Nano-scale Reinforcements and Properties of Al-Si-Cu Alloy Processed by High-Pressure Torsion

To improve the comprehensive mechanical properties of Al-Si-Cu alloy,it was treated by a high-pressure torsion process,and the effect of the deformation degree on the microstructure and properties of the Al-Si-Cu alloy was studied.The results show that the reinforcements(β-Si andθ-CuAl_(2)phases)of the Al-Si-Cu alloy are dispersed in theα-Al matrix phase with finer phase size after the treatment.The processed samples exhibit grain sizes in the submicron or even nanometer range,which effectively improves the mechanical properties of the material.The hardness and strength of the deformed alloy are both significantly raised to 268 HV and 390.04 MPa by 10 turns HPT process,and the fracture morphology shows that the material gradually transits from brittle to plastic before and after deformation.The elements interdiffusion at the interface between the phases has also been effectively enhanced.In addition,it is found that the severe plastic deformation at room temperature induces a ternary eutectic reaction,resulting in the formation of ternary Al+Si+CuAl_(2)eutectic.

Experimental and Finite Element Analysis of Corroded High-Pressure Pipeline Repaired by Laminated Composite

Repairs of corroded high-pressure pipelines are essential for fluids transportation under high pressure.One of the methods used in their repairs is the use of layered composites.The composite used must have the necessary strength.Therefore,the experiments and analytical solutions presented in this paper are performed according to the relevant standards and codes,including ASME PCC-2,ASME B31.8S,ASME B31.4,ISO 24817 and ASME B31.G.In addition,the experimental tests are replicated numerically using the finite element method.Setting the strain gauges at different distances from the defect location,can reduce the nonlinear effects,deformation,and fluctuations due to the high pressure.The direct relationship between the depth of an axial defect and the stress concentration is observed at the inner side edges of the defect.Composite reparation reduces the non-linearities related to the sharp variation of the geometry and a more reliable numerical simulation could be performed.

A new transition metal diphosphideα-MoP_(2) synthesized by a high-temperature and high-pressure technique

Monoclinicα-MoP_(2),with the OsGe2-type structure(space group C2/m,Z=4)and lattice parameters a=8.7248(11)Å,b=3.2322(4)Å,c=7.4724(9)Å,andβ=119.263°,was synthesized under a pressure of 4~GPa at a temperature between 1100℃and 1200℃.The structure ofα-MoP_(2) and its relationship to other transition metal diphosphides are discussed.Surprisingly,the ambient pressure phase orthorhombicβ-MoP_(2)(space group Cmc21)is denser in structure thanα-MoP_(2).Room-temperature high-pressure x-ray diffraction studies exclude the possibility of phase transition fromβ-MoP_(2) to α-MoP_(2),suggesting thatα-MoP_(2) is a stable phase at ambient conditions;this is also supported by the total energy and phonon calculations.

Numerical Simulation Analysis of the Transformer Fire Extinguishing Process with a High-Pressure Water Mist System under Different Conditions

To thoroughly study the extinguishing effect of a high-pressure water mist fire extinguishing system when a transformer fire occurs,a 3D experimental model of a transformer is established in this work by employing Fire Dynamics Simulator(FDS)software.More specifically,by setting different parameters,the process of the highpressure water mist fire extinguishing system with the presence of both diverse ambient temperatures and water mist sprinkler laying conditions is simulated.In addition,the fire extinguishing effect of the employed high-pressure water mist system with the implementation of different strategies is systematically analyzed.The extracted results show that a fire source farther away fromthe centerline leads to a lower local temperature distribution.In addition,as the ambient temperature increases,the temperature above the fire source decreases,while the temperature and the concentrationof theupperflue gas layer bothdecrease.Interestingly,after thehigh-pressurewatermist sprinkler begins to operate,both the temperature distribution above the fire source and the concentration of the flue gas decrease,which indicates that the high-pressure water mist system plays the role of cooling and dust removal.By comparing various sprinkler laying methods,it is found that the lower sprinkler height has a better effect on the temperature above the fire source,the temperature of the upper flue gas layer,and the concentration of the flue gas.Moreover,when the sprinkler is spread over thewhole transformer,the cooling effect on both the temperature above the fire source and the temperature of the upper flue gas layer is good,whereas the change in the concentration of the flue gas above the fire source is not obvious compared to the case where the sprinkler is not fully spread.

High-pressure new phases of V–N compounds

The high-pressure diagram of V–N compounds is enriched by proposed seven new stable high-pressure phases.The P-1-VN_4with the armchair N-rich structure may be quenched to ambient conditions.The formed N–N covalent bond plays an important role for the structural stability of N-chain.The charge transfer results in a V–N ionic bond interaction,which further improves the stability of N-chain structure.The P-1-VN_4,P4mnc-VN_8,and Immm-VN_(10)with the outstanding detonation properties have potential application in explosive field.

The discovery of TiO_(2)-Ⅱ,the α-PbO_(2)-structured high-pressure polymorph of rutile,in the Suizhou L6 chondrite

We report the discovery of TiO_(2)-Ⅱ in the unmelted rock of the shocked Suizhou L6 chondrite.Natural TiO_(2)-Ⅱ was previously found in ultrahigh-pressure metamorphic and mantle-derived rocks,terrestrial impact structures,and tektite.Our microscopic,Raman spectroscopic,electron microprobe and transmission electron microscopic investigations have revealed:(1) All observed TiO_(2)-Ⅱ grains are related with ilmenite and pyrophanite;(2) TiO_(2)-Ⅱ occurs as needle-and leaf-shaped inclusions in llmenite and patch-,tape-shaped body in pyrophanite;(3)The composition of TiO_(2)-Ⅱ is identical with that of its precursor rutile;(4) The Raman spectrum of TiO_(2)-Ⅱ is in good agreement with that of natural and synthesized α-PbO_(2)-type TiO_(2);(5) TiO_(2)-Ⅱ occurs mainly in the form of well-ordered nano-domains and small mis-orientation among the domains can be observed.(6) All electron diffraction reflections from TiO_(2)-Ⅱ can be indexed to α-PbO_(2)structure in space group Pbcn with lattice parameters of a=4.481 ?,b=5.578 A and c=4.921 A;(7) The exsolution inclusions of rutile from host ilmenite are mostly connected with an alternation process along the lamellar twinning plane of ilmenite induced by shockinduced high pressure and high temperature;(8) The P-T regime of 20-25 GPa and 1000 ℃ estimated for the Suizhou unmelted rock is suitable for phase transition of rutile into TiO_(2)-Ⅱ phase.

Accurate calculations of the high-pressure elastic constants based on the first-principles

The energy term corresponding to the first order of the strain in Taylor series expansion of the energy with respect to strain is always ignored when high-pressure elastic constants are calculated. Whether the modus operandi would affect the results of the high-pressure elastic constants is still unsolved. To clarify this query, we calculate the high-pressure elastic constants of tantalum and rhenium when the energy term mentioned above is considered and neglected, respectively.Results show that the neglect of the energy term corresponding to the first order of the strain indeed would influence the veracity of the high-pressure elastic constants, and this influence becomes larger with pressure increasing. Therefore, the energy term corresponding to the first-order of the strain should be considered when the high-pressure elastic constants are calculated.

Gedankenexperiment for Modified ZPE and Planck’s “Constant”, h, in the Beginning of Cosmological Expansion, Partly Due to NLED

We initially look at a non singular universe representation of entropy, based in part on what was brought up by Muller and Lousto. This is a gateway to bringing up information and computational steps (as defined by Seth Lloyd) as to what would be available initially due to a modified ZPE formalism. The ZPE formalism is modified as due to Matt Visser’s alternation of k (maximum) ~ 1/(Planck length), with a specific initial density giving rise to initial information content which may permit fixing the initial Planck’s constant, h, which is pivotal to the setting of physical law. The settings of these parameters depend upon NLED.

Elementary Fermions: Strings, Planck Constant, Preons and Hypergluons

Using real fields instead of complex ones, it is suggested here that the fermions are pairs of coupled strings with an internal tension. The interaction between the two coupled strings is due to an exchange mechanism which is proportional to Planck’s constant. This may be the result of two massless bosons (hypergluons) coupled by a preon (prequark) exchange. It also gives a physical explanation to the origin of the Planck constant, and origin of spin.

ESTIMATE ON THE BLOCH CONSTANT FOR CERTAIN HARMONIC MAPPINGS UNDER A DIFFERENTIAL OPERATOR

In this paper,we first obtain the precise values of the univalent radius and the Bloch constant for harmonic mappings of the formL(f)=zfz-zfz,where f represents normalized harmonic mappings with bounded dilation.Then,using these results,we present better estimations for the Bloch constants of certain harmonic mappings L(f),where f is a K-quasiregular harmonic or open harmonic.Finally,we establish three versions of BlochLandau type theorem for biharmonic mappings of the form L(f).These results are sharp in some given cases and improve the related results of earlier authors.

The Extremal Universe Exact Solution from Einstein’s Field Equation Gives the Cosmological Constant Directly

Einstein’s field equation is a highly general equation consisting of sixteen equations. However, the equation itself provides limited information about the universe unless it is solved with different boundary conditions. Multiple solutions have been utilized to predict cosmic scales, and among them, the Friedmann-Lemaître-Robertson-Walker solution that is the back-bone of the development into today standard model of modern cosmology: The Λ-CDM model. However, this is naturally not the only solution to Einstein’s field equation. We will investigate the extremal solutions of the Reissner-Nordström, Kerr, and Kerr-Newman metrics. Interestingly, in their extremal cases, these solutions yield identical predictions for horizons and escape velocity. These solutions can be employed to formulate a new cosmological model that resembles the Friedmann equation. However, a significant distinction arises in the extremal universe solution, which does not necessitate the ad hoc insertion of the cosmological constant;instead, it emerges naturally from the derivation itself. To the best of our knowledge, all other solutions relying on the cosmological constant do so by initially ad hoc inserting it into Einstein’s field equation. This clarification unveils the true nature of the cosmological constant, suggesting that it serves as a correction factor for strong gravitational fields, accurately predicting real-world cosmological phenomena only within the extremal solutions of the discussed metrics, all derived strictly from Einstein’s field equation.

Enriched Constant Elements in the Boundary Element Method for Solving 2D Acoustic Problems at Higher Frequencies

The boundary element method(BEM)is a popular method for solving acoustic wave propagation problems,especially those in exterior domains,owing to its ease in handling radiation conditions at infinity.However,BEM models must meet the requirement of 6–10 elements per wavelength,using the conventional constant,linear,or quadratic elements.Therefore,a large storage size of memory and long solution time are often needed in solving higher-frequency problems.In this work,we propose two new types of enriched elements based on conventional constant boundary elements to improve the computational efficiency of the 2D acoustic BEM.The first one uses a plane wave expansion,which can be used to model scattering problems.The second one uses a special plane wave expansion,which can be used tomodel radiation problems.Five examples are investigated to showthe advantages of the enriched elements.Compared with the conventional constant elements,the new enriched elements can deliver results with the same accuracy and in less computational time.This improvement in the computational efficiency is more evident at higher frequencies(with the nondimensional wave numbers exceeding 100).The paper concludes with the potential of our proposed enriched elements and plans for their further improvement.

New Approach to Synchronize General Relativity and Quantum Mechanics with Constant “K”-Resulting Dark Matter as a New Fundamental Force Particle

Planck scale plays a vital role in describing fundamental forces. Space time describes strength of fundamental force. In this paper, Einstein’s general relativity equation has been described in terms of contraction and expansion forces of space time. According to this, the space time with Planck diameter is a flat space time. This is the only diameter of space time that can be used as signal transformation in special relativity. This space time diameter defines the fundamental force which belongs to that space time. In quantum mechanics, this space time diameter is only the quantum of space which belongs to that particular fundamental force. Einstein’s general relativity equation and Planck parameters of quantum mechanics have been written in terms of equations containing a constant “K”, thus found a new equation for transformation of general relativity space time in to quantum space time. In this process of synchronization, there is a possibility of a new fundamental force between electromagnetic and gravitational forces with Planck length as its space time diameter. It is proposed that dark matter is that fundamental force carrying particle. By grand unification equation with space-time diameter, we found a coupling constant as per standard model “αs” for that fundamental force is 1.08 × 10-23. Its energy calculated as 113 MeV. A group of experimental scientists reported the energy of dark matter particle as 17 MeV. Thorough review may advance science further.

Probing the electric double layer structure at nitrogen-doped graphite electrodes by constant-potential molecular dynamics simulations

Electric double layer(EDL)is a critical topic in electrochemistry and largely determines the working performance of lithium batteries.However,atomic insights into the EDL structures on heteroatom-modified graphite anodes and EDL evolution with electrode potential are very lacking.Herein,a constant-potential molecular dynamics(CPMD)method is proposed to probe the EDL structure under working conditions,taking N-doped graphite electrodes and carbonate electrolytes as an example.An interface model was developed,incorporating the electrode potential and atom electronegativities.As a result,an insightful atomic scenario for the EDL structure under varied electrode potentials has been established,which unveils the important role of doping sites in regulating both the EDL structures and the following electrochemical reactions at the atomic level.Specifically,the negatively charged N atoms repel the anions and adsorb Li~+at high and low potentials,respectively.Such preferential adsorption suggests that Ndoped graphite can promote Li~+desolvation and regulate the location of Li~+deposition.This CPMD method not only unveils the mysterious function of N-doping from the viewpoint of EDL at the atomic level but also applies to probe the interfacial structure on other complicated electrodes.

Cyclic shear behavior of en-echelon joints under constant normal stiffness conditions

To reveal the mechanism of shear failure of en-echelon joints under cyclic loading,such as during earthquakes,we conducted a series of cyclic shear tests of en-echelon joints under constant normal stiffness(CNS)conditions.We analyzed the evolution of shear stress,normal stress,stress path,dilatancy characteristics,and friction coefficient and revealed the failure mechanisms of en-echelon joints at different angles.The results show that the cyclic shear behavior of the en-echelon joints is closely related to the joint angle,with the shear strength at a positive angle exceeding that at a negative angle during shear cycles.As the number of cycles increases,the shear strength decreases rapidly,and the difference between the varying angles gradually decreases.Dilation occurs in the early shear cycles(1 and 2),while contraction is the main feature in later cycles(310).The friction coefficient decreases with the number of cycles and exhibits a more significant sensitivity to joint angles than shear cycles.The joint angle determines the asperities on the rupture surfaces and the block size,and thus determines the subsequent shear failure mode(block crushing and asperity degradation).At positive angles,block size is more greater and asperities on the rupture surface are smaller than at nonpositive angles.Therefore,the cyclic shear behavior is controlled by block crushing at positive angles and asperity degradation at negative angles.

Upsilon Constants and Their Usefulness in Planck Scale Quantum Cosmology

This paper introduces the two Upsilon constants to the reader. Their usefulness is described with respect to acting as coupling constants between the CMB temperature and the Hubble constant. In addition, this paper summarizes the current state of quantum cosmology with respect to the Flat Space Cosmology (FSC) model. Although the FSC quantum cosmology formulae were published in 2018, they are only rearrangements and substitutions of the other assumptions into the original FSC Hubble temperature formula. In a real sense, this temperature formula was the first quantum cosmology formula developed since Hawking’s black hole temperature formula. A recent development in the last month proves that the FSC Hubble temperature formula can be derived from the Stephan-Boltzmann law. Thus, this Hubble temperature formula effectively unites some quantum developments with the general relativity model inherent in FSC. More progress towards unification in the near-future is expected.

The Planck Constant and Its Relation to the Compton Frequency

The Planck constant is considered one of the most important universal constants of physics, and despite all we know much about it, the physical nature of it has not been fully understood. Further investigation and new perspectives on the Planck constant should therefore be of interest. We demonstrate that the Planck constant also can be directly linked to the Compton frequency of one, which again is divided by the Compton frequency in one kg. If this is right, it means also the Planck constant is linked to quantization of matter, not only energy. However, as we will show the frequency of one when expressed in relation to kg will be observational time dependent. This means the missing mass gap surprisingly both is equal to the Planck mass, which is larger than any known particle and also it is linked to a very small mass that again is equal to what has been suggested as the photon mass in the existing literature. This new view could be an important step forward in understanding the physical nature of the Planck constant as well as the mass gap and even the rest mass of a photon.

Introducing a 2nd Universal Space-Time Constant Can Explain the Observed Age of the Universe and Dark Energy

The purpose of this paper is to introduce new theoretical concepts as opposed to accepting the existence of dark entities, such as dark energy. This research sought to introduce a 2nd universal space-time constant, besides having a finite speed constant (speed of light in vacuum c). A finite universal age constant b is introduced. Namely, this paper shows that the changes in the Earth’s anomalistic year duration over time support the hypothesis of the age of the universe correlating with a maximum number of orbital revolutions constant. Neglecting the gravitational influence of other cosmological entities in the proximity of the Earth, the constant maximum number of revolutions is herewith determined solely by the Earth’s orbital revolutions around the Sun. The value of the universal age constant b is calculated to be around 13.8 billion orbital revolutions, derived out of an equation related to the changes in the Earth’s anomalistic year duration over time and the so-called Hubble tension. The above-mentioned calculated value b correlates well with the best fit to measured data of the cosmic microwave background radiation (CMBR) by the Planck spacecraft, the age of the observed universe is measured to be approximately 13.787 ± 0.020 billion years (2018 final data release). Developing a theory with this 2nd universal space-time constant b, being covariant with respect to the Lorentz transformations when time spans are large, gives results such as: A confirmation of the measured CMBR value of 13.787 ± 0.020 billion years. Correlating well with the observed expansion rate of the universe (dark energy). The universe’s expansion accelerating over the last four to five billion years.

Robust Nonlinear Current Sensorless Control of the Boost Converter with Constant Power Load

The boost converter feeding a constant power load (CPL) is a non-minimum phase system that is prone to the destabilizing effects of the negative incremental resistance of the CPL and presents a major challenge in the design of stabilizing controllers. A PWM-based current-sensorless robust sliding mode controller is developed that requires only the measurement of the output voltage. An extended state observer is developed to estimate a lumped uncertainty signal that comprises the uncertain load power and the input voltage, the converter parasitics, the component uncertainties and the estimation of the derivative of the output voltage needed in the implementation of the controller. A linear sliding surface is used to derive the controller, which is simple in its design and yet exhibits excellent features in terms of robustness to external disturbances, parameter uncertainties, and parasitics despite the absence of the inductor’s current feedback. The robustness of the controller is validated by computer simulations.

Stoichiometry and Stability Constant Values for Copper (II) Chelates with Ethylene Diamine in Deep Eutectic Solvents (DES) (Ethaline) Solutions

In this study we used the deep eutectic solvents (ionic liquids) to investigate the reaction between copper (II) with ethylene diamine (en). Two of the existing methods for analyzing spectrophotometric measurements have been applied for establishing, the stoichiometry and whenever possible, the stability constants of the chelates formed. The method of continuous variations was necessary to determine first whether, the metal ion and the ligand ethylene diamine form one or more than one chelate, when more than one chelate formed, the results obtained depend on the wavelength and for meaningful conclusions the wavelengths were carefully selected. The empirical formulae of the chelates were further substantiated by the molar ratio method. The effect of time and temperature on the formation and stability of these chelates in solution is also studied. The stability constants, K1 and K2 for the copper (II) chelates were calculated, though reliable, and are comparable to literature values.