In research work, little has been heard of the lanthanide salts of TCNQ, preliminary reports were known of the synthesis of Ce<sup>3+</sup>（TCNQ）<sub>3</sub>·6H<sub>2</sub>O ...In research work, little has been heard of the lanthanide salts of TCNQ, preliminary reports were known of the synthesis of Ce<sup>3+</sup>（TCNQ）<sub>3</sub>·6H<sub>2</sub>O and Sm<sup>3+</sup>（TCNQ）<sub>3</sub>·6H<sub>2</sub>O and the electrical resistivity of the latter compound （2×10<sup>4</sup> ohm·cm）. This note reports the synthesis of 11 TCNQ lanthanide salts and 5 TCNQ lanthanide salts with macrocyclic ligand and their spectroscopic and electrical properties.展开更多
文摘In research work, little has been heard of the lanthanide salts of TCNQ, preliminary reports were known of the synthesis of Ce<sup>3+</sup>（TCNQ）<sub>3</sub>·6H<sub>2</sub>O and Sm<sup>3+</sup>（TCNQ）<sub>3</sub>·6H<sub>2</sub>O and the electrical resistivity of the latter compound （2×10<sup>4</sup> ohm·cm）. This note reports the synthesis of 11 TCNQ lanthanide salts and 5 TCNQ lanthanide salts with macrocyclic ligand and their spectroscopic and electrical properties.
