N-[1-（2-Methyl-1-methylcarbamoyl-propylcarbamoyl）-2,3-diphenyl-cyclopropyl]-ben- zamide, C29H31N3O3, has been synthesized and characterized by IR, ^1H NMR, ^13C NMR and singlecrystal X-ray diffraction. The crystal i...N-[1-（2-Methyl-1-methylcarbamoyl-propylcarbamoyl）-2,3-diphenyl-cyclopropyl]-ben- zamide, C29H31N3O3, has been synthesized and characterized by IR, ^1H NMR, ^13C NMR and singlecrystal X-ray diffraction. The crystal is of orthorhombic, space group P212121 with a = 11.0855（11）, b = 18.7756（19）, c = 24.434（2）A, V = 5085.5（9）A^3, Z = 8, Mr = 469.57, Dc = 1.227 g/cm^3, λ = 0.71070 A,μ（MoKα） = 0.080 mm^-1, F（000） = 2000, the final R = 0.0579 and wR = 0.1111 for 4569 observed reflections with I 〉 2σ（I）. The N-H and oxygen atom are involved in intermolecular hydrogen bonds which link the molecules into a one-dimensional chain.展开更多
N-[2-（4-chlorophenyl）-1-（1-methylcarbamoyl-2-phenyl-ethylcarbamoyl）-3-phenyl-cyclopropyl]benzamide,C33H30ClN3O3,has been synthesized and characterized by IR,1H NMR,13C NMR and single-crystal X-ray diffraction.The ...N-[2-（4-chlorophenyl）-1-（1-methylcarbamoyl-2-phenyl-ethylcarbamoyl）-3-phenyl-cyclopropyl]benzamide,C33H30ClN3O3,has been synthesized and characterized by IR,1H NMR,13C NMR and single-crystal X-ray diffraction.The crystal is of triclinic,space group P1 with a = 11.646（2）,b = 13.795（3）,c = 14.559（3）,α = 76.422（4）,β = 78.028（4）,γ = 74.500（4）°,V = 2164.6（7）3,Z = 3,Mr = 552.05,Dc = 1.270 g/cm3,λ = 0.71073 ,μ（MoKα）= 0.171 mm–1,F（000）= 870,the final R = 0.0469 and wR = 0.0805 for 5554 observed reflections with I 2σ（I）.The N–H and oxygen atoms are involved in one-dimensional intermolecular hydrogen bonds,which further stabilize the structure.展开更多
基金the Foundation of 100 Young and Middle-aged Disciplinary Leaders of Guangxi Province in the 21st century (No. 2004219)the Science Foundation of Guangxi Province (No. 0731054)the Foundation of Innovation Project of Guangxi Graduate Education (No. 2006106020703M32)
文摘N-[1-（2-Methyl-1-methylcarbamoyl-propylcarbamoyl）-2,3-diphenyl-cyclopropyl]-ben- zamide, C29H31N3O3, has been synthesized and characterized by IR, ^1H NMR, ^13C NMR and singlecrystal X-ray diffraction. The crystal is of orthorhombic, space group P212121 with a = 11.0855（11）, b = 18.7756（19）, c = 24.434（2）A, V = 5085.5（9）A^3, Z = 8, Mr = 469.57, Dc = 1.227 g/cm^3, λ = 0.71070 A,μ（MoKα） = 0.080 mm^-1, F（000） = 2000, the final R = 0.0579 and wR = 0.1111 for 4569 observed reflections with I 〉 2σ（I）. The N-H and oxygen atom are involved in intermolecular hydrogen bonds which link the molecules into a one-dimensional chain.
基金Supported by the National Natural Science Foundation of China (No.20862003)Natural Science Foundation of Guangxi Province (No.2010GXNSFF013001)
文摘N-[2-（4-chlorophenyl）-1-（1-methylcarbamoyl-2-phenyl-ethylcarbamoyl）-3-phenyl-cyclopropyl]benzamide,C33H30ClN3O3,has been synthesized and characterized by IR,1H NMR,13C NMR and single-crystal X-ray diffraction.The crystal is of triclinic,space group P1 with a = 11.646（2）,b = 13.795（3）,c = 14.559（3）,α = 76.422（4）,β = 78.028（4）,γ = 74.500（4）°,V = 2164.6（7）3,Z = 3,Mr = 552.05,Dc = 1.270 g/cm3,λ = 0.71073 ,μ（MoKα）= 0.171 mm–1,F（000）= 870,the final R = 0.0469 and wR = 0.0805 for 5554 observed reflections with I 2σ（I）.The N–H and oxygen atoms are involved in one-dimensional intermolecular hydrogen bonds,which further stabilize the structure.
