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Ti_(3)C_(2)T_(x) MXene/carbon composites for advanced supercapacitors:Synthesis,progress,and perspectives 被引量:1
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作者 Yanqing Cai Xinggang Chen +4 位作者 Ying Xu Yalin Zhang Huijun Liu Hongjuan Zhang Jing Tang 《Carbon Energy》 SCIE EI CAS CSCD 2024年第2期113-142,共30页
MXenes are a family of two-dimensional(2D)layered transition metal carbides/nitrides that show promising potential for energy storage applications due to their high-specific surface areas,excellent electron conductivi... MXenes are a family of two-dimensional(2D)layered transition metal carbides/nitrides that show promising potential for energy storage applications due to their high-specific surface areas,excellent electron conductivity,good hydrophilicity,and tunable terminations.Among various types of MXenes,Ti_(3)C_(2)T_(x) is the most widely studied for use in capacitive energy storage applications,especially in supercapacitors(SCs).However,the stacking and oxidation of MXene sheets inevitably lead to a significant loss of electrochemically active sites.To overcome such challenges,carbon materials are frequently incorporated into MXenes to enhance their electrochemical properties.This review introduces the common strategies used for synthesizing Ti_(3)C_(2)T_(x),followed by a comprehensive overview of recent developments in Ti_(3)C_(2)T_(x)/carbon composites as electrode materials for SCs.Ti_(3)C_(2)T_(x)/carbon composites are categorized based on the dimensions of carbons,including 0D carbon dots,1D carbon nanotubes and fibers,2D graphene,and 3D carbon materials(activated carbon,polymer-derived carbon,etc.).Finally,this review also provides a perspective on developing novel MXenes/carbon composites as electrodes for application in SCs. 展开更多
关键词 electrochemical performance MXene/carbon composites SUPERCAPACITORS
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Ultraviolet‑Irradiated All‑Organic Nanocomposites with Polymer Dots for High‑Temperature Capacitive Energy Storage 被引量:1
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作者 Jiale Ding Yao Zhou +5 位作者 Wenhan Xu Fan Yang Danying Zhao Yunhe Zhang Zhenhua Jiang Qing Wang 《Nano-Micro Letters》 SCIE EI CSCD 2024年第3期398-406,共9页
Polymer dielectrics capable of operating efficiently at high electric fields and elevated temperatures are urgently demanded by next-generation electronics and electrical power systems.While inorganic fillers have bee... Polymer dielectrics capable of operating efficiently at high electric fields and elevated temperatures are urgently demanded by next-generation electronics and electrical power systems.While inorganic fillers have been extensively utilized to improved high-temperature capacitive performance of dielectric polymers,the presence of thermodynamically incompatible organic and inorganic components may lead to concern about the long-term stability and also complicate film processing.Herein,zero-dimensional polymer dots with high electron affinity are introduced into photoactive allyl-containing poly(aryl ether sulfone)to form the all-organic polymer composites for hightemperature capacitive energy storage.Upon ultraviolet irradiation,the crosslinked polymer composites with polymer dots are efficient in suppressing electrical conduction at high electric fields and elevated temperatures,which significantly reduces the high-field energy loss of the composites at 200℃.Accordingly,the ultraviolet-irradiated composite film exhibits a discharged energy density of 4.2 J cm^(−3)at 200℃.Along with outstanding cyclic stability of capacitive performance at 200℃,this work provides a promising class of dielectric materials for robust high-performance all-organic dielectric nanocomposites. 展开更多
关键词 High-temperature energy storage Polymer dots Ultraviolet irradiation All-organic composite dielectrics
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Self‑Assembly of Binderless MXene Aerogel for Multiple‑Scenario and Responsive Phase Change Composites with Ultrahigh Thermal Energy Storage Density and Exceptional Electromagnetic Interference Shielding 被引量:1
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作者 Chuanbiao Zhu Yurong Hao +8 位作者 Hao Wu Mengni Chen Bingqing Quan Shuang Liu Xinpeng Hu Shilong Liu Qinghong Ji Xiang Lu Jinping Qu 《Nano-Micro Letters》 SCIE EI CSCD 2024年第3期367-382,共16页
The severe dependence of traditional phase change materials(PCMs)on the temperature-response and lattice deficiencies in versatility cannot satisfy demand for using such materials in complex application scenarios.Here... The severe dependence of traditional phase change materials(PCMs)on the temperature-response and lattice deficiencies in versatility cannot satisfy demand for using such materials in complex application scenarios.Here,we introduced metal ions to induce the self-assembly of MXene nanosheets and achieve their ordered arrangement by combining suction filtration and rapid freezing.Subsequently,a series of MXene/K^(+)/paraffin wax(PW)phase change composites(PCCs)were obtained via vacuum impregnation in molten PW.The prepared MXene-based PCCs showed versatile applications from macroscale technologies,successfully transforming solar,electric,and magnetic energy into thermal energy stored as latent heat in the PCCs.Moreover,due to the absence of binder in the MXene-based aerogel,MK3@PW exhibits a prime solar-thermal conversion efficiency(98.4%).Notably,MK3@PW can further convert the collected heat energy into electric energy through thermoelectric equipment and realize favorable solar-thermal-electric conversion(producing 206 mV of voltage with light radiation intensity of 200 mw cm^(−2)).An excellent Joule heat performance(reaching 105℃with an input voltage of 2.5 V)and responsive magnetic-thermal conversion behavior(a charging time of 11.8 s can achieve a thermal insulation effect of 285 s)for contactless thermotherapy were also demonstrated by the MK3@PW.Specifically,as a result of the ordered arrangement of MXene nanosheet self-assembly induced by potassium ions,MK3@PW PCC exhibits a higher electromagnetic shielding efficiency value(57.7 dB)than pure MXene aerogel/PW PCC(29.8 dB)with the same MXene mass.This work presents an opportunity for the multi-scene response and practical application of PCMs that satisfy demand of next-generation multifunctional PCCs. 展开更多
关键词 Self-assembly Multiple-scenario Phase change composites Thermal energy storage Electromagnetic interference shielding
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Effects of Sinusoidal Vibration of Crystallization Roller on Composite Microstructure of Ti/Al Laminated Composites by Twin-Roll Casting
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作者 李励 杜凤山 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2024年第1期196-205,共10页
A new,innovative vibration cast-rolling technology of “electromagnetic stirring+dendrite breaking+asynchronous rolling” was proposed with the adoption of sinusoidal vibration of crystallization roller to prepare Ti/... A new,innovative vibration cast-rolling technology of “electromagnetic stirring+dendrite breaking+asynchronous rolling” was proposed with the adoption of sinusoidal vibration of crystallization roller to prepare Ti/Al laminated composites,and the effect of sinusoidal vibration of crystallization roller on composite microstructure was investigated in detail.The results show that the metallurgical bonding of titanium and aluminum is realized by mesh interweaving and mosaic meshing,instead of transition bonding by forming metal compound layer.The meshing depth between titanium and aluminum layers (6.6μm) of cast-rolling materials with strong vibration of crystallization roller (amplitude 0.87 mm,vibration frequency 25 Hz) is doubled compared with that of traditional cast-rolling materials (3.1μm),and the composite interfacial strength(27.0 N/mm) is twice as high as that of traditional cast-rolling materials (14.9 N/mm).This is because with the action of high-speed superposition of strong tension along the rolling direction,strong pressure along the width direction and rolling force,the composite linearity evolves from "straight line" with traditional casting-rolling to "curved line",and the depth and number of cracks in the interface increases greatly compared with those with traditional cast-rolling,which leads to the deep expansion of the meshing area between interfacial layers and promotes the stable enhancement of composite quality. 展开更多
关键词 laminated composites sinusoidal vibration composite microstructure
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Rational design and synthesis of Cr_(1-x)Te/Ag_(2)Te composites for solid-state thermoelectromagnetic cooling near room temperature
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作者 孙笑晨 谢承昊 +3 位作者 陈思汗 万京伟 谭刚健 唐新峰 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第5期580-586,共7页
Materials with both large magnetocaloric response and high thermoelectric performance are of vital importance for all-solid-state thermoelectromagnetic cooling.These two properties,however,hardly coexist in single pha... Materials with both large magnetocaloric response and high thermoelectric performance are of vital importance for all-solid-state thermoelectromagnetic cooling.These two properties,however,hardly coexist in single phase materials except previously reported hexagonal Cr_(1-x)Te half metal where a relatively high magnetic entropy change(-△S_(M))of~2.4 J·kg^(-1)·K^(-1)@5 T and a moderate thermoelectric figure of merit(ZT)of~1.2×10^(-2)@300 K are simultaneously recorded.Herein we aim to increase the thermoelectric performance of Cr_(1-x)Te by compositing with semiconducting Ag_(2)Te.It is discovered that the in-situ synthesis of Cr_(1-x)Te/Ag_(2)Te composites by reacting their constitute elements above melting temperatures is unsuccessful because of strong phase competition.Specifically,at elevated temperatures(T>800 K),Cr_(1-x)Te has a much lower deformation energy than Ag_(2)Te and tends to become more Cr-deficient by capturing Te from Ag_(2)Te.Therefore,Ag is insufficiently reacted and as a metal it deteriorates ZT.We then rationalize the synthesis of Cr_(1-x)Te/Ag_(2)Te composites by ex-situ mix of the pre-prepared Cr_(1-x)Te and Ag_(2)Te binary compounds followed by densification at a low sintering temperature of 573 K under a pressure of 3.5 GPa.We show that by compositing with 7 mol%Ag_(2)Te,the Seebeck coefficient of Cr_(1-x)Te is largely increased while the lattice thermal conductivity is considerably reduced,leading to 72%improvement of ZT.By comparison,-△S_(M)is only slightly reduced by 10%in the composite.Our work demonstrates the potential of Cr_(1-x)Te/Ag_(2)Te composites for thermoelectromagnetic cooling. 展开更多
关键词 thermoelectromagnetic cooling thermoelectric MAGNETOCALORIC composite chromium telluride
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乳头状甲状腺癌组织中SPCS 2基因表达水平及其意义
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作者 陈澎涛 项承 《精准医学杂志》 2024年第2期159-162,166,共5页
目的探讨信号肽酶复合体亚基2(SPCS 2)基因在乳头状甲状腺癌(papillary thyroid carcinoma,PTC)组织中的表达水平及其意义。方法利用UALCAN及HPA数据分析平台评估PTC组织和正常组织中SPCS 2基因表达水平。在Gepia数据库预测SPCS 2基因... 目的探讨信号肽酶复合体亚基2(SPCS 2)基因在乳头状甲状腺癌(papillary thyroid carcinoma,PTC)组织中的表达水平及其意义。方法利用UALCAN及HPA数据分析平台评估PTC组织和正常组织中SPCS 2基因表达水平。在Gepia数据库预测SPCS 2基因表达水平对PTC患者无病生存时间的影响。Cox回归模型分析影响PTC患者预后的独立危险因素。并对该基因进行KEGG、GO和GSEA分析,确定参与PTC的重要信号通路。结果PTC患者肿瘤组织中SPCS 2基因表达水平均显著低于正常组织(Z=-43.219,P<0.001)。与SPCS 2低表达的PTC患者相比,SPCS 2基因高表达组PTC患者无病生存时间更长(P<0.05)。Cox回归模型分析显示,PTC患者肿瘤组织中SPCS 2低表达是导致PTC患者预后不良的独立危险因素(HR=0.573,P<0.05)。富集分析预测显示,线粒体氧化磷酸化通路富集在SPCS2高表达组。结论PTC患者肿瘤组织中SPCS 2基因表达水平下调,SPCS 2基因可能参与线粒体氧化磷酸化信号通路的调控,该基因可能是评估PTC患者预后的重要生物标志物。 展开更多
关键词 甲状腺癌 乳头状 基因表达 spcs 2基因 预后 线粒体 氧化磷酸化 代谢网络和途径
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Effects of BN on the Mechanical and Thermal Properties of PP/BN Composites
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作者 陈厚振 王艳芝 +4 位作者 NAN Yu WANG Xu YUE Xianyang ZHANG Yifei FAN Huiling 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2024年第2期345-352,共8页
In order to explore the thermal conductivity of polypropylene(PP)/hexagonal boron nitride(BN) composites,PP composites filled with different proportions of BN were prepared through extrution compounding,injection moul... In order to explore the thermal conductivity of polypropylene(PP)/hexagonal boron nitride(BN) composites,PP composites filled with different proportions of BN were prepared through extrution compounding,injection moulding and compression moulding.The composites were filled with BN particles of 5 and 20 μm respectively,and their mass fractions in composites were considered.Percentage of BN was varied from 0 to 25wt% in steps of 5wt%.The effects of BN filler on mechanical properties of the composites were evaluated.The thermal behaviors were studied using DSC and TGA,and the thermal conductivity was also investigated by Laser Flash Device and the Model of 3D Heat Conduction respectively.The experimental results show that impact strength of PP/BN can be enhanced with the addition of BN,but that composites exhibit lower breaking elongation & tensile strength when compared to unfilled ones.It is found that mass fraction of BN influenced the final thermal stability and degree of crystallization of PP matrix,the degree of crystallization of PP with 15wt% of 20 μm BN can be improved by 25% than neat PP.Meanwhile,crystallization temperatures of PP composites are elevated by about 10 ℃.The thermal conductivity results demonstrate that the maximum value of the thermal conductivity is achieved from PP/BN with 20wt% of 20 μm BN,higher than that of pure PP by 95.65%,close to the simulation one. 展开更多
关键词 thermal properties POLYPROPYLENE composites hexagonal boron nitride
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MHz cut-off frequency and permeability mechanism of iron-based soft magnetic composites
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作者 Xiao-Wei Jin Tong Li +1 位作者 Hui-Gang Shi De-Sheng Xue 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第9期560-564,共5页
The lack of soft magnetic composites with high power density in MHz frequency range has become an obstacle in the efficient operation of the electrical and electronic equipments.Here,a promising method to increase the... The lack of soft magnetic composites with high power density in MHz frequency range has become an obstacle in the efficient operation of the electrical and electronic equipments.Here,a promising method to increase the cut-off frequency of iron-based soft magnetic composites to hundreds of MHz is reported.The cut-off frequency is increased from 10 MHz to 1 GHz by modulating the height of the ring,the distribution of particles,and the particle size.The mechanism of cut-off frequency and permeability is the coherent rotation of domain modulated by inhomogeneous field due to the eddy current effect.An empirical formula for the cut-off frequency in a magnetic ring composed of iron-based particles is established from experimental data.This work provides an effective approach to fabricate soft magnetic composites with a cut-off frequency in hundreds of MHz. 展开更多
关键词 CUT-OFF frequency PERMEABILITY EDDY current effect SOFT magnetic composites
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Understanding the corrosion and bio-corrosion behaviour of Magnesium composites – a critical review
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作者 Prithivirajan Sekar S.K.Panigrahi 《Journal of Magnesium and Alloys》 SCIE EI CAS CSCD 2024年第3期890-939,共50页
Realising the potential of Magnesium(Mg),several globally leading ventures have invested in the Mg industry,but their relatively poor corrosion resistance is a never ending saga till date.The corrosion and bio-corrosi... Realising the potential of Magnesium(Mg),several globally leading ventures have invested in the Mg industry,but their relatively poor corrosion resistance is a never ending saga till date.The corrosion and bio-corrosion behaviour of Mg has gained research attention and still remains a hot topic in the application of automobile,aerospace and biomedical industries.The intrinsic high electrochemical nature of Mg limits their utilization in diverse application.This scenario has prompted the development of Mg composites with an aim to achieve superior corrosion and bio-corrosion resistance.The present review enlightens the influence of grain size(GS),secondary phase,texture,type of matrix and reinforcement on the corrosion and bio-corrosion behaviour of Mg composites.Firstly,the corrosion and bio-corrosion behaviour of Mg composites manufactured by primary and secondary processing routes are elucidated.Secondly,the comprehensive corrosion and bio-corrosion mechanisms of these Mg composites are proposed.Thirdly,the individual role of GS,texture and corrosive medium on corrosion and bio-corrosion behaviour of Mg composites are clarified and revealed.The challenges encountered,unanswered issues in this field are explained in detail and accordingly the scope for future research is framed.The review is presented from basic concrete background to advanced corrosion mechanisms with an aim of creating interest among the readers like students,researchers and industry experts from various research backgrounds.Indeed,the corrosion and bio-corrosion behaviour of Mg composites are critically reviewed for the first time to:(i)contribute to the body of knowledge,(ii)foster research and development,(iii)make breakthrough,and(iv)create life changing innovations in the field of Mg composite corrosion. 展开更多
关键词 CORROSION Bio corrosion Magnesium alloys Magnesium composites Magnesium implants.
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Microstructural characterization and mechanical properties of(TiC+TiB)/TA15 composites prepared by an in-situ synthesis method
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作者 Zhi-yong Zhang Jiao-jiao Cheng +3 位作者 Jia-qi Xie Shi-bing Liu Kun Shi Jun Zhao 《China Foundry》 SCIE EI CAS CSCD 2024年第2期168-174,共7页
Titanium matrix composites reinforced with ceramic particles are considered a promising engineering material due to their combination of high specific strength,low density,and high modulus.In this study,the TA15-based... Titanium matrix composites reinforced with ceramic particles are considered a promising engineering material due to their combination of high specific strength,low density,and high modulus.In this study,the TA15-based composites reinforced with a volume fraction of 10% to 25%(TiB+TiC)were prepared using powder metallurgy and casting technique.Microstructural characterization and phase constitution were examined using optical microscopy(OM),scanning electron microscopy(SEM),and X-ray diffraction(XRD).In addition,the microhardness,room temperature(RT)and high temperature(HT)tensile properties of the composites were evaluated.Results revealed that the reinforcements are distributed uniformly even in the composites with a high volume of TiB and TiC.However,as the volume fraction exceeds 15%,TiB and TiC particles become coarsening and exhibit rod-like and dendritic-like morphology.Microhardness increases gradually from 321.2 HV for the base alloy to a maximum of 473.3 HV as the reinforcement increases to 25vol.%.Tensile test results indicate that a reinforcement volume fraction above 20% is beneficial for enhancing tensile strength and yield strength at high temperatures,but it has an adverse effect on room temperature elongation.Conversely,if the reinforcement volume fraction is below 20%,it can improve high-temperature elongation when the temperature exceeds 600℃. 展开更多
关键词 titanium matrix composites microstucture MICROHARDNESS tensile properties in-situ synthesis
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Valorization of Tree Bark-Derived Suberin in Applications for the Bio-Based Composites Industry–A Recent Review
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作者 Aleksandra Jeżo 《Journal of Renewable Materials》 EI CAS 2024年第6期1029-1042,共14页
Bark extracts are sustainable sources of biopolymers and hold great promise for replacing fossil fuel-based polymers,for example,in wood-based composites.In addition to primary and secondary metabolites,tree bark also... Bark extracts are sustainable sources of biopolymers and hold great promise for replacing fossil fuel-based polymers,for example,in wood-based composites.In addition to primary and secondary metabolites,tree bark also contains suberin,which plays a major role in protecting the tree from environmental conditions.Suberin is a natural aliphatic-aromatic cross-linked polyester present in the cell walls of both normal and damaged external tissues,the main component of which are long-chain aliphatic acids.Its main role as a plant ingredient is to protect against microbiological factors and water loss.One of the most important suberin monomers are suberin fatty acids,known for their hydrophobic and barrier properties.Therefore,due to the diverse chemical composition of suberin,it is an attractive alternative to hydrocarbon-based materials.Although its potential is recognized,it is not widely used in biocomposites technology,including wood-based composites and the polymer industry.The article will discuss the current knowledge about the potential of suberin and its components in biocomposites technology,which will include surface finishes,composite adhesives and polymer blends. 展开更多
关键词 SUBERIN suberinic acids wood composites BIOcomposites biopolyester
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3D-printable Boron Nitride/Polyacrylic Hydrogel Composites with High Thermal Conductivities
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作者 DAI Jialei XUE Bingyu +5 位作者 QIAN Qi HE Wenhao ZHU Chenglong LEI Liwen WANG Kun XIE Jingjing 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2024年第5期1303-1310,共8页
Polyacrylic acid(PAA)hydrogel composites with different hexagonal boron nitride(h-BN)fillers were synthesized and successfully 3D-printed while their thermal conductivity was systematically studied.With the content of... Polyacrylic acid(PAA)hydrogel composites with different hexagonal boron nitride(h-BN)fillers were synthesized and successfully 3D-printed while their thermal conductivity was systematically studied.With the content of h-BN increasing from 0.1 wt%to 0.3 wt%,the thermal conductivity of the 3D-printed composites has been improved.Moreover,through the shear force given by the 3D printer,a complete thermal conductivity path is obtained inside the hydrogel,which significantly improves the thermal conductivity of the h-BN hydrogel composites.The maximum thermal conductivity is 0.8808 W/(m·K),leading to a thermal conductive enhancement of 1000%,compared with the thermal conductivity of pure PAA hydrogels.This study shows that using h-BN fillers can effectively and significantly improve the thermal conductivity of hydrogelbased materials while its 3D-printable ability has been maintained. 展开更多
关键词 hydrogel composites boron nitride 3D printing thermal conductivity
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Supposition of graphene stacks to estimate the contact resistance and conductivity of nanocomposites
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作者 Y.ZARE M.T.MUNIR +1 位作者 G.J.WENG K.Y.RHEE 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI CSCD 2024年第4期663-676,共14页
In this study,the effects of stacked nanosheets and the surrounding interphase zone on the resistance of the contact region between nanosheets and the tunneling conductivity of samples are evaluated with developed equ... In this study,the effects of stacked nanosheets and the surrounding interphase zone on the resistance of the contact region between nanosheets and the tunneling conductivity of samples are evaluated with developed equations superior to those previously reported.The contact resistance and nanocomposite conductivity are modeled by several influencing factors,including stack properties,interphase depth,tunneling size,and contact diameter.The developed model's accuracy is verified through numerous experimental measurements.To further validate the models and establish correlations between parameters,the effects of all the variables on contact resistance and nanocomposite conductivity are analyzed.Notably,the contact resistance is primarily dependent on the polymer tunnel resistivity,contact area,and tunneling size.The dimensions of the graphene nanosheets significantly influence the conductivity,which ranges from 0 S/m to90 S/m.An increased number of nanosheets in stacks and a larger gap between them enhance the nanocomposite's conductivity.Furthermore,the thicker interphase and smaller tunneling size can lead to higher sample conductivity due to their optimistic effects on the percolation threshold and network efficacy. 展开更多
关键词 graphene polymer composite stacked nanosheet tunneling conductivity contact resistance INTERPHASE
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Optimization Mechanism of Mechanical Properties of Basalt Fiber-Epoxy Resin Composites by Interfacially Enriched Distribution of Nano-Starch Crystals
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作者 Yanpeng Wei Jiale Zhao +2 位作者 Jian Zhuang Peng Zhang Zhiwu Han 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2024年第3期289-296,共8页
Fibre reinforced polymer composites have become a new generation of structural materials due to their unique advantages such as high specific strength,designability,good dimensional stability and ease of large-area mo... Fibre reinforced polymer composites have become a new generation of structural materials due to their unique advantages such as high specific strength,designability,good dimensional stability and ease of large-area monolithic forming.However,the problem of interfacial bonding between the resin matrix and the fibres limits the direct use of reinforcing fibres and has become a central difficulty in the development of basalt fibre-epoxy composites.This paper proposes a solution for enhancing the strength of the fibre-resin interface using maize starch nanocrystals,which are highly yield and eco-friendly.Firstly,in this paper,corn starch nanocrystals(SNC)were prepared by hydrolysis,and were deposited on the surface of basalt fibers by electrostatic adsorption.After that,in order to maximize the modification effect of nano-starch crystals on the interface,the basalt fiber-epoxy resin composite samples were prepared by mixing in a pressureless molding method.The test results shown that the addition of basalt fibers alone led to a reduction in the strength of the sample.Deposition of 0.1 wt%SNC on the surface of basalt fibers can make the strength consistent with pure epoxy resin.When the adsorption amount of SNC reached 0.5 wt%,the tensile strength of the samples was 23.7%higher than that of pure epoxy resin.This is due to the formation of ether bond homopolymers between the SNC at the fibre-epoxy interface and the epoxy resin,which distorts the originally smooth interface,leading to increased stress concentration and the development of cracks.This enhances the binding of basalt fibers.The conclusions of this paper can provide an effective,simple,low-cost and non-polluting method of interfacial enhancement modification. 展开更多
关键词 Basalt fibres Epoxy resin Fibre reinforced composites Starch nanocrystals ECO-FRIENDLY
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SPCS装配式技术在高层建筑的应用研究
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作者 汪丹 《价值工程》 2024年第24期162-164,共3页
随着现代建筑技术的不断进步,装配式建筑因其高效、环保、节能等优点逐渐成为建筑行业的发展趋势。三一筑工提出的装配整体式叠合混凝土结构体系(简称SPCS体系)作为一种新型的装配式体系,在施工效率、成本等方面均更有优势。本文结合金... 随着现代建筑技术的不断进步,装配式建筑因其高效、环保、节能等优点逐渐成为建筑行业的发展趋势。三一筑工提出的装配整体式叠合混凝土结构体系(简称SPCS体系)作为一种新型的装配式体系,在施工效率、成本等方面均更有优势。本文结合金地峯范项目的 SPCS技术试点落地,通过工法楼的建设,分别从吊装、浇筑施工、构件设计等方面,通过相阵超声波仪器探测密实度,钻芯取样,成本测算等方法,重点探讨了SPCS体系在建筑领域的实际应用落地路径,验证了SPCS体系的优势。同时通过对其技术特点、施工流程、优势分析以及实际工程案例的探讨,表明SPCS装配式技术在提升建筑质量、效率和可持续性方面的重要作用。 展开更多
关键词 装配式建筑 spcs体系 叠合混凝土结构 建筑工业化
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Microstructural characterization,tribological and corrosion behavior of AA7075-TiC composites
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作者 Surendarnath Sundaramoorthy Ramesh Gopalan Ramachandran Thulasiram 《China Foundry》 SCIE EI CAS CSCD 2024年第4期334-342,共9页
Aluminum alloys are the potential materials in the automobile and aerospace sectors due to their lower density,easy forming and excellent corrosion resistance.The demand of high strength-to-weight ratio materials in s... Aluminum alloys are the potential materials in the automobile and aerospace sectors due to their lower density,easy forming and excellent corrosion resistance.The demand of high strength-to-weight ratio materials in structural applications needs the engineering industries to seek aluminum alloy with new versions of hard and brittle ceramic particles.The microstructure,hardness,wear and corrosion behaviors of AA7075 composites with 2.5wt.%and 5wt.%TiC particles were studied.Microscopic analysis is evident that the transformation of the strong dendritic morphology to non-dendritic morphology on the incorporation of TiC into AA7075.Furthermore,the precipitation of the second-phase compounds such as Al_(2)CuMg,Al_(2)Cu andFe-rich Al_6(Cu,Fe)/Al_(7)Cu_(2)Fe)is promoted by TiC particles at inter-and intra-dendritic regions.Accordingly,the hardness of composites is improved by grain boundary strengthening and particulate strengthening mechanisms.Both coefficient of friction and wear rate have an inverse relation with TiC concentration.The base alloy without TiC shows adhesive-type wear-induced deformation due to the formation of an oxide film,while composite samples exhibit a mechanically mixed layer and abrasive-type wear behavior.Composite samples shows a higher corrosion rate due to the presence of numerous precipitates which promote pitting corrosion. 展开更多
关键词 AA7075 alloy TiC reinforcement composite microstructure WEAR corrosion TRIBOLOGICAL
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Cooperative composites anchored with single atom Pb and carbon confined PbO nanoparticles for superior lead-carbon batteries
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作者 Puqiang He Yi Yang +4 位作者 Hui Huang Jing Huang Hongbiao Wang Yapeng He Zhongcheng Guo 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第10期486-497,I0010,共13页
The mitigation of sulphation and parasitic hydrogen evolution is considered as prominent research emphasis for the development of lead-carbon batteries(LCBs)in large-scale energy storage applications.Here,cooperative ... The mitigation of sulphation and parasitic hydrogen evolution is considered as prominent research emphasis for the development of lead-carbon batteries(LCBs)in large-scale energy storage applications.Here,cooperative Pb-C composites consisting of single atom Pb and carbon-encapsulated PbO nanoparticles were prepared by freeze-drying technique and pyrolytic reduction to address above obstacles.The innovative use of Pb^(2+)to cross-link sodium alginate enabled a uniform distribution of Pb in the composites,generating Pb-C-PbO three-phase heterostructure.Experimental analysis and theoretical calculations revealed the synergistic interactions between single-atom Pb and PbO nanoparticles in suppressing parasitic hydrogen evolution and promoting the adsorption of Pb atoms.The presence of monatomic Pb and PbO enhanced the affinity of the composites for the negative active materials and facilitated the transformation of the active materials from bulk into spherical shapes to enhance the specific surface area,thereby counteracting sulphation.Through the coordinated integration of various functionalities offered by Pb@C-x,the cycle life of the battery at HRPSoC reaches 7025 cycles,which is two times for LCB with pure carbon materials.Additionally,the discharge capacity increased from 3.52 to 3.79 Ah.This study provides substantial insights into the construction of Pb-C composites for LCBs to inhibit negative sulphation and hydrogen evolution. 展开更多
关键词 Lead-carbon battery Negative sulphation Hydrogen evolution SINGLE-ATOM Lead carbon composites
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Mechanical Properties and Thermal Shock Resistance of SrAl_(2)Si_(2)O_(8) Reinforced BN Ceramic Composites
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作者 WANG Bo CAI Delong +7 位作者 ZHU Qishuai LI Daxin YANG Zhihua DUAN Xiaoming LI Yanan WANG Xuan JIA Dechang ZHOU Yu 《无机材料学报》 SCIE EI CAS CSCD 北大核心 2024年第10期1182-1188,共7页
Hexagonal boron nitride(h-BN)ceramics have become exceptional materials for heat-resistant components in hypersonic vehicles,owing to their superior thermal stability and excellent dielectric properties.However,their ... Hexagonal boron nitride(h-BN)ceramics have become exceptional materials for heat-resistant components in hypersonic vehicles,owing to their superior thermal stability and excellent dielectric properties.However,their densification during sintering still poses challenges for researchers,and their mechanical properties are rather unsatisfactory.In this study,SrAl_(2)Si_(2)O_(8)(SAS),with low melting point and high strength,was introduced into the h-BN ceramics to facilitate the sintering and reinforce the strength and toughness.Then,BN-SAS ceramic composites were fabricated via hot press sintering using h-BN,SrCO_(3),Al_(2)O_(3),and SiO_(2) as raw materials,and effects of sintering pressure on their microstructure,mechanical property,and thermal property were investigated.The thermal shock resistance of BN-SAS ceramic composites was evaluated.Results show that phases of as-preparedBN-SAS ceramic composites are h-BN and h-SrAl_(2)Si_(2)O_(8).With the increase of sintering pressure,the composites’densities increase,and the mechanical properties shew a rising trend followed by a slight decline.At a sintering pressure of 20 MPa,their bending strength and fracture toughness are(138±4)MPa and(1.84±0.05)MPa·m^(1/2),respectively.Composites sintered at 10 MPa exhibit a low coefficient of thermal expansion,with an average of 2.96×10^(-6) K^(-1) in the temperature range from 200 to 1200℃.The BN-SAS ceramic composites prepared at 20 MPa display higher thermal conductivity from 12.42 to 28.42 W·m^(-1)·K^(-1) within the temperature range from room temperature to 1000℃.Notably,BN-SAS composites exhibit remarkable thermal shock resistance,with residual bending strength peaking and subsequently declining sharply under a thermal shock temperature difference ranging from 600 to 1400℃.The maximum residual bending strength is recorded at a temperature difference of 800℃,with a residual strength retention rate of 101%.As the thermal shock temperature difference increase,the degree of oxidation on the ceramic surface and cracks due to thermal stress are also increased gradually. 展开更多
关键词 BN MATRIX composite hot-press SINTERING mechanical PROPERTY thermal shock resistance service reliability
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Damping properties and mechanism of aluminum matrix composites reinforced with glass cenospheres
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作者 Kai SUN Lin WANG +5 位作者 Hang SU Jia-yi GENG Qiang ZHANG Bo MENG Zeng-yan WEI Gao-hui WU 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2024年第9期2743-2755,共13页
The damping properties were improved by preparing Al matrix composites reinforced with glass cenospheres through the pressure infiltration method.Transmission electron microscopy and scanning electron microscopy were ... The damping properties were improved by preparing Al matrix composites reinforced with glass cenospheres through the pressure infiltration method.Transmission electron microscopy and scanning electron microscopy were employed to characterize the microstructure of the composites.The low-frequency damping properties were examined by using a dynamic mechanical thermal analyzer,aiming at exploring the changing trend of damping capacity with strain,temperature,and frequency.The findings demonstrated that the damping value rose as temperature and strain increased,with a maximum value of 0.15.Additionally,the damping value decreased when the frequency increased.Dislocation damping under strain and interfacial damping under temperature served as the two primary damping mechanisms.The increase in the density of dislocation strong pinning points following heat treatment reduced the damping value,which was attributed to the heat treatment enhancement of the interfacial bonding force of the composites. 展开更多
关键词 glass cenospheres Al matrix composites MICROSTRUCTURE low-frequency damping properties
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Tailoring the texture and mechanical properties of 3%Y_(2)O_(3)p/ZGK200 composites fabricated by unidirectional and cross rolling followed by annealing
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作者 Xihai Li Hong Yan +1 位作者 Zhiwei Shan Rongshi Chen 《Journal of Magnesium and Alloys》 SCIE EI CAS CSCD 2024年第4期1479-1495,共17页
3%Y_(2)O_(3)p/ZGK200 composites were subjected to unidirectional rolling(UR)and cross rolling(CR)at 400℃and 350℃followed by annealing at 300℃for 1 h.The microstructure,texture and mechanical properties of rolled an... 3%Y_(2)O_(3)p/ZGK200 composites were subjected to unidirectional rolling(UR)and cross rolling(CR)at 400℃and 350℃followed by annealing at 300℃for 1 h.The microstructure,texture and mechanical properties of rolled and annealed composites were systematically studied.The rolled composites exhibited a heterogeneous microstructure,consisting of deformed grains elongated along rolling direction(RD)and Y_(2)O_(3)particles bands distributed along RD.After annealing,static recrystallization(SRX)occurred and most deformed grains transformed into equiaxed grains.A non-basal texture with two strong T-texture components was obtained after UR while a non-basal elliptical/circle texture with circle multi-peaks was obtained after CR,indicating that rolling path had great influences on texture of the composites.After annealing process,R-texture component disappeared or weakened,as results,a non-basal texture with double peaks tilting from normal direction(ND)to transverse direction(TD)and a more random non-basal texture with circle multi-peaks were obtained for UR and CR composites,respectively.The yield strength of rolled composites after UR showed obvious anisotropy along RD and TD while a low anisotropic yield strength was obtained after CR.Some Y_(2)O_(3)particles broke during rolling.The fracture of the composites was attributed to the existence of Y_(2)O_(3)clusters and interfacial debonding between particles and matrix during tension,as a result,the ductility was not as superior as matrix alloy. 展开更多
关键词 Magnesium matrix composites Unidirectional rolling Cross rolling TEXTURE Mechanical properties
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