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Characteristics of shell thickness in a slab continuous casting mold 被引量:3
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作者 Di-feng Wu Shu-sen Cheng Zi-jian Cheng 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2009年第1期25-31,共7页
The key to reduce shell breakout in the continuous casting process is to control shell thickness in the mold. A numerical simulation on the turbulent flow and heat transfer coupled with solidification in the slab mold... The key to reduce shell breakout in the continuous casting process is to control shell thickness in the mold. A numerical simulation on the turbulent flow and heat transfer coupled with solidification in the slab mold using the volume of fluid (VOF) model and the enthalpy-porosity scheme was conducted and the emphasis was put upon the flow effect on the shell thickness profiles in longitudinal and transverse directions. The results show that the jet acts a stronger impingement on the shell of narrow face, which causes a zero-increase of shell thickness in a certain range near the impingement point. The thinnest shell on the slab cross-section locates primarily in the center of the narrow face, and secondly near the comer of the wide face. Nozzle optimization can obviously increase the shell thickness and make it more uniform. 展开更多
关键词 continuous casting slab mold shell thickness nozzle optimization
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EXACT SOLUTION FOR LAMINATED CONTINUOUSOPEN CYLINDRICAL SHELLS
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作者 盛宏玉 范家让 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI 1997年第11期0-0,0-0+0-0+0-0+0-0+0-0+0-0,共14页
Discarding any assumption about displacement models and stress distribution andintroducing δ-function into the present study, we established the state equation for thecontinuous orthotropic open cylindrical shells. A... Discarding any assumption about displacement models and stress distribution andintroducing δ-function into the present study, we established the state equation for thecontinuous orthotropic open cylindrical shells. An thentical exocl solution is presentedfor the statics of thin. moderately thick and thick laminated continuous openrylindrical shells. Numerical results are obtained and compared with those calculatedusing SAP5. 展开更多
关键词 laminated continuous open cylindrical shell ORTHOTROPY state equation exact solution
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Mold Thermo-Mechanical Rigidity Criterion for Surface Quality of Continuous Casting of Steel 被引量:2
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作者 Mostafa Omar El-Bealy 《Materials Sciences and Applications》 2013年第1期39-51,共13页
A theoretical investigation of heat flow, solidification and solid shell resistance “Ic” has been undertaken by using a mathematical model and previous plant trials. The ultimate purpose is to develop operating cond... A theoretical investigation of heat flow, solidification and solid shell resistance “Ic” has been undertaken by using a mathematical model and previous plant trials. The ultimate purpose is to develop operating conditions and therefore to improve the surface quality for continuously cast steel slabs. A new simple criterion called mold thermomechanical rigidity “MTMR” has been proposed to evaluate and to improve these purposes. The parameters of MTMR and its non-dimensional number which use to control the surface defects are present in this investigation. Previous plant trails of slab surface defects formation have been investigated thermo-mechanically with this criterion. The predications show that this criterion is very sensitive of operating parameters and is a significant qualitative tool to evaluate the surface quality. From examination of the behavior of MTMR, the susceptibility and mechanism of surface defects formations with MTMR have been primarily discussed. 展开更多
关键词 continuous CASTING of Steel Surface Quality Solid shell Resistance
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A Geometrically Exact Triangular Shell Element Based on Reproducing Kernel DMS-Splines
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作者 Hanjiang Chang Qiang Tian Haiyan Hu 《Computer Modeling in Engineering & Sciences》 SCIE EI 2023年第7期825-860,共36页
Tomodel amultibody systemcomposed of shell components,a geometrically exact Kirchho-Love triangular shell element is proposed.The middle surface of the shell element is described by using the DMS-splines,which can ex... Tomodel amultibody systemcomposed of shell components,a geometrically exact Kirchho-Love triangular shell element is proposed.The middle surface of the shell element is described by using the DMS-splines,which can exactly represent arbitrary topology piecewise polynomial triangular surfaces.The proposed shell element employs only nodal displacement and can automatically maintain C1 continuity properties at the element boundaries.A reproducing DMS-spline kernel skill is also introduced to improve computation stability and accuracy.The proposed triangular shell element based on reproducing kernel DMS-splines can achieve an almost optimal convergent rate.Finally,the proposed shell element is validated via three static problems of shells and the dynamic simulation of aexible multibody system undergoing both overall motions and large deformations. 展开更多
关键词 DMS-splines reproducing kernel kirchhoff-love shell C^(1)continuity multibody system dynamics
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基于改进拟连续算法的回转弹仓位置控制
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作者 陈冬 钱林方 +3 位作者 陈志群 陈龙淼 邹权 陈军华 《兵工学报》 EI CAS CSCD 北大核心 2024年第5期1436-1448,共13页
为提高大口径火炮自动装填过程中回转弹仓工作的精确性和鲁棒性,在分析现有拟连续算法相关研究内容的基础上,设计一种全新的改进拟连续控制器对回转弹仓进行位置控制。通过与滑模扰动观测器相结合,新控制器增益不依赖于系统扰动的不确... 为提高大口径火炮自动装填过程中回转弹仓工作的精确性和鲁棒性,在分析现有拟连续算法相关研究内容的基础上,设计一种全新的改进拟连续控制器对回转弹仓进行位置控制。通过与滑模扰动观测器相结合,新控制器增益不依赖于系统扰动的不确定性边界,且不需引入额外的控制器参数,降低了控制器的设计和调试难度。通过Lyapunov方程验证控制器本身及闭环系统的稳定性。仿真和试验结果表明:新设计的控制器相对于已有拟连续算法具有优越性,在受到不确定时变负载和不确定参数扰动的情况下,新设计的改进控制器在应用于回转弹仓时,在趋近段可以获得更快的收敛速度,减小到位超调量,并在滑动段有效减弱抖振。 展开更多
关键词 回转弹仓 不确定扰动 改进拟连续控制器 滑模扰动观测器
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钛合金室温受压蠕变损伤本构模型
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作者 郭育豪 刘刚 宋育泽 《哈尔滨工程大学学报》 EI CAS CSCD 北大核心 2024年第4期642-650,共9页
为了解决工程上在评估深潜器耐压壳体安全可靠性时不考虑拉压蠕变破坏机理产生的差异,会导致较大计算误差问题,本文提出了适用于室温蠕变的蠕变损伤本构模型。通过分析钛合金材料蠕变特性,考虑了室温环境下位错堆积造成的蠕变阻力,并且... 为了解决工程上在评估深潜器耐压壳体安全可靠性时不考虑拉压蠕变破坏机理产生的差异,会导致较大计算误差问题,本文提出了适用于室温蠕变的蠕变损伤本构模型。通过分析钛合金材料蠕变特性,考虑了室温环境下位错堆积造成的蠕变阻力,并且位错堆积的现象与时间有关。基于微分自洽法提出了适用于室温环境下的钛合金蠕变本构模型,得到受压情况下TC4ELI的相关材料参数,并将该模型用USDFLD和CREEP子程序进行定义。研究表明:对于受压结构而言,使用通过拉伸蠕变实验得到的本构模型的计算结果会过于保守,对于含V型缺口平板受压时等效蠕变应变的相对误差为168.20%。本文所提出的模型适用于环肋耐压壳结构的蠕变损伤分析。 展开更多
关键词 钛合金 室温蠕变 蠕变损伤 本构模型 拉压不同 连续损伤力学 有限元法 耐压壳
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不同引发体系合成有机硅-聚苯乙烯核壳结构微球的研究
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作者 张镇鹏 刘美意 马凤国 《有机硅材料》 CAS 2024年第4期37-41,共5页
以羟基硅油、苯乙烯为主要原料,采用半连续乳液聚合方法制得具有核壳结构的有机硅-聚苯乙烯聚合物乳液,将其进行喷雾干燥制得聚合物粉末,考察了3种不同引发体系对聚合物乳液稳定性和单体转化率的影响,并对其进行了红外光谱、透射电子显... 以羟基硅油、苯乙烯为主要原料,采用半连续乳液聚合方法制得具有核壳结构的有机硅-聚苯乙烯聚合物乳液,将其进行喷雾干燥制得聚合物粉末,考察了3种不同引发体系对聚合物乳液稳定性和单体转化率的影响,并对其进行了红外光谱、透射电子显微镜分析。结果表明,3种引发体系均成功合成了有机硅-聚苯乙烯共聚物,且制得的聚合物乳液有较明显的核壳结构和较好的稳定性;采用过硫酸铵、亚硫酸氢钠和过氧化二苯甲酰组成的复合引发体系(APS+NaHSO3+BPO)制备的聚合物乳液单体转化率最高,可达93.24%。对由APS+NaHSO3+BPO复合引发体系制备的聚合物粉末进行了扫描电镜和热失重表征,结果显示,在-50~180℃内有机硅-聚苯乙烯粉末没有明显的失重峰,在500~580℃区间内,粉末热失重达61.91%,表明该聚合物具有良好的耐高低温性能,可在较宽温度范围内使用并仍旧保持良好的性能。 展开更多
关键词 半连续 乳液聚合 引发体系 核壳结构 微球粉末 有机硅 聚苯乙烯
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大跨度小曲线半径转体连续梁钢壳合龙技术
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作者 沈耀海 《石家庄铁路职业技术学院学报》 2024年第2期44-48,共5页
转体连续梁在既有铁路上方合龙施工时采用钢壳法,不但便于施工、费用较低,而且钢模板可作为结构的一部分无需拆除,极大提高了施工效率、降低了施工风险。本文以新建安九铁路孔垄上行联络线上跨既有京九线(72+128+72)m转体连续梁施工为背... 转体连续梁在既有铁路上方合龙施工时采用钢壳法,不但便于施工、费用较低,而且钢模板可作为结构的一部分无需拆除,极大提高了施工效率、降低了施工风险。本文以新建安九铁路孔垄上行联络线上跨既有京九线(72+128+72)m转体连续梁施工为背景,介绍了大跨度、小曲线半径、低净空、施工天窗点有限等控制条件下的中跨合龙段钢壳设计、计算及施工方案。该方案的顺利实施,对今后类似工程有很好的参考借鉴意义。 展开更多
关键词 大跨度 小曲线半径 转体连续梁 钢壳合龙技术
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Vibration and Buckling Approximation of an Axially Loaded Cylindrical Shell with a Three Lobed Cross Section Having Varying Thickness
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作者 Mousa Khalifa Ahmed 《Applied Mathematics》 2011年第3期329-342,共14页
On the basis of the thin-shell theory and on the use of the transfer matrix approach, this paper presents the vibrational response and buckling analysis of three-lobed cross-section cylindrical shells, with circumfere... On the basis of the thin-shell theory and on the use of the transfer matrix approach, this paper presents the vibrational response and buckling analysis of three-lobed cross-section cylindrical shells, with circumferentially varying thickness, subjected to uniform axial membrane loads. A Fourier approach is used to separate the variables, and the governing equations of the shell are formulated in terms of eight first-order differential equations in the circumferential coordinate, and by using the transfer matrix of the shell, these equations are written in a matrix differential equation. The transfer matrix is derived from the non-linear differential equations of the cylindrical shells with variable thickness by introducing the trigonometric series in the longitudinal direction and applying a numerical integration in the circumferential direction. The natural frequencies and critical loads beside the mode shapes are calculated numerically in terms of the transfer matrix elements for the symmetrical and antisymmetrical vibration modes. The influences of the thickness variation of cross- section and radius 展开更多
关键词 Free VIBRATION BUCKLING VIBRATION of continuous System Noncircular Cylindrical shell Transfer Matrix Approach Variable Thickness AXIAL Loads
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中国黄海湿地博物馆结构设计 被引量:1
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作者 徐晓明 张士昌 +5 位作者 史炜洲 潘钦 倪萍 侯双军 崔家春 巫燕贞 《建筑结构》 北大核心 2023年第1期29-35,共7页
中国黄海湿地博物馆在原盐城火车站基础上进行改建,下部结构采用框架+BRB结构,上部屋盖采用大跨度桁架加强网壳结构。对大跨度屋盖选型优化进行了简化模型对比分析,对格构柱底铰接、刚接方案进行了讨论,对超限判断和应对措施、钢屋盖整... 中国黄海湿地博物馆在原盐城火车站基础上进行改建,下部结构采用框架+BRB结构,上部屋盖采用大跨度桁架加强网壳结构。对大跨度屋盖选型优化进行了简化模型对比分析,对格构柱底铰接、刚接方案进行了讨论,对超限判断和应对措施、钢屋盖整体稳定和抗连续倒塌能力、下部主体结构加固方案进行了介绍。结果表明:桁架加强网壳结构结合了桁架和网壳结构的优势,钢屋盖整体稳定性能和抗连续倒塌性能均较好。马鞍形屋面相比平屋面,竖向和水平刚度均大很多,结构设计时充分利用桁架加强网壳结构和马鞍形造型的优势,实现了用较小的结构高度实现大跨空间。 展开更多
关键词 中国黄海湿地博物馆 大跨空间结构 桁架加强网壳结构 整体稳定 抗连续倒塌 拱脚推力 结构加固
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Heat Transfer and Deformation Behavior of Shell Solidification in Wide and Thick Slab Continuous Casting Mold 被引量:4
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作者 Jing-xin SONG Zhao-zhen CAI +1 位作者 Feng-yun PIAO Miao-yong ZHU 《Journal of Iron and Steel Research(International)》 SCIE EI CAS CSCD 2014年第S1期1-9,共9页
With the considerations of the behaviors of shell deformation, mold flux film and air gap dynamic distribution in shell/mold gap, a two dimensional slice-travel transient thermo-mechanical coupled model of simulation ... With the considerations of the behaviors of shell deformation, mold flux film and air gap dynamic distribution in shell/mold gap, a two dimensional slice-travel transient thermo-mechanical coupled model of simulation shell solidification in wide and thick slab continuous casting mold was developed by using the commercial program ANSYS. The evolutions of strand-mold system thermal behaviors, including the air gap formation and the mold flux film dynamical distribution in shell/mold gap and shell temperature field, and the evolutions of shell deformation and stress distribution of peritectic steel solidified in a 2120 mm wide and 266 mm thick slab continuous casting mold were analyzed. The results show that the air gap formation and the thick mold flux film distribution mainly concentrate in the regions 0–21 mm and 0–7 mm, 0–120 mm and 0–100 mm off the shell wide and narrow faces corners, and thus the hot spots are given rise to form in the regions 15–55 mm and 15–50 mm off the shell wide and narrow face corners. The shell server deformation occurs in the off-corners in the middle and lower parts of the mold. The stress evolution in shell surface is tensile stress, while that in shell solidification front is compressive stress. 展开更多
关键词 continuous casting mold heat transfer shell deformation air gap numerical simulation
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Growth of solidified shell in bloom continuous casting mold of hypo-peritectic steel based on a FeS tracer method 被引量:5
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作者 Da-peng Li Hua-zhang Wu +1 位作者 Hai-feng Wang Hong Li 《Journal of Iron and Steel Research(International)》 SCIE EI CAS CSCD 2020年第7期782-787,共6页
Solidification behavior in the mold region plays an important role in production efficiency and steel quality.To investigate shell growth within a mold,the sulfur prints of the entire shell thickness profile the menis... Solidification behavior in the mold region plays an important role in production efficiency and steel quality.To investigate shell growth within a mold,the sulfur prints of the entire shell thickness profile the meniscus to 100 mm below the mold were obtainedadding FeS tracer into molten steel during bloom continuous casting of hypo-peritectic steel.The law of shell thickness evolution along mold height and circumference was analyzed.The results show that there are three weak regions of solidification,which are in the mold upper part,in the mold lower part,and just below mold exit,possibly resulting periodic fluctuation of air gap between the shell and the mold,the impingement of melt jets on the solidification front,and the decreasing cooling intensity,respectively.Initial solidification point along casting direction appears at approximately 35 mm below the meniscus.Overall,the solidified shell thickness in the inner side of the mold is a little larger than that in the outer side,and the former and the latter reach 25.5 and 24.3 mm at the mold exit,respectively.The non-uniform shell growth in the inner side of the bloom is provided,while shell thicknesses in the narrow face and the outer side follow relatively regular growth.Out of the mold,the thinnest shells on the transverse section exist in the regions of 60&ndash;90 mm and 40&ndash;70 mm the corners of the inner and outer sides,respectively,i.e.,the of-corners. 展开更多
关键词 continuous casting MOLD Hypo-peritectic steel Solidified shell Sulfur print
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Numerical Simulation on Inclusion and Bubble Entrapment in Solidified Shell in Model Experiment and in Mold of Continuous Caster With DC Magnetic Field 被引量:1
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作者 Yuji Miki Hiroyuki Ohno +2 位作者 Yasuo Kishimoto Kohei Furumai Shinya Tanaka 《Journal of Iron and Steel Research(International)》 SCIE EI CAS CSCD 2012年第S2期853-857,共5页
A model experiment investigating entrapment of inclusions and bubbles on the solidified shell was performed using molten steel,and the conditions for inclusion and bubble entrapment and mechanism of entrapment were st... A model experiment investigating entrapment of inclusions and bubbles on the solidified shell was performed using molten steel,and the conditions for inclusion and bubble entrapment and mechanism of entrapment were studied. The results were applied to the flow behavior in the casting mold of a continuous caster.At the solid-liquid interface, entrapment of inclusions is greatly reduced by the existence of a low velocity flow,e.g.,0.05m/s.The above-mentioned interfacial flow velocity dependency of inclusion entrapment is considered to be largely influenced by changes in the thickness of the concentration boundary layer,which depend on the interfacial flow velocity.Specifically,bubbles and inclusions which enter the concentration boundary layer are drawn to the solid-liquid interface by a suction force which is several orders larger than the Saffman's force.In addition to the above-mentioned suction force,the so-called cleaning effect is determined by fluid-dynamic forces such as drag force,etc.which act on particles,and furthermore,by resident time of particles at the solid-liquid interface,which depends on the solidification rate.In a FC mold with a 2-stage electromagnetic brake,flotation of bubbles entrained in the jet flow from the nozzle is accelerated with the large DC magnetic field.This is attributed to the braking effect of the DC field on the nozzle jet and the upward flow by the buoyancy of the bubbles.As a result,the interfacial flow velocity can be normalized by increasing the strength of the magnetic field,and entrapment of large bubbles and inclusions can be reduced. 展开更多
关键词 continuous casting MOLD molten steel numerical simulation flow solidified shell surface defect INCLUSION BUBBLE ENTRAPMENT interfacial tension electromagnetic field
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转体连续梁桥钢壳合龙技术研究
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作者 刘显晖 张浩阳 +2 位作者 梁欢 李建强 杨帆 《城市道桥与防洪》 2023年第10期62-64,94,M0008,共5页
随着我国跨线桥梁的逐渐增多,传统的跨线施工不可避免的对既有线路产生一定的影响。钢壳合龙技术能够有效避免对既有线路的影响,可以保证既有线路安全运营,非常适合于预应力混凝土结构合龙段施工。以新建福厦铁路漳州下行联络线特大桥... 随着我国跨线桥梁的逐渐增多,传统的跨线施工不可避免的对既有线路产生一定的影响。钢壳合龙技术能够有效避免对既有线路的影响,可以保证既有线路安全运营,非常适合于预应力混凝土结构合龙段施工。以新建福厦铁路漳州下行联络线特大桥为依托,简述了钢壳合龙技术的构成、加工以及安装,运用大型有限元软件Ansys建立了中跨合龙段钢壳的有限元模型,分析出合龙段钢壳在混凝土浇筑过程中的应力应变情况,为指导合龙段混凝土施工以及桥梁顺利合龙提供依据。 展开更多
关键词 转体连续梁桥 钢壳合龙技术 有限元模拟 应力分析
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某超长异形曲面单层网壳结构设计与分析
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作者 沈金 王俊 +1 位作者 王成志 林巍 《建筑结构》 北大核心 2023年第20期33-39,共7页
秦皇河国家湿地修复及保护技术中心包含四季植物温室、接待中心、综合服务中心、湿地修复展厅、植物科普体验馆(城市展厅)、设备用房以及室外灰空间等。5个单体通过一个自由曲面的大跨度屋盖连成整体,上部为大跨单层钢网壳屋盖,下部为... 秦皇河国家湿地修复及保护技术中心包含四季植物温室、接待中心、综合服务中心、湿地修复展厅、植物科普体验馆(城市展厅)、设备用房以及室外灰空间等。5个单体通过一个自由曲面的大跨度屋盖连成整体,上部为大跨单层钢网壳屋盖,下部为钢筋混凝土框架。本工程存在超长、异形、大跨等复杂情况,设计时进行多软件复核计算、抗震性能化设计、抗连续倒塌验算、网壳非线性稳定及支座刚度敏感性分析、复杂构件及节点细部有限元分析等计算分析并采取合理的构造措施,保证整体结构的工作性能和结构的经济性。 展开更多
关键词 超长异形曲面结构 单层网壳 大跨度屋盖 非线性稳定 抗震性能化设计 抗连续倒塌
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高铁连续梁转体不锈钢壳合龙施工技术
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作者 丁进福 《价值工程》 2023年第31期78-81,共4页
高铁连续梁转体跨越既有铁路、公路、市政道路等立交结构物为首选施工技术,转体的跨度、宽度、吨位、角度等不断在刷新记录,高铁转体上跨既有铁路因纵坡、限界、净高等影响,梁底与接触网承力索距离极其有限,如何在这样的条件下安全可靠... 高铁连续梁转体跨越既有铁路、公路、市政道路等立交结构物为首选施工技术,转体的跨度、宽度、吨位、角度等不断在刷新记录,高铁转体上跨既有铁路因纵坡、限界、净高等影响,梁底与接触网承力索距离极其有限,如何在这样的条件下安全可靠进行合龙,是需要解决的难题。依托南玉铁路福庆特大桥跨湘桂铁路双线转体实践,首次采用不锈钢壳合龙技术,较好解决了上跨既有铁路转体桥中合龙施工、钢壳生锈、安装困难等难题,为类似转体桥中跨合龙施工提供了新的解决方案,是一种技术创新,推广价值较高。 展开更多
关键词 高铁连续梁 转体施工 不锈钢壳 合龙 技术应用
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半固态连铸过程的滞留层尺寸预测 被引量:4
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作者 邢书明 曾大本 +3 位作者 胡汉起 翟启杰 马静 李亚敏 《中国有色金属学报》 EI CAS CSCD 北大核心 2000年第6期800-803,共4页
通过对凝固层的受力分析 ,提出了滞留层初期尺寸的预测模型及定量计算方法 ,并据此分析了各工艺因素的影响趋势。结果表明 ,在通常范围内增加结晶器直径或减小其长度、提高凝固系数或提高结晶器内的纵向温度梯度、减小拉坯速度、降低制... 通过对凝固层的受力分析 ,提出了滞留层初期尺寸的预测模型及定量计算方法 ,并据此分析了各工艺因素的影响趋势。结果表明 ,在通常范围内增加结晶器直径或减小其长度、提高凝固系数或提高结晶器内的纵向温度梯度、减小拉坯速度、降低制浆室高度、改善结晶器润滑 ,都可以提高初期裂口的形成位置 ,减小滞留尺寸 ,进而有利于提高半固态连铸过程的稳定性。验证实验表明 ,这一预测模型的误差在 5 %~ 10 展开更多
关键词 半固态金属 连铸 滞留层 尺寸预测 半固态连铸
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316不锈钢板坯连铸结晶器内坯壳厚度模拟 被引量:14
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作者 邢淑清 白亮 +2 位作者 麻永林 李慧琴 冯佃臣 《铸造技术》 CAS 北大核心 2010年第7期910-913,共4页
为研究连铸过程中高温区δ铁素体含量对凝固传热的影响,采用商业有限元软件ANSYS,利用单元生死技术,对316不锈钢板坯的浇注过程进行了模拟。采用2-D模型,分别计算了δ铁素体含量为0、25%、50%、75%及100%时坯壳出口温度、坯壳厚度及表... 为研究连铸过程中高温区δ铁素体含量对凝固传热的影响,采用商业有限元软件ANSYS,利用单元生死技术,对316不锈钢板坯的浇注过程进行了模拟。采用2-D模型,分别计算了δ铁素体含量为0、25%、50%、75%及100%时坯壳出口温度、坯壳厚度及表面温度的变化,探讨了坯壳生长及厚度变化规律。结果表明,随着δ铁素体含量升高,坯壳出口温度升高,表面温度变化剧烈,坯壳的出口厚度减薄。 展开更多
关键词 316不锈钢 连铸 结晶器 坯壳厚度 数值模拟
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核壳结构含氟丙烯酸酯乳液的制备 被引量:10
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作者 朱长健 陈松林 +1 位作者 王嵩 聂康明 《安徽大学学报(自然科学版)》 CAS 北大核心 2010年第1期82-86,共5页
采用预乳化-半连续滴加法合成以甲基丙烯酸甲酯(MMA)和丙烯酸丁酯(BA)为核,以含氟单体和前二者进行复配预乳化滴加聚合得到具有核壳结构的氟丙乳液.研究了乳化剂用量及配比、交联单体(HEMA)用量、含氟单体用量对核壳聚合过程稳定性的影... 采用预乳化-半连续滴加法合成以甲基丙烯酸甲酯(MMA)和丙烯酸丁酯(BA)为核,以含氟单体和前二者进行复配预乳化滴加聚合得到具有核壳结构的氟丙乳液.研究了乳化剂用量及配比、交联单体(HEMA)用量、含氟单体用量对核壳聚合过程稳定性的影响.结果表明:随着含氟单体用量的增加,乳胶膜的耐水性、热稳定性以及耐溶剂性都有明显提高. 展开更多
关键词 预乳化 半连续 核壳结构
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圆坯连铸结晶器温度场模拟与坯壳厚度预测 被引量:8
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作者 姚曼 詹慧英 +4 位作者 王旭东 郭亮亮 尹合壁 刘晓 于艳 《北京科技大学学报》 EI CAS CSCD 北大核心 2007年第11期1091-1095,共5页
基于连铸圆坯结晶器温度与热流实测数据,建立了连铸圆坯凝固的三维传热模型,计算出结晶器和铸坯的温度场,并得到铸坯的固相率与坯壳厚度分布情况.温度计算结果与实测数据符合较好,表明此数学模型能够较为准确地反映实际情况.讨论了拉速... 基于连铸圆坯结晶器温度与热流实测数据,建立了连铸圆坯凝固的三维传热模型,计算出结晶器和铸坯的温度场,并得到铸坯的固相率与坯壳厚度分布情况.温度计算结果与实测数据符合较好,表明此数学模型能够较为准确地反映实际情况.讨论了拉速、浇注温度等因素对坯壳厚度的影响,并对利用模型计算与经验公式计算得到的坯壳厚度进行了对比. 展开更多
关键词 连铸 圆坯 坯壳 温度场 数值模拟
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