Assessing the behaviour and concentration of waste pollutants deposited between two parallel plates is essential for effective environmental management.Determining the effectiveness of treatment methods in reducing po...Assessing the behaviour and concentration of waste pollutants deposited between two parallel plates is essential for effective environmental management.Determining the effectiveness of treatment methods in reducing pollution scales is made easier by analysing waste discharge concentrations.The waste discharge concentration analysis is useful for assessing how effectively wastewater treatment techniques reduce pollution levels.This study aims to explore the Casson micropolar fluid flow through two parallel plates with the influence of pollutant concentration and thermophoretic particle deposition.To explore the mass and heat transport features,thermophoretic particle deposition and thermal radiation are considered.The governing equations are transformed into ordinary differential equations with the help of suitable similarity transformations.The Runge-Kutta-Fehlberg’s fourthfifth order technique and shooting procedure are used to solve the reduced set of equations and boundary conditions.The integration of a neural network model based on the Levenberg-Marquardt algorithm serves to improve the accuracy of predictions and optimize the analysis of parameters.Graphical outcomes are displayed to analyze the characteristics of the relevant dimensionless parameters in the current problem.Results reveal that concentration upsurges as the micropolar parameter increases.The concentration reduces with an upsurge in the thermophoretic parameter.An upsurge in the external pollutant source variation and the local pollutant external source parameters enhances mass transport.The surface drag force declines for improved values of porosity and micropolar parameters.展开更多
To describe the complex kinetics of formation and destruction mechanism of nitrogen dioxide(NO2), there is an increasing demand for real-time and in situ analysis of NO2 in the discharge region. Pulsed cavity ring-d...To describe the complex kinetics of formation and destruction mechanism of nitrogen dioxide(NO2), there is an increasing demand for real-time and in situ analysis of NO2 in the discharge region. Pulsed cavity ring-down spectroscopy(CRDS) provides an excellent diagnostic approach. In the present paper, CRDS has been applied in situ for time evolution measurement of NO2 concentration which is rarely investigated in gas discharges. In pulsed direct current discharge of NO2/Ar mixture at a pressure of 500 Pa, a peak voltage of -1300 V and a frequency of 30 Hz, for higher initial NO2 concentration(3.05×10^(14)cm^(-3), 8.88×10^(13)cm^(-3)),the NO2 concentration sharply decreases at the beginning of the discharge afterglow and then becomes almost constant, and the pace of decline increases with pulse duration; however, for lower initial NO2 concentration of 1.69×10^(13)cm^(-3), the NO2 concentration also decreases at the beginning of the discharge afterglow for 200 ns and 1 μs pulse durations, while it slightly increases and then declines for 2 μs pulse duration. Thus, the removal of low-level NO2 could not be promoted by a higher mean energy input.展开更多
Quantifying the functional relationships relating river discharge and weathering products places key constraints on the negative feedback between the silicate weathering and climate. In this study we analyze the conce...Quantifying the functional relationships relating river discharge and weathering products places key constraints on the negative feedback between the silicate weathering and climate. In this study we analyze the concentration–discharge relationships of weathering products from global rivers using previously compiled time-series datasets for concentrations and discharge from global rivers. To analyze the nature of the covariation between specific discharge and concentrations, we use both a power law equation and a recently developed solute production equation. The solute production equation allows us to quantify weathering efficiency, or the resistance to dilution at high runoff, via the Damkohler coefficient. These results are also compared to those derived using average concentration–discharge pairs.Both the power law exponent and the Damkohler coefficient increase and asymptote as catchments exhibit increasingly chemostatic behavior, resulting in an inverse relationship between the two parameters. We also show that using thedistribution of average concentration–discharge pairs from global rivers, rather than fitting concentration–discharge relationships for each individual river, underestimates global median weathering efficiency by up to a factor of ~10. This study demonstrates the utility of long time-series sampling of global rivers to elucidate controlling processes needed to quantify patterns in global silicate weathering rates.展开更多
The oxidation of elemental mercury (Hg~) by dielectric barrier discharge reactors was studied at room temperature, where concentric cylinder discharge reactor (CCDR) and surface discharge plasma reactor (SDPR) w...The oxidation of elemental mercury (Hg~) by dielectric barrier discharge reactors was studied at room temperature, where concentric cylinder discharge reactor (CCDR) and surface discharge plasma reactor (SDPR) were employed. The parameters (e.g. Hg^0 oxidation efficiency, energy constant, energy yield, energy consumption, and O3 concentration) were discussed. From comparison of the two reactors, higher Hg^0 oxidation efficiency and energy constant in the SDPR system were obtained by using lower specific energy density. At the same applied voltage, energy yield in the SDPR system was larger than that in the CCDR system, and energy consumption in the SDPR system was much less. Additionally, more 03 was generated in the SDPR system. The experimental results showed that 98% of Hg^0 oxidation efficiency, 0.6 J·L^-1 of energy constant, 13.7 μg·J^-1 of energy yield, 15.1 eV·molecule^-1 of energy consumption, and 12.7 μg·J^-1 of O3 concentration were achieved in the SDPR system. The study reveals an alternative and economical technology for Hg^0 oxidation in the coal-fired flue gas.展开更多
In this paper,an absorption spectroscopy measurement method was applied on two atmospheric pressure plasma sources to determine their production of nitric oxide.The concentrations are essential for evaluating the plas...In this paper,an absorption spectroscopy measurement method was applied on two atmospheric pressure plasma sources to determine their production of nitric oxide.The concentrations are essential for evaluating the plasma sources based on the principle of the Dielectric Barrier Discharge(DBD)for applications in plasma medicine.The described method is based on a setup with an electrodeless discharge lamp filled with a mixture of oxygen and nitrogen.One of the emitted wavelengths is an important resonance wavelength of nitric oxide(λ = 226.2 nm).By comparing the absorption behaviour at the minimum and maximum of the spectral absorption cross section of nitric oxide around that wavelength,and measuring the change in intensity by the absorbing plasma,the concentration of nitric oxide inside the plasma can be calculated.The produced nitric oxide concentrations depend on the pulse duration and are in the range of 180 ppm to 1400 ppm,so that a distance of about 10 cm to the respiratory tract is enough to conform to the VDI Guideline 2310.展开更多
文摘Assessing the behaviour and concentration of waste pollutants deposited between two parallel plates is essential for effective environmental management.Determining the effectiveness of treatment methods in reducing pollution scales is made easier by analysing waste discharge concentrations.The waste discharge concentration analysis is useful for assessing how effectively wastewater treatment techniques reduce pollution levels.This study aims to explore the Casson micropolar fluid flow through two parallel plates with the influence of pollutant concentration and thermophoretic particle deposition.To explore the mass and heat transport features,thermophoretic particle deposition and thermal radiation are considered.The governing equations are transformed into ordinary differential equations with the help of suitable similarity transformations.The Runge-Kutta-Fehlberg’s fourthfifth order technique and shooting procedure are used to solve the reduced set of equations and boundary conditions.The integration of a neural network model based on the Levenberg-Marquardt algorithm serves to improve the accuracy of predictions and optimize the analysis of parameters.Graphical outcomes are displayed to analyze the characteristics of the relevant dimensionless parameters in the current problem.Results reveal that concentration upsurges as the micropolar parameter increases.The concentration reduces with an upsurge in the thermophoretic parameter.An upsurge in the external pollutant source variation and the local pollutant external source parameters enhances mass transport.The surface drag force declines for improved values of porosity and micropolar parameters.
基金supported by National Natural Science Foundation of China(Nos.11175035,11405022,11475039,11605023)the National Magnetic Confinement Fusion Science Program of China(No.2013GB109005)+2 种基金Chinesisch-Deutsches Forschungsprojekt(No.GZ768)the Fundamental Research Funds for the Central Universities(Nos.DUT14ZD(G)04,DUT15RC(3)072,DUT15TD44,DUT16TD13)China Postdoctoral Science Foundation(No.2016M591423)
文摘To describe the complex kinetics of formation and destruction mechanism of nitrogen dioxide(NO2), there is an increasing demand for real-time and in situ analysis of NO2 in the discharge region. Pulsed cavity ring-down spectroscopy(CRDS) provides an excellent diagnostic approach. In the present paper, CRDS has been applied in situ for time evolution measurement of NO2 concentration which is rarely investigated in gas discharges. In pulsed direct current discharge of NO2/Ar mixture at a pressure of 500 Pa, a peak voltage of -1300 V and a frequency of 30 Hz, for higher initial NO2 concentration(3.05×10^(14)cm^(-3), 8.88×10^(13)cm^(-3)),the NO2 concentration sharply decreases at the beginning of the discharge afterglow and then becomes almost constant, and the pace of decline increases with pulse duration; however, for lower initial NO2 concentration of 1.69×10^(13)cm^(-3), the NO2 concentration also decreases at the beginning of the discharge afterglow for 200 ns and 1 μs pulse durations, while it slightly increases and then declines for 2 μs pulse duration. Thus, the removal of low-level NO2 could not be promoted by a higher mean energy input.
基金supported by a Stanford EDGE-STEM Fellowshipinitiated under NSF EAR-1254156 to Kate Maher and was also supported by the California Alliance Research Exchange NSF HRD-1306595 to C.Page Chamberlain
文摘Quantifying the functional relationships relating river discharge and weathering products places key constraints on the negative feedback between the silicate weathering and climate. In this study we analyze the concentration–discharge relationships of weathering products from global rivers using previously compiled time-series datasets for concentrations and discharge from global rivers. To analyze the nature of the covariation between specific discharge and concentrations, we use both a power law equation and a recently developed solute production equation. The solute production equation allows us to quantify weathering efficiency, or the resistance to dilution at high runoff, via the Damkohler coefficient. These results are also compared to those derived using average concentration–discharge pairs.Both the power law exponent and the Damkohler coefficient increase and asymptote as catchments exhibit increasingly chemostatic behavior, resulting in an inverse relationship between the two parameters. We also show that using thedistribution of average concentration–discharge pairs from global rivers, rather than fitting concentration–discharge relationships for each individual river, underestimates global median weathering efficiency by up to a factor of ~10. This study demonstrates the utility of long time-series sampling of global rivers to elucidate controlling processes needed to quantify patterns in global silicate weathering rates.
基金supported by National Natural Science Foundation of China(No.51177007)Ministry of Science and Technology of China(No.2009AA064101-4)
文摘The oxidation of elemental mercury (Hg~) by dielectric barrier discharge reactors was studied at room temperature, where concentric cylinder discharge reactor (CCDR) and surface discharge plasma reactor (SDPR) were employed. The parameters (e.g. Hg^0 oxidation efficiency, energy constant, energy yield, energy consumption, and O3 concentration) were discussed. From comparison of the two reactors, higher Hg^0 oxidation efficiency and energy constant in the SDPR system were obtained by using lower specific energy density. At the same applied voltage, energy yield in the SDPR system was larger than that in the CCDR system, and energy consumption in the SDPR system was much less. Additionally, more 03 was generated in the SDPR system. The experimental results showed that 98% of Hg^0 oxidation efficiency, 0.6 J·L^-1 of energy constant, 13.7 μg·J^-1 of energy yield, 15.1 eV·molecule^-1 of energy consumption, and 12.7 μg·J^-1 of O3 concentration were achieved in the SDPR system. The study reveals an alternative and economical technology for Hg^0 oxidation in the coal-fired flue gas.
文摘In this paper,an absorption spectroscopy measurement method was applied on two atmospheric pressure plasma sources to determine their production of nitric oxide.The concentrations are essential for evaluating the plasma sources based on the principle of the Dielectric Barrier Discharge(DBD)for applications in plasma medicine.The described method is based on a setup with an electrodeless discharge lamp filled with a mixture of oxygen and nitrogen.One of the emitted wavelengths is an important resonance wavelength of nitric oxide(λ = 226.2 nm).By comparing the absorption behaviour at the minimum and maximum of the spectral absorption cross section of nitric oxide around that wavelength,and measuring the change in intensity by the absorbing plasma,the concentration of nitric oxide inside the plasma can be calculated.The produced nitric oxide concentrations depend on the pulse duration and are in the range of 180 ppm to 1400 ppm,so that a distance of about 10 cm to the respiratory tract is enough to conform to the VDI Guideline 2310.