Co Complexes as a Corrosion Inhibitor for 316 L Stainless Steel in H2SO4 Solution

The effect of Co complexes with a Schiff base ligand on the electrochemical corrosion behavior of 316 L SS in 0.1 M H2SO4 at 25℃ has been investigated at various inhibitor concentration using electrochemical techniques (impedance spectroscopy (EIS), polarization curves). Corrosion measurements indicate that Co complex act as moderately inhibitors. Results revealed that increasing the concentration of Co complex increases the corresponding IE% values till 100 ppm. Co complex acts as mixed type inhibitors with predominant effect on the anodic dissolution of iron. Adsorption studies showed that the process follows Langmuir adsorption isotherm.

Complex Precipitation Mechanism of Ti-Nb-V Microalloyed Bainitic Base High Strength Steel

The addition of high Ti（>0.1%） in microalloyed bainitic high strength steel was designed, and the precipitation morphology of steels with different Ti, Nb, and V contents was studied by utilizing transmission electron microscopy（TEM）. Based on the classical nucleation-crystal growth theory and the Johnson-Mehl-Avrami equation, the precipitation thermodynamic and kinetic model of second phase particles in austenite was established in the form of（Nbx,Vy,Tiz）C, and the complex precipitation mechanism of second phase particles was emphatically studied. The experimental results show that the complex precipitation particles could be divided into two categories: the coarser particles with about 100 nm grain size and the independent complex precipitation particles in the form of（Nb,V,Ti）C with 35-50 nm grain size. The latter has a better precipitation strengthening effect, and the calculated PTT curve shows a typical "C" shape. When the deformed storage energy is 3 820 J?mol-1, the fastest precipitation temperature of calculated PTT curve is 925 °C, and the calculated result is essentially consistent with experimental values. The increase of Ti content increased the nose point temperature and expanded the range of fastest precipitation temperature.

Effect of Rare Earth Fluoride Complex Additives on Properties of Steel

A technique of treating steel with rare earth fluoride complex additives(REFCA),effects and influnce factors have been studied.REFCA play a role on controlling inclusion morphology,purifying the molten steel and improving properties of steel.The optimum composition of REFCA is REF_3 42%;CaO 33%;SiCa 25%,and the amount of REF_3 is 0.5 wt%～0.6 wt% of steel.

BEHAVIOR OF FINE V-Ti COMPLEX CARBONITRIDE IN STEEL 09MnVTiN DURING REHEATING

An investigation was carried out of the morphology and microstructure of V-Ti complex carbonitride in steel 09MnVTiN during reheating under analytical electron microscope.The prior V-rich ellipsoid V-Ti complex carbonitride particles are replaced progressively by Ti-rich cubic ones as the reheating temperature elevated from 1050 to 1400℃.The Ti con- tents in the core and border of particles increase from 15 and 6% in hot-rolled specimens into 84 and94% at 1400℃ respectively.

Research and development of hot-rolled ultra-high strength steel at Baosteel

The effects of the composition and cooling process on the microstructures and properties of hot-rolled ultra-high strength low alloy （HSLA） steel, complex phase steel and martensite steel were studied in the laboratory. And S700MC and MP1200 ultra-high strength steels were trial produced at the 1 880 mm hot-rolling line of Baosteel. Compared with conventional hot-rolled high strength products,the idea that water is alloy was applied in the newly developed hot-rolled ultra-high strength steel. By the use of the economical composition design and controlled cooling after hot-rolling effectively,ultra-high strength steel of different steel grades can be obtained.

Oxide Inclusions at Different Steps of Steel Production

The formation of oxide inclusions in one of the carbon steel productions of Mobarakeh Steel Complex of Isfahan has been evaluated. Several samples from different steps of steel production were taken, from arc furnace, ladle furnace, tundish, and continuous casting mold. Moreover, samples of slab and hot rolling products were prepared. The samples were investigated by optical and scanning electron microscopes equipped with the EDS system. According to the results, the number, composition, and kind of inclusions were directly influenced by the production variables. It was found that when the amount of dissolved oxygen was high （say more than 0. 002 5%）, the dissolved aluminum was able to reduce silicon oxide and react with the dissolved oxygen simultaneously, whilst, the dissolved aluminum could reduce the magnesium oxide only when the oxygen content was below 0. 000 5%. Based on this research, a mechanism for forming the complex inclusions was suggested. It was also found that if the aluminum is added to the melt as late as possible, a cleaner melt with fewer inclusions is prepared; this method will be more effective, especially in the case of complex inclusions.

Gelcasting of 316L stainless steel

A novel near-net process, gelcasting, was successfully used to prepare larger size 316L stainless steel parts with complex shape. In this study, the effects of process parameters on the viscosity of the slurry and the dry green strength were investigated. The results show that gas atomization （GA） powder is more suitable for gelcasting compared with water atomization （WA） powder. The maximum solid loading is 55vo1% for ball-milled slurry with GA powders. And the optimum amounts of monomers （acrylamide （AM）＋methylenebisacrylamide （MBAM）; the mass ratio, 30：1） and initiator in the AM system are 1.8% （based on the weight of metal powder） and 0.8%-1.4% （based on the weight of monomers）, respectively, at which, the maximum green strength obtained is 33.7 MPa. The mechanical properties of the sintered specimen are as follows： ultimate tensile strength, 493 MPa; yield strength, 162 MPa; and HRB, 72.

西安城市展示中心长悬挑、大跨度钢结构设计

西安城市展示中心由南馆、北馆和连桥组成,其中南馆悬挑长度62m,连桥跨度150m。结合建筑方案特点,南馆与连桥采用整层钢桁架结构体系,结构布置与建筑形态高度契合。介绍了南馆、连桥、穹顶、屋面等位置的结构布置情况,明确了超限项和抗震性能目标,对于多杆件复杂交汇钢节点进行有限元分析。针对南馆、连桥屋楼盖振动舒适度不足,设计布置了调谐质量阻尼器(TMD),实测减振效果显著。对连桥提升过程进行施工模拟,结果表明该过程增加了连桥挠度,需要考虑提前起拱。对超长连体结构温度和地震行波效应进行分析,根据结果对连桥楼板配筋和局部框架柱进行了加强。大震弹塑性分析与防连续倒塌分析结果表明,结构满足“大震不倒”的性能目标,结构冗余度较高,具有良好的防连续倒塌能力。

Precipitation of Epsilon Copper in Ferrite Antibacterial Stainless Steel

The precipitation of epsilon copper at 1023 K ageing in ferrite antibacterial stainless steel was investigated by a combination of electron microscopy and micro-Vickers hardness measurement. The results show that epsilon copper precipitation occurs within 90 s, Complex multilayer structure confirmed as twins and stacking faults on {111}ε-Cu planes was observed in the precipitates. The precipitates grow by the lengthwise enlargement of a set of parallel layers, having [111]ε-Cu and [112]ε-Cu preferred growth orientations. The volume fraction of precipitates f formed within 120 min can be predicted by a modified Avrami equation （In1/1-f= kt ＋ b）. Simultaneously, substituent atom clusters with a size of 5-10 nm was found to occur in the solution and cause matrix strain. The precipitate morphology and distribution on the surface of ferrite antibacterial stainless steel are associated with surface crystallographic orientation of the matrix. The precipitates are predominantly located within the ferrite grains of 〈110〉 orientation. The precipitates located on {111}α-Fe surface planes have sphere or ellipse shape.

Effect of Ca^(2+) on CO_2 corrosion properties of X65 pipeline steel

The effect of Ca^2＋ on CO2 corrosion to X65 pipeline steel was investigated in the simulated stratum water of an oil field containing different concentrations of Ca^2＋. It is found that Ca^2＋ can enhance the corrosion rate, especially in the Ca^2＋ concentration from 256 to 512 mg/L, which can be attributed to the growing grain size and loosing structure of corrosion scales with increasing Ca^2＋ concentration. X-ray diffraction （XRD） and X-ray photoelectron spectroscopy （XPS） investigations reveal that a complex carbonate （Fe, Ca）CO3 forms at high Ca^2＋ concentration due to the gradual replacement of Fe^2＋ in FeCO3 by Ca^2＋.

基于点云数据的大型复杂钢结构智能化施工方法

大型复杂钢结构施工过程中,常面临施工尺寸质量难以把控、构件提升变形监测困难和合拢段现场配切效率低等问题。三维激光扫描技术可全覆盖地、快速精准地获取复杂构部件在施工过程中的点云数据,这为解决上述问题提供了新方法。为此,该文以重庆两江新区寨子路钢拱桥为工程背景,开展基于点云数据的大型复杂钢拱桥智能化施工方法的全流程研究。基于标靶球检测算法、快速四点一致集算法、迭代最近邻算法等实现标靶球点云数据的自动检测及多站点云数据之间的自动配准;通过BIM点云化技术、kNN算法等完成目标点云数据的半自动化提取,实现拱肋尺寸的智能化检测;基于八叉树算法、区域增长算法等实现拱肋提升变形的智能检测;为缩短拱肋的合拢工期,基于BIM模型焊缝信息提取技术、主成分分析算法、Canny边界检测算法、霍夫变换算法等提出数字化预拼装算法,得到合拢段的配切量。工程应用表明,该文所提出的智能施工方法效率高、自动化程度好,研究成果可为大型复杂钢结构的施工质量和安装效率的提升提供理论和算法支撑。

丝线重建颈后方韧带复合体联合Centerpiece支撑钢板在颈后路单开门椎管成形术中的应用

目的:分析丝线重建颈后方韧带复合体联合Centerpiece支撑钢板在颈后路单开门椎管成形术中的应用价值。方法:选取2021年6月—2023年6月我院收治的80例多节段脊髓型颈椎病患者作为研究对象,采用随机数字表法将患者分为对照组(n=40)和观察组(n=40),对照组实施传统颈后路单开门缝线悬吊门轴干预;观察组实施丝线重建颈后方韧带复合体联合Centerpiece支撑钢板干预。比较两组患者神经功能、影像学观测指标(椎管矢状径、颈椎曲度、C_(2)~C_(7)Cobb角、颈椎活动度、最窄节段椎管面积)。结果:术后3个月~1年,观察组JOA评分高于对照组(P<0.05)。术后3个月~1年,观察组椎管矢状径、颈椎曲度、C_(2)~C_(7)Cobb角、颈椎活动度、最窄节段椎管面积均优于对照组(P<0.05)。术后3个月观察组C_(4)、C_(6)门轴骨愈合情况优于对照组(P<0.05),术后1年,两组患者C_(4)、C_(6)门轴骨愈合情况比较无差异(P>0.05)。结论:丝线重建颈后方韧带复合体联合Centerpiece支撑钢板应用于颈后路单开门椎管成形术中具备良好的治疗效果,能有效恢复颈椎功能,减轻对最窄节段椎管面积、颈椎活动度、门轴骨愈合情况及椎管扩大程度的影响,又能在一定程度上减少颈椎轴性症状的发生。

冷弯不等肢复杂卷边角钢轴压试验及承载力设计方法

为研究冷弯薄壁不等肢复杂卷边角钢屈曲性能和稳定承载力设计方法,对24根不同截面、长细比、宽厚比的不等肢复杂卷边角钢进行了轴压试验。试验结果表明,长细比较大且宽厚比较小的试件易发生弯扭屈曲,长细比较小而宽厚比较大的试件易发生局部屈曲或弯扭和局部相关屈曲。采用ABAQUS有限元软件对试件进行了有限元模拟,屈曲模式和承载力与试验结果吻合良好,表明建立的有限元分析模型是可行的。因此可采用经验证的有限元模型对不同长细比、卷边形式和卷边比的轴心受压不等肢复杂卷边角钢进行了参数化分析。结果表明,试件极限承载力受长细比的影响最为明显,将卷边比控制在一定范围内或改变卷边形式可提高试件极限承载力。最后将试验结果与直接强度法计算结果进行对比,表明直接强度法计算试件承载力较不安全。因此基于试验和数值分析结果提出轴心受压冷弯薄壁不等肢复杂卷边角钢构件考虑整体屈曲后强度的直接强度法修正公式,并通过对比试验结果和有限元分析结果验证了该修正公式的准确性和可行性。

喷丸强化对预变形CP800复相钢疲劳性能的影响

喷丸强化可以提高CP800复相钢的抗疲劳性能.采用低(0.15 mmA)、中(0.3 mmA)、高(0.5 mmA)3种喷丸强度对5%预拉伸变形后的CP800复相钢进行表面喷丸处理,研究了喷丸后材料的表面形貌和表面残余应力,并通过拉压疲劳试验分析了疲劳断口.研究发现:2 mm板厚的CP800复相钢更适合采用低喷丸强度,疲劳寿命约为未喷丸试样的3倍;疲劳寿命的提升归因于表层发生塑性变形、位错密度提高,且残余压应力可抑制裂纹萌生;喷丸后材料表面粗糙度增大;喷丸强度过高易造成表面缺陷增多,尤其在高喷丸强度下,试样表面会出现分层损伤现象,对疲劳性能有不利影响.

利用等效复磁导率幅值对硅钢叠片铁心的改进均质化方法

工程上通常用电工钢等低损耗软磁材料制作电力变压器叠片铁心,并通过减少磁性材料叠片厚度和涂抹绝缘涂层来降低叠片的涡流损耗。在计算机仿真中通常用均质化方法对多层薄叠片进行建模,但需要在边缘处进行加密剖分以考虑集肤效应,计算成本较未均质化时有所下降,但依然较高。本文利用含有集肤效应的等效复磁导率幅值改进均质化公式,降低边缘网格的剖分数目,进一步降低计算成本。将国际基准问题TEAM 21d-M的20层硅钢片均质化并进行磁通以及损耗计算,结果显示本文所提方法在仿真数据上与实验结果最大误差不超过6%,内存占用、计算耗时上较已有的均质化方法大幅提升,表明改进均质化方法准确度高、速度快。

基于BIM的超高层复杂钢结构施工技术研究与分析

为探讨BIM技术在超高层复杂钢结构施工中的应用,提出优化方案。采用文献综述法,阐述BIM技术的基本概念和原理,并探讨其在超高层建筑和复杂钢结构施工中的应用。通过建立BIM模型,研究BIM技术在施工过程中的应用,包括施工过程优化和效率提升。研究结果表明,BIM技术能够有效解决超高层复杂钢结构施工中的难点和安全问题,并提高施工效率和质量。

广交会展馆四期扩建工程展厅钢结构屋盖设计

广交会展馆四期扩建工程项目展厅的钢结构屋盖由珠江散步道、标准展厅和卡车通道组成。为了满足业主对标准展厅跨度及净高的功能要求,对5种钢结构屋盖的结构体系进行比选,最终采用了下弦设置穿心式预应力钢绞线的倒三角形立体桁架的结构体系。对所采用的结构体系的基本设计信息进行介绍,并对其进行了荷载分析、施工模拟分析及屋盖抗连续倒塌分析。结果表明所采用的结构方案在满足业主需求的情况下是安全可靠且经济合理的,各项指标均满足规范要求。

汽车车轮用高扩孔率热轧复相钢带的研制

设计了一种微合金化的汽车车轮用高扩孔率热轧复相钢,并对其进行了工业试制。采用金相检验、力学性能测试等方法研究了高扩孔率热轧复相钢的显微组织及力学性能。结果表明:试制产品的显微组织主要由贝氏体、铁素体构成,还分布有少量的马氏体、残余奥氏体以及弥散析出的第二相粒子,产品的屈服强度、抗拉强度、断后伸长率分别超过了520,610MPa和24%,屈强比为0.85~0.87,扩孔率达到83%以上,沿板宽方向的扩孔率在10%以内波动;增加Si元素含量能明显改善扩孔性能,同时会影响产品的表面质量,将Si元素的质量分数控制在0.20%左右较为合适;试制产品具有优异的局部成形性、良好的抗疲劳性和焊接性能,在疲劳试验承载力为1700 N·m的条件下,车轮弯曲疲劳寿命达到60万次以上。

苏州某大型复杂商业连体结构设计

苏州某大型商业综合体项目位于7度抗震设防烈度区,为体型重叠建筑。通过5道防震缝将建筑整体划分为购物中心A区、购物中心B区、停车楼、商业街A区、商业街B区五个独立结构单元。购物中心A区为复杂连体高层建筑,1~5层采用框架-剪力墙结构,两个单体在3~5层中区由钢桁架相连,顶部(6层)钢桁架结构与两个单体通过成品球铰支座连接,形成强连体结构。充分考虑了周期比、位移比双指标平衡后对购物中心A区剪力墙布置进行了优化;屋顶钢桁架结构支座采用变刚度设计,局部设置滑动支座解决恒载下杆件应力比较高的问题。通过性能化设计,该复杂结构连体部位可以满足中震弹性、大震不屈服的性能目标要求。性能化设计及专项分析表明,影院钢结构具有良好的抗震性能、楼盖舒适度及防倒塌性能。

南通美术馆复杂钢结构设计

南通美术馆采用钢筋混凝土框架-剪力墙+带支撑钢框架结构,具有扭转不规则、楼板不规则、构件间断等不规则项。小展馆沿圆弧扇形布置,采用带支撑钢框架结构。上、下层小展馆之间存在局部层叠的转角关系,竖向构件无法直接落地,采用多层多次转换钢框架和整体悬挑钢桁架。钢结构体系具有定位复杂无规律、多层多次转换、整体悬挑尺度大、桁架跨度大、荷载大等特点。针对结构特点,对重要构件提出了更高的性能目标;对复杂钢结构设计关键问题进行分析并提出对应措施。采用ETABS、PKPM、SAP2000等软件进行整体模型分析和各种补充分析,包括:防倾覆验算、小展馆独立模型承载力验算、楼板应力分析及舒适度分析等。计算结果表明结构各项指标均满足要求,结构安全可靠。通过重视结构概念和构造设计,保证结构整体性和稳定性。