装配式双槽钢拼合PEC柱受压性能试验研究

为发挥钢-混组合结构优良性能及装配式结构施工节能、质量可控的优势,满足建筑模块化、工业化发展需求,提出螺栓连接装配式双槽钢拼合部分包裹混凝土(PEC)组合柱,开展1个纯钢拼合柱、5个组合拼合柱轴心受压及偏心压弯性能试验,结合数值模拟对组合柱破坏形态、应变发展规律、变形性能和承载能力进行分析研究,揭示了螺栓间距、混凝土外伸宽度、相对偏心距大小等因素对双槽钢拼合柱受压力学性能的影响规律.研究结果表明:轴心受压双槽钢拼合柱破坏模式均为整体失稳破坏,偏心受压双槽钢拼合柱均为压弯破坏,使用钢板及螺栓能可靠连接构件,加载过程双肢未发生分离;加密螺栓间距能有效增强组合柱峰后延性,在一定间距范围内构件具较高刚度,由1000mm加至500 mm极限承载力提高4.43%;开孔钢板连接件能约束且保证混凝土与型钢协同工作,破坏阶段前混凝土与型钢未出现明显黏结分离;混凝土外伸宽度增加能提高构件稳定性能.提出考虑单肢影响的轴压承载力计算方法与基于Eurocode 4规范双槽钢拼合柱轴力-弯矩(N-M)相关曲线,理论结果与试验吻合较好,可为装配式拼合柱设计应用提供理论支撑.

混合联肢PEC墙结构简化力学分析模型及承载力计算

为克服钢筋混凝土墙肢底部易发生脆性破坏的缺点,提高联肢剪力墙结构的抗震性能,采用PEC剪力墙肢代替混合联肢剪力墙结构中的钢筋混凝土剪力墙肢,形成新型混合联肢PEC墙结构.通过改变钢连梁截面尺寸、PEC墙肢宽厚比以及楼层数形成3个系列共8个模型,研究了弹性耦连比和改变弹性耦连比的方式对混合联肢PEC墙结构滞回性能和应力分布的影响.结果表明:各个系列模型滞回曲线均饱满而稳定,未出现明显捏缩现象,证明混合联肢PEC墙结构抗震性能好、耗能能力强,适用于高烈度抗震设防地区;与已有联肢墙结构研究成果一致,弹性耦连比是影响混合联肢PEC墙结构整体性能的主要因素,并不会因为实现方式不同而影响结构应力分布规律;为保证结构达极限承载能力状态时各层钢连梁均发生剪切屈服并充分发展塑性,同时避免受拉侧墙肢发生延性较差的小偏心受拉破坏,应控制弹性耦连比小于等于70%;基于有限元模型分析结果,探讨了混合联肢PEC墙结构受力机理,建立了结构简化力学分析模型,给出了极限承载力计算公式;试验及有限元模型分析结果与理论计算结果误差在15%以内,且均为理论值偏低,证明本文提出的混合联肢PEC墙结构极限承载力计算公式精度较高且偏于安全,可用于计算结构极限承载力.

T形PEC柱抗震性能的数值模拟分析

利用ABAQUS软件对14个T形PEC柱进行低周反复加载模拟,分析不同参数对T形PEC柱抗震性能的影响规律。结果表明:T形PEC柱的滞回曲线呈饱满的平行四边形,且刚度退化稳定,耗能能力和延性良好;提高混凝土强度等级虽然可增大柱的初始刚度,但混凝土强度等级过高则会导致柱的延性降低,刚度退化加剧,抗震性能降低;在T形PEC柱内设置横向拉杆,且将x方向和z方向的横向拉杆相互焊接,有利于对混凝土形成套箍作用从而提高柱的抗震性能,但拉杆间距不宜大于150 mm;在T形PEC柱的两侧阴角处分别设置1根纵筋并将其与横向拉杆绑定后形成钢筋笼,能够明显的改善柱的抗震性能。

带PEC柱钢板剪力墙结构(弱轴连接)抗震性能有限元分析

为研究边缘柱为部分外包混凝土组合柱的钢板剪力墙结构(弱轴连接)的抗震性能,使用有限元软件ABAQUS完成1榀边缘柱为H型钢柱、5榀边缘柱为PEC柱的钢板剪力墙结构(弱轴连接)在循环荷载作用下的有限元数值模拟,得到结构的应力分布、破坏模式、滞回曲线、耗能性能、骨架曲线以及刚度退化曲线,并完成了1榀带PEC柱的钢板剪力墙结构(弱轴连接)的试验,验证了有限元模拟的正确性.分析表明在钢板剪力墙结构中(弱轴连接),将PEC柱作为剪力墙的边缘框架柱,同样可以很好的约束屈曲后的钢板剪力墙,使其充分发挥屈曲后的性能,显著提升整体结构的抗侧刚度、承载力以及耗能性能.

PEC柱-钢梁摩擦耗能部分自复位组合框架抗震试验研究

为系统研究梁柱采用自复位连接组合框架的抗震机理,选取预拉杆长度设置、PEC柱截面强弱轴布置和柱脚连接方式3个设计参数,设计制作了4榀PEC柱-钢梁梁柱摩擦耗能部分自复位连接组合框架1∶2缩尺试件并进行拟静力抗震试验。通过试验现象观察和数据分析,对试件的滞回特性、抗侧刚度退化、复位能力、滞回耗能等抗震性能进行研究。结果表明:摩擦耗能部分自复位连接通过T形件长圆孔合理设置实现了“设计地震水平阶段实现复位,大震设计水平阶段自复位连接连接转化为伴随出现螺栓承压型受力实现部分自复位”的性能化设计目标;设计地震阶段,试件主要通过辅助摩擦耗能件耗能,且卸载残余侧移小于自复位结构侧移限值(0.3%),在大震作用阶段,试件通过辅助摩擦耗能件与结构构件损伤联合耗能,承载能力仍继续增大,且仍具有部分自复位能力;预拉杆设置有限长度可显著增强结构整体性,PEC柱弱轴布置一定程度上降低了结构整体性,而PEC柱脚采用铰接可显著削弱结构整体性。

Probing electronic structures of transition metal complexes using electron paramagnetic resonance spectroscopy

Electron paramagnetic resonance(EPR)or electron spin resonance(ESR)has been widely employed to characterize transition metal complexes.However,because of the high degree of complexity of transition metal EPR spectra,how to extract the underlying electronicstructure information inevitably poses a major challenge to beginners,in particular for systems with S>1/2.In fact,the physical principles of transition metal EPR have long been well-established and since 1970s a series of dedicated voluminous monographs have been published already.Not surprisingly,they are not appropriate stating points for novices to grasp a panorama of the profound theory prior to scrutinizing in-depth references.The present review aims to fill this gap to provide a perspective of transition metal EPR and unveil some peculiar subtleties thereof on the basis of our recent work.

Assessment of the Characteristics of Demersal Fish Communities Using Species-and Trait-Based Approaches in the Coastal Habitats Along Rongcheng Bay,Shandong Peninsula,China

Biodiversity declines have motivated many studies on the relationship between species diversity and ecosystem functioning.In this study,we described the spatial-temporal characteristics of demersal fish communities along a coastal habitat in Rongcheng Bay,Shandong Peninsula,China with both species-based and biological trait-based approaches.The field survey was carried out monthly using traps from April to October of 2018,and divided into three seasons(spring:April and May;summer:June,July and August;autumn:September,October and November).The study area included five distinct habitats:seagrass bed,natural rocky reef,bare sand,artificial reef together with natural rocky reef,and artificial reef together with bare sand.We analyzed the fish communities with three taxonomic diversity indices,including Shannon-Wiener,Simpson,and Pielou Evenness,as well as four functional diversity indices,including FRic,FEve,FDiv,and FDis,based on 7 functional groups which are categorized into 27 traits.The results showed that there were no significant differences in taxonomic diversity indices among different habitats in the three seasons.However,significant differences were found in the functional richness of fish communities among different habitats in three seasons.Seagrass bed represented the highest functional richness in spring and autumn.This study demonstrates that seagrass bed is very important in enhancing the functional diversity of fish communities in a complex habitat.The study also indicates that the combination of taxonomic diversity and functional diversity will provide a more detailed description of the characteristics of fish communities.

Synthesis and Physico-Chemical Characterizations of Novel Hydrazone Ligands and Their Metal Complexes against Hormone-Dependent and Independent Cancers

This work deals with the synthesis and physicochemical characterizations of a new group of novel retinoidal ligands and their metal complexes. Their in vitro anti-proliferative activities have shown that ligand L1 is effective against human breast cancer BT-20 and MCF-7 cell lines. At the same time, compound L2 exerts its effect on human prostate cancer PC-3 and human breast cancer MDA-MB-231 and MCF-7 cell lines respectively. The retinoid ligands exert their pleiotropic action toward retinoic acid receptors (RARs) than their metal complexes but all compounds exhibit concentration-dependent.

Ecological network analysis reveals complex responses of tree species life stage interactions to stand variables

Tree interactions are essential for the structure,dynamics,and function of forest ecosystems,but variations in the architecture of life-stage interaction networks(LSINs)across forests is unclear.Here,we constructed 16 LSINs in the mountainous forests of northwest Hebei,China based on crown overlap from four mixed forests with two dominant tree species.Our results show that LSINs decrease the complexity of stand densities and basal areas due to the interaction cluster differentiation.In addition,we found that mature trees and saplings play different roles,the first acting as“hub”life stages with high connectivity and the second,as“bridges”controlling information flow with high centrality.Across the forests,life stages with higher importance showed better parameter stability within LSINs.These results reveal that the structure of tree interactions among life stages is highly related to stand variables.Our efforts contribute to the understanding of LSIN complexity and provide a basis for further research on tree interactions in complex forest communities.

Structures and magnetism of dinuclear Co complexes based on imine derivatives

This study presents the synthesis of three dinuclear cobalt complexes based on three imine derivatives:bis-[4-(2-pyridylmethyleneamino)-phenyl]thioether(L1),bis-[4-(2-pyridylmethyleneamino)-phenyl]ether(L2),and bis-[4-(2-pyridylmethyleneamino)-phenyl]methane(L3).Single-crystal X-ray diffraction analysis reveals that the complexes[Co_(2)(L1)3](ClO_(4))4·2CH_(3)CN(1),[Co_(2)(L2)3](ClO_(4))4·2CH_(3)OH(2),and[Co_(2)(L3)3](ClO_(4))4·2CH_(3)OH(3)all exhibit a dinuclear structure.Magnetic test results show that complex 3 exhibited irreversible SCO behavior induced by loss of solvent at 300 K,with the average Co-N bond length increasing from 0.2139(3)to 0.2153(3)nm.Meanwhile,the desolvated complex 3 exhibited paramagnetic behavior similar to that of complexes 1 and 2.Variable-temperature UV-Vis spectroscopic studies also indicate that complex 3 undergoes a solvent-loss-induced spin-state transition.CCDC:2347354,1(120 K);2347355,2(120 K);2347356,3(120 K);2347357,3(400 K).

3,6-Bis-β-Dicarbonylsubstituted Carbazoles Bearing N-Spacers and Their Eu(III) Complexes as Immunofluorescent Labelling Agents

New reagents for immunofluorescence analysis of carbazole series containing fluorinated β-dicarbonyl fragments and carboxylic substituent groups separated by spacers of different lengths from the light-gathering carbazole scaffold have been developed. The markers in complex with Eu3+ ions possess stability in the aqueous phase, intense and prolonged luminescence (τ 550 - 570 μs) with characteristic emission maxima in the region of 615 nm and excitation wavelengths in the region of 380 - 390 nm, which distinguishes them from most of the analogs used. In the study of marker conjugation with streptavidin, a reagent containing 4 - 5 europium labeling complexes based on spacer-containing carbazole tetraketone was obtained. The marker-doped silicate nanoparticles exhibit intense and long-lived luminescence in the characteristic region.

Migration Networks Pattern of China’s Floating Population from the Perspective of Complex Network

Since China’s reform and opening-up,the growing disparity between urban and rural areas and regions has led to massive migration.With China’s Rural Revitalization Strategy and the industrial transfer from the eastern coastal areas to the inland,the migration direction and pattern of the floating population have undergone certain changes.Using the 2017 China Migrants Dynamic Survey(CMDS),excluding Hong Kong,Macao,and Taiwan regions of China,organized by China’s National Health Commission,the relationship matrix of the floating population is constructed according to the inflow place of the interviewees and their outflow place(the location of the registered residence)in the questionnaire survey.We then apply the complex network model to analyze the migration direction and network pattern of China’s floating population from the city scale.The migration network shows an obvious hierarchical agglomeration.The first-,second-,third-and fourth-tier distribution cities are municipalities directly under the central government,provincial capital cities,major cities in the central and western regions and ordinary cities in all provinces,respectively.The migration trend is from the central and western regions to the eastern coastal areas.The migration network has‘small world’characteristics,forming nine communities.It shows that most node cities in the same community are closely linked and geographically close,indicating that the migration network of floating population is still affected by geographical proximity.Narrowing the urban-rural and regional differences will promote the rational distribution this population.It is necessary to strengthen the reform of the registered residence system,so that the floating population can enjoy urban public services comparable to other populations,and allow migrants to live and work in peace.

Catalytic Effect of Transition Metal Complexes of Triaminoguanidine on the Thermolysis of Energetic NC/DEGDN Composite

The transition metal complexes of triaminoguanidine(TAG-M,where M=Cobalt(Co)or Iron(Fe))have been prepared.The catalytic effect of these complexes on the thermolysis of energetic composite based on nitrocellulose and diethylene glycol dinitrate,has been investigated.Extensive characterization of the resulting energetic composites was carried out using scanning electron microscopy(SEM),X-ray diffraction(XRD),Fourier transform infrared spectroscopy(FTIR),and differential scanning calorimetry(DSC).Isoconversional kinetic analysis was performed to determine the Arrhenius parameters associated with the thermolysis of the elaborated energetic formulations.It is found that TAG-M complexes have strong catalytic effect on the thermo-kinetic decomposition of NC/DEGDN by decreasing the apparent activation energy and significantly increased the total heat release.The models that govern the decomposition processes are also studied,and it is revealed that different reaction processes are accomplished by introduction metal complexes of triaminoguanidine.Overall,this study serves as a valuable reference for future research focused on the investigation of catalytic combustion features of solid propellants.

Elaborately engineered Au(I)-based AIEgens: Robust and broad-spectrum elimination abilities toward drug-resistant bacteria

Antimicrobial resistance(AMR)remains an urgent and formidable challenge to global public health.Developing new medicines or alternative therapies to address AMR is imperative.Herein,we rationally designed and synthesized a series of Au(I)-based aggregation-induced emission luminogens(AIEgens)to combat drug-resistant bacterial infections.Through systematic screening,we identified an optimal AIEgen,called complex 5,which can rapidly discriminate between gram-positive(G^(+))and gram-negative bacteria(G^(-))bacteria,and exert robust and broad-spectrum antimicrobial potency against diverse drug-resistant bacterial strains,including those intractable to treat in clinic.Furthermore,extensive testing against a variety of clinical drug-resistant isolates,coupled with the successful treatment of methicillin-resistant Staphylococcus aureus-infected skin wounds unequivocally validates the high efficiency and broad-spectrum activity of complex 5.Therefore,complex 5 emerges as a promising candidate for combating drug-resistant bacterial infections in clinic,and this work provides inspiration for developing new solutions to address the escalating global challenge of AMR.

孤独症儿童PECS行为训练图卡插图风格设计研究

目的:近年来的研究数据显示,中国孤独症儿童的患病率持续上升,引起了学术界的关注。如何有效地对孤独症儿童进行干预和治疗,已成为当前亟待解决的问题。社会各界纷纷呼吁重视与关怀孤独症群体,建立更加科学、人性化和本土化的干预辅助体系。文章探讨符合我国孤独症儿童认知特点的PECS(Picture Exchange Communication System,图片交流沟通系统)行为训练图卡插图的设计表现风格,以增强图卡的有效性和吸引力。方法:通过系统的文献研究、线上调研以及专业意见收集,深入研究儿童插图的发展现状,并结合孤独症儿童的视觉偏好,总结出符合我国孤独症儿童PECS行为训练图卡插图的设计表现风格。结论:研究结果表明,扁平化、简洁具象化的插图风格更符合我国孤独症儿童的审美偏好,清晰的图形及具象化的表达方式能降低认知负担,使图像更易于理解,有助于提供稳定且可预测的视觉信息,符合孤独症儿童对简单直观视觉元素的偏好,能够显著提高孤独症儿童的学习兴趣和参与度,从而增强孤独症儿童的行为能力和沟通表达能力。设计应遵循独特的创意表达、简化和重复、注重细节等原则,从而使孤独症儿童PECS行为训练图卡满足孤独症儿童的学习、表达和发展需求。

Subtraction of liposome signals in cryo-EM structural determination of protein-liposome complexes

Reconstituting membrane proteins in liposomes and determining their structure is a common method for determining membrane protein structures using single-particle cryo-electron microscopy(cryo-EM).However,the strong signal of liposomes under cryo-EM imaging conditions often interferes with the structural determination of the embedded membrane proteins.Here,we propose a liposome signal subtraction method based on single-particle two-dimensional(2D)classification average images,aimed at enhancing the reconstruction resolution of membrane proteins.We analyzed the signal distribution characteristics of liposomes and proteins within the 2D classification average images of protein–liposome complexes in the frequency domain.Based on this analysis,we designed a method to subtract the liposome signals from the original particle images.After the subtraction,the accuracy of single-particle three-dimensional(3D)alignment was improved,enhancing the resolution of the final 3D reconstruction.We demonstrated this method using a PIEZO1-proteoliposome dataset by improving the resolution of the PIEZO1 protein.

基于PEC技术的水电站照明电源设计研究

本研究针对水电站的照明用电需求,设计了一套基于光电化学电池(Photoelectrochemical Cell,PEC)技术的自主照明电源系统。该系统采用高效率的单晶硅光伏组件作为光电转换设备,结合镍氢电池构建储能单元,并通过最大功率点跟踪(Maximum Power Point Tracking,MPPT)技术和智能化控制策略,实现了对水电站照明负荷的稳定供电。实验结果表明,系统在连续运行15 d的测试中,光伏发电量、储能容量以及负荷供电均达到预期目标,证明了系统的高效性、稳定性以及可靠性。此外,系统的模块化设计和智能控制策略提高了系统的灵活性与可维护性,为水电站提供了一种环保、高效且经济的照明解决方案。

Cultural Complex Design from the Perspective of Urban Renewal: A Case Study of Incheon Geomdan Cultural Complex in South Korea

Urban development should rely on the form of architecture,and incorporating urban planning concepts into architectural design can better assist urban construction.Taking the design of Incheon Geomdan Cultural Complex in South Korea as an example,this paper analyzes how to reflect urban planning elements in architectural design,and studies the role and value of cultural complex architecture in urban development from multiple perspectives such as culture,ecological environment,and public space.It hopes to gain more research and design ideas to promote the development of cultural industries in the region,leverage the advantages of regional cultural formats,and create new cultural settlements in cities.

Motion and Special Relativity in Complex Spaces

A natural extension of the Lorentz transformation to its complex version was constructed together with a parallel extension of the Minkowski M4 model for special relativity (SR) to complex C4 space-time. As the [signed] absolute values of complex coordinates of the underlying motion’s characterization in C4 one obtains a Newtonian-like type of motion whereas as the real parts of the complex motion’s description and of the complex Lorentz transformation, all the SR theory as modeled by M4 real space-time can be recovered. This means all the SR theory is preserved in the real subspace M4 of the space-time C4 while becoming simpler and clearer in the new complex model’s framework. Since velocities in the complex model can be determined geometrically, with no primary use of time, time turns out to be definable within the equivalent theory of the reduced complex C4 model to the C3 “para-space” model. That procedure allows us to separate time from the (para)space and consider all the SR theory as a theory of C3 alone. On the other hand, the complex time defined within the C3 theory is interpreted and modeled by the single separate C1 complex plane. The possibility for application of the C3 model to quantum mechanics is suggested. As such, the model C3 seems to have unifying abilities for application to different physical theories.

Towards complex scenes: A deep learning-based camouflaged people detection method for snapshot multispectral images

Camouflaged people are extremely expert in actively concealing themselves by effectively utilizing cover and the surrounding environment. Despite advancements in optical detection capabilities through imaging systems, including spectral, polarization, and infrared technologies, there is still a lack of effective real-time method for accurately detecting small-size and high-efficient camouflaged people in complex real-world scenes. Here, this study proposes a snapshot multispectral image-based camouflaged detection model, multispectral YOLO(MS-YOLO), which utilizes the SPD-Conv and Sim AM modules to effectively represent targets and suppress background interference by exploiting the spatial-spectral target information. Besides, the study constructs the first real-shot multispectral camouflaged people dataset(MSCPD), which encompasses diverse scenes, target scales, and attitudes. To minimize information redundancy, MS-YOLO selects an optimal subset of 12 bands with strong feature representation and minimal inter-band correlation as input. Through experiments on the MSCPD, MS-YOLO achieves a mean Average Precision of 94.31% and real-time detection at 65 frames per second, which confirms the effectiveness and efficiency of our method in detecting camouflaged people in various typical desert and forest scenes. Our approach offers valuable support to improve the perception capabilities of unmanned aerial vehicles in detecting enemy forces and rescuing personnel in battlefield.