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Equivalent materials simulation experimental study on bed separations developing and mining subsidence in constant humidity and constant temperature conditions
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作者 付志亮 王素华 高延法 《Journal of Coal Science & Engineering(China)》 2008年第4期585-590,共6页
A new experiment was made on the developing of bed separations and mining subsidence from Tangshan T2192 working face by equivalent materials simulation.The overburden deformation and the developing of bed separations... A new experiment was made on the developing of bed separations and mining subsidence from Tangshan T2192 working face by equivalent materials simulation.The overburden deformation and the developing of bed separations with working face advanc- ing was simulated by a new model.The results show that the maximum value of bed separations moved forward gradually along with the working face advancing;the maxi- mum value of bed separations is 0.31~0.50 times of mining thickness.The key strata have a great influence upon surface subsidence during the overburden movement process.The mechanics parameters of new experiment are fitted with results in fields perfectly. 展开更多
关键词 SUBSIDENCE bed separations constant humidity constant temperature equivalent simulation experiment
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Effects of Varying Temperature and Constant Temperature on Hatching Result of Fertilized Peacock Eggs
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作者 张京和 张孝和 +2 位作者 胡平 张颖 聂可心 《Agricultural Science & Technology》 CAS 2016年第6期1458-1461,共4页
In order to investigate the effect of temperature on hatching result of fertilized peacock eggs, they were hatched under conditions of varying temperature and constant temperature respectively. The result shows that t... In order to investigate the effect of temperature on hatching result of fertilized peacock eggs, they were hatched under conditions of varying temperature and constant temperature respectively. The result shows that the hatching rate in the varying temperature treatment group (Group Ⅰ) is higher than that in the constant temperature treatment group (Group Ⅱ). It suggests that the varying temperature treatment (high temperature in the early period, medium temperature in the middle period, slightly lower temperature in the late period, and slightly higher temperature in the hulling period) is in line with the optimum temperature variation in the hatching of fertilized peacock eggs, contributing the hatching of fertilized peacock eggs. 展开更多
关键词 PEACOCK Fertilized egg Artificial incubation Hatching rate Varyingtemperature constant temperature
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Design and application of automatic constant temperature moxibustion box
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作者 Wei Xie Yu Leng +4 位作者 Ping Li Ping Liu Hai-BoLi Hua-Qian Dong Wan-Feng Yang 《TMR Integrative Nursing》 2018年第4期160-164,共5页
Objective:To explore the clinical application effect of self-designed automatic constant temperature moxibustion box.Methods:From June 2016 to January 2017,150 patients with neck,shoulder,back and leg pain admitted to... Objective:To explore the clinical application effect of self-designed automatic constant temperature moxibustion box.Methods:From June 2016 to January 2017,150 patients with neck,shoulder,back and leg pain admitted to our hospital were treated with moxibustion under the informed consent of the patients.The patients were randomly divided into control group and observation group,75 cases each.The group used traditional moxibustion box for moxibustion treatment,and the observation group used automatic constant temperature moxibustion box for moxibustion treatment for 15 days.After the treatment,the patient's safety,comfort,satisfaction and adverse reactions were compared,and the results were analyzed using SPSS 20 statistical software.Results:The comfort and satisfaction in study group were all superior to that of control group,with statistically significant difference(P<0.01).For patient's safety,the ratio of patients suffered from scald in study and control groups was 5.3/100 and 0,respectively.Conclusions:It is of great significance for improving clinical efficacy and preventing medical risks.It is worthy of clinical application. 展开更多
关键词 Moxibustion box Automatic constant temperature temperature control device Clinical application
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Research of refrigeration system for a new type of constant temperature hydraulic tank 被引量:1
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作者 郭锐 Zhang Zhenmiao +2 位作者 Zhao Jingyi Ning Chao Li Bingliang 《High Technology Letters》 EI CAS 2016年第4期436-444,共9页
Different from the traditional hydraulic oil cooling method,a new type of constant temperature oil tank cooling system based on semiconductor refrigeration technology is designed. This paper studies the principle of s... Different from the traditional hydraulic oil cooling method,a new type of constant temperature oil tank cooling system based on semiconductor refrigeration technology is designed. This paper studies the principle of semiconductor refrigeration and establishes a heat transfer model. Semiconductor cooler on piping refrigeration is simulated,and influence of the parameters on the outlet temperature,such as pipe pressure difference of inlet and outlet,pipe length,pipe radius,are gotten,and then hydraulic tank semiconductor refrigeration system is proposed. The semiconductor refrigeration system can control temperature at 37 ± 1°C. 展开更多
关键词 refrigeration system constant temperature control semiconductor refrigeration technology hydraulic tank simulated analysis experimental study
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Z-D Relationship during Compression atConstant Temperature on TC11 Alloy
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作者 白秉哲 杨鲁义 +1 位作者 张柏清 韩其勇 《Rare Metals》 SCIE EI CAS CSCD 1996年第2期110-115,共6页
The dynamic evolution of microstructure and the characteristics of deformation , as well as the relationshipbetween them have ben studied for TCll alloy with different original conditions, including as-cast, as-rolled... The dynamic evolution of microstructure and the characteristics of deformation , as well as the relationshipbetween them have ben studied for TCll alloy with different original conditions, including as-cast, as-rolled ,as-forged and as-predeformed on casting, during comparison at constant temperature (CCT). The resultsshow that (1) Micrcotructural process during CCT of cast TCll comprises two stages: (i) Founding ofu dynamic equilibrium ”. Original coarse structure breaks up and becomes equiaxed, while the stras decreasesaccordingly. The microstructure gradually trends towards some kind of “dynamic ellullibrium” morphology;(ii) Keeping of “dynamic equilibrium”. Both stress and micrcostructural morphology preserve stable althoughdeformation continues. (2) The final pouilibrium morphology das not depend on its initial microstructure, buton the parameter Z(T, e) . 展开更多
关键词 TCll alloy Compression at constant temperature Z-D
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Predicting High Precision Hubble Constant Determinations Based on a New Theoretical Relationship between CMB Temperature and H0
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作者 Eugene Terry Tatum Espen Gaarder Haug Stéphane Wojnow 《Journal of Modern Physics》 2024年第11期1708-1716,共9页
Based on considerable progress made in understanding the Cosmic Microwave Background (CMB) temperature from a deep theoretical perspective, this paper demonstrates a useful and simple relationship between the CMB temp... Based on considerable progress made in understanding the Cosmic Microwave Background (CMB) temperature from a deep theoretical perspective, this paper demonstrates a useful and simple relationship between the CMB temperature and the Hubble constant. This allows us to predict the Hubble constant with much higher precision than before by using the CMB temperature. This is of great importance, since it will lead to much higher precision in various global parameters of the cosmos, such as the Hubble radius and the age of the universe. We have improved uncertainty in the Hubble constant all the way down to 66.8712 ± 0.0019 km/s/Mpc based on data from one of the most recent CMB studies. Previous studies based on other methods have rarely reported an uncertainty much less than approximately ±1 km/s/Mpc for the Hubble constant. Our deeper understanding of the CMB and its relation to H0seems to be opening a new era of high-precision cosmology, which may well be the key to solving the Hubble tension, as alluded to herein. Naturally, our results should also be scrutinized by other researchers over time, but we believe that, even at this stage, this deeper understanding of the CMB deserves attention from the research community. 展开更多
关键词 Hubble constant CMB Planck temperature Upsilon constant
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Upsilon Constants and Their Usefulness in Planck Scale Quantum Cosmology
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作者 Eugene Terry Tatum 《Journal of Modern Physics》 2024年第2期167-173,共7页
This paper introduces the two Upsilon constants to the reader. Their usefulness is described with respect to acting as coupling constants between the CMB temperature and the Hubble constant. In addition, this paper su... This paper introduces the two Upsilon constants to the reader. Their usefulness is described with respect to acting as coupling constants between the CMB temperature and the Hubble constant. In addition, this paper summarizes the current state of quantum cosmology with respect to the Flat Space Cosmology (FSC) model. Although the FSC quantum cosmology formulae were published in 2018, they are only rearrangements and substitutions of the other assumptions into the original FSC Hubble temperature formula. In a real sense, this temperature formula was the first quantum cosmology formula developed since Hawking’s black hole temperature formula. A recent development in the last month proves that the FSC Hubble temperature formula can be derived from the Stephan-Boltzmann law. Thus, this Hubble temperature formula effectively unites some quantum developments with the general relativity model inherent in FSC. More progress towards unification in the near-future is expected. 展开更多
关键词 Quantum Cosmology Hubble constant Planck Scale Upsilon constant Flat Space Cosmology Black Holes CMB temperature ΛCDM Cosmology Quantum Gravity Unification
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Explanation of the Necessity of the Empirical Equations That Relate the Gravitational Constant and the Temperature of the CMB
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作者 Tomofumi Miyashita 《Journal of Modern Physics》 CAS 2023年第4期432-444,共13页
In previous papers, we proposed an empirical equation for the fine-structure constant. Using this equation, we proposed a refined version of our own former empirical equations about the electromagnetic force and gravi... In previous papers, we proposed an empirical equation for the fine-structure constant. Using this equation, we proposed a refined version of our own former empirical equations about the electromagnetic force and gravity in terms of the temperature of the cosmic microwave background. The calculated values of the temperature of the cosmic microwave background (T<sub>c</sub>) and the gravitational constant (G) were 2.726312 K and 6.673778 × 10<sup>-11</sup> m<sup>3</sup>⋅kg<sup>-1</sup>⋅ s<sup>-2</sup>, respectively. Then, for the values of the factors 9/2 and π in our equations, we used 4.488519503 and 3.132011447, respectively. However, we could not provide a theoretical explanation for the necessity of these empirical equations. In this paper, using the redefinition method for the UNIT, we show the necessity for our empirical equations. 展开更多
关键词 Gravitational constant temperature of the Cosmic Microwave Background
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Potentiometric Study of Dissociation Constants of Dihydroxybenzoic Acids at Reduced Ionic Strengths and Temperatures
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作者 Jorgen Rosenqvist Caroline M.Jonsson 《American Journal of Analytical Chemistry》 2017年第2期142-150,共9页
The dissociation behavior of two dihydroxybenzoic acid isomers, 2,3-DHBA and 3,4-DHBA, at 281 K and 293 K was determined by potentiometric titrations in 0.01 M NaCl and 0.03 M NaCl. Results showed that the dissociatio... The dissociation behavior of two dihydroxybenzoic acid isomers, 2,3-DHBA and 3,4-DHBA, at 281 K and 293 K was determined by potentiometric titrations in 0.01 M NaCl and 0.03 M NaCl. Results showed that the dissociation enthalpy for the carboxylic group in DHBA is close to zero, resulting in dissociation constants that do not vary appreciably with temperature, whereas the dissociation constants for the first hydroxyl group vary significantly with temperature. Increasing ionic strength was found to result in increased values for the second dissociation constant, whereas the effect on the first dissociation constant was less clear. 展开更多
关键词 2 3-Dihydroxybenzoic Acid 3 4-Dihydroxybenzoic Acid Dissociation constant PKA temperature Ionic Strength Surface Water
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Temperature-dependent development of Neoseiulus barked (Acari: Phytoseiidae) on Tetranychus urticae (Acari: Tetranychidae) at seven constant temperatures 被引量:4
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作者 Shahriar Jafari Yaghoub Fathipour Farid Faraji 《Insect Science》 SCIE CAS CSCD 2012年第2期220-228,共9页
The effect of seven constant temperatures of 15, 20, 25, 27, 30, 35 and 37℃ on developmental time ofNeoseiulus barkeri Hughes were determined in laboratory conditions under 65% - 5% RH and a photoperiod of 12 : 12 ... The effect of seven constant temperatures of 15, 20, 25, 27, 30, 35 and 37℃ on developmental time ofNeoseiulus barkeri Hughes were determined in laboratory conditions under 65% - 5% RH and a photoperiod of 12 : 12 (L : D) h on nymphal stages of Tetranychus urticae Koch. Total developmental time of females (from egg to adult emergence) at the above-mentioned temperatures was 26.59, 14.43, 6.32, 5.64, 4.59, 3.98 and 4.67 days, respectively. Developmental rate of the N. barkeri increased as temperature increased from 15 to 35℃, but declined at 37℃. A linear and two nonlinear models were fitted to developmental rate of immature stages ofN. barkeri to predict the developmental rate as a function of temperature, as well as to estimate the thermal constant (K) and critical temperatures (i.e., Tmin, Topt and Tmax). The estimated values of the Tmin and K for total developmental time using the linear model were 12.07℃ and 86.20 degree-days (DD), respectively. The Trnin and Tmax estimated by the Sharpe-Schoolfield-Ikemoto (SSI) model were 11.90℃ and 37.41℃, respectively. The estimated Topt for overall immature stage development ofN. barkeri by the Lactin and SSI models were 33.89℃ and 24.51℃, respectively. Based on the biological criteria of model evaluation, the linear and SSI models were found to be the best models for describing the developmental rate of overall immature stages of N. barkeri and estimating the temperature thresholds. 展开更多
关键词 Neoseiulus barkeri temperature thresholds temperature-dependent development Tetranychus urticae thermal constant
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Constant temperature control of tundish induction heating power supply for metallurgical manufacturing 被引量:2
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作者 Yufei YUE Qianming XU +1 位作者 Peng GUO An LUO 《Frontiers in Energy》 SCIE CSCD 2019年第1期16-26,共11页
The tundish induction heating power supply(TIHPS)is one of the most important equipment in the continuous casting process for metallurgical manufacturing.Specially,the constant temperature control is greatly significa... The tundish induction heating power supply(TIHPS)is one of the most important equipment in the continuous casting process for metallurgical manufacturing.Specially,the constant temperature control is greatly significant for metallurgical manufacturing.In terms of the relationship between TIH load temperature and output power of TIHPS,the constant temperature control can be realized by power control.In this paper,a TIHPS structure with three-phase PWM rectifiers and full-bridge cascaded inverter is proposed.Besides,an input harmonic current blocking strategy and a load voltage feedforward control are also proposed to realize constant temperature control.To meet the requirement of the system,controller parameters are designed properly.Experiments are con?ducted to validate the feasibility and effectiveness of the proposed TIHPS topology and the control methods. 展开更多
关键词 TUNDISH INDUCTION heating power supply(TIHPS) constant temperature control input HARMONIC current BLOCKING load voltage FEEDFORWARD
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Magnesium (II) Adsorption from Aqueous Solutions on China Clay and the Stability Constants for Complex Formation 被引量:1
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作者 S.BEGUM F.U.KHAN 《Pedosphere》 SCIE CAS CSCD 1998年第2期169-174,共6页
China clay was employed as an adsorbent for the removal of Mg 2+ from water at pH 7.0 within the temperature range of 303~328 K. The linearity of the plots indicated Langmuir type isotherms. The reaction was ex... China clay was employed as an adsorbent for the removal of Mg 2+ from water at pH 7.0 within the temperature range of 303~328 K. The linearity of the plots indicated Langmuir type isotherms. The reaction was exothermic. A maximum removal of 35% was obtained at 0.50 mmol L -1 metal concentration and a pH of 7.0 at 303 K. The H + rel /Mg 2+ ads ratio changed from a fractional value to 2.5. Strong chemical bondings took place between oxygen atom of the surface and Mg 2+ , resulting in a surface complex species. Temperature had a significant effect on H + rel , and the stability constants also increased with increasing temperature. 展开更多
关键词 H + releasing Mg 2+ adsorption stability constants temperature
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Application of Neural network PID Controller in Constant Temper-ature and Constant Liquid-level System 被引量:11
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作者 (College of information and control engineering, University of Petroleum, Dongying 257061, China) Chen Guochu Hao Ninmei Liu Xianguang(College of electricity engineering, University of Xi ’ an Communication, Xi’ an 710049, China) Zhang Lin (Workshop of Instrument of Plastic Plant, Qilu Petrochemical Corp., Zibo 255411, China) Wang Junhong 《微计算机信息》 2003年第1期23-24,42,共3页
Guided by the principle of neural network, an intelligent PID controller based on neural network is devised and applied to control of constant temperature and constant liquidlevel system. The experiment results show t... Guided by the principle of neural network, an intelligent PID controller based on neural network is devised and applied to control of constant temperature and constant liquidlevel system. The experiment results show that this controller has high accuracy and strong robustness and good characters. 展开更多
关键词 PID控制器 神经网络 PID控制 恒温恒液位系统
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Multi-stage constant current charging strategy considering SOC intervals and voltage thresholds
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作者 Yu Zhang Si Xu Tiezhou Wu 《Global Energy Interconnection》 EI CAS CSCD 2022年第2期143-153,共11页
Conventional multi-stage constant current charging strategies often use higher multiples of current to charge the battery in pursuit of shorter charging times.However,this leads to an increase in battery temperature,w... Conventional multi-stage constant current charging strategies often use higher multiples of current to charge the battery in pursuit of shorter charging times.However,this leads to an increase in battery temperature,while shortening the charging time.This in turn affects the safety of the charging process.Furthermore,the higher charging currents are not ideal for shortening the charging time in the later stages of charging.To solve the aforementioned problems,in this study,a multi-stage constant current charging strategy is presented.This strategy can shorten the battery charging time by using the increase in battery temperature during the charging process as a constraint,using a genetic algorithm to calculate the charging current value,and investigating the phased approach to charging.Finally,the charging strategy is experimentally validated at different ambient temperatures and different initial SOCs.The experimental results show that the charging strategy proposed in this paper not only reduces the amount of calculations,but also reduces the temperature rise by up to 46.4%and charging time by up to 4.2%under different operating conditions. 展开更多
关键词 Charging time Battery temperature rise Genetic algorithm Multi-stage constant current charging
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Elastic constants characterization on graphite at 500℃ by the virtual fields method 被引量:1
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作者 Baoqiao Guo Huaixi Wang +1 位作者 Huimin Xie Pengwan Chen 《Theoretical & Applied Mechanics Letters》 CAS 2014年第2期59-65,共7页
In this paper the elastic constants of graphite at elevated temperature were experimentally investigated by using the virtual fields method (VFM). A new method was presented for the characterization of mechanical pr... In this paper the elastic constants of graphite at elevated temperature were experimentally investigated by using the virtual fields method (VFM). A new method was presented for the characterization of mechanical properties at elevated temperature. The three-point bending tests were performed on graphite materials by an universal testing machine equipped with heating fumace. Based on the heterogeneous deformation fields measured by the digital image correlation (DIC) technique, the elastic constants were then extracted by using VFM. The measurement results of the elastic constants at 500℃ were obtained. The ef- fect on the experimental results was also analyzed. The successful results verify the feasibility of using the proposed method to measure the properties of graphite at high temperature, and the proposed method is believed to have a good potential for further applications. 展开更多
关键词 elastic constants GRAPHITE high temperature digital image correlation virtualfields method
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The Rate Constant Calculations for the Reaction H(2S)+NH(X3Σˉ) to N(4S)+H_(2) by using Quantum Mechanics Method
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作者 ZHAI Hong-Sheng ZHOU Pan-Wang 《Chinese Physics Letters》 SCIE CAS CSCD 2012年第6期122-124,共3页
The quantum reactive scattering dynamics calculations are carried out over the collision energy range of 0-1.0e V on the double many-body exparsion (DMBE) potential etergy surface reported by Poveda and Varandas [Phys... The quantum reactive scattering dynamics calculations are carried out over the collision energy range of 0-1.0e V on the double many-body exparsion (DMBE) potential etergy surface reported by Poveda and Varandas [Phys.Chem.Chem.Phys.7(2005) 2867].The reaction probabilities,integral cross-section and rate constantsfor the title reaction are calculated.The calculated rate constants are in agreement with the available experimental results at high temperature but lower than the experimental results at low temperature. 展开更多
关键词 temperature constantS COLLISION
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Algorithms for Empirical Equations in Terms of the Cosmic Microwave Background Temperature
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作者 Tomofumi Miyashita 《Journal of Modern Physics》 2024年第10期1567-1585,共19页
Previously, we presented several empirical equations using the cosmic microwave background (CMB) temperature. Next, we propose an empirical equation for the fine-structure constant. Considering the compatibility among... Previously, we presented several empirical equations using the cosmic microwave background (CMB) temperature. Next, we propose an empirical equation for the fine-structure constant. Considering the compatibility among these empirical equations, the CMB temperature (Tc) and gravitational constant (G) were calculated to be 2.726312 K and 6.673778 × 10−11 m3∙kg−1∙s−2, respectively. Every equation can be explained numerically in terms of the Compton length of an electron (λe), the Compton length of a proton (λp) and α. Furthermore, every equation can also be explained in terms of the Avogadro number and the number of electrons at 1 C. We show that every equation can be described in terms of the Planck constant. Then, the ratio of the gravitational force to the electric force can be uniquely determined with the assumption of minimum mass. In this report, we describe the algorithms used to explain these equations in detail. Thus, there are no dimension mismatch problems. 展开更多
关键词 temperature of the Cosmic Microwave Background Minimum Mass The Ratio of Gravitational Force to Electric Force Dimension Analysis Redefinition Method Fine Structure constant
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Influence of Temperature and Frequency on Microwave Dielectric Properties of Lunar Regolith Simulant 被引量:3
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作者 MENG Zhiguo CHEN Shengbo +3 位作者 DU Xiaojuan EDWARD Matthew Osei Jnr LU Peng WANG Zijun 《Chinese Geographical Science》 SCIE CSCD 2011年第1期94-101,共8页
The dielectric constant of the lunar regolith can directly influence the reflection coefficient and the trans-mission coefficient of the Moon′s surface, and plays an important role in the Moon research. In order to s... The dielectric constant of the lunar regolith can directly influence the reflection coefficient and the trans-mission coefficient of the Moon′s surface, and plays an important role in the Moon research. In order to study the di-electric properties of the lunar regolith, the lunar regolith simulant was made according to the making procedure of the CAS-1 simulant made by Chinese Academy of Sciences. Then the dielectric constants of the lunar regolith simulant were measured with 85070E Aiglent Microwave Network Analyzer in the frequency ranging from 0.2 GHz to 20.0 GHz and at temperature of 25.1℃, 17.7℃, 13.1℃, 11.5℃, 9.6℃, 8.0℃, 4.1℃, -0.3℃, -4.7℃, -9.5℃, -18.7℃, -27.7℃, and -32.6℃, respectively. The Odelevsky model was employed to remove the influence of water in the air on the final effective dielectric constants. The results indicate that frequency and temperature have apparent influences on the dielectric constants of the lunar regolith simulant. The real parts of the dielectric constants increase fast over the range of 0.2 GHz to 3.0 GHz, but decrease slowly over the range of 4.0 GHz to 20.0 GHz. The opposite phenomenon occurs in the imaginary parts. The influences of the frequency and temperature on the brightness temperature were also estimated based on the radiative transfer equation. The result shows that the variation of the frequency and temperature results in great changes of the microwave brightness temperature emitting from the lunar regolith. 展开更多
关键词 lunar regolith simulant dielectric constant temperature FREQUENCY
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Mechanical properties of Ga_xIn_(1-x)As_yP_(1-y)/GaAs system at different temperatures and pressures 被引量:1
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作者 A.R.Degheidy E.B.Elkenany 《Chinese Physics B》 SCIE EI CAS CSCD 2015年第9期313-318,共6页
The mechanical properties, such as the elastic constants C11, C12, C44, and bulk, Young's, and shear moduli, of a Ga x In1-x As y P1-y alloy lattice matching to a Ga As substrate are calculated for various As concent... The mechanical properties, such as the elastic constants C11, C12, C44, and bulk, Young's, and shear moduli, of a Ga x In1-x As y P1-y alloy lattice matching to a Ga As substrate are calculated for various As concentrations. The calculations are based on the pseudo-potential method within the virtual crystal approximation containing the effective disorder potential. The variations of the studied properties with pressure and temperature are investigated. A comparison between the calculated results and the available published data for binary parent compounds shows that they have good agreement,while the calculated results for the quaternary alloys at various temperature and pressure may be taken as a reference. 展开更多
关键词 elastic constants temperature and pressure electronic band gaps
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Kinetics Study on Reaction between Dihydroartemisinic Acid and Singlet Oxygen: An Essential Step to Photochemical Synthesis of Artemisinin
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作者 Xian-wang Zhang Xuan Zhao +1 位作者 Kun-hui Liu Hong-mei Su 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2020年第2期145-150,I0002,共7页
Artemisinin is an excellent antimalarial drug widely used in clinical medicine.However,due to the limitation of natural source of artemisinin,the chemical synthesis of artemisinin has achieved substantial attention.Di... Artemisinin is an excellent antimalarial drug widely used in clinical medicine.However,due to the limitation of natural source of artemisinin,the chemical synthesis of artemisinin has achieved substantial attention.Dihydroartemisinic acid is a key precursor for the synthesis of artemisinin.The reaction of dihydroartemisinic acid with singlet oxygen to form peroxide is a pivotal step in the photochemical preparation of artemisinin.Nevertheless,the reaction kinetics of dihydroartemisinic acid with singlet oxygen has not been investigated previously.Herein,we report the rate constants of the reaction between dihydroartemisinic acid and singlet oxygen.By directly detecting the luminescence decay kinetics of singlet oxygen at 1270 nm at room temperature,the reaction rate constants of singlet oxygen and dihydroartemisinic acid in different solvents are obtained to be 1.81×10^5(mol/L)^-1·s^-1 in CCl4,5.69×10^5(mol/L)^-1·s^-1 in CH3CN,and 3.27×10^6(mol/L)^-1·s^-1 in DMSO,respec-tively.It is found that the reaction rate constants of dihydroartemisinic acid with singlet oxygen increase as polarity of the solvent increases among the three solvents.These results provide fundamental knowledge to optimize experiment conditions of photochemical synthesis of artemisinin for improving the yields of artemisinin. 展开更多
关键词 Dihydroartemisinic acid ARTEMISININ Singlet oxygen Rate constant Transient absorption spectroscopy
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