Suppression of Co(Ⅱ)ion deposition and hazards:Regulation of SEI film composition and structure

Despite the presence of Li F components in the solid electrolyte interphase(SEI)formed on the graphite anode surface by conventional electrolyte,these Li F components primarily exist in an amorphous state,rendering them incapable of effectively inhibiting the exchange reaction between lithium ions and transition metal ions in the electrolyte.Consequently,nearly all lithium ions within the SEI film are replaced by transition metal ions,resulting in an increase in interphacial impedance and a decrease in stability.Herein,we demonstrate that the SEI film,constructed by fluoroethylene carbonate(FEC)additive rich in crystalline Li F,effectively inhibits the undesired Li^(+)/Co^(2+)ion exchange reaction,thereby suppressing the deposition of cobalt compounds and metallic cobalt.Furthermore,the deposited cobalt compounds exhibit enhanced structural stability and reduced catalytic activity with minimal impact on the interphacial stability of the graphite anode.Our findings reveal the crucial influence of SEI film composition and structure on the deposition and hazards associated with transition metal ions,providing valuable guidance for designing next-generation electrolytes.

Floristic Composition, Population Structure, and Recruitment Status of Plant Species: A Case Study of Farmer-Managed Natural Regeneration Practices in Arid and Semi-Arid Lands in Kenya

The technique of Farmer Managed Natural Regeneration (FMNR) is being promoted as a cost-effective approach for restoring degraded arable dry lands. Its effectiveness has been observed in many countries across the globe, where it is a traditional practice, and is now being encouraged across the African continent. This study aimed to evaluate the impact of FMNR on floristic Composition, Vegetation Structure, and Regeneration Status of woody Plant Species in the severely degraded Central Rift, Kenya. The study systematically assessed how FMNR influenced species composition, vegetation structure and regeneration status from two sample plots involved in FMNR practices. Transect lines and quadrats methods were utilized to collect data, specifically regarding the floristic composition, vegetation structure, and regeneration status of woody plant species. Quadrats and sub-quadrats of varying sizes (10 m by 10 m, 5 m by 5 m, and 1 m by 1 m) were nested along the transect lines for data collection. Furthermore, measurements of tree growth and development, including root collar diameter, diameter at breast height (D130) and heights within the study blocks, were taken. The data was then analyzed using R-software. Results showed a marked progressive increase in numbers of trees, saplings, seedlings, shrubs and herbs in all FMNR sites and reductions in all non-FMNR sites. The study advocates for widespread promotion of the FMNR practice both as an environmental conservation and restoration strategy.

A Discussion on the Structure and Spatial Composition of Long Museum West Bund

The Long Museum,with its distinctive T-shaped“umbrella-vault”structure,offers a rich array of spatial experiences.This article delves into space from both structural and compositional perspectives.As the construction mediator,the umbrella vault embodies the consistency of construction and implies the causality of the surface.Presented as an element,the space flows freely,showing diverse fields and order.In terms of the liberation of its meaning,the space offers static perception and dynamic experience,creating a rich exhibition atmosphere.As a distinct entity,the umbrella-vault presents the physical nature,and the dialogue between the Long Museum and the city makes it a museum of art for the people.

Analysis on the Composition and Structure of Branches of Two Kinds of Tree Shapes in Korla Fragrant Pear

ObjectiveThe thesis aims at investigating the distribution and structural characteristics of various branches in canopy of Korla fragrant pear. MethodStatistic work and analysis were conducted on the numbers and distribution characteristics of various branches in each cubic lattice by using the canopy cellular method. ResultThe results showed that： The total number of scaffold branches of evacuation layered tree shape was 97, which mainly distributed in the lower layer and middle part of the canopy; the total number of scaffold branches of open-center tree shape was 94, which mainly distributed in the lower layer and middle part of the canopy. The total number of annual branches of evacuation layered tree shape was 3 920, which mainly distributed in the middle layer and outer part of the canopy; and the total number of annual branches of the open-center tree shape was 3 183, which mainly distributed in middle layer and outer part of the canopy. The total number of perennial branches of evacuation layered tree shape was 2 184, which mainly distributed in lower layer and outer part of the canopy; the total number of perennial branches of open-center tree shape was 1 444, which mainly distributed in middle layer and outer part of the canopy. ConclusionThe total number and the distribution positions of scaffold branches in the canopy of each tree shape were basically the same. The total numbers of annual branches of the two kinds of tree shapes were different, but the distribution positions were basically the same. The total numbers and the distribution positions of perennial branches in the canopy of the two kinds of tree shapes were different.

Comparative Studies on the Fine Structure and Elemental Composition of Envelopes of Trachelomonas and Strombomonas (Euglenophyta)

Fine structure and elemental composition of envelopes of 10 taxa of Trachelomonas and Strombomonas from natural freshwater bodies in China were studied and phylogeny of both genera were discussed. The results indicate that iron (Fe) and silicon (Si) are the primary mineral elements of the envelopes. Composition of mineral elements was uncorrelated with envelope color, however, it was highly correlated with the microarchitecture of the envelopes. Content of Si was higher than that of Fe in all species of Strombomonas and some species of Trachelomonas with rough surface. In most species of Trachelomonas, especially those with dense and smoothy surface, content of Fe was higher than that of Si. Based on the above results, we propose to assign those species of Strombomonas into Trachelomonas and consider them as a group of the latter. These species were the most primitive among the group with envelopes in Euglenaceae.

Microstructure and phase composition of as-cast Mg-9Er-6Y-xZn-0.6Zr alloys

The microstructure and phase composition of as-cast Mg-9Er-6Y-xZn-0.6Zr （x=1, 2, 3, 4; normal mass fraction in %） alloys were investigated. In low Zn content, aside from the major second phase of Mg24（Er, Y, Zn）5, there are a few lamellar phases that grow parallel with each other from the grain boundaries to the grain interior. With Zn content increasing, the Mg24（Er, Y, Zn）5 phase decreases, but the Mg12Zn（Y, Er） phase and lamellar phases continuously increase. When Zn content reaches 4% （normal mass fraction）, the Mg12Zn（Y, Er） phase mainly exists as large bulks, and some a-Mg grains are thoroughly penetrated by the lamellar phases. Moreover, the crystallography structures of the Mgl2Zn（Y, Er） and Mg24（Er, Y, Zn）5 phases are confirmed as 18R-type long-period stacking ordered structure and body-centred cubic structure, respectively.

VALENCE ELECTRON STRUCTURE OF HIGH PROPERTY HIGH SPEED RESISTANCE STEEL AND ITS COMPOSITION DESIGN

Theempiricalelectrontheory of solidsand molecules( EET) and theimproved TFDtheory wereapplied tocalculatethe phasestructurefactorsand interfaceconjunction factorsofcom mon alloying elementsin high speed impact resistance ( HSIR) steel. According tothese va lenceelectron structure parametersitis deduced thatthe alloying elements of high propertyHSIRsteelshould be Mn, Cr, Ni and Mo. The microscopicstructure ofthesteel with this compositionisthe mixtureof martensite, bainiteand austeniteafter quenching andlow tem peraturetempering.Itspropertiesare:σb = 1750 MPa,σ0 2 = 1460 MPa,δ5 = 12 7 % , AKV(at 40 ℃, cross direction) = 21J, which exceed the requirement of design. For the thick plateof high property HSIRsteel,itissuggestedto add alittleamountof Cu on thebasisofabovecomposition .

Influence of Binder Composition and Concrete Pore Structure on Chloride Diffusion Coefficient in Concrete

The influence of binder composition and pore structure of concrete on chloride diffusion coefficient in concrete were investigated by the natural immersion test, MIP test, SEM and EDS test, respectively. The experimental results showed that the effect of binder composition on chloride diffusion coefficient was the comprehensive result of concrete pore structure and binder hydration products, and the porosity and pore size distribution were the main factors that influence the changes of diffusion coefficient. The chloride diffusion coefficient decreased with increasing the curing temperature and the relative humidity. The hydration degree were promoted by improving curing temperatures, and then the porosity of concrete decreased and the proportion of gel pore and transitional pore increased, respectively. But the water evaporation decreased with increasing the relative humidity and then decreased porosity and increased the proportion of gel pore and transitional pore. Additionally, The chloride diffusion coefficient of concrete got the lower value when the appropriate replacement of fly ash in the ranges of 10%-20%, when the double-adding fly ash and slag content was 50%. The porosity increased and the ratio of C/S in C-S-H decreased with further increasing the fly ash content, which led to increase the chloride diffusion coefficient in concrete.

Variability of phytoplankton absorption in the northern South China Sea:influence of the size structure and pigment composition of algal populations

Data from three cruises conducted in the Zhujiang River （ZR）, coastal waters of Guangdong （CWGD） and the northern South China Sea （NSCS） during 2003 and 2004 were examined for assessing the relative importance of pigment composition and packaging effect in modifying the specific absorption coefficients of phytoplankton. The three survey regions differ widely in their phytoplankton community with large cells dominating the ZR and CWGD waters and small cells dominating the NSCS region. Variations in the size structure and the accessory pigments have much effect on the chlorophyll a-specific absorption coefficient of phytoplankton. The size index accounted for about 42% and 33% of the variation of the specific absorption coefficient at 440 and 675 nm, respectively. Using the multiple regression analysis approach, pigment concentrations for each sample were calculated. The accessory pigments other than chlorophyll a contribute to absorption mainly in the blue - to - green region of the spectrum and their absorptions account for about 44%, 43% and 53% on the average of the total phytoplankton absorption at 440 nm for the ZR, CWGD and NSCS regions. Among the accessory pigments, the photosynthetic carotenoids （noted PSC） play a dominant role in the ZR and CWGD waters, while in the NSCS the nonphotosynthetic carotenoids （noted PPG） as well as PSC have important contributions. Because the variations of both the size structure and accessory pigments in algal populations contributed to the variability of the specific absorption coefficient in the study regions, these factors may be considered explicitly in future bio - optical algorithms to derive chlorophyll a concentration more accurately.

Chemical composition and structure characterization of distillation residues of middle-temperature coal tar

The distillation residues of middle-temperature coal tar(DRMCT) were separated into saturate, aromatic, resin and asphaltene fractions by using the combination of solvent extraction and column chromatography separation.The isolated four fractions have been further characterized through the combination of elemental analysis,Fourier transform infrared(FTIR) spectra, proton nuclear magnetic resonance spectrum(~1H NMR) and molecular weight analysis. The analysis results confirm the view that the saturate fraction from DRMCT was mainly composed of long-chain alkanes and almost all of the heteroatoms(S, N and O) were existed in aromatic structures.The asphaltene fraction had the highest molecular weight, the most amount of heteroatom(especially oxygen)and was the most condensed with shortest alkyl side chains among all the fractions. In addition, for the heavier components, the resin and asphaltene fractions from DRMCT contained lower ratio of H/C, lower molecular weight and higher aromaticity degree when compared with crude oils.

Seismic Velocity Structure and Composition of the Continental Crust of Eastern China

On the basis of a one-by-one latitude-longitude grid three-dimensional seismic velocity model, the crustal P-wave velocity structure in eastern China (105-125°E and 18-41°N) is obtained, and a set of geotherms for each grid is established for P-T correction on P-wave velocities. The average depths of sub-crustal layers and their average P-wave velocities of 18 tectonic units in eastern China are exhibited. Our result presents a 32-34 km thick crust beneath eastern China, which is thinner than previous studies, with an average velocity of 6.54 km/s, corresponding to a 5 kg/m3 variation in crustal mean density. The thicker upper but thinner middle and lower crust results in a lower average seismic velocity of eastern China. An intermediate crustal composition with a SiO2 content of 59.7 wt% has been estimated. However, there exists a significant lateral variation in the crustal structures among the tectonic units of eastern China. The structure and composition features of some regions in eastern China indicate that extension has played an important role in the continental crust evolution of eastern China.

Structure, composition and enzymatic hydrolysis of steam-exploded lespedeza stalks

Pretreatment of lespedeza stalks by steam explosion has been studied. The results indicate that steam-exploded pretreatment has strong effects on physical features, morphology, crystallinity, and composition of lespedeza stalks as shown by scanning electron microscopy （SEM）, infrared （IR）, and X-ray diffraction spectrometry methods. After steam explosion, the cellulose and lignin contents of lespedeza stalks varied only slightly, but the hemicellulose content had decreased from 29.34% to 7.48%. The cellulose obtained by steam-exploded pretreatment had a higher degree of crystallinity than that of the raw material. At the explosion condition of 2.25 MPa and 4 min, lignocellulose is easier to hydrolyze by enzyme than the original lignocellulose. The concentration of reduced sugar in the hydrolyzate liquid increased from 71.77 to 162.84 g·L^-1.

Forest structure and woody plant species composition after a wildfire in beech forests in the north of Iran

Beech （Fagus orientalis Lipsky） forest covers about 565,000 ha of land in Guilan province, north of Iran and forms a major carbon pool. It is an important economic, soil protection and recreation resource. We studied long-term effects of fire on the structure and composition 37 years after fire occurrence in these forests. To do this research, we selected 85 ha burned and 85 ha unburned beech forests）. The results indicated that the fire had not changed the overall uneven-aged structure, but it changed forest composition from pure stands to mixed stands that now include species such as Carpinus betulus, Acer cappadocicum and Alnus subcordata. The density of trees and regeneration was significantly increased, while the density of shrubs significantly decreased. The main reasons for increased tree regeneration were attributed to （1） reduction of litter depth, and （2） increase in available light from opening of the canopy and reduction in shrub competition. It is apparent that the forest is on a path to return to its natural state before the fire after 37 years.

Effects of Logging Intensity on Structure and Composition of a Broadleaf-Korean Pine Mixed Forest on Changbai Mountains,Northeast China

In order to identify a harvesting model which is beneficial for broadleaf-Korean pine mixed forest （BKF） sustainability, we investigated four types of harvested stands which have been logged with intensities of 0 （T0, control）, 15% （T1, low intensity）, 35% （T2, moderate intensity）, and 100% （T3, clear-cutting）, and examined the impacts of logging intensity on composition and structure of these stands. Results showed that there were no significant differences between To and T1 for all structural characteristics, except for density of seeding and large trees. The mean diameter at breast height （DBH, 1.3 m above the ground）, stem density and basal area of large trees in T2 were significantly lower than in To, while the density of seedlings and saplings were significantly higher in T2 than in To. Structural characteristics in T3 were entirely different from To. Dominant tree species in primary BKF comprised 93%, 85%, 45% and 10% of the total basal area in T0, T1, T2 and T3, respectively. Three community similarity indices, the Jaccard＇s similarity coefficient （Cj）; the Morisita-Hom index （CMH）; and the Bray-Curtis index （CN）, were the highest for T0 and T1, followed by T0 and T2, and T0 and T3, in generally. These results suggest that effects of harvesting on forest composition and structure are related to logging intensities. Low intensity harvesting is conductive to preserving forest structure and composition, allowing it to recover in a short time period. The regime characterized by low logging intensity and short rotations appears to be a sustainable harvesting method for BKF on the Changbai Mountains.

Crystal Structure and Chemical Composition of Ludwigite from Vranovac Ore Deposit (Boranja Mountain,Serbia)

The crystal structure of ludwigite from Vranovac ore deposit （Boranja Mt., Serbia） was refined using the X-ray powder diffraction （XRPD） Rietveld method in the space group Pbam to a final RB=7.45% and RF=5.26%. It has the unit cell dimensions of： a=9.2515（2） A; b=12.3109（2） A; c=3.03712 （7） A; and V=345.91（1） A3. The calculated distances and angles are mostly in good agreement with the Mg2＋-Fe2＋ substitutions across the M（1） and M（3） sites, as well as with the Fe3＋-AI3＋ replacement in the M（4） site. However, the mean observed M（2）-O distance is considerably shorter than prescribed, due to a slight increase of the Fe3＋ content in the M（2） site. Such replacement was compensated by slight increase of the Fe2＋ content in the M（4） site, resulting in the （Mg1.4sFe2＋o.46Fe3＋o.osMno.o2）2.o1 （Fe3＋o.94Fe2＋0.04Al0.02）1.00B1.00Os composition. The formation temperature was estimated to be about 500- 600C. The influences of the various chemical compositions to the crystallographic parameters, M-O distances, M（3） and M（4） sites shift, distortion parameters and estimated valences, were also studied and compared with other reference samples.

Structure of the Intermetallic Compound Ni_3Al Synthesized under Compression of the Powder Mixture of Pure Elements Part Ⅰ: Phase Composition and Microstructure of Main Phase

It was shown by TEM and X-ray analysis that there are four types of grains of the main Ni3Al phase in the structure of the intermetallic obtained by the self-propagation high temperature method (SHS). Every type of grains has its own domain and dislocation structure. There are mono- and polydomains with and without dislocations. The grains of the main phase of monoand polydomains without dislocations and polydomains with dislocations were formed by diffusion in the solid phase. In these conditions NiAl3 phase is located on the grain boundary of the main phase. The Ni2Al3 phase is located at the triple joints of the main phase.

Floristic Composition, Structure and Soil Properties of Mixed Deciduous Forest and Deciduous Dipterocarp Forest: Case Study in Madan Watershed, Myanmar

Patterns of woody regeneration in terms of species composition and diversity were studied in mixed deciduous forest (MDF) and deciduous dipterocarp forest (DDF) in Minbyin reserved forest of Lewe Township. A total of 57 plant species of MDF belonging to 28 families and 342 individuals and 25 plant species of DDF consist of 15 families and 285 individuals were identified. Plant species diversity was quantitatively higher in the MDF (H' = 3.68) compared to the DDF (H' = 2.39). Tectona grandis showed the highest density (30), dominance (4.40 m2) and IVI (27.01) of MDF and Dipterocarpus tuberculatus also composed the highest density (109), dominance (9.02 m2) and IVI (81.87) in DDF. The smallest diameter class (10 - 20 cm) comprised with 29 species, 103 individuals in MDF and 18 species, 85 individuals in DDF. The size class distribution displayed a reverse J-shaped pattern. The largest numbers of species were concentrated in the smallest height class in both investigated forests because of height and diameter distribution is closely related. The total densities of seedlings and saplings were 1219 and 531 ha-1 in MDF and 988 and 444 ha-1 in DDF respectively. Although soil texture of (40 - 50 cm) and (90 - 100 cm) were sandy clay loam in mixed deciduous forest, the other layers of both investigated forests were sandy loam.

Properties,Compositions and Structure Characteristics of Kazakhstan and Russian Vacuum Residua

Kazakhstan vacuum residue （KAZVR） and Russia vacuum residue （RUSVR） were respectively cut into a number of narrow cuts and non-extractable end-cut by supercritical fluid extraction and fractionation （SFEF）. The properties distribution and SARA compositions of the fractions were analyzed, structure parameters and structure configurations were determined by means of the modified BL method based on 13C-NMR and 1H-NMR data. The results show uneven enriching of contaminants in heavier fractions and much complex structure for end-cuts and removing end-cuts from residua will greatly favor further upgrading. The results would help detailed understanding of KAZVR and RUSVR and their processing adaptability.

Composition and Structure of Ti-6Al-4V Alloy Plasma-based Ion Implanted with Nitrogen

The composition and structure of Ti 6Al 4V alloy plasma based ion implanted with nitrogen was investigated.The nitrogen depth distribution shows more antiballistic with distribution peak heightened with increased implantation time(dose),and more like a parabola at the low implantation pulse voltage.When implantation pulse voltage is increased,the implantation depth increased with the nitrogen distribution peak being deepened,widened and lowered somewhat.TiN,TiN+Ti 2N,or Ti 2N second phases were formed in the implanted layer.The relative percentage of nitrogen content in the form of TiN increases when going deeper into the implanted(TiN formed) layer.The increase of implantation pulse width and/or time is favourable for the formation of TiN rather than Ti 2N.It is unfavourable for formation of any nitrides when implantation pulse voltage is decreased to 30kV or less.Tiny crystalline particles (made mainly of Ti 2N and a smaller percentage of TiO 2 phases) of regular shapes such as triangle and tetragon, etc .(about 20 nm) are found distrbuted dispersively in the near surface region of samples implanted at the high implantation pulse voltage (75kV).

Fine structure and phase composition of Fe–14Mn–1.2C steel:influence of a modified mixture based on refractory metals

The effect of TiO;,ZrO;and Na;AlF;ultrafine powders on the fine structure and the phase composition of Fe–14Mn–1.2C steel was investigated.The introduction of the ultrafine powders into the melt influenced the grain size,the quantity,and the character of distribution of nonmetallic inclusions in the railroad frogs.The microstructure of castings was improved significantly because of the refinement of the grain structure and an increase of the grain-boundary area.After the modifying mixture was introduced into the melt,either the microtwins of one or two intersecting systems or the precipitations of ε-martensite of different types,or simultaneously the microtwins and wafers of ε-martensite,were present in each grain.