Textural and compositional zoning in plagioclase phenocrysts:implications for magma chamber processes in the Emeishan large Igneous Province,SW China

Textural and compositional zoning within plagioclase phenocrysts records the magma chamber processes,such as magma differentiation,magma recharge and mixing,and crustal contamination.The plagioclase phenocrysts in the Daqiao and Qiaojia plagioclase-phyric basalts from the Emeishan Large Igneous Province(LIP)show complex textural and compositional zoning patterns,e.g.,normal,reverse,oscillatory,and patchy zoning patterns.Most plagioclase phenocrysts exhibit a core–rim normal zoning pattern(Pl-A)with euhedral high-An cores(An=76–78%,in mole fraction)and low-An rims(An=68–72%),indicative of the crystal regrowth processes caused by recharge of relatively evolved magmas after the formation of high-An cores.Some phenocrysts have a core–rim reverse zoning pattern(Pl-B)with irregular ovaloid cores,characterized by extremely low An(60–61 mol%)and Ba(84–88 ppm)contents and extremely high87Sr/86Sr ratios(0.7120–0.7130).The rims of the Pl-B have relatively high An(69–72%),Ba(~160 ppm)contents,and low87Sr/86Sri(~0.7056).These Pl-B plagioclase phenocrysts preserve the information about the interaction between the crustal xenocrysts and the transporting magmas.Some plagioclase phenocrysts show a core–mantle–rim oscillatory zoning pattern(Pl-C)with multiple oscillations of An(70–80%),Ba(88–147ppm)from core to rim,revealing replenishment and mixing of multiple batches of basaltic melts with diverse compositions.87Sr/86Sr ratios of the Pl-C do not vary significantly(0.7050–0.7054).A small portion of phenocrysts has patchy patterns in the cores(Pl-D),where the low-An patches(72–75%)in form of elliptical or irregular elongated shapes were enclosed by the high-An domains(80–87%).These features can be attributed to crystal dissolution and regrowth processes during the reaction between earlyformed low-Cumulates and recharged hot primitive melts.The cores,mantles,and rims of different types of plagioclase phenocrysts(except the core of Pl-B)commonly display nearly constant Sr isotopic compositions,implying insignificant wall-rock assimilation at shallow-level magma reservoir(s)during the growth of these plagioclase phenocrysts.In conclusion,the massive crystallization of plagioclase in the late stage was an important controlling factor for the formation of iron-rich basalts in the Emeishan LIP.

Micro-area Chemical Composition and Preserved P-T Evolution Trace of Phengite in Albite Gneiss from the Donghai Ultrahigh-Pressure Metamorphic Area,East China

Study of micro-area chemical compositions indicates that phengite in albite gneiss from hole ZK2304 of the Donghai region has evident compositional zoning. SiO2 and tetrahedrally coordinated Si contents decrease, and Al2O3, AlIVand AlVIcontents increase gradually from core to rim. However, K2O, MgO and FeO contents basically remain unchanged from core to rim. According to P-T estimates obtained from geothermometers and barometers, combined with previous experimental data, the core belt (micro-area I) of phengite was formed at T=637–672°C and P=1.55–1.73 GPa, and the transitional belt (micro-area II) of the phengite were formed at T=594–654°C and P=1.35–1.45 GPa. Towards the rim belt (micro-area III), the temperature decreased slightly, but the pressure decreased rapidly with T=542–630°C and P=1.12–1.19 GPa. The P-T evolution path recorded by the compositional zoning of phengite is characterized by significant near-isothermal decompression, revealing that the gneiss has undergone high-pressure-ultrahigh-pressure metamorphism. The compositional zoning of the phengite in the albite gneiss may have formed in the geodynamic process of rapid exhumation in the Sulu ultrahigh-pressure metamorphic belt.

Continuum damage mechanics based modeling progressive failure of woven-fabric composite laminate under low velocity impact

A continuum damage mechanics (CDM) meso-model was derived for both intraply and interply progressive failure behaviors of a 2D woven-fabric composite laminate under a transversely low velocity impact.An in-plane anisotropic damage constitutive model of a 2D woven composite ply was derived based on CDM within a thermodynamic framework,an elastic constitutive model with damage for the fibre directions and an elastic-plastic constitutive model with damage for the shear direction.The progressive failure behavior of a 2D woven composite ply is determined by the damage internal variables in different directions with appropriate damage evolution equations.The interface between two adjacent 2D woven composite plies with different ply orientations was modeled by a traction-separation law based interface element.An isotropic damage constitutive law with CDM properties was used for the interface element,and a damage surface which combines stress and fracture mechanics failure criteria was employed to derive the damage initiation and evolution for the mixed-mode delamination of the interface elements.Numerical analysis and experiments were both carried out on a 2D woven glass fibre/epoxy laminate.The simulation results are in agreement with the experimental counterparts,verifying the progressive failure model of a woven composite laminate.The proposed model will enhance the understanding of dynamic deformation and progressive failure behavior of composite laminate structures in the low velocity impact process.