We report a new kagome quantum spin liquid candidate CuaZn（OH）6FBr, which does not experience any phase transition down to 50inK, more than three orders lower than the antiferromagnetic Curie-Weiss temperature （-20...We report a new kagome quantum spin liquid candidate CuaZn（OH）6FBr, which does not experience any phase transition down to 50inK, more than three orders lower than the antiferromagnetic Curie-Weiss temperature （-200 K）. A clear gap opening at low temperature is observed in the uniform spin susceptibility obtained from 19F nuclear magnetic resonance measurements. We observe the characteristic magnetic field dependence of the gap as expected for fractionalized spin-1/2 spinon excitations. Our experimental results provide firm evidence for spin fractionalization in a topologically ordered spin system, resembling charge fraetionalization in the fractional quantum Hall state.展开更多
Two new D--A type compounds, where electron-donor D is tertiary amino group, electron-acceptor A is 2-benzothiazolyl and ?is two conjugated styryl units, have been synthesized. They are named as trans, trans-2-{4-[4-(...Two new D--A type compounds, where electron-donor D is tertiary amino group, electron-acceptor A is 2-benzothiazolyl and ?is two conjugated styryl units, have been synthesized. They are named as trans, trans-2-{4-[4-(N, N-diethylamino)styryl]styryl}-1, 3-benzothiazole and trans, trans-2-{4-[4-(N, N-diphenylamino)styryl]styryl}-1, 3-benzothiazole. Both compounds show strong two-photon excited fluorescence in yellow-orange region when excited by a femtosecond laser at 800 nm.展开更多
To improve the quality of ultrasonic elastography, by taking the advantage of code excitation and frequency compounding, a transmitting-side multi-frequency with coded excitation for elastography(TFCCE) was proposed. ...To improve the quality of ultrasonic elastography, by taking the advantage of code excitation and frequency compounding, a transmitting-side multi-frequency with coded excitation for elastography(TFCCE) was proposed. TFCCE adopts the chirp signal excitation scheme and strikes a balance in the selection of sub-signal bandwidth, the bandwidth overlap and the number of sub-strain image based on theoretical derivation, so as to further improve the quality of elastic image. Experiments have proved that, compared with the other optimizing methods, the elastographyic signal-to-niose ratio(Re-SN) and contrast-to-noise ratio( Re-CN) are improved significantly with different echo signal-to-noise ratios(ReSN) and attenuation coefficients. When ReSN is 50 dB, compared with short pulse, Re-SN and Re-CN obtained by TFCCE increase by 53% and 143%, respectively. Moreover, in a deeper investigation(85-95 mm), the image has lower strain noise and clear details. When the attenuation coefficient is in the range of 0-1 dB/(cm·MHz), Re-SN and Re-CN obtained by TFCCE can be kept in moderate ranges of 5<Re-SN<6.8 and 11.4<Re-CN<15.2, respectively. In particular, for higher tissue attenuation, the basic image quality cannot be ensured with short pulse excitation, while mediocre quality strain figure can be obtained by TFCCE. Therefore, the TFCCE technology can effectively improve the elastography quality and can be applied to ultrasonic clinical trials.展开更多
The vehicle drive line system is subjected to torsional vibration from different sources of the system such as;engine fluctuating torque, Hook’s joint and the final drive. However, the essential source is the frictio...The vehicle drive line system is subjected to torsional vibration from different sources of the system such as;engine fluctuating torque, Hook’s joint and the final drive. However, the essential source is the friction torque induced in the friction elements, during their engagement. In the automatic transmission system, the planetary gear set includes several friction elements such as;clutch, band brakes, and one way clutch. During the engagement, severe torsional vibration is induced by friction which is noticeable by the passengers in the form of what so called vehicle shunt. In present paper, a torsional vibration model for Drive Line (DL) system includes three different configurations of automatic transmission is constructed. A computer program using MATLAB subroutines is implemented to obtain the system response. Effect of system parameters on the dynamic behavior and stability has been investigated. The system damping and the trend of the friction coefficient have an essential effect on the dynamic behavior and stability of the system. The system response is now predictable with change of the system parameters which opens up the opportunity in future to control the vibration level.展开更多
Low-dimensional quantum spin systems with the Cu2+ central ion are still in the focus of experimental and theoretical research. Here is reported on growth of mm-sized single-crystals of the low-dimensional S = 1/2 spi...Low-dimensional quantum spin systems with the Cu2+ central ion are still in the focus of experimental and theoretical research. Here is reported on growth of mm-sized single-crystals of the low-dimensional S = 1/2 spin compound Cu6(Ge,Si)6O18·6H2O by a diffusion technique in aqueous solution. A route to form Si-rich crystals down to possible dioptase, the pure silicate, is discussed. Motivated by previously reported incorrect assignments of UV-VIS spectra, the assignment of dd excitations from such spectra of the hexahydrate and the fully dehydrated compound is proposed in comparison to dioptase and selected Cu(II) oxo-compounds using bond strength considerations. Non-doped cuprates as layer compounds show higher excitation energies than the title compound. However, when the antiferromagnetic interaction energy as Jz·ln(2) is taken into account for cuprates, a single linear relationship between the Dqe excitation energy and equatorial Cu(II)-O bond strength is confirmed for all compounds. A linear representation is also confirmed between 2A1g energies and a function of axial and equatorial Cu-O bond distances if auxiliary axial bonds are used for four-coordinated compounds. The quotient Dt/Ds of experimental orbital energies deviating from the general trend to smaller values indicates the existence of H2O respectively Cl−axial ligands in comparison to oxo-ligands, whereas larger Dt/Dqe values indicate missing axial bonds. The quotient of the excitation energy 2A1g by 2·2Eg-2B2g allows checking for correctness of the assignment and to distinguish between axial oxo-ligands and others like H2O or Cl−.展开更多
基金Supported by the National Key Research and Development Program of China under Grant Nos 2016YFA0300502,2016YFA0300503,2016YFA0300604,2016YF0300300 and 2016YFA0300802the National Natural Science Foundation of China under Grant Nos 11421092,11474330,11574359,11674406,11374346 and 11674375+3 种基金the National Basic Research Program of China(973 Program)under Grant No 2015CB921304the National Thousand-Young-Talents Program of Chinathe Strategic Priority Research Program(B) of the Chinese Academy of Sciences under Grant Nos XDB07020000,XDB07020200 and XDB07020300supported by DOE-BES under Grant No DE-FG02-04ER46148
文摘We report a new kagome quantum spin liquid candidate CuaZn（OH）6FBr, which does not experience any phase transition down to 50inK, more than three orders lower than the antiferromagnetic Curie-Weiss temperature （-200 K）. A clear gap opening at low temperature is observed in the uniform spin susceptibility obtained from 19F nuclear magnetic resonance measurements. We observe the characteristic magnetic field dependence of the gap as expected for fractionalized spin-1/2 spinon excitations. Our experimental results provide firm evidence for spin fractionalization in a topologically ordered spin system, resembling charge fraetionalization in the fractional quantum Hall state.
文摘Two new D--A type compounds, where electron-donor D is tertiary amino group, electron-acceptor A is 2-benzothiazolyl and ?is two conjugated styryl units, have been synthesized. They are named as trans, trans-2-{4-[4-(N, N-diethylamino)styryl]styryl}-1, 3-benzothiazole and trans, trans-2-{4-[4-(N, N-diphenylamino)styryl]styryl}-1, 3-benzothiazole. Both compounds show strong two-photon excited fluorescence in yellow-orange region when excited by a femtosecond laser at 800 nm.
基金Project(2013GZX0147-3) supported by the Natural Science Foundation of Sichuan Province,China
文摘To improve the quality of ultrasonic elastography, by taking the advantage of code excitation and frequency compounding, a transmitting-side multi-frequency with coded excitation for elastography(TFCCE) was proposed. TFCCE adopts the chirp signal excitation scheme and strikes a balance in the selection of sub-signal bandwidth, the bandwidth overlap and the number of sub-strain image based on theoretical derivation, so as to further improve the quality of elastic image. Experiments have proved that, compared with the other optimizing methods, the elastographyic signal-to-niose ratio(Re-SN) and contrast-to-noise ratio( Re-CN) are improved significantly with different echo signal-to-noise ratios(ReSN) and attenuation coefficients. When ReSN is 50 dB, compared with short pulse, Re-SN and Re-CN obtained by TFCCE increase by 53% and 143%, respectively. Moreover, in a deeper investigation(85-95 mm), the image has lower strain noise and clear details. When the attenuation coefficient is in the range of 0-1 dB/(cm·MHz), Re-SN and Re-CN obtained by TFCCE can be kept in moderate ranges of 5<Re-SN<6.8 and 11.4<Re-CN<15.2, respectively. In particular, for higher tissue attenuation, the basic image quality cannot be ensured with short pulse excitation, while mediocre quality strain figure can be obtained by TFCCE. Therefore, the TFCCE technology can effectively improve the elastography quality and can be applied to ultrasonic clinical trials.
文摘The vehicle drive line system is subjected to torsional vibration from different sources of the system such as;engine fluctuating torque, Hook’s joint and the final drive. However, the essential source is the friction torque induced in the friction elements, during their engagement. In the automatic transmission system, the planetary gear set includes several friction elements such as;clutch, band brakes, and one way clutch. During the engagement, severe torsional vibration is induced by friction which is noticeable by the passengers in the form of what so called vehicle shunt. In present paper, a torsional vibration model for Drive Line (DL) system includes three different configurations of automatic transmission is constructed. A computer program using MATLAB subroutines is implemented to obtain the system response. Effect of system parameters on the dynamic behavior and stability has been investigated. The system damping and the trend of the friction coefficient have an essential effect on the dynamic behavior and stability of the system. The system response is now predictable with change of the system parameters which opens up the opportunity in future to control the vibration level.
文摘Low-dimensional quantum spin systems with the Cu2+ central ion are still in the focus of experimental and theoretical research. Here is reported on growth of mm-sized single-crystals of the low-dimensional S = 1/2 spin compound Cu6(Ge,Si)6O18·6H2O by a diffusion technique in aqueous solution. A route to form Si-rich crystals down to possible dioptase, the pure silicate, is discussed. Motivated by previously reported incorrect assignments of UV-VIS spectra, the assignment of dd excitations from such spectra of the hexahydrate and the fully dehydrated compound is proposed in comparison to dioptase and selected Cu(II) oxo-compounds using bond strength considerations. Non-doped cuprates as layer compounds show higher excitation energies than the title compound. However, when the antiferromagnetic interaction energy as Jz·ln(2) is taken into account for cuprates, a single linear relationship between the Dqe excitation energy and equatorial Cu(II)-O bond strength is confirmed for all compounds. A linear representation is also confirmed between 2A1g energies and a function of axial and equatorial Cu-O bond distances if auxiliary axial bonds are used for four-coordinated compounds. The quotient Dt/Ds of experimental orbital energies deviating from the general trend to smaller values indicates the existence of H2O respectively Cl−axial ligands in comparison to oxo-ligands, whereas larger Dt/Dqe values indicate missing axial bonds. The quotient of the excitation energy 2A1g by 2·2Eg-2B2g allows checking for correctness of the assignment and to distinguish between axial oxo-ligands and others like H2O or Cl−.
