The 2D limit equilibrium method is widely used for slope stability analysis.However,with the advancement of dump engineering,composite slopes often exhibit significant 3D mechanical effects.Consequently,it is of signi...The 2D limit equilibrium method is widely used for slope stability analysis.However,with the advancement of dump engineering,composite slopes often exhibit significant 3D mechanical effects.Consequently,it is of significant importance to develop an effective 3D stability calculation method for composite slopes to enhance the design and stability control of open-pit slope engineering.Using the composite slope formed by the mining stope and inner dump in Baiyinhua No.1 and No.2 open-pit coal mine as a case study,this research investigates the failure mode of composite slopes and establishes spatial shape equations for the sliding mass.By integrating the shear resistance and sliding force of each row of microstrip columns onto the bottom surface of the strip corresponding to the main sliding surface,a novel 2D equivalent physical and mechanical parameters analysis method for the strips on the main sliding surface of 3D sliding masses is proposed.Subsequently,a comprehensive 3D stability calculation method for composite slopes is developed,and the quantitative relationship between the coordinated development distance and its 3D stability coefficients is examined.The analysis reveals that the failure mode of the composite slope is characterized by cutting-bedding sliding,with the arc serving as the side interface and the weak layer as the bottom interface,while the destabilization mechanism primarily involves shear failure.The spatial form equation of the sliding mass comprises an ellipsoid and weak plane equation.The analysis revealed that when the coordinated development distance is 1500 m,the error rate between the 3D stability calculation result and the 2D stability calculation result of the composite slope is less than 8%,thereby verifying the proposed analytical method of equivalent physical and mechanical parameters and the 3D stability calculation method for composite slopes.Furthermore,the3D stability coefficient of the composite slope exhibits an exponential correlation with the coordinated development distance,with the coefficient gradually decreasing as the coordinated development distance increases.These findings provide a theoretical guideline for designing similar slope shape parameters and conducting stability analysis.展开更多
Bioactive thermal spray coatings produced via high-velocity oxygen fuel spray(HVOF)from hydroxyapatite(HAp)and bioactive glasses(BG)have the potential to be employed on temporary implants due to the ability of both HA...Bioactive thermal spray coatings produced via high-velocity oxygen fuel spray(HVOF)from hydroxyapatite(HAp)and bioactive glasses(BG)have the potential to be employed on temporary implants due to the ability of both HAp and BG to dissolve and promote osseointegration,considering that both phases have different reaction and dissolution rates under in-vitro conditions.In the present work,75%wt.HAp-25%wt.S53P4 bioactive glass powders were HVOF-sprayed to obtain HAp/S53P4 BG composite coatings on a bioresorbable AZ31 alloy.The study is focused on exploring the effect of the stand-off distance and fuel/oxygen ratio variation as HVOF parameters to obtain stable structural coatings and to establish their effect on the phases and microstructure produced in those coatings.Different characterization techniques,such as scanning electron microscopy,X-ray diffraction,and Fourier transform infrared spectroscopy,were employed to characterize relevant structural and microstructural properties of the composite coatings.The results showed that thermal gradients during coating deposition must be managed to avoid delamination due to the high temperature achieved(max 550℃)and the differences in coefficients of thermal expansion.It was also found that both spraying distance and oxygen/fuel ratio allowed to keep the hydroxyapatite as the main phase in the coatings.In addition,in-vitro electrochemical studies were performed on the obtained HAp/S53P4 BG composite coatings and compared against the uncoated AZ31 alloy.The results showed a significant decrease in hydrogen evolution(at least 98%)when the bioactive coating was applied on the Mg alloy during evaluation in simulated body fluid(SBF).展开更多
To make full use of plant shellfibers(rice husk,walnut shell,chestnut shell),three kinds of wood-plastic com-posites of plant shellfibers and polyvinyl chloride(PVC)were prepared.X-ray diffraction analysis was carried o...To make full use of plant shellfibers(rice husk,walnut shell,chestnut shell),three kinds of wood-plastic com-posites of plant shellfibers and polyvinyl chloride(PVC)were prepared.X-ray diffraction analysis was carried out on three kinds of plant shellfibers to test their crystallinity.The aging process of the composites was conducted under 2 different conditions.One was artificial seawater immersion and xenon lamp irradiation,and the other one was deionized water spray and xenon lamp irradiation.The mechanical properties(tensile strength,flexural strength,impact strength),changes in color,water absorption,Fourier transform infrared spectroscopy(FTIR),and microstructures of the composites before and after the two aging experiments were analyzed.The results showed that the chestnut shell had the highest crystallinity,which was 42%.The chestnut shell/PVC composites had the strongest interface bonding,the least internal defects,and the best general mechanical properties among the three composites.Its tensile strength,bending strength and impact strength were 23.81 MPa,34.12 MPa,and 4.32 KJ·m^(-2),respectively.Comparing the two aging conditions,artificial seawater immersion and xenon lamp irradiation destroyed the quality of the combination of plant shellfibers and PVC,making the internal defects of the composites increase.This made the water absorption ability and changes in the color of the composites more obvious and led to a great decrease in the mechanical properties.The general mechanical properties of the chestnut shell/PVC composites were the best,but their water absorption ability changed more obviously.展开更多
Silica fibers-reinforced, fused silica composites were fabricated with repeated vacuum-assisted liquid-phase infiltration. The mechanical properties, thermal properties, and ablative properties of the samples were eva...Silica fibers-reinforced, fused silica composites were fabricated with repeated vacuum-assisted liquid-phase infiltration. The mechanical properties, thermal properties, and ablative properties of the samples were evaluated. The effect of the silica fiber content and treatment temperature on the flexural strength of the three-dimensional SiO2 (3-D SiO2) composites also was investigated. The SiO2 composites show good mechanical properties and excellent ablative performance. The flexural strength increases with an increase in silica fiber content, and decreases with an increase in treatment temperature. When the volume fraction of the silica fiber is 50vo1% and the treatment temperature is 700℃ the flexural strength of the composites reaches a maximum value of 78 MPa. By adding cyclohexanone surfactant, the infiltration property can be largely improved, resulting in the density of SiO2 composites increasing up to 1.65 g/cm^3. The fracture surfaces of the flexural specimens observed using SEM, show that the pseudoplasticity and the toughening mechanisms of the composites are caused by absorption of a lot of energy by interface debonding and fiber pulling out.展开更多
Particulate-reinforced metal matrix composites(PRMMCs)are difficult to machine due to the inclusion of hard,brittle reinforcing particles.Existing experimental investigations rarely reveal the complex material removal...Particulate-reinforced metal matrix composites(PRMMCs)are difficult to machine due to the inclusion of hard,brittle reinforcing particles.Existing experimental investigations rarely reveal the complex material removal mechanisms(MRMs)involved in the machining of PRMMCs.This paper develops a three-dimensional(3D)microstructure-based model for investigating the MRM and surface integrity of machined PRMMCs.To accurately mimic the actual microstructure of a PRMMC,polyhedrons were randomly distributed inside the matrix to represent irregular SiC particles.Particle fracture and matrix deformation and failure were taken into account.For the model’s capability comparison,a two-dimensional(2D)analysis was also conducted.Relevant cutting experiments showed that the established 3D model accurately predicted the material removal,chip morphology,machined surface finish,and cutting forces.It was found that the matrix-particle-tool interactions led to particle fractures,mainly in the primary shear and secondary deformation zones along the cutting path and beneath the machined surface.Particle fracture and dilodegment greatly influences the quality of a machined surface.It was also found that although a 2D model can reflect certain material removal features,its ability to predict microstructural variation is limited.展开更多
Three-dimensional( 3 D) fabric composite is a newly developed sandwich structure,consisting of two identical parallel fabric decks woven integrally and mechanically together by means of vertical woven fabrics. In this...Three-dimensional( 3 D) fabric composite is a newly developed sandwich structure,consisting of two identical parallel fabric decks woven integrally and mechanically together by means of vertical woven fabrics. In this paper,six types of 3 D fabric sandwich composites were developed in terms of compressive and flexural properties as a function of pile height( 10, 20 and30 mm) and pile distance( 16, 24 and 32 mm) in pile structures. The mechanical characteristics and the damage modes of the 3 D fabric sandwich composites under compressive and flexural load conditions were investigated. Besides,the influence of pile height and pile distance on the 3 D fabric sandwich composites mechanical properties was analyzed. The results showed that the compressive properties decreased with the increase of the pile height and the pile distance. Flexural properties increased with the increase of pile height, while decreased with the increase of pile distance.展开更多
The effects of fiber volume fraction on damping properties of carbon fiber three-dimensional and five-directional( 3D-5Dir)braided carbon fiber / epoxyres in composite cantilever beams were studied by experimental mod...The effects of fiber volume fraction on damping properties of carbon fiber three-dimensional and five-directional( 3D-5Dir)braided carbon fiber / epoxyres in composite cantilever beams were studied by experimental modal analysis method. Meanwhile,carbon fiber plain woven laminated / epoxy resin composites with different fiber volume fraction were concerned for comparison. The experimental result of braided specimens shows that the first three orders of natural frequency increase and the first three orders of the damping ratios of specimens decrease, when the fiber volume fraction increases. Furthermore,larger fiber volume fraction will be valuable for the better anti-exiting property of braided composites,and get an opposite effect on dissipation of vibration energy. The fiber volume fraction is an important factor for vibration performance design of braided composites. The comparison between the braided specimens and laminated specimens reveals that 3D braided composites have a wider range of damping properties than laminated composites with the same fiber volume fractions.展开更多
This work provides a method to predict the three-dimensional equivalent elastic properties of the filament-wound composites based on the multi-scale homogenization principle.In the meso-scale,a representative volume e...This work provides a method to predict the three-dimensional equivalent elastic properties of the filament-wound composites based on the multi-scale homogenization principle.In the meso-scale,a representative volume element(RVE)is defined and the bridging model is adopted to establish a theoretical predictive model for its three-dimensional equivalent elastic constants.The results obtained through this method for the previous experimental model are compared with the ones gained respectively by experiments and classical laminate theory to verify the reliability of this model.In addition,the effects of some winding parameters,such as winding angle,on the equivalent elastic behavior of the filament-wound composites are analyzed.The rules gained can provide a theoretical reference for the optimum design of filament-wound composites.展开更多
To improve the specific capacitance and rate capability of electrode material for supercapacitors, a three-dimensional graphene/polyaniline (3DGN/PANI) composite is prepared via in situ polymerization on GN hydrogel...To improve the specific capacitance and rate capability of electrode material for supercapacitors, a three-dimensional graphene/polyaniline (3DGN/PANI) composite is prepared via in situ polymerization on GN hydrogel. PANI grows on the GN surface as a thin film, and its content in the composite is controlled by the concentration of the reaction monomer. The specific capacitance of the 3DGN/PANI composite containing 10 wt% PANI reaches 322.8 F.g-1 at a current density of 1 A.g-1, nearly twice as large as that of the pure 3DGN (162.8 F.g-1). The capacitance of the composite is 307.9 F.g-1 at 30 A.g-1 (maintaining 95.4%), and 89% retention after 500 cycles. This study demonstrates the exciting potential of 3DGN/PANI with high capacitance, excellent rate capability and long cycling life for supercapacitors.展开更多
As a thermosetting resin with excellent properties,epoxy resin is used in many areas such as electronics,transportation,aerospace,and other fields.However,its relatively low thermal conductivity limits its wide applic...As a thermosetting resin with excellent properties,epoxy resin is used in many areas such as electronics,transportation,aerospace,and other fields.However,its relatively low thermal conductivity limits its wide application in more demanding fields.Here,a three-dimensional carbon(3DC)network was prepared through NaCl template-assisted in situ chemical vapor deposition(CVD)and used to reinforce epoxy resin for enhancing its thermal conductivity.The 3DC was prepared with a molar ratio of sodium atom to carbon atom of 100:20,and argon atmosphere in CVD led to an optimal improvement in the thermal conductivity of epoxy resin.The thermal conductivity of epoxy resin increased by 18%when the filling content was 3 wt.%of 3DC network because of the high contact area,uniform dispersion,and enhanced formation of conductive paths with epoxy resin.As the amount of 3DC addition increases,the thermal conductivity of composites also increases.As an innovative exploration,the work presented in this paper is of great significance for the thermal conductivity application of epoxy resin in the future.展开更多
By making use of the direct integration method,an exact analysis of the general three-dimensional thermoelasticity problem is performed for the case of a transversely isotropic homogeneous half-space subject to local ...By making use of the direct integration method,an exact analysis of the general three-dimensional thermoelasticity problem is performed for the case of a transversely isotropic homogeneous half-space subject to local thermal and force loadings.The material plane of isotropy is assumed to be parallel to the limiting surface of the halfspace.By reducing the original thermoelasticity equations to the governing ones for individual stress-tensor components,the effect of material anisotropy in the stress field is analyzed with regard to the feasibility requirement,i.e.,the finiteness of the stress field at a distance from the disturbed area.As a result,the solution is constructed in the form of explicit analytical dependencies on the force and thermal loadings for various kinds of transversely isotropic materials and agrees with the basic principles of the continua mechanics.The solution can be efficiently used as a benchmark one for the direct computation of temperature and thermal stresses in transversely isotropic semi-infinite domains,as well as for the verification of solutions constructed by different means.展开更多
Three-dimensional(3D)braided composites with better properties have been used in some particular industries.Some have had obvious signs of crack when they are braided.Others have had catastrophic failures occuring wit...Three-dimensional(3D)braided composites with better properties have been used in some particular industries.Some have had obvious signs of crack when they are braided.Others have had catastrophic failures occuring without warning.A new methodology for the analysis of failure modes in composite materials by means of acoustic emission techniques has been developed.The occurrence of fiber-breakage during tensile loading tests has been observed by the acoustic emission technology.Using acoustic emission technology is investigated as a means of monitoring 3D braided composites structures,detecting damage,and predicting impending damage.Some of the findings of the research project were presented.展开更多
Ultrasonic arc spray atomization (UASA) method was used to prepare high-melting-point, immiscible AgNi15 (mass fraction, %) composite particles. Sieving was used to determine the size distribution of the AgNi15 partic...Ultrasonic arc spray atomization (UASA) method was used to prepare high-melting-point, immiscible AgNi15 (mass fraction, %) composite particles. Sieving was used to determine the size distribution of the AgNi15 particles. The morphology, rapidly solidified structure and metastable solution expansion of the AgNi15 particles were analyzed by scanning electron microscopy (SEM), X-ray diffraction (XRD) and energy dispersive spectroscopy (EDS), respectively. The results show that the AgNi15 composite particles are spherical and well-dispersed, and the mass fractions of the particles with diameters <74μm and <55 μm are 99.5% and 98%, respectively. The rapidly solidified structure of the AgNi15 particles consists of spherical nickel-richβ(Ni)-phase particles dispersed throughout a silver-richα(Ag)-phase matrix andα(Ag)-phase nanoparticles dispersed throughout largerβ(Ni)-phase particles. The silver and nickel in the AgNi15 particles form a reciprocally extended metastable solution, and the solid solubility of nickel in the silver matrix at room temperature is in the range of 0.16%?0.36% (mole fraction).展开更多
Al-Si/15%SiCp(volume fraction) composites with different silicon contents were fabricated by spray deposition technique, and typical microstructures of these composites were studied by optical microscopy(OM). Dry slid...Al-Si/15%SiCp(volume fraction) composites with different silicon contents were fabricated by spray deposition technique, and typical microstructures of these composites were studied by optical microscopy(OM). Dry sliding wear tests were carried out using a block-on-ring wear machine to investigate the effect of applied load range of 10-220 N on the wear and friction behavior of these composites sliding against SAE 52100 grade bearing steel. Scanning electron microscopy(SEM) and energy-dispersive X-ray microanalysis(EDAX) were utilized to examine the morphologies of the worn surfaces in order to observe the wear characteristics and investigate the wear mechanism. The results show that the wear behavior of these composites is dependent on the silicon content in the matrix alloy and the applied load. Al-Si/15%SiCp composites with higher silicon content exhibit better wear resistance in the applied load range. Under lower loads, the major wear mechanisms are oxidation wear and abrasive wear for all tested composites. Under higher loads, severe adhesive wear becomes the main wear mechanisms for Al-7Si/15%SiCp and Al-13Si/15%SiCp composites, while Al-20Si/15%SiCp presents a compound wear mechanism, consisting of oxidation, abrasive wear and adhesion wear.展开更多
A fully dense carbon nanotubes (CNTs) reinforced AlSi matrix composite with the multiscale nacre-like architecture was designed and successfully realized by flake powder metallurgy followed by cold spraying (CS). The ...A fully dense carbon nanotubes (CNTs) reinforced AlSi matrix composite with the multiscale nacre-like architecture was designed and successfully realized by flake powder metallurgy followed by cold spraying (CS). The nanolaminated and ultrafine-grained structure initially created in the CNT/AlSi flaky powder was perfectly conserved, due to the typical ‘cold’ feature of CS. As discussed based on finite element analysis and single splat observation, self-alignment behavior of the flaky powders during impact also allowed the formation of the microlaminated structure. Hence, the scalable CS technique opens a new avenue for bioinspired material design and fabrication with complex shape.展开更多
The effects of microwave sintering on the properties, phases and microstructure of W-2OCu alloy, using composite powder fabricated by spray pyrolysis-continuous reduction technology, were investigated. Compared with t...The effects of microwave sintering on the properties, phases and microstructure of W-2OCu alloy, using composite powder fabricated by spray pyrolysis-continuous reduction technology, were investigated. Compared with the conventional hot-press sintering, microwave sintering to W-2OCu composites could be achieved with lower sintering temperature and shorter sintering time. Furthermore, microwave sintered W-Cu composites with high densification, homogenous microstructure and excellent properties were obtained. Microwave sintering could also result in finer microstructures. :~展开更多
In situ TiB2/Cu composites were fabricated by both solid-liquid(S-L)and liquid-liquid(L-L)reactive spray deposition in combination with cold rolling and annealing.The microstructure and properties of the fabricated Ti...In situ TiB2/Cu composites were fabricated by both solid-liquid(S-L)and liquid-liquid(L-L)reactive spray deposition in combination with cold rolling and annealing.The microstructure and properties of the fabricated TiB2/Cu composites were investigated.The results show that the reactive mode and rolling treatment are the main factors affecting the microstructure and properties of the TiB2/Cu composite.The in situ reaction in the L-L reaction can be carried out more completely.By controlling the rolling and annealing process,the relative density and the properties of the as-deposited composites are optimized.The comprehensive performance of the deformed TiB2/Cu composite prepared by L-L reactive spray deposition(401 MPa and 83.5%IACS)is better than that by S-L reactive spray deposition(520 MPa and 20.2%IACS).展开更多
In spray atomization and codeposition, a molten stream of metal is disintegrated into a fine dispersion of droplets by high velocity gas jets. The resulting semi-solidified droplets are directed towards a substrate wh...In spray atomization and codeposition, a molten stream of metal is disintegrated into a fine dispersion of droplets by high velocity gas jets. The resulting semi-solidified droplets are directed towards a substrate where they impact and collect as rapidly solidified splats. Relatively high rates of solidification are achieved as a result of the thinness of the splats and the rapid heat extraction during flight and upon impacting with the substrate. The processing method uses codeposition of the metallic semi-solidified droplets (metallic matrix) with the injected reinforcement ceramic particles. In the present paper, the microstructures, mechanical properties, interfacial properties, thermal stability and aging behaviour of spray atomized and codeposited Al-Li-X MMC's (injected X=SiC, Al2O3) are reported and correlated to the processing conditions.展开更多
The influence of the injection of reinforcing particles (for the production of metal matrix composites and of the droplets-to-substrate heat transfer on the resulting microstructural uniformity of spray atomized and c...The influence of the injection of reinforcing particles (for the production of metal matrix composites and of the droplets-to-substrate heat transfer on the resulting microstructural uniformity of spray atomized and codeposited composite material is analyzed. The reinforcement particles injection velocity has to be limited between an upper and a lower critical values. in order to ensure entrapment into the matrix droplets in flight. The thermal history of the injected droplets during the deposition stage is calculated with the assumption that the in-flight solidifying droplets reach the substrate while containing still at least 20% liquid volume fraction, in order to avoid porosity of the deposited material. The substrate to pouring-tube orifice distance where that condition is achieved depends strongly on the atomization pressure and the convective heat transfer coefficient of the substrate. It is demonstrated that 'tailoring' the microstructures and the reinforcement volume percent in the deposited material is feasible. The critical process parameters : the atomization pressure, the melt flow rate. the substrate to pouring-tube orifice distance, the reinforcement particles injection location and rate can all be adequately chosen in order to obtain any desired microstructure, grain size, reinforcement volume percent, with the additional benefit, if wanted, of rapid solidification processing展开更多
基金supported by the National Natural Science Foundation of China (No.52374124)National Youth Science Foundation of China (No.52204135)+3 种基金Xing Liao Talent Plan (No.XLYC2202004)Young Elite Scientists Sponsorship Program by CAST (No.2023QNRC001)Liaoning Province International Science and Technology Cooperation Plan (No.2022JH2/1070004)Liaoning Natural Science Foundation Program (No.2022-BS-327)。
文摘The 2D limit equilibrium method is widely used for slope stability analysis.However,with the advancement of dump engineering,composite slopes often exhibit significant 3D mechanical effects.Consequently,it is of significant importance to develop an effective 3D stability calculation method for composite slopes to enhance the design and stability control of open-pit slope engineering.Using the composite slope formed by the mining stope and inner dump in Baiyinhua No.1 and No.2 open-pit coal mine as a case study,this research investigates the failure mode of composite slopes and establishes spatial shape equations for the sliding mass.By integrating the shear resistance and sliding force of each row of microstrip columns onto the bottom surface of the strip corresponding to the main sliding surface,a novel 2D equivalent physical and mechanical parameters analysis method for the strips on the main sliding surface of 3D sliding masses is proposed.Subsequently,a comprehensive 3D stability calculation method for composite slopes is developed,and the quantitative relationship between the coordinated development distance and its 3D stability coefficients is examined.The analysis reveals that the failure mode of the composite slope is characterized by cutting-bedding sliding,with the arc serving as the side interface and the weak layer as the bottom interface,while the destabilization mechanism primarily involves shear failure.The spatial form equation of the sliding mass comprises an ellipsoid and weak plane equation.The analysis revealed that when the coordinated development distance is 1500 m,the error rate between the 3D stability calculation result and the 2D stability calculation result of the composite slope is less than 8%,thereby verifying the proposed analytical method of equivalent physical and mechanical parameters and the 3D stability calculation method for composite slopes.Furthermore,the3D stability coefficient of the composite slope exhibits an exponential correlation with the coordinated development distance,with the coefficient gradually decreasing as the coordinated development distance increases.These findings provide a theoretical guideline for designing similar slope shape parameters and conducting stability analysis.
基金the National Council of Humanities,Science,and Technology(CONAHCYT)through the"Investigadores por Mexico"program,projects 848 and 881。
文摘Bioactive thermal spray coatings produced via high-velocity oxygen fuel spray(HVOF)from hydroxyapatite(HAp)and bioactive glasses(BG)have the potential to be employed on temporary implants due to the ability of both HAp and BG to dissolve and promote osseointegration,considering that both phases have different reaction and dissolution rates under in-vitro conditions.In the present work,75%wt.HAp-25%wt.S53P4 bioactive glass powders were HVOF-sprayed to obtain HAp/S53P4 BG composite coatings on a bioresorbable AZ31 alloy.The study is focused on exploring the effect of the stand-off distance and fuel/oxygen ratio variation as HVOF parameters to obtain stable structural coatings and to establish their effect on the phases and microstructure produced in those coatings.Different characterization techniques,such as scanning electron microscopy,X-ray diffraction,and Fourier transform infrared spectroscopy,were employed to characterize relevant structural and microstructural properties of the composite coatings.The results showed that thermal gradients during coating deposition must be managed to avoid delamination due to the high temperature achieved(max 550℃)and the differences in coefficients of thermal expansion.It was also found that both spraying distance and oxygen/fuel ratio allowed to keep the hydroxyapatite as the main phase in the coatings.In addition,in-vitro electrochemical studies were performed on the obtained HAp/S53P4 BG composite coatings and compared against the uncoated AZ31 alloy.The results showed a significant decrease in hydrogen evolution(at least 98%)when the bioactive coating was applied on the Mg alloy during evaluation in simulated body fluid(SBF).
基金This study was supported by the financial support of Natural Science Research Projects in Higher Education Institutions in Jiangsu Province(No.18KJD430002).
文摘To make full use of plant shellfibers(rice husk,walnut shell,chestnut shell),three kinds of wood-plastic com-posites of plant shellfibers and polyvinyl chloride(PVC)were prepared.X-ray diffraction analysis was carried out on three kinds of plant shellfibers to test their crystallinity.The aging process of the composites was conducted under 2 different conditions.One was artificial seawater immersion and xenon lamp irradiation,and the other one was deionized water spray and xenon lamp irradiation.The mechanical properties(tensile strength,flexural strength,impact strength),changes in color,water absorption,Fourier transform infrared spectroscopy(FTIR),and microstructures of the composites before and after the two aging experiments were analyzed.The results showed that the chestnut shell had the highest crystallinity,which was 42%.The chestnut shell/PVC composites had the strongest interface bonding,the least internal defects,and the best general mechanical properties among the three composites.Its tensile strength,bending strength and impact strength were 23.81 MPa,34.12 MPa,and 4.32 KJ·m^(-2),respectively.Comparing the two aging conditions,artificial seawater immersion and xenon lamp irradiation destroyed the quality of the combination of plant shellfibers and PVC,making the internal defects of the composites increase.This made the water absorption ability and changes in the color of the composites more obvious and led to a great decrease in the mechanical properties.The general mechanical properties of the chestnut shell/PVC composites were the best,but their water absorption ability changed more obviously.
文摘Silica fibers-reinforced, fused silica composites were fabricated with repeated vacuum-assisted liquid-phase infiltration. The mechanical properties, thermal properties, and ablative properties of the samples were evaluated. The effect of the silica fiber content and treatment temperature on the flexural strength of the three-dimensional SiO2 (3-D SiO2) composites also was investigated. The SiO2 composites show good mechanical properties and excellent ablative performance. The flexural strength increases with an increase in silica fiber content, and decreases with an increase in treatment temperature. When the volume fraction of the silica fiber is 50vo1% and the treatment temperature is 700℃ the flexural strength of the composites reaches a maximum value of 78 MPa. By adding cyclohexanone surfactant, the infiltration property can be largely improved, resulting in the density of SiO2 composites increasing up to 1.65 g/cm^3. The fracture surfaces of the flexural specimens observed using SEM, show that the pseudoplasticity and the toughening mechanisms of the composites are caused by absorption of a lot of energy by interface debonding and fiber pulling out.
文摘Particulate-reinforced metal matrix composites(PRMMCs)are difficult to machine due to the inclusion of hard,brittle reinforcing particles.Existing experimental investigations rarely reveal the complex material removal mechanisms(MRMs)involved in the machining of PRMMCs.This paper develops a three-dimensional(3D)microstructure-based model for investigating the MRM and surface integrity of machined PRMMCs.To accurately mimic the actual microstructure of a PRMMC,polyhedrons were randomly distributed inside the matrix to represent irregular SiC particles.Particle fracture and matrix deformation and failure were taken into account.For the model’s capability comparison,a two-dimensional(2D)analysis was also conducted.Relevant cutting experiments showed that the established 3D model accurately predicted the material removal,chip morphology,machined surface finish,and cutting forces.It was found that the matrix-particle-tool interactions led to particle fractures,mainly in the primary shear and secondary deformation zones along the cutting path and beneath the machined surface.Particle fracture and dilodegment greatly influences the quality of a machined surface.It was also found that although a 2D model can reflect certain material removal features,its ability to predict microstructural variation is limited.
基金National Key R&D Program of China(Nos.2016YFB0303104,2018YFC0810306)Jiangsu Overseas Visiting Scholar Program for University Prominent Younge Middle-aged Teachers and PresidentsSix Talent Peaks Project in Jiangsu Province,China(No.XCL-061)
文摘Three-dimensional( 3 D) fabric composite is a newly developed sandwich structure,consisting of two identical parallel fabric decks woven integrally and mechanically together by means of vertical woven fabrics. In this paper,six types of 3 D fabric sandwich composites were developed in terms of compressive and flexural properties as a function of pile height( 10, 20 and30 mm) and pile distance( 16, 24 and 32 mm) in pile structures. The mechanical characteristics and the damage modes of the 3 D fabric sandwich composites under compressive and flexural load conditions were investigated. Besides,the influence of pile height and pile distance on the 3 D fabric sandwich composites mechanical properties was analyzed. The results showed that the compressive properties decreased with the increase of the pile height and the pile distance. Flexural properties increased with the increase of pile height, while decreased with the increase of pile distance.
基金Tianjin Municipal Science and Technologies Commission,China(Nos.10SYSYJC27800,1ZCKFSF00500)
文摘The effects of fiber volume fraction on damping properties of carbon fiber three-dimensional and five-directional( 3D-5Dir)braided carbon fiber / epoxyres in composite cantilever beams were studied by experimental modal analysis method. Meanwhile,carbon fiber plain woven laminated / epoxy resin composites with different fiber volume fraction were concerned for comparison. The experimental result of braided specimens shows that the first three orders of natural frequency increase and the first three orders of the damping ratios of specimens decrease, when the fiber volume fraction increases. Furthermore,larger fiber volume fraction will be valuable for the better anti-exiting property of braided composites,and get an opposite effect on dissipation of vibration energy. The fiber volume fraction is an important factor for vibration performance design of braided composites. The comparison between the braided specimens and laminated specimens reveals that 3D braided composites have a wider range of damping properties than laminated composites with the same fiber volume fractions.
文摘This work provides a method to predict the three-dimensional equivalent elastic properties of the filament-wound composites based on the multi-scale homogenization principle.In the meso-scale,a representative volume element(RVE)is defined and the bridging model is adopted to establish a theoretical predictive model for its three-dimensional equivalent elastic constants.The results obtained through this method for the previous experimental model are compared with the ones gained respectively by experiments and classical laminate theory to verify the reliability of this model.In addition,the effects of some winding parameters,such as winding angle,on the equivalent elastic behavior of the filament-wound composites are analyzed.The rules gained can provide a theoretical reference for the optimum design of filament-wound composites.
基金Project supported by the National Basic Research Program of China(Grant Nos.2011CB932700 and 2011CB932703)the National Natural Science Foundation of China(Grant Nos.61335006,61378073,and 61077044)+1 种基金the Beijing Natural Science Foundation,China(Grant No.4132031)the Fundamental Research Funds for the Central Universities of Beijing Jiaotong University,China(Grant No.2014YJS136)
文摘To improve the specific capacitance and rate capability of electrode material for supercapacitors, a three-dimensional graphene/polyaniline (3DGN/PANI) composite is prepared via in situ polymerization on GN hydrogel. PANI grows on the GN surface as a thin film, and its content in the composite is controlled by the concentration of the reaction monomer. The specific capacitance of the 3DGN/PANI composite containing 10 wt% PANI reaches 322.8 F.g-1 at a current density of 1 A.g-1, nearly twice as large as that of the pure 3DGN (162.8 F.g-1). The capacitance of the composite is 307.9 F.g-1 at 30 A.g-1 (maintaining 95.4%), and 89% retention after 500 cycles. This study demonstrates the exciting potential of 3DGN/PANI with high capacitance, excellent rate capability and long cycling life for supercapacitors.
基金the Key Projects of Tianjin Natural Science Foundation(No.16ZXCLGX00130).
文摘As a thermosetting resin with excellent properties,epoxy resin is used in many areas such as electronics,transportation,aerospace,and other fields.However,its relatively low thermal conductivity limits its wide application in more demanding fields.Here,a three-dimensional carbon(3DC)network was prepared through NaCl template-assisted in situ chemical vapor deposition(CVD)and used to reinforce epoxy resin for enhancing its thermal conductivity.The 3DC was prepared with a molar ratio of sodium atom to carbon atom of 100:20,and argon atmosphere in CVD led to an optimal improvement in the thermal conductivity of epoxy resin.The thermal conductivity of epoxy resin increased by 18%when the filling content was 3 wt.%of 3DC network because of the high contact area,uniform dispersion,and enhanced formation of conductive paths with epoxy resin.As the amount of 3DC addition increases,the thermal conductivity of composites also increases.As an innovative exploration,the work presented in this paper is of great significance for the thermal conductivity application of epoxy resin in the future.
基金supported by Joint Fund of Advanced Aerospace Manufacturing Technology Research(No. U1937601)the partial financial support of this research by the budget program of Ukraine“Support for the Development of Priority Research Areas”(No.CPCEC 6451230)。
文摘By making use of the direct integration method,an exact analysis of the general three-dimensional thermoelasticity problem is performed for the case of a transversely isotropic homogeneous half-space subject to local thermal and force loadings.The material plane of isotropy is assumed to be parallel to the limiting surface of the halfspace.By reducing the original thermoelasticity equations to the governing ones for individual stress-tensor components,the effect of material anisotropy in the stress field is analyzed with regard to the feasibility requirement,i.e.,the finiteness of the stress field at a distance from the disturbed area.As a result,the solution is constructed in the form of explicit analytical dependencies on the force and thermal loadings for various kinds of transversely isotropic materials and agrees with the basic principles of the continua mechanics.The solution can be efficiently used as a benchmark one for the direct computation of temperature and thermal stresses in transversely isotropic semi-infinite domains,as well as for the verification of solutions constructed by different means.
基金Tianjin Natural Science Sustentation Fund Project,China(No.043600711)Ministry of Education Sustentation Fund Project,China(No.03008)
文摘Three-dimensional(3D)braided composites with better properties have been used in some particular industries.Some have had obvious signs of crack when they are braided.Others have had catastrophic failures occuring without warning.A new methodology for the analysis of failure modes in composite materials by means of acoustic emission techniques has been developed.The occurrence of fiber-breakage during tensile loading tests has been observed by the acoustic emission technology.Using acoustic emission technology is investigated as a means of monitoring 3D braided composites structures,detecting damage,and predicting impending damage.Some of the findings of the research project were presented.
基金Project(2009CC010)supported by the Application Basic Research Foundation of Yunnan Province,ChinaProject(51264037)supported by the National Natural Science Foundation of China
文摘Ultrasonic arc spray atomization (UASA) method was used to prepare high-melting-point, immiscible AgNi15 (mass fraction, %) composite particles. Sieving was used to determine the size distribution of the AgNi15 particles. The morphology, rapidly solidified structure and metastable solution expansion of the AgNi15 particles were analyzed by scanning electron microscopy (SEM), X-ray diffraction (XRD) and energy dispersive spectroscopy (EDS), respectively. The results show that the AgNi15 composite particles are spherical and well-dispersed, and the mass fractions of the particles with diameters <74μm and <55 μm are 99.5% and 98%, respectively. The rapidly solidified structure of the AgNi15 particles consists of spherical nickel-richβ(Ni)-phase particles dispersed throughout a silver-richα(Ag)-phase matrix andα(Ag)-phase nanoparticles dispersed throughout largerβ(Ni)-phase particles. The silver and nickel in the AgNi15 particles form a reciprocally extended metastable solution, and the solid solubility of nickel in the silver matrix at room temperature is in the range of 0.16%?0.36% (mole fraction).
基金Project(2013GK3021)supported by the Science and Technology Plan of Hunan Province,ChinaProject supported by Young Teacher Growth Plan of Hunan University,China
文摘Al-Si/15%SiCp(volume fraction) composites with different silicon contents were fabricated by spray deposition technique, and typical microstructures of these composites were studied by optical microscopy(OM). Dry sliding wear tests were carried out using a block-on-ring wear machine to investigate the effect of applied load range of 10-220 N on the wear and friction behavior of these composites sliding against SAE 52100 grade bearing steel. Scanning electron microscopy(SEM) and energy-dispersive X-ray microanalysis(EDAX) were utilized to examine the morphologies of the worn surfaces in order to observe the wear characteristics and investigate the wear mechanism. The results show that the wear behavior of these composites is dependent on the silicon content in the matrix alloy and the applied load. Al-Si/15%SiCp composites with higher silicon content exhibit better wear resistance in the applied load range. Under lower loads, the major wear mechanisms are oxidation wear and abrasive wear for all tested composites. Under higher loads, severe adhesive wear becomes the main wear mechanisms for Al-7Si/15%SiCp and Al-13Si/15%SiCp composites, while Al-20Si/15%SiCp presents a compound wear mechanism, consisting of oxidation, abrasive wear and adhesion wear.
基金financial support from China Scholarship Council for his Ph.D. projectThe TEM facility in Lille, France, is supported by the Conseil Regional du Nord-Pas de Calais and the European Regional Development Fund
文摘A fully dense carbon nanotubes (CNTs) reinforced AlSi matrix composite with the multiscale nacre-like architecture was designed and successfully realized by flake powder metallurgy followed by cold spraying (CS). The nanolaminated and ultrafine-grained structure initially created in the CNT/AlSi flaky powder was perfectly conserved, due to the typical ‘cold’ feature of CS. As discussed based on finite element analysis and single splat observation, self-alignment behavior of the flaky powders during impact also allowed the formation of the microlaminated structure. Hence, the scalable CS technique opens a new avenue for bioinspired material design and fabrication with complex shape.
基金the Project for Science and Technology Plan of Wuhan City (No. 200910321092)the Youth Science Plan for Light of the Morning Sun of Wuhan City (No. 200750731270)the Fundamental Research Funds for the Central Universities (No. 2010-Ⅱ-020)
文摘The effects of microwave sintering on the properties, phases and microstructure of W-2OCu alloy, using composite powder fabricated by spray pyrolysis-continuous reduction technology, were investigated. Compared with the conventional hot-press sintering, microwave sintering to W-2OCu composites could be achieved with lower sintering temperature and shorter sintering time. Furthermore, microwave sintered W-Cu composites with high densification, homogenous microstructure and excellent properties were obtained. Microwave sintering could also result in finer microstructures. :~
基金Projects(U1502274,51834009)supported by the National Natural Science Foundation of ChinaProject(2017ZDXM-GY-028)supported by the Key Research and Development Program of Shaanxi,China。
文摘In situ TiB2/Cu composites were fabricated by both solid-liquid(S-L)and liquid-liquid(L-L)reactive spray deposition in combination with cold rolling and annealing.The microstructure and properties of the fabricated TiB2/Cu composites were investigated.The results show that the reactive mode and rolling treatment are the main factors affecting the microstructure and properties of the TiB2/Cu composite.The in situ reaction in the L-L reaction can be carried out more completely.By controlling the rolling and annealing process,the relative density and the properties of the as-deposited composites are optimized.The comprehensive performance of the deformed TiB2/Cu composite prepared by L-L reactive spray deposition(401 MPa and 83.5%IACS)is better than that by S-L reactive spray deposition(520 MPa and 20.2%IACS).
文摘In spray atomization and codeposition, a molten stream of metal is disintegrated into a fine dispersion of droplets by high velocity gas jets. The resulting semi-solidified droplets are directed towards a substrate where they impact and collect as rapidly solidified splats. Relatively high rates of solidification are achieved as a result of the thinness of the splats and the rapid heat extraction during flight and upon impacting with the substrate. The processing method uses codeposition of the metallic semi-solidified droplets (metallic matrix) with the injected reinforcement ceramic particles. In the present paper, the microstructures, mechanical properties, interfacial properties, thermal stability and aging behaviour of spray atomized and codeposited Al-Li-X MMC's (injected X=SiC, Al2O3) are reported and correlated to the processing conditions.
文摘The influence of the injection of reinforcing particles (for the production of metal matrix composites and of the droplets-to-substrate heat transfer on the resulting microstructural uniformity of spray atomized and codeposited composite material is analyzed. The reinforcement particles injection velocity has to be limited between an upper and a lower critical values. in order to ensure entrapment into the matrix droplets in flight. The thermal history of the injected droplets during the deposition stage is calculated with the assumption that the in-flight solidifying droplets reach the substrate while containing still at least 20% liquid volume fraction, in order to avoid porosity of the deposited material. The substrate to pouring-tube orifice distance where that condition is achieved depends strongly on the atomization pressure and the convective heat transfer coefficient of the substrate. It is demonstrated that 'tailoring' the microstructures and the reinforcement volume percent in the deposited material is feasible. The critical process parameters : the atomization pressure, the melt flow rate. the substrate to pouring-tube orifice distance, the reinforcement particles injection location and rate can all be adequately chosen in order to obtain any desired microstructure, grain size, reinforcement volume percent, with the additional benefit, if wanted, of rapid solidification processing