A new heptanuclear trigonal prismatic cluster [PrCu6(μ3-OH)3(Gly)6im6](ClO4)6 was synthesized through the self-assembly of Pr3+, Cu2+, glycine and imidazole in aqueous solution and characterized by X-ray structure ...A new heptanuclear trigonal prismatic cluster [PrCu6(μ3-OH)3(Gly)6im6](ClO4)6 was synthesized through the self-assembly of Pr3+, Cu2+, glycine and imidazole in aqueous solution and characterized by X-ray structure analysis. The compound belongs to the trigonal R3 space group with a = b = 15.8761(2), c = 23.4943(5) ?, V = 5128.4(1) ?3, Z = 3, Dc = 1.965 g/cm3, μ = 2.869 mm-1, F(000) = 3012, the final R = 0.0332 and wR = 0.0844 for 3596 independent reflections. In the cation, the Pr3+ ion is situated at the center of a prism formed by six copper atoms and coordinates to nine oxygen atoms with a tricapped trigonal prismatic coordination polyhedron. Six glycine ligands and six imidazole terminal ligands participate in constructing the cluster.展开更多
Using a lithium niobate （LN） material, we propose a broadband polarization beam splitter （PBS） with high efficiency by employing a negative refractive photonic crystal （PhC） wedge slab with an angle of 60°....Using a lithium niobate （LN） material, we propose a broadband polarization beam splitter （PBS） with high efficiency by employing a negative refractive photonic crystal （PhC） wedge slab with an angle of 60°. It can split the incident light into two parts at about 90° with TE and TM polarizations. The transmissions of polarized light for an LN-based PBS are more than 80% with a broad angle and wavelength bandwidth of 8° and 70 nm at 1.55μm, while with a Si-based PhC, no PBS with high efficiency can be realized for the relatively lower transmission of TM output light.展开更多
基金This research was supported by the State Key Laboratory of Structural Chemistry the National Science and Technology of China (001CB1089)+8 种基金 the Chinese Academy of Sciences (CAS) the National Science Foundation of China (20333070 2027307390206040) and the Science Foundation of CAS and Fujian Province (2002F0142003J0422004J0412004H201-1)
文摘A new heptanuclear trigonal prismatic cluster [PrCu6(μ3-OH)3(Gly)6im6](ClO4)6 was synthesized through the self-assembly of Pr3+, Cu2+, glycine and imidazole in aqueous solution and characterized by X-ray structure analysis. The compound belongs to the trigonal R3 space group with a = b = 15.8761(2), c = 23.4943(5) ?, V = 5128.4(1) ?3, Z = 3, Dc = 1.965 g/cm3, μ = 2.869 mm-1, F(000) = 3012, the final R = 0.0332 and wR = 0.0844 for 3596 independent reflections. In the cation, the Pr3+ ion is situated at the center of a prism formed by six copper atoms and coordinates to nine oxygen atoms with a tricapped trigonal prismatic coordination polyhedron. Six glycine ligands and six imidazole terminal ligands participate in constructing the cluster.
基金supported by the National Natural Science Foundation of China under Grant Nos.11574208 and 1174204
文摘Using a lithium niobate （LN） material, we propose a broadband polarization beam splitter （PBS） with high efficiency by employing a negative refractive photonic crystal （PhC） wedge slab with an angle of 60°. It can split the incident light into two parts at about 90° with TE and TM polarizations. The transmissions of polarized light for an LN-based PBS are more than 80% with a broad angle and wavelength bandwidth of 8° and 70 nm at 1.55μm, while with a Si-based PhC, no PBS with high efficiency can be realized for the relatively lower transmission of TM output light.
