New experimental results,which are important for the potential use of small levitating droplets as biochemical microreactors,are reported.It is shown that the combination of infrared heating and reduced evaporation of...New experimental results,which are important for the potential use of small levitating droplets as biochemical microreactors,are reported.It is shown that the combination of infrared heating and reduced evaporation of saline water under the droplet cluster is sufficient to produce equilibriumsaltwater droplets over a wide temperature range.The resulting universal dependence of droplet size on temperature simplifies the choice of optimal conditions for generating stable droplet clusters with droplets of the desired size.A physical analysis of the experimental results on the equilibrium size of saltwater droplets makes it possible to separate the effects related to the salinity of the water layer under the droplet cluster from the effects related to the reduction of water evaporation from the water droplets.This is expected to be important for further studies of heat transfer and diffusion in layers of evaporating solutions and condensed droplets.展开更多
Organic Rankine cycle(ORC)is widely used for the low grade geothermal power generation.However,a large amount of irreversible loss results in poor technical and economic performance due to its poor matching between th...Organic Rankine cycle(ORC)is widely used for the low grade geothermal power generation.However,a large amount of irreversible loss results in poor technical and economic performance due to its poor matching between the heat source/sink and the working medium in the condenser and the evaporator.The condensing temperature,cooling water temperature difference and pinch point temperature difference are often fixed according to engineering experience.In order to optimize the ORC system comprehensively,the coupling effect of evaporation and condensation process was proposed in this paper.Based on the laws of thermodynamics,the energy analysis,exergy analysis and entropy analysis were adopted to investigate the ORC performance including net output power,thermal efficiency,exergy efficiency,thermal conductivity,irreversible loss,etc.,using geothermal water at a temperature of 120℃as the heat source and isobutane as the working fluid.The results show that there exists a pair of optimal evaporating temperature and condensing temperatures to maximize the system performance.The net power output and the system comprehensive performance achieve their highest values at the same evaporating temperature,but the system comprehensive performance corresponds to a lower condensing temperature than the net power output.展开更多
An evaporation/condensation flow cell was developed and interfaced with the matrix-assisted laser desorption/ionization (MALDI) time-of-flight mass spectrometer for on-line bioaerosol detection and characterization,...An evaporation/condensation flow cell was developed and interfaced with the matrix-assisted laser desorption/ionization (MALDI) time-of-flight mass spectrometer for on-line bioaerosol detection and characterization, which allows matrix addition by condensation onto the laboratory-generated bioaerosol particles. The final coated particle exiting from the con- denser is then introduced into the aerodynamic particle sizer spectrometer or home-built aerosol laser time-of-flight mass spectrometer, and its aerodynamic size directly effects on the matrix-to-analyte molar ratio, which is very important for MALDI technique. In order to observe the protonated analyte molecular ion, and then determine the classification of bi- ological aerosols, the matrix-to-analyte molar ratio must be appropriate. Four experimental parameters, including the temperature of the heated reservoir, the initial particle size, its number concentration, and the matrix material, were tested experimentally to analyze their influences on the final particle size. This technique represents an on-line system of detection that has the potential to provide rapid and reliable identification of airborne biological aerosols.展开更多
A two-dimensional steady state model was developed and solved numerically to predict the performance of evaporative condensing regenerator.Two-dimensional parameter distributions of air,solution and refrigerant were c...A two-dimensional steady state model was developed and solved numerically to predict the performance of evaporative condensing regenerator.Two-dimensional parameter distributions of air,solution and refrigerant were calculated by the mathematical model.The solution content first increases and then decreases along the solution flow direction.At y/Hr=0.98(where Hr is the height of regenerator),air humidity increases from 1.99% to 2.348% firstly and then decreases.The experimental results were used to validate mathematical model.It is indicated that the simulation results agree with experimental data well.The results not only show that the mathematical model can be used to predict the performance of regenerator,but also has great value in the design and improvement of evaporative condensing regenerator.展开更多
The thermal resistances distribution in different wet-bulb temperatures, air velocities and spraying water densities were achieved by the experimental test. The fluctuation of the water film convection and the water-a...The thermal resistances distribution in different wet-bulb temperatures, air velocities and spraying water densities were achieved by the experimental test. The fluctuation of the water film convection and the water-air interfacial thermal resistance were reviewed especially. In the distribution of thermal resistance, the rank of the thermal resistance proportion (from max to min) is air flow heat transfer resistance, heat transfer resistance between refrigerant and wall, water film convection resistance and wall heat transfer resistance. When the heat flux is constant, the total resistance lowers nearly along with the increasing of air flow and water spray density. But there are a best air flow value of 2.98 m/s and a best spray water density of 0.064 kg/(m ·s) respectively, if continue to increase them, condensation performance is not significantly improved any more. The test results are available to improve the evaporative condenser performance and the designing lever.展开更多
In this paper,an ejector enhanced high-temperature heat pump with dual-pressure condensation and evaporation is proposed to improve the system performance.Theoretical analyses of the system operation characteristics a...In this paper,an ejector enhanced high-temperature heat pump with dual-pressure condensation and evaporation is proposed to improve the system performance.Theoretical analyses of the system operation characteristics are conducted using energetic and exergetic methods.The performance comparisons among the basic cycle,parallel compression cycle,and ejector enhanced cycle are conducted with six different refrigerants,including R245fa,R600a,R1234ze(Z),R1336mzz(Z),R1224yd(Z),and R1233zd(E).The results demonstrate that environmentally-friendly refrigerant R1234ze(Z)would be a promising alternative refrigerant.Compared with the basic cycle and parallel compression cycle at selected operation conditions,29.5%and 12.6%improvements in COP,and 16.7%and 11.1%higher system exergy efficiency are achieved in the ejector enhanced cycle on average.The volumetric heating capacity of the ejector enhanced cycle is increased by 15.7%–21.7%.The ejector enhanced cycle outperforms the other two cycles in high-temperature heat pump applications at the large temperature lift and temperature rise in the heat sink.The assessment offers an option to improve the energy utilization efficiency of the high-temperature heat pumps.展开更多
In this article,a new evaporative condenser with an annular elliptic firmed tube heat exchanger that includes a round inner tube and elliptic outer finned tube was designed and analyzed.The refrigerant flows between t...In this article,a new evaporative condenser with an annular elliptic firmed tube heat exchanger that includes a round inner tube and elliptic outer finned tube was designed and analyzed.The refrigerant flows between the round inner tube and the elliptic outer tube,and it simultaneously exchanges heat with the cooling water in the inner tube,the spray water,and the cooling air flowing past the outer tube.Using field measurement for the traditional round finned tube evaporative condenser in the Futong Metro Station of Line 14 in Beijing,China,the theoretical heat transfer performance of the annular elliptic finned tube evaporative condenser was analyzed and simulated.Compared with a round finned tube heat exchanger,the heat exchange capacity of the annular elliptic finned tube increased by 2.34%to 9.28%;the total heat transfer coefficient increased by 47.42%,and the power consumption of the fan in the air-conditioning system with an annular elliptic finned tube heat exchanger decreased by 11.18%to 14.65%.Therefore,the energy-saving performance and the heat transfer performance of the new annular elliptic finned tube heat exchanger were enhanced compared to the round finned tube heat exchanger.展开更多
This paper focuses on the numerical study of heat and moisture transfer in clothing assemblies,based on a multi-component and multiphase flow model which includes heat/moisture convection and conduction/diffusion as w...This paper focuses on the numerical study of heat and moisture transfer in clothing assemblies,based on a multi-component and multiphase flow model which includes heat/moisture convection and conduction/diffusion as well as phase change.A splitting semi-implicit finite volume method is proposed for solving a set of nonlinear convection-diffusion-reaction equations,in which the calculation of liquid water content absorbed by fiber is decoupled from the rest of the computation.The method maintains the conservation of air,vapor and heat flux(energy).Four types of clothing assemblies are investigated and comparison with experimental measurements are also presented.展开更多
It is a challenge to determine the source and genetic relationship of condensate, waxy and heavy oils in one given complicated petroliferous area, where developed multiple sets of source rocks with different maturity ...It is a challenge to determine the source and genetic relationship of condensate, waxy and heavy oils in one given complicated petroliferous area, where developed multiple sets of source rocks with different maturity and various chemical features.The central part of southern margin of Junggar Basin, NW China is such an example where there are condensates, light oils, normal density oils, heavy crude oils and natural gases. The formation mechanism of condensates has been seriously debated for long time;however, no study has integrated it with genetic types of waxy and heavy oils. Taking the central part of southern margin of Junggar Basin as a case, this study employs geological and geochemical methods to determine the formation mechanism of condensates,waxy and heavy oils in a complicated petroliferous area, and reveals the causes and geochemical processes of the co-occurrence of different types of crude oils in this region. Based on detailed geochemical analyses of more than 40 normal crude oils, light oils,condensates and heavy oils, it is found that the condensates are dominated by low carbon number n-alkanes and enriched in light naphthenics and aromatic hydrocarbons. Heptane values of these condensates range from 19% to 21%, isoheptane values from1.9 to 2.1, and toluene/n-heptane ratios from 1.5 to 2.0. The distribution of n-alkanes in the condensates presents a mirror image with high density waxy crude oils and heavy oils. Combined with the oil and gas-source correlations of the crude oils, condensates and natural gas, it is found that the condensates are product of evaporative fractionation and/or phase-controlled fractionation of reservoir crude oils which were derived from mature Cretaceous lacustrine source rocks in the relatively early stage. The waxy oils are the intermediate products of evaporative fractionation and/or phase-controlled fractionation of reservoir crude oils, while the heavy oils are in-situ residuals. Therefore, evaporative fractionation and/or phase-controlled fractionation would account for the formation of the condensate, light oil, waxy oil and heavy oil in the central part of southern margin of Junggar Basin, resulting in a great change of the content in terms of light alkanes, naphthenics and aromatics in condensates, followed by great uncertainties of toluene/n-heptane ratios due to migration and re-accumulation. The results suggest that the origin of the condensate cannot be simply concluded by its ratios of toluene/n-heptane and n-heptane/methylcyclohexane on the Thompson's cross-plot, it should be comprehensively determined by the aspects of geological background, thermal history of source rocks and petroleum generation,physical and chemical features of various crude oils and natural gas, vertical and lateral distribution of various crude oils in the study area.展开更多
Single aerosol particles were measured by matrix-assisted laser desorp-tion/ionization (MALDI) with an aerosol time-of-flight mass spectrometer (ATOFMS). The inlet to the ATOFMS was coupled with an evaporation/condens...Single aerosol particles were measured by matrix-assisted laser desorp-tion/ionization (MALDI) with an aerosol time-of-flight mass spectrometer (ATOFMS). The inlet to the ATOFMS was coupled with an evaporation/condensation flow cell that allowed matrix addition by condensation onto the particles. The coated particles entered the ion source through three-stage differentially pumped capillary inlet and were then ionized by a focused 266 nm Nd:YAG laser. The mass spectra and aerodynamic size of the single particles can be obtained simultaneously. The on-line matrix addition technique makes it possible to identify biological aerosols in real-time.展开更多
基金the Russian Science Foundation(Project No.24-29-00303)for the financial support of the present study.
文摘New experimental results,which are important for the potential use of small levitating droplets as biochemical microreactors,are reported.It is shown that the combination of infrared heating and reduced evaporation of saline water under the droplet cluster is sufficient to produce equilibriumsaltwater droplets over a wide temperature range.The resulting universal dependence of droplet size on temperature simplifies the choice of optimal conditions for generating stable droplet clusters with droplets of the desired size.A physical analysis of the experimental results on the equilibrium size of saltwater droplets makes it possible to separate the effects related to the salinity of the water layer under the droplet cluster from the effects related to the reduction of water evaporation from the water droplets.This is expected to be important for further studies of heat transfer and diffusion in layers of evaporating solutions and condensed droplets.
基金Project(2018YFB1501805)supported by the National Key Research and Development Program of ChinaProject(51406130)supported by the National Natural Science Foundation of ChinaProject(201604-504)supported by the Key Laboratory of Efficient Utilization of Low and Medium Grade Energy(Tianjin University),China
文摘Organic Rankine cycle(ORC)is widely used for the low grade geothermal power generation.However,a large amount of irreversible loss results in poor technical and economic performance due to its poor matching between the heat source/sink and the working medium in the condenser and the evaporator.The condensing temperature,cooling water temperature difference and pinch point temperature difference are often fixed according to engineering experience.In order to optimize the ORC system comprehensively,the coupling effect of evaporation and condensation process was proposed in this paper.Based on the laws of thermodynamics,the energy analysis,exergy analysis and entropy analysis were adopted to investigate the ORC performance including net output power,thermal efficiency,exergy efficiency,thermal conductivity,irreversible loss,etc.,using geothermal water at a temperature of 120℃as the heat source and isobutane as the working fluid.The results show that there exists a pair of optimal evaporating temperature and condensing temperatures to maximize the system performance.The net power output and the system comprehensive performance achieve their highest values at the same evaporating temperature,but the system comprehensive performance corresponds to a lower condensing temperature than the net power output.
文摘An evaporation/condensation flow cell was developed and interfaced with the matrix-assisted laser desorption/ionization (MALDI) time-of-flight mass spectrometer for on-line bioaerosol detection and characterization, which allows matrix addition by condensation onto the laboratory-generated bioaerosol particles. The final coated particle exiting from the con- denser is then introduced into the aerodynamic particle sizer spectrometer or home-built aerosol laser time-of-flight mass spectrometer, and its aerodynamic size directly effects on the matrix-to-analyte molar ratio, which is very important for MALDI technique. In order to observe the protonated analyte molecular ion, and then determine the classification of bi- ological aerosols, the matrix-to-analyte molar ratio must be appropriate. Four experimental parameters, including the temperature of the heated reservoir, the initial particle size, its number concentration, and the matrix material, were tested experimentally to analyze their influences on the final particle size. This technique represents an on-line system of detection that has the potential to provide rapid and reliable identification of airborne biological aerosols.
基金Project(PHR201007127) supported by Academic Human Resources Development Fund of Institutions of Higher Learning under the Jurisdiction of Beijing Municipality, China Project(bsbe2010-05) supported by the Opening Funds of State Key Laboratory of Building Safety and Built Environment, China Project supported by the Doctoral Startup Foundation of Beijing University of Civil Engineering and Architecture, China
文摘A two-dimensional steady state model was developed and solved numerically to predict the performance of evaporative condensing regenerator.Two-dimensional parameter distributions of air,solution and refrigerant were calculated by the mathematical model.The solution content first increases and then decreases along the solution flow direction.At y/Hr=0.98(where Hr is the height of regenerator),air humidity increases from 1.99% to 2.348% firstly and then decreases.The experimental results were used to validate mathematical model.It is indicated that the simulation results agree with experimental data well.The results not only show that the mathematical model can be used to predict the performance of regenerator,but also has great value in the design and improvement of evaporative condensing regenerator.
文摘The thermal resistances distribution in different wet-bulb temperatures, air velocities and spraying water densities were achieved by the experimental test. The fluctuation of the water film convection and the water-air interfacial thermal resistance were reviewed especially. In the distribution of thermal resistance, the rank of the thermal resistance proportion (from max to min) is air flow heat transfer resistance, heat transfer resistance between refrigerant and wall, water film convection resistance and wall heat transfer resistance. When the heat flux is constant, the total resistance lowers nearly along with the increasing of air flow and water spray density. But there are a best air flow value of 2.98 m/s and a best spray water density of 0.064 kg/(m ·s) respectively, if continue to increase them, condensation performance is not significantly improved any more. The test results are available to improve the evaporative condenser performance and the designing lever.
基金financially supported by the National Natural Science Foundation of China(NSFC)under grant No.51806160the China Postdoctoral Science Foundation(CPSF)under grant No.2018M640982。
文摘In this paper,an ejector enhanced high-temperature heat pump with dual-pressure condensation and evaporation is proposed to improve the system performance.Theoretical analyses of the system operation characteristics are conducted using energetic and exergetic methods.The performance comparisons among the basic cycle,parallel compression cycle,and ejector enhanced cycle are conducted with six different refrigerants,including R245fa,R600a,R1234ze(Z),R1336mzz(Z),R1224yd(Z),and R1233zd(E).The results demonstrate that environmentally-friendly refrigerant R1234ze(Z)would be a promising alternative refrigerant.Compared with the basic cycle and parallel compression cycle at selected operation conditions,29.5%and 12.6%improvements in COP,and 16.7%and 11.1%higher system exergy efficiency are achieved in the ejector enhanced cycle on average.The volumetric heating capacity of the ejector enhanced cycle is increased by 15.7%–21.7%.The ejector enhanced cycle outperforms the other two cycles in high-temperature heat pump applications at the large temperature lift and temperature rise in the heat sink.The assessment offers an option to improve the energy utilization efficiency of the high-temperature heat pumps.
基金The work was supported by the Natural Science Foundation of Shaanxi Province(No.2018JM5084)“the 13th Five-Year”National Science and Technology Major Project of China(No.2017YFC0702202)+1 种基金the Shaanxi Key Science and Technology Innovative Tea m Project(No.2016KCT-22)the Fundamental Research Funds for the Central Universities(CHD300102289203).
文摘In this article,a new evaporative condenser with an annular elliptic firmed tube heat exchanger that includes a round inner tube and elliptic outer finned tube was designed and analyzed.The refrigerant flows between the round inner tube and the elliptic outer tube,and it simultaneously exchanges heat with the cooling water in the inner tube,the spray water,and the cooling air flowing past the outer tube.Using field measurement for the traditional round finned tube evaporative condenser in the Futong Metro Station of Line 14 in Beijing,China,the theoretical heat transfer performance of the annular elliptic finned tube evaporative condenser was analyzed and simulated.Compared with a round finned tube heat exchanger,the heat exchange capacity of the annular elliptic finned tube increased by 2.34%to 9.28%;the total heat transfer coefficient increased by 47.42%,and the power consumption of the fan in the air-conditioning system with an annular elliptic finned tube heat exchanger decreased by 11.18%to 14.65%.Therefore,the energy-saving performance and the heat transfer performance of the new annular elliptic finned tube heat exchanger were enhanced compared to the round finned tube heat exchanger.
基金The research of Ye and Sun was supported in part by a grant from CityU(7001926)The research of Huang is supported by the Natural Science and Engineering Council(NSERC)and the Mathematics of Information Technology and Complex Systems(MITACS)of Canada.The research of Fan is supported by Hong Kong Polytechnic University(Project No.G-U165).
文摘This paper focuses on the numerical study of heat and moisture transfer in clothing assemblies,based on a multi-component and multiphase flow model which includes heat/moisture convection and conduction/diffusion as well as phase change.A splitting semi-implicit finite volume method is proposed for solving a set of nonlinear convection-diffusion-reaction equations,in which the calculation of liquid water content absorbed by fiber is decoupled from the rest of the computation.The method maintains the conservation of air,vapor and heat flux(energy).Four types of clothing assemblies are investigated and comparison with experimental measurements are also presented.
基金supported by the PetroChina Science and Technology Special Projects (Grant Nos. 06-10A-01-02, 2011A-0201, 2014A-0211 and 2016A-0202)
文摘It is a challenge to determine the source and genetic relationship of condensate, waxy and heavy oils in one given complicated petroliferous area, where developed multiple sets of source rocks with different maturity and various chemical features.The central part of southern margin of Junggar Basin, NW China is such an example where there are condensates, light oils, normal density oils, heavy crude oils and natural gases. The formation mechanism of condensates has been seriously debated for long time;however, no study has integrated it with genetic types of waxy and heavy oils. Taking the central part of southern margin of Junggar Basin as a case, this study employs geological and geochemical methods to determine the formation mechanism of condensates,waxy and heavy oils in a complicated petroliferous area, and reveals the causes and geochemical processes of the co-occurrence of different types of crude oils in this region. Based on detailed geochemical analyses of more than 40 normal crude oils, light oils,condensates and heavy oils, it is found that the condensates are dominated by low carbon number n-alkanes and enriched in light naphthenics and aromatic hydrocarbons. Heptane values of these condensates range from 19% to 21%, isoheptane values from1.9 to 2.1, and toluene/n-heptane ratios from 1.5 to 2.0. The distribution of n-alkanes in the condensates presents a mirror image with high density waxy crude oils and heavy oils. Combined with the oil and gas-source correlations of the crude oils, condensates and natural gas, it is found that the condensates are product of evaporative fractionation and/or phase-controlled fractionation of reservoir crude oils which were derived from mature Cretaceous lacustrine source rocks in the relatively early stage. The waxy oils are the intermediate products of evaporative fractionation and/or phase-controlled fractionation of reservoir crude oils, while the heavy oils are in-situ residuals. Therefore, evaporative fractionation and/or phase-controlled fractionation would account for the formation of the condensate, light oil, waxy oil and heavy oil in the central part of southern margin of Junggar Basin, resulting in a great change of the content in terms of light alkanes, naphthenics and aromatics in condensates, followed by great uncertainties of toluene/n-heptane ratios due to migration and re-accumulation. The results suggest that the origin of the condensate cannot be simply concluded by its ratios of toluene/n-heptane and n-heptane/methylcyclohexane on the Thompson's cross-plot, it should be comprehensively determined by the aspects of geological background, thermal history of source rocks and petroleum generation,physical and chemical features of various crude oils and natural gas, vertical and lateral distribution of various crude oils in the study area.
文摘Single aerosol particles were measured by matrix-assisted laser desorp-tion/ionization (MALDI) with an aerosol time-of-flight mass spectrometer (ATOFMS). The inlet to the ATOFMS was coupled with an evaporation/condensation flow cell that allowed matrix addition by condensation onto the particles. The coated particles entered the ion source through three-stage differentially pumped capillary inlet and were then ionized by a focused 266 nm Nd:YAG laser. The mass spectra and aerodynamic size of the single particles can be obtained simultaneously. The on-line matrix addition technique makes it possible to identify biological aerosols in real-time.