Electrodeposition of Ni-W Amorphous Alloy and Ni-W-SiC Composite Deposits

Ni-W alloys and their composite deposits are electroplated on the metals when an appropriate complex agent is selected on the base of the theories of electrochemistry and complex chemistry, and the principle of induced codeposition. Effects of the bath composition, pH value, temperature and current density on the electrode position of Ni-W alloys and their composite deposits have been investigated, and the effect of heat treatment temperature on the hardness, structure and cohesive force of the amorphous Ni-W alloys and their composite deposits are also discussed. Results showed that the alloys containing more than 44 wt pct W content and the composite deposits containing 7.8 wt pct SiC content could be obtained by making use of the appropriate bath composition and plating conditions. Alloys and their composite deposits with over 44 wt pct W content show amorphous structure. The hardness of amorphous Ni-W alloys and their composite deposits increases obviously when heated, and can reach to 1350 HV and 1520 HV respectively for 46 wt pct W content. The cohesion on Cu, carbon steel and stainless steel is very good.

Structure and Tribological Property of TiBN Nanocomposite Multilayer Synthesized by Ti-BN Composite Cathode Plasma Immersion Ion Implantation and Deposition

A Ti-BN complex cathode is made from Ti and h-BN powders by the powder metallurgy technology, and TiBN coating is obtained by plasma immersion ion implantation and deposition with this Ti-BN composite cathode. The TiBN coating shows a self-forming multilayered nanocomposite structure while with relative uniform elemental distributions. High resolution transmission electron microscopy images reveal that the multilayered structure is derived from different grain sizes in the nanocomposite. Due to the existence of h-BN phase, the friction coefficient of the coating is about 0.25.

Failure mechanism of a large-scale composite deposits caused by the water level increases

The failure of slope caused by variations in water levels on both banks of reservoirs is common.Reservoir landslides greatly threaten the safety of reservoir area.Taking large-scale composite deposits located on the Lancang River in Southwest China as a study case,the origin of the deposits was analyzed based on the field investigation and a multi-material model was established in the physical model test.Combined with numerical simulation,the failure mechanism of the composite deposits during reservoir water level variations was studied.The results indicate that the deformation of the large-scale composite deposits is a staged sliding mode during the impoundment process.The first slip deformation is greatly affected by the buoyancy weight-reducing effect,and the permeability of soil and variation in the water level are the factors controlling slope deformation initiation.The high water sensitivity and low permeability of fine grained soil play an important role in the re-deformation of deposits slope.During the impoundment process,the deformation trend of the deposit slope is decreasing,and vertical consolidation of soil and increasing hydrostatic pressure on the slope surface are the main reasons for deformation attenuation.It is considered that the probability of large-scale sliding of the deposits during the impoundment period is low.But the damage caused by local bank collapse of the deposit slope still needs attention.The results of this paper will further improve our understanding of the failure mechanism of composite deposits caused by water level increases and provide guidance for the construction of hydropower stations.

Effects of Carbon Nanotubes by Electrophoretic Deposition on Interlaminar Properties of Two Dimensional Carbon/carbon Composites

Carbon nanotubes（CNTs） were deposited uniformly on carbon cloth by electrophoretic deposition（EPD）. Thereafter, CNT-doped clothes were stacked and densified by pyrocarbon via chemical vapor infiltration to fabricate two-dimensional（2 D） carbon/carbon（C/C） composites. Effects of EPD CNTs on interlaminar shear performance and mode Ⅱ interlaminar fracture toughness（GⅡc） of 2 D C/C composites were investigated. Results showed that EPD CNTs were uniformly covered on carbon fibers, acting as a porous coating. Such a CNT coating can obviously enhance the interlaminar shear strength and GⅡc of 2 D C/C composites. With increaing EPD CNTs, the interlaminar shear strength and GⅡc of 2 D C/C composites increase greatly and then decrease, both of which run up to their maximum values, i e, 13.6 MPa and 436.0 J·m-2, when the content of EPD CNTs is 0.54 wt%, 2.27 and 1.45 times of the baseline. Such improvements in interlaminar performance of 2 D C/C composites are mainly beneficial from their increased cohesion of interlaminar matrix, which is caused not only by the direct reinforcing effect of EPD CNT network but also by the capacity of EPD CNTs to refine pyrocarbon matrix and induce multilayered microstructures that greatly increase the crack propagation resistance through ＂crack-blocking and-deflecting mechanisms＂.

Effect of pH on Mechanical, Physical and Tribological Properties of Electroless Ni-P-Al2〇 3 Composite Deposits for Marine Applications

Successful co-deposition of fine particulate matter within an Electroless Nickel-Phosphorous(ENi-P) matrix is dependent on various factors like bath composition, particle compatibility with metallic matrix, bath reactivity(pH), particle size and their distribution. ENi-P deposits incorporating Al_2O_3/Alumina in a disperse phase have varied effects on properties and attributes like surface roughness(Ra), microhardness, wear resistance, corrosion resistance and surface morphology of the deposits obtained. This paper experimentally investigates the effect of alumina(1.55 g/L) on Ra, microhardness, surface morphology, deposition rate, wettability, wear resistance and corrosion resistance of ENi-P-Al_2O_3 composite deposits on mild steel substrates at bath pH 5, 7 and 9. Study reveals that optimum deposit parameters and deposition rates are achieved with bath pH. However, not much study has been undertaken concerning composite deposits obtained from higher bath pH or basic bath. This is attributable to the fact that at higher bath pH or alkaline baths, the bath gets unstable and eventually degrades or decomposes, thereby resulting in sub optimal or poor deposition. Hence, experimental investigations carried out by preparing suitable baths, operating under optimum conditions, and enabling successful composite deposition in acidic and alkaline baths have revealed that there is a significant improvement in the above mentioned properties of the as-deposited composite deposits, as the pH is increased from pH 5 to pH 9. This aspect can therefore be advantageously utilized for preparing various marine components like fasteners, nuts, bolts, washers, pipes, cables, components having relative motion etc.

Experimental and Modeling Studies on the Chemical Vapor Infiltration with Respect to the Effects of Thermal Gradient and Other Operating Parameters

Effects of operating parameters in the thermal gradient chemical vapor infiltration of propane such as thermal gradient, diffusion, infiltrations time, and concentration of propane were studied by focusing on the visualizations of the intrinsic effects of these parameters. A uniform deposition in the preform was obtained with a gradually increasing temperature along the gas flow. The uniformity of deposition through the preform got improved with increasing deposition time. Results of numerical modeling estimated the experimental data very well when the pre-exponential factor of the overall rate of carbon deposition from propane reported by Vaidyaraman[1] was multiplied by 4. The average density of a preform increased by about 3 times from 0.38 to 1.15 g/cm3 after 60 hr deposition with a thermal gradient under the conditions of 3% propane in nitrogen and 840 to 900 ℃.

Study on the Pyrolytic Carbon Generated by the Electric Heating CVD Method

A new method of fabricating C/C composite materials, namely electric heating CVD method, was used, which electrified the carbon fiber directly by using the conductivity of itself. Acetylene was used as the carbon source with nitrogen as dilution gas, and the pyrolytic carbon started to deposit on the carbon fiber surface when the deposition temperature was reached. The morphology of pyrolytic carbon was characterized by SEM, and the surface properties of carbon fibers before and after CVD were characterized by Raman spectroscopy. The experimental results show that the electric heating method is a novel method to fabricate C/C composite materials, which can form a dense C/C composite material in a short time. The order degree and the average crystallite size of the carbon fiber surface were decreased after the experiment.

Size and elemental composition of dry-deposited particles during a severe dust storm at a coastal site of Eastern China

Dry-deposited particles were collected during the passage of an extremely strong dust storm in March, 2010 at a coastal site in Qingdao（36.15°N, 120.49°E）, a city located in Eastern China. The size, morphology, and elemental composition of the particles were quantified with a scanning electron microscope equipped with an energy dispersive X-ray instrument（SEM–EDX）. The particles appeared in various shapes, and their size mainly varied from 0.4to 10 μm, with the mean diameters of 0.5, 1.5, and 1.0 μm before, during, and after the dust storm, respectively. The critical size of the mineral particles settling on the surface in the current case was about 0.3–0.4 μm before the dust storm and about 0.5–0.7 μm during the dust storm. Particles that appeared in high concentration but were smaller than the critical size deposited onto the surface at a small number flux. The elements Al, Si and Mg were frequently detected in all samples, indicating the dominance of mineral particles. The frequency of Al in particles collected before the dust storm was significantly lower than for those collected during and after the dust storm. The frequencies of Cl and Fe did not show obvious changes, while those of S, K and Ca decreased after the dust arrival. These results indicate that the dust particles deposited onto the surface were less influenced by anthropogenic pollutants in terms of particle number.