The paper studies CO2 degassing and controlling factors under the condition of contact metamorphism in the Shuangshan area, southern Tan-Lu fault belt and the method of calculating the amount of CO2 degassing. The res...The paper studies CO2 degassing and controlling factors under the condition of contact metamorphism in the Shuangshan area, southern Tan-Lu fault belt and the method of calculating the amount of CO2 degassing. The results show that the amount of CO2 degassing is controlled by the characteristics of the country rocks, including the thermal conductivity, penetrability, porosity and connectivity. Compositions, size and depth of intrusive rock also have an important influence on CO2 degassing, i.e., they generated numerous cracks in the country rocks, and thus allowed the easy flow and accumulation of fluids. The amount of CO2 flux in contact metamorphism is calculated quantitatively based on the metamorphic reaction and time-integrated fluid flux. The value （0.729- 2.446×10^4 mol/cm^2） of CO2 flux suggests that CO2 was provided mainly by the contact metamorphic reaction. The generation and releasing of CO2 are positively correlated with the degree of metamorphism, and XCO2 in fluids gradually increases from dolomite zone to calcite zone, but in the zone of grossular, fluid flux is the largest and XCO2 sharply decreases due to involvement of magmatic water. This study presents evidence that a large amount of industrial-scale CO2 can be produced during contact metamorphism. On the basis of theoretical and practical studies, a cone model has been proposed to response CO2 degassing for the contact metamorphism, and it can be used to explore CO2 accumulations beyond the oil-gas basins. This model can also be applied to the study of inorganic genesis of CO2 accumulations.展开更多
Plate tectonic activity has played a critical role in the development of petrotectonic associations in the Kadiri schist belt. The calc alkaline association of basalt, andesite, dacite and rhyolite （BADR） is the sig...Plate tectonic activity has played a critical role in the development of petrotectonic associations in the Kadiri schist belt. The calc alkaline association of basalt, andesite, dacite and rhyolite （BADR） is the signature volcanic rock suite of the convergent margin. The N-S belt has gone below the unconformity plane of Cuddapah sediments. In the northern part geochemical and structural attributes of the Kadiri greenstone belt is studied along with microscopic observations of selected samples. Harker diagram plots of major elements generally indicate a liquid line of descent from a common source, such that BADR rocks are derived from a common parent magma of basaltic to andesitic composition. These calc-alkaline volcanic rocks are formed at convergent margins where more silicic rocks represent more highly fractionated melt. All the litho-units of this greenstone belt indicate crush and strain effects. The stretched pebbles in the deformed volcanic matrix with tectonite development along with associated greenschist facies metamorphism, alteration and hydration is remarkable. Flow foliation plane with N-S strike and very low angle （5~ to 10~） easterly dip and N-S axial planar schistosity formed due to later phase isoclinal folding can be clearly identified in the field. Basic intrusives are quite common in the surrounding area. All the observations including the field setting and geochemistry clearly demonstrate ocean-continent subduction as the tectonic environment of the study area.展开更多
基金supported by grants from the Natural Science Foundation of China(grant Nos:40473021 and 40472074)the National Basic Research Program of China(grant No:2003CB214600).
文摘The paper studies CO2 degassing and controlling factors under the condition of contact metamorphism in the Shuangshan area, southern Tan-Lu fault belt and the method of calculating the amount of CO2 degassing. The results show that the amount of CO2 degassing is controlled by the characteristics of the country rocks, including the thermal conductivity, penetrability, porosity and connectivity. Compositions, size and depth of intrusive rock also have an important influence on CO2 degassing, i.e., they generated numerous cracks in the country rocks, and thus allowed the easy flow and accumulation of fluids. The amount of CO2 flux in contact metamorphism is calculated quantitatively based on the metamorphic reaction and time-integrated fluid flux. The value （0.729- 2.446×10^4 mol/cm^2） of CO2 flux suggests that CO2 was provided mainly by the contact metamorphic reaction. The generation and releasing of CO2 are positively correlated with the degree of metamorphism, and XCO2 in fluids gradually increases from dolomite zone to calcite zone, but in the zone of grossular, fluid flux is the largest and XCO2 sharply decreases due to involvement of magmatic water. This study presents evidence that a large amount of industrial-scale CO2 can be produced during contact metamorphism. On the basis of theoretical and practical studies, a cone model has been proposed to response CO2 degassing for the contact metamorphism, and it can be used to explore CO2 accumulations beyond the oil-gas basins. This model can also be applied to the study of inorganic genesis of CO2 accumulations.
文摘Plate tectonic activity has played a critical role in the development of petrotectonic associations in the Kadiri schist belt. The calc alkaline association of basalt, andesite, dacite and rhyolite （BADR） is the signature volcanic rock suite of the convergent margin. The N-S belt has gone below the unconformity plane of Cuddapah sediments. In the northern part geochemical and structural attributes of the Kadiri greenstone belt is studied along with microscopic observations of selected samples. Harker diagram plots of major elements generally indicate a liquid line of descent from a common source, such that BADR rocks are derived from a common parent magma of basaltic to andesitic composition. These calc-alkaline volcanic rocks are formed at convergent margins where more silicic rocks represent more highly fractionated melt. All the litho-units of this greenstone belt indicate crush and strain effects. The stretched pebbles in the deformed volcanic matrix with tectonite development along with associated greenschist facies metamorphism, alteration and hydration is remarkable. Flow foliation plane with N-S strike and very low angle （5~ to 10~） easterly dip and N-S axial planar schistosity formed due to later phase isoclinal folding can be clearly identified in the field. Basic intrusives are quite common in the surrounding area. All the observations including the field setting and geochemistry clearly demonstrate ocean-continent subduction as the tectonic environment of the study area.
