Changing the balance of the MTO reaction dual-cycle mechanism: Reactions over ZSM-5 with varying contact times

The methanol to olefins （MTO） reaction was performed over ZSM‐5 zeolite at 300℃ under various methanol weight hourly space velocity （WHSV） values. During these trials, the catalytic perfor‐mance was assessed, in addition to the formation and function of organic compounds retained in the zeolite. Analysis of reaction effluents and confined organics demonstrated a dual‐cycle reaction mechanism when employing ZSM‐5. The extent of the hydrogen transfer reaction, a secondary reac‐tion in the MTO process, varied as the catalyst‐methanol contact time was changed. In addition, 12C/13C‐methanol switch experiments indicated a relationship between the dual‐cycle mechanism and the extent of the hydrogen transfer reaction. Reactions employing a low methanol WHSV in conjunction with a long contact time favored the hydrogen transfer reaction to give alkene products and promoted the generation and accumulation of retained organic species, such as aromatics and methylcyclopentadienes, which enhance the aromatic cycle. When using higher WHSV values, the reduced contact times lessened the extent of the hydrogen transfer reaction and limited the genera‐tion of methylcyclopentadienes and aromatic species. This suppressed the aromatic cycle, such that the alkene cycle became the dominant route during the MTO reaction.

Mechanism of Spine Motion About Contact Time in Quadruped Running

The current research of quadruped robot focuses on the quadruped robot with spine motion. Contact time is a very important part of system performance. However, the mechanism of spine motion about contact time has not been clearly elucidated. In this paper, the e ect of spine motion on contact time is studied deeply from dynamic view.Firstly, a simplified model of the quadruped robot with spine joint is set up, its dynamic equations are derivated, and a method that can generate passive periodic locomotion is proposed. Secondly, according to the vertical spring oscillator model, the two-dimension planar locomotion of the simplified model is regarded as a special vibration in the vertical direction, and the approximate formula of calculating contact time is obtained. Finally, the approximate formula of calculating contact time is verified by the simulation results of passive periodic locomotion, and the e ect of spine motion on contact time is deeply discussed based on the approximate formula of calculating contact time. The discussion proves that spine motion indeed has little e ect on contact time, but spine motion can slightly reduce body pith movement and regulate the leg sti ness in leg contact phase. This research proposes an e ective research method which can be used to study the motion mechanism of the quadruped robot with spine motion,and the mechanism of spine motion about contact time is clearly elucidated which is helpful to set the parameters of mechanical structure and study control algorithm about the quadruped robot with spine motion.

A balancing act: Optimizing free chlorine contact time to minimize iodo-DBPs, NDMA, and regulated DBPs in chloraminated drinking water

Many drinking water treatment plants in the U.S. have switched from chlorination to chloramination to lower levels of regulated trihalomethane(THM) and haloacetic acid(HAA) disinfection byproducts(DBPs) in drinking water and meet the current regulations. However, chloramination can also produce other highly toxic/carcinogenic, unregulated DBPs: iodoacids, iodo-THMs, and N-nitrosodimethylamine(NDMA). In practice, chloramines are generated by the addition of chlorine with ammonia, and plants use varying amounts of free chlorine contact time prior to ammonia addition to effectively kill pathogens and meet DBP regulations. However, iodo-DBPs and nitrosamines are generally not considered in this balancing of free chlorine contact time. The goal of our work was to determine whether an optimal free chlorine contact time could be established in which iodo-DBPs and NDMA could be minimized, while keeping regulated THMs and HAAs below their regulatory limits. The effect of free chlorine contact time was evaluated for the formation of six iodo-trihalomethanes(iodo-THMs), six iodo-acids, and NDMA during the chloramination of drinking water. Ten different free chlorine contact times were examined for two source waters with different dissolved organic carbon(DOC) and bromide/iodide. For the low DOC water at pH 7 and 8, an optimized free chlorine contact time of up to 1 h could control regulated THMs and HAAs, as well as iodo-DBPs and NDMA. For the high DOC water, a free chlorine contact time of 5 min could control iodo-DBPs and NDMA at both p Hs, but the regulated DBPs could exceed the regulations at pH 7.

喷雾助剂对乙基多杀菌素药液在杧果叶片润湿铺展行为的影响

乙基多杀菌素是防治杧果蓟马的常用药剂之一,农药喷雾助剂的添加可以提高农药的药效。合理选择和使用助剂产品,对提高农药利用率、减少农药使用量至关重要。本研究通过测定添加5种不同类型、不同浓度的农药助剂产品后乙基多杀菌素药液的静态、动态表面张力,以及药液在杧果叶片正面、背面的接触角、铺展面积和蒸发时间,探究不同类型农药助剂产品在杧果叶片表面的润湿铺展行为。结果表明:添加不同助剂产品均能有效降低乙基多杀菌素药液的静态、动态表面张力,同时降低药液在叶片表面的接触角,提高药液在杧果叶片表面的铺展面积。除高分子类助剂(诺普信天盾)在叶片背面表现出抗蒸发性外,其他助剂产品均缩短了蒸发时间。不同类型的助剂产品在杧果叶片上的润湿性表现并不一致,有机硅类助剂(极润)润湿性最好,其余依次为硅酸金属复合盐类助剂(迈道)、改性植物油(迈飞)、橙皮精油(丹罗丰)、高分子类助剂(诺普信天盾)。通过比较不同处理组药液在杧果叶片正面、背面的润湿铺展行为,得出叶片背面比正面更难以被农药药液润湿。药液的理化性质和叶片的表面结构是影响喷雾液滴在叶片上润湿行为的重要因素。杧果蓟马常常在叶片背面活动取食,因此在防治杧果蓟马时,应根据助剂的类型、蓟马的为害特点选择合适的浓度,才能取得较好的防治效果。研究结果揭示了不同类型助剂在杧果叶片上的润湿铺展行为,为合理选择使用农药喷雾助剂产品提供数据支撑。

斜齿轮表面形貌分形特征对时变接触刚度的影响

基于改进的W-M分形函数,利用齿高和齿宽表征斜齿轮齿面的表面形貌。采用圆锥微凸体并考虑啮合过程中斜齿轮接触曲率半径的时变性建立了斜齿轮时变接触刚度模型,计算发现基于圆锥微凸体模型计算的时变啮合刚度与ISO6336-1—2006标准计算所得结果接近。研究结果表明,斜齿轮的时变接触载荷和时变接触刚度随着分形维数、特征尺度系数、量纲一接触面积、材料塑性指数的变化而表现出不同的变化趋势。

在线广告对不同渠道消费者广告响应度的动态影响

基于隐藏的动态视角,探讨不同在线广告与消费者无法被直接观测的广告响应度变化之间的关系。利用中国一家大型电子商务企业的相关数据,运用连续隐马尔可夫模型分析不同广告渠道下消费者群体的行为特征以及广告响应动态转移路径。研究发现:大多数在线广告均能显著影响消费者广告响应度的动态转移;消费者发起的广告相对于企业发起的广告,对消费者广告响应的提升作用更明显;消费者发起的广告渠道下消费者的非交易行为表现基本一致,而企业发起的广告下消费者的非交易行为有较大的差异。研究从动态转移视角揭示不同在线广告产生不同效果的深层原因,为企业有效投放在线广告提供一定指导。

基于Time Petri Net的实时系统冲撞检测与消解

time Petri net(TPN)在实时控制系统的建模中得到广泛应用,而冲撞是Petri网及其扩展模型的重要行为,解决冲撞是正确分析模型动态行为的关键.由于引入时间约束,使得TPN模型的使能和触发语义比Petri网模型的语义复杂,冲撞的检测及消解变得更加困难.首先根据时间约束,给出了变迁持续使能时延迟区间的计算方法,并证明了该方法的正确性;然后在此基础上定义并证明了TPN模型中冲撞的检测方法;给出了冲撞时间区间及修改时间约束的冲撞消解方法;最后通过实例验证说明了该方法的有效性和正确性.

计入齿根裂纹的直齿轮传动系统振动特性研究

针对裂纹故障状态下的直齿轮传动系统,提出了计入齿根裂纹不均匀分布的直齿轮传动动态仿真方法。首先将齿轮沿齿轮齿宽方向分成若干薄片,通过具有均匀分布的齿根裂纹的方法来获得每个齿轮切片的时变啮合刚度(TVMS)。考虑了齿轮和小齿轮的纵向/垂直相对位移,推导了外圈与轴承座之间的纵向/垂直接触力,根据达朗伯原理,得出了齿轮传动系统中齿轮和小齿轮的运动方程。最后通过仿真分析了裂纹从齿轮齿面一侧开始扩展时的轴承振动特性,同时通过统计指标验证了仿真分析的合理性。该模型可为齿轮齿根裂纹的检测与诊断提供理论指导。

THE INFLUENCE OF THERMAL PERFORMANCE OF TWT CATHODE-HEATER ASSEMBLY BY DIFFERENT CONTACT FORM BETWEEN INNER HEAT SHIELD AND SUPPORT CYLINDER

In this paper,the influence of thermal performance of cathode-heater assembly of Traveling Wave Tube(TWT),which has different contact form between inner heat shield and supporting cylinder,is analyzed using the simulation software ANSYS.With both thermal radiation and heat conduction are considered,the temperature and heat flux distribution of structures with different contact form are calculated,and also starting time which is needed before temperature come into steady status.The result of analysis suggests that changing the contact form between inner heat shield and support cylinder can influence the thermal performance of cathode-heater assembly and improve assembly's temperature distribution and promote heater's heating efficiency.The result of this paper provides theoretical guidance in the design of cathode-heater assembly.

海上窄压力窗口控压固井浆柱结构设计方法

针对海上油气井窄压力窗口固井顶替效率低下的技术难题,通过轻钻井液的施加以优化浆柱结构以及施加环空回压的方法实现安全高效固井的目标。考虑停泵压胶塞环空回压值≯5 MPa、冲洗液环空紊流接触时间>10min以及注替结束井筒自压稳3个关键技术要求,合理优化固井浆柱结构,计算控压固井全过程井筒当量循环密度(ECD),使井筒ECD在安全密度窗口内,形成了海上窄压力窗口控压固井浆柱结构设计方法。以乐东10-1气田某高温高压井为例,优化设计了该井的浆柱结构,并模拟计算了控压固井全过程井筒ECD及紊流接触时间。结果表明:轻钻井液用量为14~50 m^(3)且密度在1.822~2.142 g/cm^(3)之间、冲洗液用量>13 m^(3)且密度在2.36~2.45 g/cm^(3)之间、水泥浆密度在2.4~2.51 g/cm^(3)之间,可实现冲洗液紊流接触时间>10 min且满足压稳不漏的固井要求。该设计方法可实现海上窄压力窗口井安全施工和提高固井顶替效率的要求。

Research on Adjust Time of Premium

By considering economic strength and economic profit of insurance company, this paper presents a concept-contact point, and gives premium expectation adjust-time model which provides more practical significance for insurance company to make rational adjustment of premium. Finally, an illustration is given to show their application.

Design and Implementation of a Real Time Wireless Monitor System for Urinary Incontinence

Urinary incontinence is the most common health problem in aged people. Leaving incontinence events unmanaged will make a negative influence on the aged and the patient both mentally and physically. This paper presents a design and implementation of a real time wireless monitor system for urinary incontinence, which has been applied in two nursing homes in Beijing and Shanghai. We collect real time moisture information by using non-contact humidity sensor designed and manufactured by us. When urinary incontinence, the sensor will send alert to mobile device via Bluetooth. If got the alert, the mobile device will send the alert to relatives of the aged or disabled people and cloud computing platform, through which we can make this information managed and displayed and the paramedic can be informed about the alarm. This paper gives a brief introduction to the framework of this system, the design of the non-contact sensor, the transmission of wireless data and the results of tests.

Dynamics of a Dual Power-split Transmission Based on Loaded Tooth Contact Analysis

In order to implement the dynamic characteristic of a dual power-split transmission, a dynamic me- chanics model is built. Firstly, according to the method of theoretical analysis of the tooth contact analysis （TCA） and loaded tooth contact analysis （LTCA）, the actual meshing process of each gear pairs is simulated, and the time-varying mesh stiffness excitations are obtained, which can improve the numerical precision. Second- ly, by using the lumped mass method, the bending-torsional coupling three dimensional dynamic model of the dual power-split transmission is established, and the identical dimensionless equations are deduced by elimina- ting the effect of rigid displacement and the method of dimensional normalization. Finally, by the method of the fourth order Runge-Kutta algorithm with variable step lengths, the responses of this system in a frequency domain and time domain are obtained, and the dynamic load change characteristics of each gear pairs are analyzed. The results show that the establishment, solution and analysis of the system dynamics model could provide a basis for the dynamic design, and have an important significance for the dynamic efficiency analysis and dynamic perform- ance optimization design of the dual power-split transmission.

Evaluation of the Equality of Non-Polar Capillary Columns in GC/MS Analysis of Food Contact Plastics

Non-polar capillary columns for GC/MS are widely utilized in the analysis of additives for food contact materials. Though various kinds of non-polar capillary columns are commercially available, the equality of their performance has not been verified. Herein, ninety-six additives for food contact plastics were analyzed using fifteen kinds of columns, and the peak separation, retention times, and peak areas of each additive were compared. The additives, with various chemical properties, comprised forty four plasticizers, twenty lubricants, twenty antioxidants, nine ultraviolet absorbers, and three other compounds. 10 μg.mL-1 test solutions were prepared in acetone, and injected to the GC/MS. The fifteen columns were classified into five categories based on the chromatogram pattern and peak separation. To facilitate comparison of the retention time and detection sensitivity of the columns for the additives, the relative retention time (RRT) and relative peak area (RPA) were calculated by using dibutylphthalate or 4-tert-butylphenylsalicylate as an internal standard. The RRTs of the additives on each column were essentially similar. However, the RRT of the additives which were detected in the later stages differed slightly. Although the RPA of the plasticizers and lubricants were roughly similar, column-to-column differences were observed for certain additives, such as antioxidants and ultraviolet absorbers. Furthermore, certain fatty acids, antioxidants, two plasticizers, and two benzophenone type ultraviolet absorbers were not detected in the chromatograms of two columns.

稳定段曝气时间对高负荷接触稳定法碳捕获影响及微生物群落结构分析

为探究高负荷接触稳定法(HiCS)中稳定段曝气时间(ts)对废水碳捕获的影响,分析不同ts下HiCS系统的碳捕获率及污泥性质的差异,同时分析微生物群落结构差异。结果表明:当ts为1.0、2.0、3.0 h时,碳捕获率分别为43.0%、42.4%、39.2%,显著高于ts为0.5、4.0 h的20.3%和25.3%;污泥粒径较小且分布集中、微观结构粗糙多孔,有利于污泥和有机物接触絮凝。微生物群落结构分析表明,与接种污泥相比,ts为0.5 h的HiCS污泥中变形菌门(Proteobacteria)和拟杆菌门(Bacteroidetes)的相对丰度由24.7%、25.8%上升至40.0%、30.8%。FAPROTAX功能预测结果显示,与碳循环代谢相关的微生物丰度最高,占比达到60%以上,其相对丰度受ts影响显著,在1.0~3.0 h时高于0.5、4.0 h时。

考虑内、外圈复合故障的角接触球轴承振动特性研究

为描述考虑内、外圈复合故障角接触球轴承的振动特性,建立了角接触球轴承内、外圈复合故障时变位移激励模型;基于非线性Hertz接触理论,建立了角接触球轴承时变刚度模型;提出了考虑内、外圈复合故障的角接触球轴承动力学计算方法,研究了不同参数和工况条件下复合故障轴承的振动响应规律。研究结果表明:随着故障尺寸和轴承载荷的增大,复合故障轴承的振动特征频率不变,但其幅值增大;随着轴承转速的增大,复合故障轴承的振动特征频率及其幅值均增大;故障位置的变化将对复合故障轴承的振动特征产生很大影响,故障处越接近承载区,轴承的负载越大,振动特征越明显。

时滞戒毒模型的稳定性和Hopf分岔

研究了一类具有双线性接触率的时滞SLHMTQ戒毒模型.以吸毒者毒瘾复发的时滞为分岔参数,利用特征值法探究了模型的局部渐近稳定性和局部Hopf分岔存在性,推导出模型产生局部Hopf分岔的时滞临界值,并利用中心流形定理讨论了分岔周期解的性质.

基于多角度下TC4钛合金表面多颗粒动态冲蚀仿真研究

为了准确地预测TC4钛合金材料固体颗粒冲蚀的损伤过程,采用显式动力学有限元分析手段,建立了一个弹塑性有限元模型来模拟三维结构中多颗粒模型的动态冲蚀过程,并结合了Johnson-Cook材料模型和应变累积失效模型。结果表明:最大塑性变形发生在第一次碰撞时,且随着碰撞次数的增加而减小。冲蚀角度和速度显著影响颗粒和靶材表面之间的接触时间,动能损失随着冲蚀速度和角度的增加而增加。在低冲蚀角下,动态冲蚀过程中切向接触力和法向接触力有多个极大值和极小值,冲蚀机理主要是塑性变形和切向剪切。在高冲蚀角下,球形颗粒能很好地模拟冲蚀过程中对材料的剪切和挤压作用。从微观机制上解释了入射角度和入射速度对多颗粒连续冲蚀行为的影响,明确了冲蚀坑的动态冲蚀机理和几何演化规律。

Meaningful Contact Estimates among Children in a Childcare Centre with Applications to Contact Matrices in Infectious Disease Modelling

We present a mathematical model of a day care center in a developed country (such as Canada), in order to use it for the estimation of individual-to-individual contact rates in young age groups and in an educational group setting. In our model, individuals in the population are children (ages 1.5 to 4 years) and staff, and their interactions are modelled explicitly: person-to-person and person-to-environment, with a very high time resolution. Their movement and meaningful contact patterns are simulated and then calibrated with collected data from a child care facility as a case study. We present these calibration results as a first part in the further development of our model for testing and estimating the spread of infectious diseases within child care centers.

同轴式微通道壁面润湿性对微细气泡生成特性的影响规律

微细气泡的生成时间和大小对污水处理的效率具有重要影响。为探究微通道壁面润湿性对微细气泡生成特性的影响,采用两相流水平集的方法模拟研究不同接触角下微细气泡的生成过程。以接触角为主变量,液体流量、气体压强和气体类型为次变量,探究次变量对微细气泡生成时间和脱离体积的影响。设计并制造了同轴式微流控芯片,开展微细气泡生成特性的试验。结果表明接触角在0~180°递增时,微细气泡的生成时间总体呈下降趋势,脱离体积先增加后减小,其中90°接触角为生成时间的分界点和脱离体积的峰值点。此外,3个次变量中液体流量的变化对微细气泡生成特性的影响尤为显著,液体流量越大,其生成时间和脱离体积越小。实测值与仿真值的偏差在正负百分之十以内,验证了微通道壁面润湿性对微细气泡生成特性的影响规律。