaneous excavations and secondary excavation are inevitable. In the construction period from 2012 to 2016, large deformations occurred in this area, and one of the largest monitored horizontal deformations whose direction points to the opposite side of the valley even reached more than 8000 mm. According to field investigation, site monitoring and theoretical analysis, the large deformation in the Tangba high slope can be divided into two phases. In the first phase, the excavation construction breaks the original stress equilibrium state; in the second phase, the precipitation infiltration accelerates the deformation. Thus, the excavation construction and precipitation infiltration are the two major factors promoting the deformation, and the high-intensity and complex excavation process is the fundamental cause. Notably, rate of slope deformation significantly accelerated in rainy seasons due to precipitation infiltration; the rate also accelerated in early 2016 due to the high-intensity, complex excavation process. Comprehensively considering the above factors, timely and effective reinforcement measures are essential.
基金supported by the Young Scientist Project of National Key Research and Development Program of China(2021YFC2900600)National Natural Science Foundation of China(52074166)Shandong Province(ZR2021YQ38).
文摘Soft rocks, such as coal, are afected by sedimentary efects, and the surrounding rock mass of underground coal mines is generally soft and rich in joints and cracks. A clear and deep understanding of the relationship between crack geometric parameters and rock mechanics properties in cracked rock is greatly important to the design of engineering rock mass struc‑tures. In this study, computed tomography (CT) scanning was used to extract the internal crack network of coal specimens. Based on the crack size and dominant crack number, the parameters of crack area, volume, length, width, and angle were statistically analyzed by diferent sampling thresholds. In addition, the Pearson correlation coefcients between the crack parameters and uniaxial compression rock mechanics properties (uniaxial compressive strength UCS, elasticity modulus E) were calculated to quantitatively analyze the impact of each parameter. Furthermore, a method based on Pearson coefcients was used to grade the correlation between crack geometric parameters and rock mechanical properties to determine threshold values. The results indicated that the UCS and E of the specimens changed with the varied internal crack structures of the specimens, the crack parameters of area, volume, length and width all showed negative correlations with UCS and E, and the dominant crack played an important role both in weakening strength and stifness. The crack parameters of the angle are all positively correlated with the UCS and E. More crack statistics can signifcantly improve the correlation between the parameters of the crack angle and the rock mechanics properties, and the statistics of the geometric parameters of at least 16 cracks or the area larger than 5 mm2 are suggested for the analysis of complex cracked rock masses or physical reproduction using 3D printing. The results are validated and further analyzed with triaxial tests. The fndings of this study have important reference value for future research regarding the accurate and efcient selection of a few cracks with a signifcant infuence on the rock mechanical properties of surrounding rock mass structures in coal engineering.
基金Funded by the National Natural Science Foundation of China(No.51075366)
文摘The inclusion complex of β-cyclodextrin (β-CD) and sulfurized isobutylene (T321) was prepared with a co-precipitation method. The tribological properties of the complex with different concentrations were investigated by a four-ball tester in the solution of polyethylene glycol-600 (PEG-600). The experimental results suggest that the complex exhibits better anti-friction and anti-wear properties than β-CD under different load conditions. The tribo-system shows the least friction coefficient when the concentration of the complex is 0.8%. During the friction process, the complex was decomposed into various molecular fragments and the T321 molecules were released onto the friction interface to provide effective lubrication. The XPS analytical results on the worn surfaces reveal that sulfide film formed by the released T321 plays a major role, and the iron alkoxide and carbon deposition films formed by the β-CD fragments have better anti-friction effect on the sulfide film surface. The interactions of different films result in the formation of a mixed boundary lubrication film.
文摘The title complex, Zn(C24H13NO)2Cl21, has been synthesized by the reaction of zinc chloride with Schiff base ligand N-salicylidene-p-toluidine and its structure was determined by single-crystal X-ray diffraction. The crystal is of monoclinic, space group Cc with a = 14.896(3), b = 12.506(2), c = 15.352(3) A,β = 114.711 (4)°, V = 2598.0(8) A^3, C28H26ZnCl2N2O2, Mr = 558.80, Z = 4, Dc = 1 .429 g/cm^3,μ = 1.179 mm^-1, Flack parameter = 0.027(19), F(000) = 1152, R = 0.0709 and wR = 0.1041 for 3117 observed reflections (Ⅰ 〉 2σ(Ⅰ)). In complex 1, the center Zn ion is four-coordinated by two O atoms from two Schiff base ligands and two Cl atoms in a distorted tetrahedral geometry. Additionally, the thermal decomposition of complex 1 as well as its kinetic mechanisms and equations is studied under the non-isothermal integral and differential methods in air by TG-DTG curves.
基金Funded by the National Natural Science Foundation of China (No. 51075366)
文摘The inclusion complex of fl-cyclodextrin (β-CD) and sulfurized isobutylene (T321) was prepared with a co-precipitation method. The tribological properties of the complex with different concentrations were investigated by a four-ball tester in the solution of polyethylene glycol-600 (PEG-600). The experimental results suggest that the complex exhibits better anti-friction and anti-wear properties than fl-CD under different load conditions. The tribo-system shows the least friction coefficient when the concentration of the complex is 0.8%. During the friction process, the complex was decomposed into various molecular fragments and the T321 molecules were released onto the friction interface to provide effective lubrication. The XPS analytical results on the worn surfaces reveal that sulfide film formed by the released T321 plays a major role, and the iron alkoxide and carbon deposition films formed by the β-CD fragments have better anti-friction effect on the sulfide film surface. The interactions of different films result in the formation of a mixed boundary lubrication film.
基金supported in part by the National Natural Science Foundation of China (62233012,62273087)the Research Fund for the Taishan Scholar Project of Shandong Province of Chinathe Shanghai Pujiang Program of China (22PJ1400400)。
文摘The present study addresses the problem of fault estimation for a specific class of nonlinear time-varying complex networks,utilizing an unknown-input-observer approach within the framework of dynamic event-triggered mechanism(DETM).In order to optimize communication resource utilization,the DETM is employed to determine whether the current measurement data should be transmitted to the estimator or not.To guarantee a satisfactory estimation performance for the fault signal,an unknown-input-observer-based estimator is constructed to decouple the estimation error dynamics from the influence of fault signals.The aim of this paper is to find the suitable estimator parameters under the effects of DETM such that both the state estimates and fault estimates are confined within two sets of closed ellipsoid domains.The techniques of recursive matrix inequality are applied to derive sufficient conditions for the existence of the desired estimator,ensuring that the specified performance requirements are met under certain conditions.Then,the estimator gains are derived by minimizing the ellipsoid domain in the sense of trace and a recursive estimator parameter design algorithm is then provided.Finally,a numerical example is conducted to demonstrate the effectiveness of the designed estimator.
基金A project supported by the China National Natural Science Foundation(No.49070079)
文摘On the basis of the detailed field work, compositions and contents of plagioclase and K - feldspar,determination of ordering degree, statistical analysis of plagioclase elongation index, mass-balance calculation and mineral spatial distribution and geochemistry, it is concluded that the migmatites in the Dabie complex are characterized by the presence of thermocenters. There are regular changes in mineral character in the migmatites from the centers outwards. The dominant genetic mechanism is anatexis and metasomatism, whose intensities decrease from the centers outwards. Finally, according to the simulated experiment on Liesegang' s rings and non-linear dynamics (dissipative structure theory), the dynamic mechanism of migmatization is profoundly expouded as consisting of the early-stage metasomatism induced by the thermal anomaly, the cardinal-stage anatexis induced by the early-stage matasomatism and finally the last-stage post-anatexis metasomatism.
基金This project is supported by National Natural Science Foundation of China (No.59985006).
文摘The general-linear-complex singularity of Stewart mechanism is a veryimportant problem in the parallel manipulator. Its general regularity is not found yet during thepast two decades. St-Onge and Gosselin pointed Out that the singularity locus of the Stewartmechanism at some given orientations of the moving platform should be polynomial expressions withvaried degrees in 2000, but they didn't formulate the expression. Based on the kinematicssingularity principle and the geometry condition proposed by Huang Zhen in 1999, firstly thesingularity equation in degree two is derived. It is a hyperbola when the orientation of the movingplatform is given. This result is also proved using screw theory. Then some singularity surfaces aregotten in three-dimensional space. This result is of important significance.
文摘The salicylaldehyde salicylhydrazone and its complex of Er(Ⅲ) were synthesized. The formulae K·4H_2O(HL=[C_(14)H_(10)N_2O_3]^(2-), the bivalent form of the salicylaldehyde salicylhydrazone) were determined by elemental analysis and EDTA volumetric analysis. Molar conductance, IR, UV and X-ray power diffraction were carried out for the characterizations of the complex and the ligand. There are two stable five-numbered and six-numbered circles in the complex. The thermal decompositions of the ligand and the complex with the kinetic study are carried out by non-isothermal thermogravimetry. The stages of the decompositions were identified by TG-DTG curve. The non-isothermal kinetic data were analyzed by means of integral and differential methods. The possible reaction mechanism and the kinetic equation were investigated by the corresponding kinetic parameters.The activation energy value of the main step decomposition are also calculated by Kissinger′s method and Ozawa′s method.