The late Early-Paleozoic granitic magmatism in Northwestern Fujian, China: constraints on intraplate orogeny in the South China block

The Early Paleozoic tectono-thermal event was a significant orogenic activity during the Phanerozoic era,which had a profound impact on the early crust of the South China Block(SCB) and established the foundation for later tectonic activity.The Wuyi-Yunkai orogenic belt in Southeastern China was extensively exposed to Early Paleozoic magmatism,the genetic mechanism of which remains controversial.To shed light on this issue,detailed petrological,geochemical,and zircon U-Pb-Hf isotopic studies were carried out on two granitoids,namely the Yuntongshan pluton and the Gaoqiao pluton,identified in the central Wuyishan.Zircon U-Pb chronology of the Yuntongshan and Gaoqiao bodies yielded ages of437±4 Ma(MSWD=2.2) and 404±2 Ma(MSWD=12),respectively,indicating that they were emplaced during the Early Silurian and Early Devonian periods.These granitoids are primarily composed of biotite-granite and biotite-monzonitic-granites,with high concentrations of S_(i)O_(2)(73.59-75.91 wt%),K_(2)O+Na_(2)O(8.31-8.73wt%),and low contents of MgO,CaO,Cr,Ni.They are classified as high-K calc-alkaline and weakly metaluminous-strongly peraluminous S-type granites.These granitoids are enriched in light rare earth elements(LREEs) and large ion lithophile elements(LILEs) and depleted in heavy rare earth elements(HREEs) and high field strength elements(HFSEs) with arc affinity.The εHf(t) values of-3.3 to-15.4 with two-stage Hf model ages ranging from 2829 to 1644 Ma,combined with the presence of Neoproterozoic inherited zircons,suggest that the primary magma of these granitoids was derived from the partial melting of Neoproterozoic crust with a Paleoproterozoic crustal model age.These findings,combined with the spatio-temporal distribution of regional magmatism,reveal that the late Early-Paleozoic granitoids formed in the intraplate orogenic background originating from the subduction of the proto-Tethys Ocean and proto-Pacific Ocean around the margin of the east Gondwana supercontinent.

Research on Composite Errors of Long Gage Blocks

The factor having effect on compostie errors of long gage blocks and their control are discussed, and a ba-sis is therefore provided for driprovement of composite accuracy. Calculations and experiments were conduted for de-formation error resulting for clamp foree and the effect of additional bending moment on parallelism of the measure-ment surfaces. With gage blocks of different length in good conact, clamp force and suppotrs properly chosen, the composite error can be controlled within 0.1μp by reducing or eliminating the effect of additional bending moment on parallelism of measurement surfaces.

Corundum Based Composite Block Containing Plastic Phase

1 Scope This standard specifies the definition, classification, technical requirements, test methods, inspection rules, packing, marking, transportation and quality certificate of corundum block containing plastic phase.

Portland Cement-Residues-Polymers Composites and Its Application to the Hollow Blocks Manufacturing

Agricultural wastes and sawdust combined with cement matrix in the manufacture of building elements has been practiced with success in developed countries. In this study, sawdust from wood species (Pinus caribaea and Eucalyptus grandis) and an agricultural waste—rice husk (Oriza sativa) were combined with Portland cement type V (high initial strength), modified by polymer styrene-butadiene (SBR) addition. Hollow blocks produced with Eucalyptus grandis and rice husk residues showed better compressive strength;however, those produced with residues derived from Pinus caribaea presented non-satisfactory results, due to the particle size that was used.

C-V Characterization of α-Fe_2O_3/Block-Copolymer Composite Particulate Films

α-Fe_2O_3 nanocrystal was encapsulated by a block-copolymer, hydroxylated poly (styrene-b- butadiene-styrene) (HO-SBS) to fabricate composite microspheres with α-Fe_2O_3 cores and HOSBS shell. Its film fabricated on n-Si wafer acts as the insulator layer in the metal-insulator- semiconductor(MIS) structure. The capacitance-voltage (C-V) properties were measured to characterize the composite particulate films.

Coordinate unification method of high-precision composite measurement in two dimensions

Multi-sensor coordinate unification in dimensional metrology is used in order to get holistic, more accurate and reliable information about a workpiece based on several or multiple measurement values from one or more sensors. Because of the problem that standard ball is deficient as a standard artifact in the coordinate unification of high-precision composite measurement in two dimensions （2D） , a new method is proposed in this paper which uses angle gauge blocks as standard artifacts to achieve coordinate unification between the image sensor and the tactile probe. By comparing the standard ball with the angle gauge block as a standard artifact, theoretical analysis and experimental results are given to prove that it is more precise and more convenient to use angle gauge blocks as standard artifacts to achieve coordinate unification of high-precision composite measurement in two dimensions.

Influence of thickness and projectile shape on penetration resistance of the compliant composite

The present study deals with development of conceptual proof for jute rubber based flexible composite block to completely arrest the projectile impacting the target at high velocity impact of 400 m/s through numerical simulation approach using finite element(FE)method.The proposed flexible composite blocks of repeating jute/rubber/jute(JRJ)units are modelled with varying thickness from 30 mm to 120 mm in increments of 30 mm and impacted by flat(F),ogival(O)and hemispherical(HS)shaped projectiles.All the considered projectiles are impacted with proposed flexible composite blocks of different thicknesses and the penetration behaviour of the projectile in each case is studied.The penetration depth of the projectile in case of partially penetrated cases are considered and the effect of thickness and projectile shape on percentage of penetration depth is statistically analyzed using Taguchi’s design of experiments(DOE).Results reveal that the though proposed flexible composite block with thickness of 90 mm is just sufficient to arrest the complete penetration of the projectile,considering the safety issues,it is recommended to use the flexible composite with thickness of 120 mm.The nature of damage caused by the projectile in the flexible composite is also studied.Statistical studies show that thickness of the block plays a prominent role in determining the damage resistance of the flexible composite.

Preparation technique of SiCp reinforced Al matrix composite

A new preparation technique-"block dispersal and cast" method is introduced, and three kinds of powder mixing methods, vertical, horizontal and inclining styles, are compared. The results demonstrate that the inclining style is the best way to mix powders. The Al and nano SiC powders are pressed into blocks, dipped into molten Al, stirred into mold so that SiC/Al matrix composites can be obtained at last. The microstructure of SiC particle reinforced Al matrix composite prepared by "block dispersal and cast" method have been studied using scanning electron microscopy (SEM). Phase analysis has also been conducted by means of X-ray diffraction (XRD). The results show that nano SiC particles can be dispersed uniformly in Al matrix. Thus, it is feasible to prepare SiC particle reinforced Al matrix composites by this method.

STUDIES ON POLY(ETHYLENE TEREPHTHA LATE)-POLY(TETRAMETHYLENE ETHER) MULTIBLOCK COPOLYMER.Ⅰ.COMPOSITIONAL HOMOGENEITY

The compositional homogeneity of a poly (ethylene terephthalate)-poly (tetramethylene ether) multiblock copolymer sample with low content of hard segment was examined by GPC, TLC, and solubility method. The copolymer sample was found to have a uniform composition as a function of elution volume over the major portion of sample from GPC method. However within one elution fraction, the copolymer chains, although having the same hydrodynamic volume, may have some difference in composition. Two fractions with different composition were obtained by precipitation in ethanol. Some low molar mass copolymers were also separated by a TLC technique from the copolymer sample.

Sulfur/carbon composites prepared with ordered porous carbon for Li-S battery cathode

Ordered porous cabon with a 2-D hexagonal structure,high specific surface area and large pore volume was synthesized through a twostep heating method using tri-block copolymer as template and phenolic resin as carbon precursor.The results indicated the electrochemical performance of the sulfur/carbon composites prepared with the ordered porous carbon was significantly affected by the pore structure of the carbon.Both the specific capacity and cycling stability of the sulfur/carbon composites were improved using the bimodal micro/meso-porous carbon frameworks with high surface area.Its initial discharge capacity can be as high as 1200 mAh·g-1 at a current density of 167.5 mA·g-1The improved capacity retention was obtained during the cell cycling as well.

沼液滴灌条件下不同类型灌水器的堵塞特征

为了探求不同类型灌水器在沼液滴灌中的抗堵塞性能,研发适用于沼液滴灌的灌水器,明确沼液滴灌条件下灌水器的堵塞类型。选用内镶贴片式灌水器(1.38、2、3 L/h)、内镶圆柱式灌水器(2、3 L/h)、压力补偿式灌水器(2、4、6 L/h)三类灌水器,在灌水压力0.08 MPa、水沼液配比4∶1(体积比)条件下进行周期性间歇灌水试验,比较不同灌水器的堵塞情况,并使用扫描电镜分析堵塞物的粒径大小及各粒径占比情况,同时结合堵塞物的傅里叶红外光谱图分析堵塞物的组成成分。结果表明,8种灌水器(E1~E8)达到堵塞标准所需的时间分别为108、126、141、111、132、84、102和117 h;灌水器堵塞物在出水口、进水口以及过水流道内均有分布,进水口处为黄色泥沙沉积,出水口及过水流道拐角处为黑色絮状物;堵塞物成分为沙粒、碳酸盐、硫酸盐、磷酸盐等无机化合物以及烃类、蛋白质、脂类等有机物;堵塞物中88.42%的颗粒物粒径集中在0.2~1.4μm的粒径范围内,其余11.58%为大絮状物。综上所述,同类型灌水器中,额定流量越大的灌水器达到堵塞标准所需的时间越长,抗堵塞性能越好;同额定流量的灌水器,内镶贴片式灌水器的抗堵塞性能最佳;额定流量3 L/h的内镶贴片式灌水器的抗堵塞性能最佳;灌水器发生的堵塞类型为物理-化学-生物三者协同作用导致的复合型堵塞。

马鞍山长江公铁大桥主航道桥中塔下横梁施工关键技术

马鞍山长江公铁大桥主航道桥Z4号中塔采用空间四肢A形钢-混组合塔,横向两塔肢间设下横梁,下横梁间设3道系梁,纵向两塔肢间不设置横梁。下横梁采用支架法分层浇筑施工。下横梁施工支架采用落地式钢管支架配套模板体系,受力性能满足要求;通过有限元计算比选下横梁混凝土分层浇筑方案并进行优化,采取(5.5+2.5)m分层方案,上、下层混凝土分别分为2块、3块分层分块浇筑;通过低温升、易泵送、高抗裂的C60混凝土研制、下横梁与塔柱倒弧结合面抗裂措施优化、分块间接缝构造形式及施工工艺优化、下横梁与系梁混凝土浇筑施工组织优化、混凝土温度智能化监控、预应力束张拉时机控制等混凝土防裂措施,有效解决了下横梁大体积混凝土易开裂的难题。

木质素基紫外阻隔膜材料的研究进展

本文基于与纤维素、可降解塑料和其他聚合物材料复合的3种木质素复合材料体系,总结了木质素基紫外阻隔膜材料的研究进展。阐述了木质素分子结构与紫外吸收性能的相关性,以及其对复合材料光稳定性、力学强度和阻隔性能等方面的影响。对木质素在不同复合膜材料体系中的提升机制和膜材料的功能应用进行了讨论。此外,基于木质素的紫外吸收等功能特性,对其在多功能复合膜材料的开发和潜在应用进行了展望,为木质素高值转化和利用提供一定参考。

陆相页岩储集层含水饱和度测井计算方法——以川东南复兴区块凉高山组为例

陆相页岩储集层具有低孔特低渗特征,其黏土矿物含量高,岩石组成变化快,地层非均质性强,利用传统阿尔奇公式及常规数理统计模型计算的含水饱和度误差大。为提高陆相页岩储集层含水饱和度计算精度,以川东南复兴区块下侏罗统凉高山组页岩为例,分析了现有含水饱和度测井计算方法的局限性,阐述了利用阵列声波测井中的纵横波时差与测井密度组合重构的复合波阻抗计算含水饱和度的可行性。在此基础上,提出了陆相页岩储集层含水饱和度计算方法。该方法考虑了岩石矿物的影响,有效避开了电法测井和非电法测井的局限性,提高了适用性。在川东南复兴区块多口井凉高山组页岩储集层的应用效果好,计算得到的含水饱和度与岩心分析含水饱和度较吻合,绝对误差为1.3%~2.2%,满足测井评价要求。

高水头旋流阻塞复合内消能工水力特性研究

旋流阻塞复合内消能工是适用于高坝泄洪消能的一种新型消能工,为了分析其在超高作用水头下的泄洪消能适用情况,采用模型试验与数值模拟相结合的方法,对200 m作用水头条件下该消能工的水力特性进行了研究。结果表明:泄流量为1547 m^(3)/s,略大于设计值,满足泄流要求;洞内形成了稳定的空腔旋流,旋流洞段空腔直径约6~7 m,旋流角约60°,壁面压强约110×9.8 kPa,最大点流速约45 m/s;起旋器与旋流洞段为0.050~0.274 Hz的低频脉动,且水流空化数均大于1.2,运行安全;阻塞扩散段末端最小瞬时负压为-3.81×9.8 kPa,且水流空化数较小,但水流掺气率较高,有利于减免发生空蚀;阻塞扩散段末脉动优势频率为46.99 Hz;总消能率达82.1%,消能率高。研究成果可为该复合消能工在高水头下的泄洪消能应用提供参考。

临兴气田井筒堵塞机理及现场解堵工艺研究

临兴区块自投产以来,井筒堵塞问题日益严重,导致气井生产测试、措施作业等无法正常开展。文章结合区块堵塞物的粒径分析、无机成分XRD、红外等分析结果,明确了堵塞物成分主要包括石英、石盐、难溶盐垢(以硅铝酸盐垢为主)及少量的铁垢和固体砂砾等,主要堵塞类型为砂堵、腐蚀结垢及结盐堵塞等。通过解堵实验,优选出HYJD-10和CAWF两种解堵剂体系,静态溶蚀实验最高溶解率分别可达25.3%及18.3%,驱替实验最优渗透率的提高率分别可达105.9%及91.3%。现场结合注解堵剂、气举及泡沫流体等方式进行解堵作业,单井平均增产不小于9 000 m3/d,最高增产25 000 m3/d。本研究为致密气井井筒解堵试验提供了参考。

新型竖缝互锁灌孔复合砌块墙体抗压及抗震性能试验研究

新型竖缝互锁灌孔复合砌块墙体是一种绿色、环保且低碳的新型砌体结构,为研究其抗压性能与抗震性能,分别对墙体进行轴压试验与拟静力试验,分析灌孔方式与构造柱类型对该墙体抗压承载力、荷载分配与变形协调等方面的影响,以及不同构造柱类型对墙体抗震性能的影响。结果表明,随着现浇构造柱与复合砌体部分强度差的减小,墙体整体变形协调能力有所提升;提出了适用于设置构造柱的新型墙体的抗压承载力计算公式,计算值与试验值吻合度较好;芯柱构造柱对墙体延性的提升效率高于现浇构造柱墙体,而现浇构造柱墙体的抗震承载力、极限位移等指标优于芯柱构造柱墙体。研发绿色、环保、低碳的新型砌体结构是助力国家乡村振兴战略和改善村镇建筑抗灾能力的有效途径,该新型墙体结构为新疆地区村镇建筑提供了一种新的选择。

聚醚嵌段聚酰胺共聚物的合成及其在膜分离中的应用

聚醚嵌段聚酰胺共聚物(PEBA)由聚酰胺硬段和聚醚软段所组成,这种软硬结合的结构使其拥有较高的强度和弹性,应用领域广泛。本文介绍了水解开环聚合法和阴离子聚合法等PEBA两种合成方法,以及溶液浇筑法和浸渍涂覆法等PEBA及其复合膜的制备方法。综述了近年来PEBA及其复合膜在诸如有机物/水、污水处理、CO_(2)/N_(2)、烯烃/烷烃等领域的膜分离研究进展,为今后PEBA分离膜的研究应用提供参考。

异形双曲面楼承板节点构造及施工方法

为解决异形双曲面钢筋桁架组合楼板施工的难题,对某工程异形双曲面楼承板施工过程中的几种技术措施进行分析和总结,形成较为完整的施工工艺。总结的单元化、以直代曲等技术可为滑雪场、商业楼等异形双曲面钢筋桁架组合楼板施工提供借鉴。

大倾角大采高软弱顶底板工作面分区矿压规律研究

为研究内蒙古长城二矿大倾角大采高软弱顶底板复杂开采地质条件下,1305S工作面正常区、过渡区、卸压区的矿压显现规律及特征,建立了倾斜煤层采空区冒落矸石滑移充填数值模拟模型,采用数值模拟和现场实测相结合的研究方法进行研究。研究结果表明:沿倾斜方向,1305S工作面中上部所受垂直应力呈现出过渡区>正常区>卸压区的特点,工作面下部呈现出卸压区>过渡区>正常区的特点;1305S工作面推进过程中,平均周期来压步距为13.3 m,周期来压时支架工作阻力在26.75~33.05 MPa之间,沿工作面倾斜方向顶板所受垂直应力总体呈现出工作面上部>中部>下部的特点;巷道工作面一侧的边帮变形量较大。现场实测结果表明,回风巷顶板监测最大移进量为860.18 mm,运输巷顶板监测最大移进量为367.84 mm,两巷围岩移进量呈现出回风巷>运输巷的特点。