Double-metallic lead-free halide perovskites,Cs_(2)B^(I)B^(III)X_(6),sharing three-dimensional crystal structure,have been under the spotlight as the promising alternatives for the toxic and instable lead-based counte...Double-metallic lead-free halide perovskites,Cs_(2)B^(I)B^(III)X_(6),sharing three-dimensional crystal structure,have been under the spotlight as the promising alternatives for the toxic and instable lead-based counterparts.Interest in Cs_(2)B^(I)B^(III)X_(6)motivates intense research into their colloidal nanocrystals(NCs).Recently,Cs_(2)B^(I)B^(III)X_(6)NCs have made great progress in the optical performance via alloying or doping,but there are still great challenges for optoelectronic applications.In this review,the latest advances of Cs_(2)B^(I)B^(III)X_(6)NCs in synthesis approaches,bandgap engineering,photoluminescence(PL)optimization,and applications are summarized.The focus is put upon the composition-property relationships of Cs_(2)B^(I)B^(III)X_(6)NCs,which is approached by discussing the influences of composition variation on the electronic states,carrier dynamics,and optical properties.The challenges and the corresponding improving strategies in the development of high-effective and stable Cs_(2)B^(I)B^(III)X_(6)NCs for device applications are also highlighted.It is believed that this review can deepen the understanding on this burgeoning material system and shed light on their future research directions.展开更多
A high thermal-stable jet fuel design method was developed using composition-properties relations and basic specification properties of jet fuel. Tannery diagrams were provided to visualize relationships among three m...A high thermal-stable jet fuel design method was developed using composition-properties relations and basic specification properties of jet fuel. Tannery diagrams were provided to visualize relationships among three main components (n-paraffins, iso-paraffins, cycloparaffins, or aromatics) with four major specification properties (density, flash point, freezing point, net heat of combustion) and thermal sta- bility. An optimum chemical composition was established to meet performance requirements: n-paraffins 25%-45%, iso-paraffins 15%-30%, cycloparaffins 30%-50%, and aromatics 5%. The thermal stability test on four fuel samples with and without optimal composition indicated that the thermal stabilities of fuel samples with optimal composition are higher than RP-3 jet fuel, and that the theoretical design method is a reliable method to screen the basic oil for the high thermal-stable jet fuel.展开更多
基金supported by the Natural Science Foundation of Fujian Province(No.2021J01315)Quanzhou Scientific Research Project(No.2021GZ4).
文摘Double-metallic lead-free halide perovskites,Cs_(2)B^(I)B^(III)X_(6),sharing three-dimensional crystal structure,have been under the spotlight as the promising alternatives for the toxic and instable lead-based counterparts.Interest in Cs_(2)B^(I)B^(III)X_(6)motivates intense research into their colloidal nanocrystals(NCs).Recently,Cs_(2)B^(I)B^(III)X_(6)NCs have made great progress in the optical performance via alloying or doping,but there are still great challenges for optoelectronic applications.In this review,the latest advances of Cs_(2)B^(I)B^(III)X_(6)NCs in synthesis approaches,bandgap engineering,photoluminescence(PL)optimization,and applications are summarized.The focus is put upon the composition-property relationships of Cs_(2)B^(I)B^(III)X_(6)NCs,which is approached by discussing the influences of composition variation on the electronic states,carrier dynamics,and optical properties.The challenges and the corresponding improving strategies in the development of high-effective and stable Cs_(2)B^(I)B^(III)X_(6)NCs for device applications are also highlighted.It is believed that this review can deepen the understanding on this burgeoning material system and shed light on their future research directions.
基金National Hi-Tech Research and Development 863 Program of China (No. 2005AA723101)China Postdoctoral Science Foundation (No. 2005AA723101)Innovative Research Project of Petrochina Co. Ltd
文摘A high thermal-stable jet fuel design method was developed using composition-properties relations and basic specification properties of jet fuel. Tannery diagrams were provided to visualize relationships among three main components (n-paraffins, iso-paraffins, cycloparaffins, or aromatics) with four major specification properties (density, flash point, freezing point, net heat of combustion) and thermal sta- bility. An optimum chemical composition was established to meet performance requirements: n-paraffins 25%-45%, iso-paraffins 15%-30%, cycloparaffins 30%-50%, and aromatics 5%. The thermal stability test on four fuel samples with and without optimal composition indicated that the thermal stabilities of fuel samples with optimal composition are higher than RP-3 jet fuel, and that the theoretical design method is a reliable method to screen the basic oil for the high thermal-stable jet fuel.
