Recent progress and challenges in structural construction strategy of metal-based catalysts for nitrate electroreduction to ammonia

Ammonia plays an essential role in human production and life as a raw material for chemical fertilizers.The nitrate electroreduction to ammonia reaction(NO_(3)RR)has garnered attention due to its advantages over the Haber-Bosch process and electrochemical nitrogen reduction reaction.Therefore,it represents a promising approach to safeguard the ecological environment by enabling the cycling of nitrogen species.This review begins by discussing the theoretical insights of the NO_(3)RR.It then summarizes recent advances in catalyst design and construction strategies,including alloying,structure engineering,surface engineering,and heterostructure engineering.Finally,the challenges and prospects in this field are presented.This review aims to guide for enhancing the efficiency of electrocatalysts in the NO_(3)RR,and offers insights for converting NO_(3)-to NH_(3).

A Study on Integrated Construction of Luzhou Comprehensive Transportation Hub

The target of integrated construction of comprehensive transportation hub is to integrate the traffic resources,achieve butt joint of pan-regional transportation mode,and finally realize the"seamless connection"of the goods and"zero transfer"of the passenger traffic.Relying on the particularity of the geographical location and the convenience of the Yangtze River channel,Luzhou puts forth effort to build a comprehensive transport hub in Southern Sichuan and has made great efforts in traffic infrastructure construction.However,there are still some problems.Combining practice of Luzhou,using the advanced experience of foreign and domestic cities for reference,the paper pointed out that for the sake of constructing a comprehensive transportation hub,we need to build the traffic integration on the basis of the efficiency.Besides,the paper proposed the strategies for construction.

A construction strategy for a tunnel with big deformation

By integrating literature reviews, site observa- tion, field monitoring, theoretical analysis, summarization, etc., a construction strategy was proposed and verified for tunneling with big deformation in this paper. The tunnel was in phyllite, shotcrete cracks and steel arch distortion were observed, and a big deformation with a maximum of 2.0 m was monitored during the initial stage of the construction. Through carefully examining the site observation and laboratory test results, a construction principle was established for the tunneling on the basic concept of maintaining the rock strength/stiffness and keeping the rock dry, by providing confinement pressure to the rock, reducing the rock exposure time, keeping water out of the tunnel, etc. To achieve the construction principle, a set of specific construction measures with 11 items was further proposed and applied to the construction. To check the effectiveness of the construction measures, field monitoring was carried out, which showed that the rock deformation was well controlled and the tunnel became stable. An allowable deformation was then determined using the Fenner formulae and the monitored data in order to guide further construction, which received a good result. From this study, it can be concluded that providing quick strong initial support and reserving core soil at the working faceare extremely important to control the rock deformation and keep the tunnel stable.

Treatment Design and Construction Strategy for Tunnel Mud and Water Inrush Disaster

With the rapid development of the transportation industry in China,the number and scale of tunnel construction are increasing.Tunneling through fault zones and other complex geological environments is becoming more and more common.In the construction of highway tunnels,due to the special geographical environment and complex geological conditions,mud and water inrush often occur in the tunnel.Water inrush disasters pose a major risk to the construction of highway tunnels and affect the normal construction of highway tunnels.This paper combines the engineering background of the tunnel mud and water inrush accidents,carries out evaluation on the accident treatment measures and the treatment efficiency,and summarizes the main concerns in the construction process and the technical guidelines for dealing with the tunnel mud and water inrush.

The Construction Strategy of Small Towns Based on Ecological Concept

Based on the perspective of ecological concept,this study first interpreted the background of ecological civilization construction,and combed the relationship between ecological concept and small town planning.Second,it expounded the ecological problems of natural resources,economic development,landscape system,social humanities and other aspects in the construction of contemporary small towns.According to the study,the construction of small towns based on the ecological concept should establish the concept of "ecology first",practice "multiple compliance",coordinate the relationship with other planning,make reasonable planning and design in the aspects of town scale,functional orientation,structural form,road traffic,landscape style and features,humanistic characteristics,and strengthen the implementation,supervision and management of planning.Finally,summary and outlook was made,hoping that the study will be of reference value and guidance to the planning and construction of small towns.

High valence metals engineering strategies of Fe/Co/Ni-based catalysts for boosted OER electrocatalysis

Electrocatalysis for the oxygen evolution reactions(OER)has attracted much attention due to its important role in water splitting and rechargeable metal-air batteries.Therefore,designing highly efficient and low-cost catalysts for OER process is essential as the conventional catalysts still rely on precious metals.Transition metal-based compounds have been widely investigated as active OER catalysts,and renewed interest in the high valence metals engineered compounds has been achieved for superior catalytic activity and stability.However,an in-depth understanding of the construction strategies and induced effects for the high valence metals engineered catalysts is still lacking and desired.In this review,we have summarized the construction strategies of high valence metals as dopants or formed heterostructures with the iron/cobalt/nickel(Fe/Co/Ni)-based catalysts.Then the induced effects on Fe/Co/Ni-based catalysts by incorporating high valence metals,e.g.,accelerating the surface reconstruction,forming amorphous structure,generating vacancies/defects,and acting as stabilizers,are highlighted.The impacts of high valence metals on OER performance are elucidated based on different elements,including molybdenum(Mo),tungsten(W),cerium(Ce),vanadium(V),chromium(Cr),manganese(Mn),niobium(Nb),zirconium(Zr).The correlations of construction strategies,induced effects,catalytic activity and OER reaction pathways are elaborated.Finally,the remaining challenges for further enhancements of OER performance induced by high valence metals are presented.

Teaching Practice Communities in Higher Education:Roles and Strategies

In view of the problem of lacking peer coaching among college teachers,taking teachers in local universities in Hangzhou as the research subject,the paper analyzes the relationship between peer coaching and teachers’professional development.The paper then proposes to establish teaching practice communities in higher education,which is of great significance to improve the teaching quality and promote the professional development of university teachers.Strategies for constructing teaching practice communities are also discussed.

The Construction of Architectural CAD Course Competition Integration Teaching Mode

Architectural Computer-Aided Design(CAD)is a basic course for architectural engineering majors in vocational colleges.The integration of competition into teaching will not only help stimulate the students’enthusiasm,but also help them improve their professional skills.However,there are still some problems in the teaching of Architectural CAD.Therefore,teachers must continuously optimize the integration of competition content into Architectural CAD classes through various strategies,so as to give full play to the value of competition content in classes.We explored and analyzed the problems in the integration of competition content into Architectural CAD classes,and proposed specific strategies,in hopes of improving the quality of Architectural CAD teaching.

Construction Strategies of Public Activity Spaces in Residential Districts Based on Children's Activities

The relationship between children's activities and public spaces was analyzed and summarized from three perspectives, namely, children's demands on outdoor activity spaces, factors infl uencing children's behavior requirements, and planning strategies. The paper provided theoretical support for exploring the relationship between children's activities and public spaces, and proposed planning strategies for improving use effi ciency of urban outdoor public spaces and facilities, and creating public spaces capable of meeting children's psychological needs.

Research on the Regional Ecological Environment Evaluation and Application under the Influence of the Severe Earthquake Disaster

To conduct the ecological restoration and reconstruction of disaster areas after the severe earthquake, such as Wenchuan Earthquake and Lushan Earthquake, this article uses region al ecological environment evaluation and ecological footprint to construct a quantitative analysis model on the basis of ecololgical environment indexes in Mianzhu City. Through this model, resource status of the regional environment in Mianzhu is analyzed, as well as the ecological capacity and the ecological security. Based on the evaluation and analysis, this paper provides multi-path development strategies of ecological restoration and sustainable development of human settlements after the earthquake.

Strategies for the Construction of Vernacular Landscape in Urban Gardens

Vernacular landscape is the carrier of traditional techniques and local culture.The construction of vernacular landscape has gradually become the basic direction of modern urban garden design.Based on the analysis of the extraction and application of vernacular landscape elements,the application forms and design principles of each element in urban gardens are pointed out.At the same time,taking the artistic expression method of integrating vernacular landscape elements into garden landscape as the starting point and combining with case analysis,the design principles and main planning points of building vernacular landscape are put forward,and some strategies for the construction and protection of vernacular landscape in the planning of garden landscape in different regions are proposed.

Strategies for Construction of Sustainable Development Experimental Zone in Fumian District,Yulin City

From strengthening the construction of an innovation system,adhering to the green development model of the industry,advancing the rural revitalization strategy,strengthening the protection and inheritance of cultural heritage,accelerating the development of social undertakings,and expanding the space for regional cooperation,this paper discusses the strategies for the construction of sustainable development experimental zone in Fumian District,Yulin City.It is intended to build Fumian District into a vibrant,economically prosperous,urban and rural integrated,characteristic cultural,safe and harmonious,inclusive and open district.

Research progress on construction strategy and technical evaluation of aircraft icing accretion protection system

The impact of unstable supercooled water droplets suspended in the cloud on the solid will cause its surface to freeze,and the flight safety of the aircraft will be seriously affected when flying in this environment.Aircraft icing protection system is an important device to reduce icing accidents and improve aircraft safety performance,which is of great significance to ensure flight safety.Based on the energy source,this paper proposes a general strategy for constructing an aircraft icing protection system,including Active Anti-icing and De-icing(AAD)system,Passive Antiicing and De-icing(PAD)system and Composite Anti-icing and De-icing(CAD)system.The principle,scope of application,advantages and disadvantages of aircraft anti-icing and de-icing technologies such as electric pulse de-icing,low-frequency piezoelectric de-icing,and hydrophobic material anti-icing are explored in detail,and the corresponding improvement measures are proposed.The future development of aircraft anti-icing and de-icing technology is prospected,and some new ideas are provided for the improvement of aircraft anti-icing and de-icing technology.

Heterojunction： important strategy for constructing composite photocatalysts

As an ideal solution to energy and environment issues,conversion of sunlight into solar fuels by photocatalytic water splitting and greenhouse gas(CO_2)reduction has attracted keen research interest of multi-field scientists.In the past four decades,a large number of semiconductor photocatalysts have been

Design and applications of carbon dots-based ratiometric fluorescent probes:A review

Ratiometric fluorescence(FL)probes can eliminate the background interference and provide more accurate detection results than single emission intensity-based nanoprobes.Recently,carbon dots(CDs)-based ratiometric FL probes have received extensive research attention due to their excellent biocompatibility,water solubility,and multi-emission capabilities.In this review,we firstly summarize the construction strategies of CDs-based ratiometric FL probes,including physical mixing,nanohybrid,and dual-emitting CDs strategies.Additionally,we classify the sensing types of CDs-based ratiometric FL probes into five categories according to the difference in spectral variation caused by analytes:“single-response-ON”,“single-response-OFF”,“doubleresponses-ON”,“double-responses-OFF”,and“double-responses-Reverse”types.Finally,a thorough overview of CDs-based ratiometric FL probe applications in ions,molecules,pH,and temperature sensing is provided.We believe this review can show the latest research progress of CDs-based ratiometric FL sensing fields and provide perspectives on future developments for the construction of CDs-based ratiometric FL probes and their potential applications.

China＇s Sponge City construction： A discussion on technical approaches

Since 2014, China has been implementing the Sponge City Construction initiative, which represents an enormous and unprecedented effort by any government in the world for achieving urban sustainability. According to preliminary estimates, the total investment on the Sponge City Plan is roughly 100 to 150 million Yuan （RMB） （$15 to $22.5 million） average per square kilometer or 10 Trillion Yuan （RMB） （$1.5 Trillion） for the 657 cities nationwide. The Sponge City Plan （SCP） calls for the use of natural processes such as soil and vegetation as part of the urban runoff control strategy, which is similar to that of low impact development （LID） and green infrastructure （G1） practices being promoted in many parts of the world. The SCP includes as its goals not only effective urban flood control, but also rainwater harvest, water quality improvement and ecological restoration. So far, the SCP implementation has encountered-some barriers and challenges due to many factors. The present paper presents a review of those barriers and challenges, oftizrs discussions and recommendations on several technical aspects such as control goals and objectives; planning/design and construction of LID/GI practices; performance evaluation. Several key recommendations are proposed on Sponge City implementation strategy, Site-specific regulatory fi＇amework and technical gmdance, Product innovation and certification, LID/GI Project financing, LID/G1 profcssional training and certification, public outreach and education. It is expected that the successful implemen!atiun of the. SCP not only will bring about a sustainable, eco-friendly urbanization process in China, but also contribute enormously to the LID/Gl research and development with the vast amount of relevant data and experiences generated from the Sponge City construction projects.