Preparation of Ti/MnO_2 Reference Electrode and Its Application in Concrete Structures

A novel Ti/MnO2 reference electrode (TMRE) used for concrete environment was fabricated by the electro-deposition method and encapsulated carefully.The properties of the electrode were characterized by open-circuit potential,potentiodynamic polarization behavior in synthetic concrete pore solutions and electrochemical performance in cement mortar.The experimental results indicate that the TMRE shows good stability with and without the addition of Cl-ions and desirable polarization behavior in synthetic pore solution.Results of tests in cement mortar indicate that the potential of TMRE will be stable after about 7 days.The stability and desirable polarization behavior make it a promising reference electrode for concrete environment.

Oyster Cementation as Protective Covers for Exposed Marine Concrete

Cored concrete specimens from seawall exposed to marine environment for 22 years were evaluated by carbonation depth test,rapid chloride permeability test,absorption of water test and microstructure examination.The results show that concrete exposed to marine environment has smaller carbonation depth and carbonation depth of concrete exposed to tidal zone is less than that in splash zone.There are similar water absorption rate and chloride permeability for concrete exposed to splash zone compared with concrete exposed to splash zone removed 3mm surface layer.However,concrete exposed to tidal zone with bio-films has lower chloride permeability and water absorption rate than those of concrete exposed to tidal zone removed 3mm surface layer.In addition,Results of FE-SEM and EDAX indicate that concrete exposed to splash zone has loose structure,exposed finer aggregate and concrete exposed to tidal zone covers by dense structure of oyster cementation and shell.Microstructures analysis further verified that concrete covered with oysters and their cementation has beneficial effects to durability of concrete.

Performance Degradation of the Repeated Recycled Aggregate Concrete with 70% Replacement of Three-generation Recycled Coarse Aggregate

The feasibility of using different generations recycled coarse aggregate（RCA） on structural concrete was fully evaluated by studying the performance of the recycled coarse aggregates and their corresponding concretes, the different generations of RCA were recycled by following the repeated mode of ‘concrete-waste concrete-coarse aggregate-concrete＇. Moreover, the focus was on ‘three generations＇ of repeated RCAs, the RCA was produced by crushing and regenerating the artificial accelerated degraded concrete, the process was designed to follow the nature degradation of the concrete with a coupling action of accelerated carbonation and bending load. The properties of x-generation（x=1, 2 or 3） of repeated RCA were systematically investigated and the compressive and splitting tensile strengths of relating structural concretes（with 70% replacement of x-generation of RCA） were studied accordingly. The results show a competent compressive and splitting tensile strength of 30 MPa at 28 th day of structural concretes with all generations of repeated RAC. And the gradual degraded performance of the repeated RCAs was observed with an increased numbers of repetition（1〉2〉3 generations）, the overall performances of all repeated RCAs fulfill the Class Ⅲ according to Chinese Standards GB25177-2010. Our gained insight demonstrates a feasibility of using at least 3 generations of repeated RCA for the production of normal structural concrete.