A new analytical method is proposed for the determination of heroin based on a sequential perturbation caused by trace amounts of heroin in the Cu(Ⅱ)-catalyzed oscillating reaction between hydrogen peroxide and sodiu...A new analytical method is proposed for the determination of heroin based on a sequential perturbation caused by trace amounts of heroin in the Cu(Ⅱ)-catalyzed oscillating reaction between hydrogen peroxide and sodium thiocyanate in an alkaline medium with the aid of a continuous-flow stirred tank reactor(CSTR). The method relies on the linear relationship between the change in oscillation period of the system and the concentration of heroin, with a detecting limit of 4.0×10^(-7) mol/L. The calibration curve fits a linear equation very well when the concentration of heroin is in the range of 2.0×10^(-6)_1.2×10^(-5) mol/L(r=0.9971). This method features good precision(RSD=0.98%). The influences of temperature, injection point, flow rate and reaction variables on the oscillation period were investigated in detail and a possible mechanism of the performance of heroin in the Cu(Ⅱ)-catalyzed oscillating reaction system is also discussed. The proposed method opens a new avenue for the determination of heroin.展开更多
Due to the disadvantages of complexity,high maintenance and vast investment of the electro-hydraulic servo oscillator,a new mechanical device synchronously driven by double servomotors was proposed. The working princi...Due to the disadvantages of complexity,high maintenance and vast investment of the electro-hydraulic servo oscillator,a new mechanical device synchronously driven by double servomotors was proposed. The working principle of the non-sinusoidal oscillator was analyzed and the model of the oscillator was validated via simulation software.Then,taking advantage of resonance technology,the hinging force and moment were calculated. The results showed that the hinging force and driving moment reduced,which was useful in reducing the impact of the hinge and prolonging the service life of the bearing. Besides,the best initial spring pressure was 0. 9 times the mold gravity,which improved the oscillation system stability and reduced the load fluctuation and servomotor driving power.展开更多
基金Supported by the Project of International Cooperation between China and U kraine(No.0 4 3- 0 5 ) and the Project ofKJCXGC- 0 1Northwest Norm al U niversityChina
文摘A new analytical method is proposed for the determination of heroin based on a sequential perturbation caused by trace amounts of heroin in the Cu(Ⅱ)-catalyzed oscillating reaction between hydrogen peroxide and sodium thiocyanate in an alkaline medium with the aid of a continuous-flow stirred tank reactor(CSTR). The method relies on the linear relationship between the change in oscillation period of the system and the concentration of heroin, with a detecting limit of 4.0×10^(-7) mol/L. The calibration curve fits a linear equation very well when the concentration of heroin is in the range of 2.0×10^(-6)_1.2×10^(-5) mol/L(r=0.9971). This method features good precision(RSD=0.98%). The influences of temperature, injection point, flow rate and reaction variables on the oscillation period were investigated in detail and a possible mechanism of the performance of heroin in the Cu(Ⅱ)-catalyzed oscillating reaction system is also discussed. The proposed method opens a new avenue for the determination of heroin.
基金financially supported by the National Natural Science Foundation of China(51275446, 61503323 )National Natural Science Foundation of China and Baosteel Group Co.,Ltd.(U1260203)Natural Science Foundation of Hebe Province of China(E2016203492)
文摘Due to the disadvantages of complexity,high maintenance and vast investment of the electro-hydraulic servo oscillator,a new mechanical device synchronously driven by double servomotors was proposed. The working principle of the non-sinusoidal oscillator was analyzed and the model of the oscillator was validated via simulation software.Then,taking advantage of resonance technology,the hinging force and moment were calculated. The results showed that the hinging force and driving moment reduced,which was useful in reducing the impact of the hinge and prolonging the service life of the bearing. Besides,the best initial spring pressure was 0. 9 times the mold gravity,which improved the oscillation system stability and reduced the load fluctuation and servomotor driving power.
