In the presence of ethyl alcohol or emulsifier OP,molybdenum(Ⅵ) forms 1∶1∶1'water soluble colored coordination com- pound with both of 2-(2-thiazolylazo)-5-diethylaminophenol (abbreviation TAE) and hydroxylamin...In the presence of ethyl alcohol or emulsifier OP,molybdenum(Ⅵ) forms 1∶1∶1'water soluble colored coordination com- pound with both of 2-(2-thiazolylazo)-5-diethylaminophenol (abbreviation TAE) and hydroxylamine.This deep blue coordination compound is inert characteristically and remains stable in 1.7 mol/L sulfuric acid,2.4 mol/L hydrochloric or ni- tric acid.It will not be decomposed by masking agents even on boiled,while in that case,almost all the colored coordination com- pounds formed by other metal ions will be decomposed completely.This inert character of the coordination compound of molybdenum(Ⅵ) and its utilization in improving the analytical selectivity have been discussed.In the coexistence of various for- eign ions,especially in the presence of a great quantity of tungsten,which always interferes with the determination of molybdenum,the direct determination of molybdenum in the aqueous solution by applying this system has shown an acceptable sensitivity and reproducibility.From the results of determination in some synthetic and standard samples,it seems feasible to use this system in the determination of molybdenum in nonferrous alloys.展开更多
文摘In the presence of ethyl alcohol or emulsifier OP,molybdenum(Ⅵ) forms 1∶1∶1'water soluble colored coordination com- pound with both of 2-(2-thiazolylazo)-5-diethylaminophenol (abbreviation TAE) and hydroxylamine.This deep blue coordination compound is inert characteristically and remains stable in 1.7 mol/L sulfuric acid,2.4 mol/L hydrochloric or ni- tric acid.It will not be decomposed by masking agents even on boiled,while in that case,almost all the colored coordination com- pounds formed by other metal ions will be decomposed completely.This inert character of the coordination compound of molybdenum(Ⅵ) and its utilization in improving the analytical selectivity have been discussed.In the coexistence of various for- eign ions,especially in the presence of a great quantity of tungsten,which always interferes with the determination of molybdenum,the direct determination of molybdenum in the aqueous solution by applying this system has shown an acceptable sensitivity and reproducibility.From the results of determination in some synthetic and standard samples,it seems feasible to use this system in the determination of molybdenum in nonferrous alloys.
