In-situ HVEM observation on phase transition of the YBa_2Cu_3O_(7-x) superconducting compound in pro- cess of heating was carried out,and high temperature X-ray diffraction analysis in air and X-ray diffraction phase ...In-situ HVEM observation on phase transition of the YBa_2Cu_3O_(7-x) superconducting compound in pro- cess of heating was carried out,and high temperature X-ray diffraction analysis in air and X-ray diffraction phase analysis for the sample treated in vacuum condition were made.The results showed that the temperature of phase transition is related to oxygen content in the sample and in general,is 100℃ to 120℃ lower in vacu- um condition than in air.At 320℃ to 350℃ twin bands begin to disappear,and some Cu_2O are formed on the surface of the sample and transit from orthorhombic YBa_2Cu_3O_(7-x) to arthorhombic Y_2BaCuO_5 compound. This transition was completed at about 500℃.Above 900℃,this compound consists of the Y_2BaCuO_5, BaCuO_2,Y_2O_3 and some other minor compounds.No phase transition was observed during cooling the sample.展开更多
The temperature dependence of lattice parameters a and c of intermetallic compounds RMn 2Ge 2(R=La, Sm and Gd)were measured in the temperature range of 10800 K by using the X-ray diffractometer . It is found that the ...The temperature dependence of lattice parameters a and c of intermetallic compounds RMn 2Ge 2(R=La, Sm and Gd)were measured in the temperature range of 10800 K by using the X-ray diffractometer . It is found that the high temperature magnetic transitions of Mn-subsystem in light rare earth compounds from paramagnetic to antiferromagnetic state accompany the negative magnetoelastic anomalies of lattice parameters c, where a does not change. This indicates that the antiferromagnetic component of intralayer Mn-Mn exchange coupling is correlated with lattice constant c. The low temperature first order ferromagnetism→antiferromagnetism transitions(or antiferromagnetism→ferromagnetism transition) of Mn-subsystem in SmMn 2Ge 2 and GdMn 2Ge 2 accompany the abruptly decrease(or increase) of lattice parameter a, and Δa/a≈0.15%. This demonstrates that the interlayer Mn-Mn exchange interaction is very sensitive to the intralayer Mn-Mn distance. The critical value of lattice constant a k, at which the interlayer Mn-Mn coupling changes its sign, is 4.044 5×10 -10 m. Based on the molecular field model of exchange interaction the magnetic curves of GdMn 2Ge 2 single crystal at different temperatures were calculated and a good agreement with experimental data had gotten. The Gd-Gd, Gd-Mn, intralayer Mn-Mn and interlayer Mn-Mn exchange coupling parameters were estimated.展开更多
We present the temperature-dependent susceptibility and specific heat measurement of spinel ZnV204. The structural transition with orbital ordering and the antiferromagnetic transition with spin ordering were observed...We present the temperature-dependent susceptibility and specific heat measurement of spinel ZnV204. The structural transition with orbital ordering and the antiferromagnetic transition with spin ordering were observed at 50 K and 37 K, respectively. By analysis of the hysteresis behavior between the specific heat curves obtained in warming and cooling processes, the structural transition was confirmed to be the first-order transition, while the antiferromagnetic transition was found to be of the second-order type. At the structural transition, the latent heat and entropy change were calculated from the excess specific heat, and the derivative of pressure with respect to temperature was obtained using the Clausius--Clapayron equation. At the magnetic transition, the width of the critical fluctuation region was obtained to be about 0.5 K by comparing with Gaussian fluctuations. In the critical region, the critical behavior was analyzed by using renormalization-group theory. The critical amplitude ratio A＋/A- = 1.46, which deviates from the 3D Heisenburg model; while the critical exponent a is -0.011, which is close to the 3D XY model. We proposed that these abnormal critical behaviors can be attributed to strong spin-orbital coupling accompanied with the antiferromagnetic transition. Moreover, in the low temperature range （2-5 K）, the Fermi energy, the density of states near the Fermi surface, and the low limit of Debye temperature were estimated to be 2.42 eV, 2.48 eV-1, and 240 K, respectively.展开更多
研究了热处理对La Fe Si化合物组织结构的影响。结果表明,热处理保温时间在24h以内及温度在900～1300℃之间,铸态试样在两个温度点发生相变,即900～1200℃为一个相变点,α Fe相从铸态的非主相变为主相;1300℃为另一个相变点。在900～110...研究了热处理对La Fe Si化合物组织结构的影响。结果表明,热处理保温时间在24h以内及温度在900～1300℃之间,铸态试样在两个温度点发生相变,即900～1200℃为一个相变点,α Fe相从铸态的非主相变为主相;1300℃为另一个相变点。在900～1100℃范围材料中α Fe相的晶胞常数逐渐减小,当热处理温度继续增加,其α Fe相的晶胞常数缓慢增加。展开更多
文摘In-situ HVEM observation on phase transition of the YBa_2Cu_3O_(7-x) superconducting compound in pro- cess of heating was carried out,and high temperature X-ray diffraction analysis in air and X-ray diffraction phase analysis for the sample treated in vacuum condition were made.The results showed that the temperature of phase transition is related to oxygen content in the sample and in general,is 100℃ to 120℃ lower in vacu- um condition than in air.At 320℃ to 350℃ twin bands begin to disappear,and some Cu_2O are formed on the surface of the sample and transit from orthorhombic YBa_2Cu_3O_(7-x) to arthorhombic Y_2BaCuO_5 compound. This transition was completed at about 500℃.Above 900℃,this compound consists of the Y_2BaCuO_5, BaCuO_2,Y_2O_3 and some other minor compounds.No phase transition was observed during cooling the sample.
文摘The temperature dependence of lattice parameters a and c of intermetallic compounds RMn 2Ge 2(R=La, Sm and Gd)were measured in the temperature range of 10800 K by using the X-ray diffractometer . It is found that the high temperature magnetic transitions of Mn-subsystem in light rare earth compounds from paramagnetic to antiferromagnetic state accompany the negative magnetoelastic anomalies of lattice parameters c, where a does not change. This indicates that the antiferromagnetic component of intralayer Mn-Mn exchange coupling is correlated with lattice constant c. The low temperature first order ferromagnetism→antiferromagnetism transitions(or antiferromagnetism→ferromagnetism transition) of Mn-subsystem in SmMn 2Ge 2 and GdMn 2Ge 2 accompany the abruptly decrease(or increase) of lattice parameter a, and Δa/a≈0.15%. This demonstrates that the interlayer Mn-Mn exchange interaction is very sensitive to the intralayer Mn-Mn distance. The critical value of lattice constant a k, at which the interlayer Mn-Mn coupling changes its sign, is 4.044 5×10 -10 m. Based on the molecular field model of exchange interaction the magnetic curves of GdMn 2Ge 2 single crystal at different temperatures were calculated and a good agreement with experimental data had gotten. The Gd-Gd, Gd-Mn, intralayer Mn-Mn and interlayer Mn-Mn exchange coupling parameters were estimated.
基金supported by the National Basic Research Program of China(Grant No.2012CB821404)the National Natural Science Foundation of China(Grant Nos.51172166 and 61106005)+1 种基金the National Science Fund for Talent Training in Basic Science,China(Grant No.J1210061)the Doctoral Fund of Ministry of Education of China(Grant No.20110141110007)
文摘We present the temperature-dependent susceptibility and specific heat measurement of spinel ZnV204. The structural transition with orbital ordering and the antiferromagnetic transition with spin ordering were observed at 50 K and 37 K, respectively. By analysis of the hysteresis behavior between the specific heat curves obtained in warming and cooling processes, the structural transition was confirmed to be the first-order transition, while the antiferromagnetic transition was found to be of the second-order type. At the structural transition, the latent heat and entropy change were calculated from the excess specific heat, and the derivative of pressure with respect to temperature was obtained using the Clausius--Clapayron equation. At the magnetic transition, the width of the critical fluctuation region was obtained to be about 0.5 K by comparing with Gaussian fluctuations. In the critical region, the critical behavior was analyzed by using renormalization-group theory. The critical amplitude ratio A＋/A- = 1.46, which deviates from the 3D Heisenburg model; while the critical exponent a is -0.011, which is close to the 3D XY model. We proposed that these abnormal critical behaviors can be attributed to strong spin-orbital coupling accompanied with the antiferromagnetic transition. Moreover, in the low temperature range （2-5 K）, the Fermi energy, the density of states near the Fermi surface, and the low limit of Debye temperature were estimated to be 2.42 eV, 2.48 eV-1, and 240 K, respectively.
