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Combining controlled-release urea and normal urea with appropriate nitrogen application rate to reduce wheat stem lodging risk and increase grain yield and yield stability
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作者 ZHANG Guang-xin ZHAO De-hao +3 位作者 FAN Heng-zhi LIU Shi-ju LIAO Yun-cheng HAN Juan 《Journal of Integrative Agriculture》 SCIE CAS CSCD 2023年第10期3006-3021,共16页
A mixture of controlled-release urea and normal urea(CRUNU)is an efficient nitrogen(N)fertilizer type,but little is known about its effects on stem lodging resistance,grain yield,and yield stability of wheat.In this s... A mixture of controlled-release urea and normal urea(CRUNU)is an efficient nitrogen(N)fertilizer type,but little is known about its effects on stem lodging resistance,grain yield,and yield stability of wheat.In this study,a 4-year field experiment(from 2017 to 2021)was conducted to analyze the effects of N fertilizer types(CRUNU and normal urea(NU))and application rates(low level(L),135 kg ha^(–1);medium level(M),180 kg ha^(–1);high level(H),225 kg ha^(–1))on population lodging resistance,basal internode strength,lignin content and synthetase activity,stem lodging resistance,grain yield,and yield stability of wheat.Our results showed that the two N fertilizer types had the highest lodging rate under high N application rates,and the M-CRUNU treatment showed the lowest lodging rate.Compared with NU,CRUNU improved the wheat population lodging resistance under the three N application rates,mainly related to improving wheat population characteristics and breaking the strength of the second basal internode.Correlation analysis showed that the breaking strength of the second basal internode was related to the physical characteristics,chemical components,and micro-structure of the internode.Compared with NU,CRUNU significantly increased wheat grain yield by 4.47,14.62,and 3.12%under low,medium,and high N application rates,respectively.In addition,CRUNU showed no significant difference in grain yield under medium and high N application rates,but it presented the highest yield stability under the medium N application rate.In summary,CRUNU,combined with the medium N application rate,is an efficient agronomic management strategy for wheat production. 展开更多
关键词 controlled-release urea LODGING grain yield yield stability wheat
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Synthesis and Performance of Polyurethane Coated Urea as Slow/controlled Release Fertilizer 被引量:10
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作者 李青山 WU Shu +3 位作者 RU Tiejun 王利民 XING Guangzhong WANG Jinming 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2012年第1期126-129,共4页
Polyurethane coated urea slow/controlled release fertilizer was prepared based on urea granules, isocyanate, polyols and paraffin. Isocyanate reacted with polyols to synthesize the polyurethane skin layer on urea gran... Polyurethane coated urea slow/controlled release fertilizer was prepared based on urea granules, isocyanate, polyols and paraffin. Isocyanate reacted with polyols to synthesize the polyurethane skin layer on urea granules surface. Paraffin serves as a lubricant during syntheses of polyurethane skin layers. The structure and nutrient release characteristics of the polyurethane skin layers were investigated by FTIR, SEM and TG. Urea nitrogen slow-release behavior of the polyurethane coated urea was tested. The experimental results indicated that compact and dense polyurethane skin layers with a thickness of 10-15 lam were formed on urea surface, the urea nitrogen slow-release time can reach 40-50 days. Paraffin proves to play a key role in inhibiting water to penetrate into urea, but excessive addition would decrease the polyurethane crosslinking density. 展开更多
关键词 polyurethane elastomer coated urea slow / controlled release fertilizer PARAFFIN
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Shifts in soil bacterial communities induced by the controlled-release fertilizer coatings 被引量:7
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作者 PAN Pan JIANG Hui-min +5 位作者 ZHANG Jian-feng YANG Jun-cheng LI Shu-shan LIU Lian ZHANG Shui-qin LEI Mei 《Journal of Integrative Agriculture》 SCIE CAS CSCD 2016年第12期2855-2864,共10页
Coated controlled-release fertilizers (CRFs) have been widely applied in agriculture due to their increased efficiency. However, the widespread and a lot of coated CRFs application may leave undesired coating residu... Coated controlled-release fertilizers (CRFs) have been widely applied in agriculture due to their increased efficiency. However, the widespread and a lot of coated CRFs application may leave undesired coating residues in the soil due to their slow degradation. Limited information is available on the effects of substantial residual coatings on the soil bacterial community. By adding 0, 5, 10, 20, and 50 times quantities of residual coating from conventional application amount of resin and water-soluble coated CRFs, we studied the responses of soil properties and bacterial community composition to these two residual coatings in black soil. The results showed that the resin and water-soluble coatings did not essentially alter the properties of black soil or cause dramatic changes to bacterial diversity within the test concentration range. The residual resin and water-soluble coatings also did not distinctly alter the relative abundance of the top ten bacteria at phylum level. Heatmap results suggested that the treatments were basically clustered into two groups by concentration rather than types of coating material. Pearson correlation analysis showed that the Simpson's diversity index of the bacterial community was significantly correlated with microbial biomass carbon (MBC, r=0.394, P〈0.05), and the richness index abundance-based coverage estimator (ACE) of the bacterial community was significantly correlated with microbial biomass nitrogen (MBN, t=0.407, P〈0.05). Overall, results of this study suggested that substantial residual resin and water-soluble coatings with 0-50 times quantities of residual coating from conventional application amount of coated CRFs did not generate obviously negative impacts on the bacterial community in black soil. 展开更多
关键词 soil bacterial community controlled-release fertilizer residual coatings 454 pyrosequencing
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Nitrogen Cycling and Losses Under Rice-Wheat Rotations with Coated Urea and Urea in the Taihu Lake Region 被引量:32
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作者 WANG Xiao-Zhi ZHU Jian-Guo +2 位作者 GAO Ren H. YASUKAZU FENG Ke 《Pedosphere》 SCIE CAS CSCD 2007年第1期62-69,共8页
A lysimeter experiment with undisturbed soil profiles was carried out to study nitrogen cycling and losses in a paddy soil with applications of coated urea and urea under a rice-wheat rotation system in the Taihu Lake... A lysimeter experiment with undisturbed soil profiles was carried out to study nitrogen cycling and losses in a paddy soil with applications of coated urea and urea under a rice-wheat rotation system in the Taihu Lake region from 2001 to 2003. Treatments for rice and wheat included urea at conventional, 300 (rice) and 250 (wheat) kg N ha-1, and reduced levels, 150 (rice) and 125 (wheat) kg N ha-1, coated urea at two levels, 100 (rice) and 75 (wheat) kg N ha-1, and 150 (rice) and 125 (wheat) kg N ha-1, and a control with no nitrogen arranged in a completely randomized design. The results under two rice-wheat rotations showed that N losses through both NH3 volatilization and runoff in the coated urea treatments were much lower than those in the urea treatments. In the urea treatments N runoff losses were significantly (P < 0.001) positively correlated (r = 0.851) with applied N. N concentration in surface water increased rapidly to maximum two days after urea application and then decreased quickly. However, if there was no heavy rain within five days of fertilizer application, the likelihood of N loss by runoff was not high. As the treatments showed little difference in N loss via percolation, nitrate N in the groundwater of the paddy fields was not directly related to N leaching. The total yield of the two rice-wheat rotations in the treatment of coated urea at 50% conventional level was higher than that in the treatment of urea at the conventional level. Thus, coated urea was more favorable to rice production and environmental protection than urea. 展开更多
关键词 循环系统 小麦 尿素 地域性
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Increase in yield and nitrogen use efficiency of double rice with long-term application of controlled-release urea 被引量:1
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作者 TIAN Chang SUN Ming-xue +4 位作者 ZHOU Xuan LI Juan XIE Gui-xian YANG Xiang-dong PENG Jian-wei 《Journal of Integrative Agriculture》 SCIE CAS CSCD 2022年第7期2106-2118,共13页
Controlled-release urea(CRU)has better characteristics than conventional urea for synchronizing nitrogen(N)release with plant uptake.Understanding the effects of CRU on crop yield and N use efficiency(NUE)has long bee... Controlled-release urea(CRU)has better characteristics than conventional urea for synchronizing nitrogen(N)release with plant uptake.Understanding the effects of CRU on crop yield and N use efficiency(NUE)has long been the key to evaluate the performance of CRU.A long-term experiment over five consecutive years was conducted in Changsha,Hunan Province,China,to investigate the effects of polyethylene-coated urea with a 90-d release period on the yield and NUE of double rice(early and late crops are grown in the same year),the amount of residual soil mineral N and the soil–plant N balance,as well as on the economic benefits.Four N fertilizer treatments including CK(no N fertilizer),U(conventional urea),CRU1(polyethylene-coated urea with equal N application rate to U)and CRU2(20%reduction in N application rate of CRU1)were established.The results indicated that CRU1 application increased the yield and NUE of double rice by 11.0 and 13.5%,respectively,compared with U.Higher yield and NUE of late rice were found than in early rice in CRU treatments.Compared with conventional U,the yield and NUE of early rice in the CRU1 treatment were increased by 6.0 and 10.2%,respectively,and those of late rice were increased by 15.4 and 13.8%,respectively.There was no significant difference between CRU1 and CRU2 in double rice yield.Furthermore,CRU treatments(including CRU1 and CRU2)had higher apparent residual Nmin rate(ARNR)and apparent N recovery rate(ANRR),but lower apparent N loss(NS)than the conventional U treatment.Concentrations of NH_(4)^(+)-N and NO_(3)^(-)-N were greater in the surface soil(0–20 cm)and lower in the deeper soil layer(40–60 cm)with CRU treatments than in the U treatment after harvest.Moreover,CRU application produced a greater economic benefit than conventional U application.In general,CRU outperformed U fertilizer in terms of rice yield,NUE,soil–plant N balance,economic benefit,and CRU2 provided greater comprehensive benefits than CRU1.It is suggested that CRU application is beneficial for solving N management challenges in the production of rice. 展开更多
关键词 controlled-release urea RICE YIELD nitrogen use efficiency
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The Production of Organic-Inorganic Compound Film-Coated Urea and the Characteristics of Its Nutrient Release 被引量:6
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作者 ZOU Hong-tao, WANG Yao-sheng, SONG Hao-wen, HAN Yan-yu, YU Na, ZHANG Yu-ling, DANG Xiu-li, HUANG Yi and ZHANG Yu-long College of Land and Environmental Sciences, Shenyang Agricultural University/Liaoning Key Laboratory of Agricultural Resources and Environment/Northeast Key Laboratory of Soil and Environment, Ministry of Agriculture, Shenyang 110161, P.R.China 《Agricultural Sciences in China》 CSCD 2009年第6期703-708,共6页
The effect of different concentrations of natural macromolecular compound on the characteristics of nutrient release in the membrane materials of organic-inorganic compound film-coated urea was discussed, and the opti... The effect of different concentrations of natural macromolecular compound on the characteristics of nutrient release in the membrane materials of organic-inorganic compound film-coated urea was discussed, and the optimal concentrations for better nutrient release was proposed. The characteristics of nutrient release of film-coated urea were evaluated by soil column leaching experiment. Organic-inorganic compound film-coated urea showed good characteristics of nutrient release, which could be well simulated by Logistic curve. The two parameters in this curve, a and r, can be used to present nutrient release of film-coated urea, and followed the order of B 〉 C 〉 A and C 〈 B 〈 A, respectively, indicating that the release was stronger with the increasing concentration of natural macromolecular compound in the membrane, which implied better controllability of nutrient release. The concentration of 5% of natural macromolecular compound showed better characteristic of nutrient release and can be utilized as a membrane material combined with inorganic mineral powders to develop film-coated slow-release fertilizer. 展开更多
关键词 organic-inorganic compound film-coated urea nutrient release characteristics
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Release Kinetics of Urea from Polymer Coated Urea and Its Relationship with Coating Penetrability
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作者 ZHANG Hai-jun, WU Zhi-jie, CHEN Li-jun and LIANG Wen-ju(Institute of Applied Ecology , Chinese Academy of Sciences , Shenyang 110016 , P. R. China) 《Agricultural Sciences in China》 CAS CSCD 2003年第11期1232-1238,共7页
Four kinds of polymer coated urea(PCU)were put in distilled water at 30℃ to determine the variation of coating penetrability and give a precise description of the urea release kinetics. The urea release from PCU coul... Four kinds of polymer coated urea(PCU)were put in distilled water at 30℃ to determine the variation of coating penetrability and give a precise description of the urea release kinetics. The urea release from PCU could be divided into four stages: lag stage, swell stage, steady stage and decay stage. The release rate coefficient K, a measure of coating penetrability, was linearly increased at swell stage, but almost not variable at steady stage. At decay stage, the relation of X to time t could be described by the equation K= mtn-1where m and n are the coefficients). When n>1, the coating penetrability was gradually increased, and the urea release from PCU was accelerated; when n=1, the coating penetrability was steady, and the urea release from PCU obeyed the first-order kinetics; and when n<1.the coating penetrability was gradually decreased, and the urea release from PCU was delayed, resulting in a significant 'tailing effect'. 展开更多
关键词 Polymer coated urea urea release kinetics coating penetrability FITTING
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Kinetic of Adsorption of Urea Nitrogen onto Chitosan Coated Dialdehyde Cellulose under Catalysis of Immobilized Urease
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作者 ZuPeiLIANG YaQingFENG ZhiYanLIANG ShuXianMENG 《Chinese Chemical Letters》 SCIE CAS CSCD 2005年第5期697-700,共4页
关键词 ADSORPTION KINETIC urea nitrogen chitosan coated dialdehyde cellulose immobilized urease.
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Study on Membrane Microstructures and Characteristics of Infrared Spectra and Nitrogen Release of Solid-Liquid Reaction Coated Urea
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作者 MAOXiao-yun FENGXin WANGDe-han SUNKe-jun LIAOZong-wen 《Agricultural Sciences in China》 CAS CSCD 2004年第10期754-763,共10页
The membrane microstructures and the mechanism of two coated ureas formed through solid- liquid reaction were observed by scanning electron microscope and infrared spectra, the relation of the structural characteris... The membrane microstructures and the mechanism of two coated ureas formed through solid- liquid reaction were observed by scanning electron microscope and infrared spectra, the relation of the structural characteristics with the nitrogen release feature was also discussed by combining with nitrogen dissolution in water. The results showed that the membranes were made of solid particles tightly connected to each other and were piled up layer by layer through liquid glue. Porosity and aperture of membrane were determined by compactness of piled layers and the particles in a single layer and also related to the characteristics of coating materials. Research of the infrared spectra of membrane, made of a solid powder and a liquid glue, proved that O-H on the solid surface was bonded with the double bond of the liquid glue, thus forming membrane and keeping it stable. It was found that the two coated ureas showed obvious differences in nitrogen releasing due to their membrane structures, the porosity and aperture of membrane were the critical factors for nitrogen releasing. 展开更多
关键词 coated urea MEMBRANE Scanning eletron microscope Infrared spectra Characte- ristics of nitrogen release
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Strip deep rotary tillage combined with controlled-release urea improves the grain yield and nitrogen use efficiency of maize in the North China Plain
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作者 HAN Yu-ling GUO Dong +5 位作者 MA Wei GE Jun-zhu LI Xiang-ling Ali Noor MEHMOOD ZHAO Ming ZHou Bao-yuan 《Journal of Integrative Agriculture》 SCIE CAS CSCD 2022年第9期2559-2576,共18页
Inappropriate tillage practices and nitrogen(N) management have become seriously limitations for maize(Zea mays L.) yield and N use efficiency(NUE) in the North China Plain(NCP). In the current study, we examined the ... Inappropriate tillage practices and nitrogen(N) management have become seriously limitations for maize(Zea mays L.) yield and N use efficiency(NUE) in the North China Plain(NCP). In the current study, we examined the effects of strip deep rotary tillage(ST) combined with controlled-release(CR) urea on maize yield and NUE, and determined the physiological factors involved in yield formation and N accumulation during a 2-year field experiment. Compared with conventional rotary tillage(RT) and no-tillage(NT), ST increased the soil water content and soil mineral N content(Nmin) in the 20–40 cm soil layer due to reduction by 10.5 and 13.7% in the soil bulk density in the 0–40 cm soil layer, respectively. Compared with the values obtained by common urea(CU) fertilization, CR increased the Nmin in the 0–40 cm soil layers by 12.4 and 10.3% at the silking and maturity stages, respectively. As a result, root length and total N accumulation were enhanced under ST and CR urea, which promoted greater leaf area and dry matter(particularly at post-silking), eventually increasing the1 000-kernel weight of maize. Thus, ST increased the maize yield by 8.3 and 11.0% compared with RT and NT, respectively, whereas CR urea increased maize yield by 8.9% above the values obtained under CU. Because of greater grain yield and N accumulation, ST combined with CR urea improved the NUE substantially. These results show that ST coupled with CR urea is an effective practice to further increase maize yield and NUE by improving soil properties and N supply, so it should be considered for sustainable maize production in the NCP(and other similar areas worldwide). 展开更多
关键词 MAIZE strip deep rotary tillage controlled-release urea nitrogen accumulation grain yield
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Reducing Nitrogen Loss in Subsurface Tile Drainage Water with Managed Drainage and Polymer-Coated Urea in a River Bottom Soil
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作者 Patrick R. Nash Kelly A. Nelson Peter P. Motavalli 《Journal of Water Resource and Protection》 2014年第11期988-997,共10页
Poorly-drained, river bottom soils can be high corn (Zea mays L.) yielding environments, but saturated soil conditions often reduce corn yields. Wabash soils located in river bottoms in Northeast Missouri have not bee... Poorly-drained, river bottom soils can be high corn (Zea mays L.) yielding environments, but saturated soil conditions often reduce corn yields. Wabash soils located in river bottoms in Northeast Missouri have not been traditionally tile drained due to high clay content which requires narrow tile drain spacings. Increased land prices in the region have increased interest in tile draining poorly-drained bottom land soils to increase corn yields which could have a deleterious effect on water quality. The objectives of the three-year study were to determine whether use of managed subsurface drainage (MD) in combination with a controlled release N fertilizer could reduce the annual amount of NO3--N loss through tile drainage water compared to free subsurface drainage (FD) with a non-coated urea application. Annual NO3--N loss through tile drainage water with FD ranged from 28.3 to 90.1 kg·N·ha-1. Nitrogen fertilizer source did not affect NO3--N loss through tile drainage water, which was likely due to limited corn uptake over the three-year study due to adverse weather conditions. Averaged over three years, MD reduced tile water drained 52% and NO3--N loss 29% compared to FD. Reduction in NO3--N loss through tile drainage water with MD compared to FD was due to reduced tile flow during the non-cropping period. Annual flow-weighted mean concentration of NO3--N in the tile water was 5.8 mg·N·L-1 with FD and 8.1 mg·N·L-1 with MD. Tile draining river bottom soils at this location for continuous corn production may not pose a health risk over the evaluated duration. 展开更多
关键词 Free Drainage Managed Drainage NITRATE Nitrogen Polymer-coated urea SUBSURFACE TILE Drainage
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Mineral Coated Fertilizer Effect on Nitrogen-Use Efficiency and Yield of Wheat 被引量:21
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作者 LI Jian-Yun HUA Quan-Xian +2 位作者 TAN Jin-Fang ZHOU Jian-Min HOU Yan-Lin 《Pedosphere》 SCIE CAS CSCD 2005年第4期526-531,共6页
A field experiment with winter wheat (Triticum aestivum L.) was conducted on a silt loam calcaric endorusti-ustic Cambosols derived from the Yellow River alluvial deposits in Henan, China, from 2001 to 2002 to evaluat... A field experiment with winter wheat (Triticum aestivum L.) was conducted on a silt loam calcaric endorusti-ustic Cambosols derived from the Yellow River alluvial deposits in Henan, China, from 2001 to 2002 to evaluate N recovery and agronomic performance of different mineral coated fertilizers (MiCFs) compared to normal urea used in wheat cropping systems under field conditions. Five treatments, including CK (check, no N fertilizer), urea and three different MiCFs at an equivalent N application rate were established in a randomized complete block design. N release from MiCFs in soil was more synchronous with the N requirement of wheat throughout the growth stages than that from urea, with grain yield of the MiCF treatments significantly higher (P < 0.05) than that of the treatment urea. Correspondingly, the N recovery rate was greater for all MiCFs compared to urea, increasing from 32.8% up to 50.1%. Due to its high recovery and low cost, use of the mineral coated N fertilizers was recommended instead of the polymer coated N fertilizers. 展开更多
关键词 冬小麦 肥料 氮肥 肥力 土壤
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生物炭包膜尿素的制备及其固氮潜力的研究
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作者 王杰 孙程万 +3 位作者 郭建华 宁建凤 倪振宇 王弯弯 《节水灌溉》 北大核心 2024年第1期121-127,共7页
为了探究生物炭包膜尿素的缓释性能及对土壤固氮的影响,以300、500和700℃下制备的杨木生物炭为包膜材料制备了3种生物炭包膜尿素,采用间歇土柱淋溶试验对氮素的释放特征进行分析。结果表明,杨木生物炭对铵态氮和硝态氮具有较好的吸附性... 为了探究生物炭包膜尿素的缓释性能及对土壤固氮的影响,以300、500和700℃下制备的杨木生物炭为包膜材料制备了3种生物炭包膜尿素,采用间歇土柱淋溶试验对氮素的释放特征进行分析。结果表明,杨木生物炭对铵态氮和硝态氮具有较好的吸附性能,低温下制备的生物炭对铵态氮吸附效果更好;与尿素相比,施用生物炭包膜尿素土壤的总氮淋溶量减少了9.73%~14.67%,铵态氮淋溶量减少了25.28%~30.36%,硝态氮淋溶量减少了10.34%~18.38%;在同等施氮水平下,生物炭包膜尿素相较于尿素可以显著增加土壤铵态氮和硝态氮的含量。其中,土壤中铵态氮含量增加了66.4%~200.1%,土壤硝态氮的含量增加了477.9%~537.6%。因此,生物炭用作肥料的包膜材料具有广阔的应用前景。 展开更多
关键词 生物炭 包膜尿素 土柱淋溶 铵态氮 硝态氮
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控释掺混肥对小麦–玉米轮作体系产量、氮肥利用效率及氨挥发的影响
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作者 曹兵 高玮 +8 位作者 李洪杰 杜梦扬 王学霞 陈延华 倪小会 赵萌 谷佳林 董淑祺 李子双 《植物营养与肥料学报》 CAS CSCD 北大核心 2024年第5期873-885,共13页
【目的】针对华北平原冬小麦-夏玉米轮作体系氮肥施用量大、氮肥利用率低、氮素损失严重等问题,探讨不同配比的控释掺混肥减氮和一次性施肥对周年作物产量、氨挥发损失和施肥经济效益的影响,确立麦玉轮作体系轻简高效和环境友好的施肥... 【目的】针对华北平原冬小麦-夏玉米轮作体系氮肥施用量大、氮肥利用率低、氮素损失严重等问题,探讨不同配比的控释掺混肥减氮和一次性施肥对周年作物产量、氨挥发损失和施肥经济效益的影响,确立麦玉轮作体系轻简高效和环境友好的施肥技术。【方法】于2022—2023年,在山东省德州市现代农业科技园区开展田间试验。冬小麦和夏玉米均设不施氮对照(CK)、农户习惯施氮(FFP)、优化施氮(OPT)、CRBF1(包膜尿素与普通尿素在冬小麦和夏玉米上的掺混比例分别为5∶5和3∶7)和CRBF2(包膜尿素与普通尿素在冬小麦和夏玉米上的掺混比例分别为7∶3和5∶5),共5个处理。基施和追施肥后,监测了氨挥发量、强度和损失率。分析了作物干物质积累和产量、氮素吸收量和氮肥利用效率,并计算了施肥经济效益。【结果】与FFP处理相比,CRBF1和CRBF2处理的夏玉米、冬小麦和周年产量差异不显著;CRBF1和CRBF2处理夏玉米氮肥偏生产力提高了8.87~9.86 kg/kg,CRBF2处理玉米氮肥回收率提高了48.4%(P<0.05);CRBF1和CRBF2处理冬小麦季氮肥回收率、氮肥农学利用率和氮肥偏生产力分别提高了30.3%~37.2%、5.22~5.77 kg/kg和6.52~7.06 kg/kg(P<0.05)。与FFP和OPT处理相比,CRBF1和CRBF2处理的肥料+施肥人工投入减少381~960元/hm^(2),周年净收入增加1208~2654元/hm^(2)。CRBF1和CRBF2处理的周年氨挥发损失量、损失强度和损失率较FFP处理分别降低了69.7%~71.9%、72.0%~74.5%和90.0%~94.1%(P<0.05)。【结论】包膜尿素与普通尿素在冬小麦、夏玉米季按照5∶5、3∶7,或者按照7∶3、5∶5的比例掺混一次性基施,均可在减少氮肥用量和施肥劳力投入的条件下,确保周年作物产量稳定,提高生产效益,并显著降低氨挥发损失,是华北平原冬小麦-夏玉米轮作系统高产高效、轻简施肥的有效氮肥施用技术。 展开更多
关键词 冬小麦-夏玉米轮作 控释掺混肥 一次性基施 氨挥发 产量 氮肥利用效率 经济效益
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长链烷基脲类消泡剂的合成及性能研究
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作者 焦彦君 汪昌国 +1 位作者 曹添 陈小强 《化学反应工程与工艺》 CAS 2024年第1期49-57,共9页
开发无硅型消泡剂是未来消泡剂领域的发展方向之一。本工作将十八烷基异氰酸酯分别与油胺、1,6-己二胺和三(2-氨基乙基)胺反应合成了三种长链烷基脲,并以烷基脲为消泡活性物、矿物油为载体、Span-Tween为乳化剂制备了三种脲类消泡剂。... 开发无硅型消泡剂是未来消泡剂领域的发展方向之一。本工作将十八烷基异氰酸酯分别与油胺、1,6-己二胺和三(2-氨基乙基)胺反应合成了三种长链烷基脲,并以烷基脲为消泡活性物、矿物油为载体、Span-Tween为乳化剂制备了三种脲类消泡剂。用核磁共振氢谱(1H NMR)和红外光谱(FT-IR)对产物进行结构表征。通过显微观察手段研究了疏水粒子在油基消泡剂中的消泡过程和机理,并通过单因素实验探究了各组成及用量对消泡剂性能的影响。结果表明:当选用低黏度白油,脲消泡活性物占消泡剂质量分数为4%,Span-Tween复合乳化剂亲水亲油平衡(HLB)值为8、用量占消泡剂质量分数为5%时,制得的脲类消泡剂在涂料应用中有着比同类市售产品更优异的消泡性能。 展开更多
关键词 消泡剂 消泡机理 消泡性能 涂料
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低甲醛脲醛树脂基钢结构防火涂料的制备
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作者 叶刚 邓跃全 +5 位作者 徐成超 李恒 李敏 何志强 高川林 龙鹏程 《非金属矿》 2024年第1期50-53,共4页
本试验制备了一种低甲醛脲醛树脂基膨胀型钢结构防火涂料,探究了脲醛树脂加入量对防火涂料性能的影响,并分析其耐火机理。结果表明,在甲醛与尿素低摩尔比(0.8∶1)时,加入0.1%过氧化氢,制备低甲醛脲醛树脂,甲醛含量符合GB 18582-2020规定... 本试验制备了一种低甲醛脲醛树脂基膨胀型钢结构防火涂料,探究了脲醛树脂加入量对防火涂料性能的影响,并分析其耐火机理。结果表明,在甲醛与尿素低摩尔比(0.8∶1)时,加入0.1%过氧化氢,制备低甲醛脲醛树脂,甲醛含量符合GB 18582-2020规定;加入脲醛树脂对膨胀型钢结构防火涂料的基本性能无影响,对涂层发泡性能和耐火性能影响显著,当脲醛树脂加入量在6%~10%时,涂层发泡厚度在3 cm以上,钢板背面温度在300℃以下,最低为271.9℃;脲醛树脂发生热解,分子链断裂产生大量阻燃气体,形成致密碳层,起到气源、碳源的作用。 展开更多
关键词 脲醛树脂 钢结构 防火涂料 发泡性能 耐火性能
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缓释包膜尿素配施对土壤性质和夏玉米生长的影响
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作者 殷金忠 唐蛟 +2 位作者 吕利娟 吴大付 张喜焕 《河南科技学院学报(自然科学版)》 2024年第2期25-32,共8页
缓释肥料根据作物需肥特征可达到养分释放与作物吸收同步的目的.缓释包膜尿素与普通尿素混施既可以降低肥料成本,又能够满足作物生长需求,实现氮肥的合理运筹.研究通过在黄淮海平原豫北地区连续两年(2017—2018年)开展不同施氮剂量下包... 缓释肥料根据作物需肥特征可达到养分释放与作物吸收同步的目的.缓释包膜尿素与普通尿素混施既可以降低肥料成本,又能够满足作物生长需求,实现氮肥的合理运筹.研究通过在黄淮海平原豫北地区连续两年(2017—2018年)开展不同施氮剂量下包膜尿素与普通尿素配施试验,于收获季收集0-20 cm表层土壤和植物样品,进行土壤基本理化性质和植株生长指标测定.试验共设置2个施氮水平(L,低氮施用量;H,高氮施用量)和3个配施比例(CU1,包膜尿素∶普通尿素=40∶60;CU2,包膜尿素∶普通尿素=49∶51;CU3,包膜尿素∶普通尿素=57∶43),并设置常规高施氮量全普通尿素处理对照(CK),共计7个处理.研究结果表明,土壤含全氮、速效磷和有效钾量分别较对照增加37.1%~142.0%、16.5%~33.6%和22.0%~73.1%,含有机质量提高7.0%~42.5%,碳氮比降低33.7%~48.8%.各配施处理连续两年夏玉米的株高、基径、千粒质量和产量较对照增加21.4%~31.2%、10.4%~18.7%、6.18%~11.2%和15.2%~32.7%.综合考虑作物产量和土壤肥力等指标,建议采用低氮水平下高包膜尿素配施比例NPK混合方案(包膜缓释尿素148.2 kg/hm^(2),普通尿素111.8 kg/hm^(2),过磷酸钙833 kg/hm^(2)和硫酸钾180.0 kg/hm^(2))既能满足夏玉米高产对养分的需求,又能保证土地持续的生产力. 展开更多
关键词 玉米 产量 土壤理化性质 包膜缓释尿素 配施
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Material characterization and inter/intra-particle validation for DEM simulation of urea coating process
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作者 Salma A.Nouh KuZilati KuShaari +1 位作者 Lau Kok Keong Shafirah Samsuri 《Particuology》 SCIE EI CAS CSCD 2024年第5期32-48,共17页
Particle coating is a common operation in the controlled-release fertilizer (CRF) industry,where a coating layer is appliedto the urea cores.A discrete element method (DEM) computer simulation was applied to model the... Particle coating is a common operation in the controlled-release fertilizer (CRF) industry,where a coating layer is appliedto the urea cores.A discrete element method (DEM) computer simulation was applied to model the coating process for the urea granules using measured model parameters.The accuracy of DEM input parameters for the coating material properties and the physical and mechanical characterizations of urea granules are crucial to the study of particle coating processes.Thus,to enhance the simulation accuracy,information on the material properties (urea granules) is required.In this study,the elasticity parameters,shear modulus ,coefficient of restitution (CoR),and coefficient of rolling and static friction (CoRF) and (CoSF) of urea granules are estimated experimentally in addition to the physical characteristics.The sensitivity of the angle of repose of the urea bed was investigated at different coefficients of friction.According to the obtained experimental value of the angle of repose,values of 0.2 and 0.3 for CoRF and CoSF,respectively,were adjusted to obtain consistent urea granules’ motion for simulation and the experiment.Moreover,the spray droplet sizes and velocity distributions were estimated using the video-imaging process technique.Based on this experimental characterization,elasticity parameters and spray properties were integrated into DEM simulation software as input data to perform numerical analysis of the coating process to compare simulation and experimental results,which show uniformity at three different pan speeds with a maximum deviation of 0.033 at 5 rpm.Also,consistency between DEM and experiment results was achieved in terms of average coating thickness (μm) of the selected samples and average intra-particle thickness variation ( CoV intra ).These results revealed that the coating film thickness is proportional to the rotation speed for the experiment and simulation.To enhance the inter-particle coating uniformity,the effects of the most significant parameters such as pan speed,filling ratio,particle size,spray rate,and spray angle,were examined.A low spray rate,filling ratio,and high pan speed improved the coating uniformity.The particle size and spray angle show considerable influence on the coating uniformity,where larger particle sizes and spray angles tend to reduce the inter-particle coating uniformity. 展开更多
关键词 Contact model Discrete element method urea fertilizer coating process
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不同包被缓释尿素的瘤胃缓释效果的评价
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作者 曹力文 冯春燕 +4 位作者 温世宝 郑文金 申军士 毛胜勇 朱伟云 《南京农业大学学报》 CAS CSCD 北大核心 2024年第1期157-165,共9页
[目的]本文旨在通过体外批次发酵、瘤胃灌注和持续动态人工瘤胃模拟系统等不同方法评价包被缓释尿素的瘤胃缓释效果。[方法]体外发酵试验:选取1种普通尿素和4种商业包被缓释尿素,体外培养24 h,采集不同时间点(0、1、3、6、9、12、24 h)... [目的]本文旨在通过体外批次发酵、瘤胃灌注和持续动态人工瘤胃模拟系统等不同方法评价包被缓释尿素的瘤胃缓释效果。[方法]体外发酵试验:选取1种普通尿素和4种商业包被缓释尿素,体外培养24 h,采集不同时间点(0、1、3、6、9、12、24 h)发酵液测定氨氮浓度,将筛选出缓释效果最好的缓释尿素用于进一步的研究。瘤胃灌注试验:12只体重(平均27.6 kg)相近的安装有瘤胃瘘管的育肥公湖羊,随机平均分为2组,分别向瘤胃中灌注剂量为日干物质采食量0.5%的普通尿素或日采食量0.55%的缓释尿素(等氮当量),灌注后不同时间点(0、1、3、6、9、12和24 h)采集瘤胃液,测定pH值和氨氮浓度。人工瘤胃试验:在基础日粮中分别添加3.5%的豆粕(普通日粮组)、0.5%的普通尿素(普通尿素组)和0.55%的缓释尿素(缓释尿素组),使用玉米补充普通尿素和缓释尿素组能量的缺乏;试验重复3次,每次持续7 d(4 d适应期和3 d采样期),采样期每天早上投料前后不同时间点采集发酵液和溢流液,测定发酵参数和微生物蛋白浓度。[结果]体外发酵试验:在发酵开始的9、12 h,缓释尿素A组的氨氮浓度显著低于普通尿素组和其余3个缓释尿素处理组(P<0.05)。体内瘤胃灌注试验:在灌注尿素后1 h,缓释尿素组瘤胃pH值和氨氮浓度显著低于普通尿素组(P<0.05),在灌注尿素后6 h,缓释尿素组的pH值显著高于普通尿素组(P<0.05)。人工瘤胃模拟试验:相比于其他2组,日粮添加缓释尿素显著提高了发酵液中丙酸和微生物蛋白的浓度(P<0.05);相比于普通日粮组,日粮添加缓释尿素显著降低了发酵液pH值(P<0.05)。[结论]不同包被缓释尿素的瘤胃缓释效果存在差异,体外发酵筛选出的缓释尿素A在动物瘤胃灌注条件下同样表现出较好的缓释效果。在人工瘤胃发酵试验中添加缓释尿素A能够改善瘤胃发酵,促进微生物蛋白的合成,但对生长性能和瘤胃菌群的影响仍需动物饲养试验做进一步的验证。 展开更多
关键词 包被缓释尿素 体外发酵 瘤胃灌注 持续动态人工瘤胃模拟系统 发酵参数
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Preparation and Characteristic of Self-regulation Water-transmitting Coating Fiber 被引量:2
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作者 张增志 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2009年第4期520-524,共5页
Common clay, Kaolin and Bentonite were used as additives to prepare water-transmitting coating fiber, respectively, and the water-transmitting characteristic of coating fiber was studied. Different water-transmitting ... Common clay, Kaolin and Bentonite were used as additives to prepare water-transmitting coating fiber, respectively, and the water-transmitting characteristic of coating fiber was studied. Different water-transmitting coating fibers were prepared by coating fiber using coating material with different mass proportions of additives to adhesive. And the coating materials were made from three kinds of inorganic clays as additives respectively and polyvinyl alcohol (PVA) as adhesive. Furthermore, the surface morphology and water-transmitting capacity of coating fiber were studied by SEM, Perkin Elmer Diamond SII thermal multi-analyzer and instrument for quick measurement moisture M30. The experimental results indicate that water-transmitting coating fibers made from three kinds of clays all have water-transmitting capacity. The surface of water-transmitting coating fiber prepared by common clay T is continuous and compact, and the water-transmitting effect is better than coating fibers made from other clays. 展开更多
关键词 self-regulation water-transmitting coating fiber storage and controlled-release film composite film inorganic clay
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