Effects of mixed fertilizers formed by the compounding of two targeted controlled-release nitrogen fertilizers on yield,nitrogen use efficiency,and ammonia volatilization in double-cropping rice

One-time application of mixed fertilizer formed by the compounding of two controlled-release nitrogen fertilizers(CRUs)with targeted N supply during the periods from transplantation(TS)to panicle initiation(PI)and from PI to heading(HS)is expected to synchronize the double-peak N demand of rice.However,its effects on the yield and N use efficiency(NUE)of labor-intensive double-cropping rice were unknown.Two targeted CRU(CRU_(A)and CRU_(B))were compounded in five ratios(CRU_(A):CRU_(B)=10:0,7:3,5:5,3:7,and 0:10)to form five mixed fertilizers(BBFs):BBF1-5.A field experiment was performed to investigate the characteristics of N supply in early and late seasons under different BBFs and their effects on N uptake,yield,and ammonia volatilization(AV)loss from paddy fields of double-cropping rice.Conventional high-yield fertilization(CK,three split applications of urea)and zero-N treatments were established as controls.The N supply dropped significantly with the increased compound ratio of CRU_(B)during the period from TS to PI,but increased during the period from PI to HS.With the exception of the period from TS to PI in the late rice season,the N uptake of early and late rice maintained close synchronicity with the N supply of BBFs during the double-peak periods.Excessive N supply(BBF1 and BBF2)in the late rice season during the period from TS to PI increased N loss by AV.The effect of BBF on grain yield increase varied widely between seasons,irrespective of year.Among the BBFs,the BBF2 treatment of early rice not only stabilized the spikelets per panicle but also ensured a high number of effective panicles by promoting N uptake during the period from TS to PI and a high grain-filling percentage by appropriately reducing the N supply at the later PI stage,resulting in the highest rice yield.While stabilizing the effective panicle number,the BBF4 treatment of late rice increased the number of spikelets per panicle by promoting N uptake during the period from PI to HS,resulting in the highest rice yield.The two-year average yield and apparent N recovery efficiency of the BBF2 treatment during the early rice season were 9.6 t ha 1 and 45.3%,while those of late rice in BBF4 were 9.6 t ha 1 and 43.0%,respectively.The yield and NUE indexes of BBF2 in early rice and BBF4 in late rice showed no significant difference from those of CK.The AVs of BBF2 during the early rice season and of BBF4 during the late rice season were 50.0%and 76.8%lower,respectively,than those of CK.BBF2 and BBF4 could effectively replace conventional urea split fertilization in early and late rice seasons,ensuring rice yield and NUE and reducing AV loss in paddy fields.

Controlled-release fertilizer(CRF): A green fertilizer for controlling non-point contamination in agriculture

Fertilizers contribute greatly to high yields but also result in environmental non-point contamination, including the emission of greenhouse gas(N 2O) and eutrophication of water bodies. How to solve this problem has become a serious challenge, especially for China as its high ecological pressure. Controlled-release fertilizer(CRF) has been developed to minimize the contamination while keeping high yield and has become a green fertilizer for agriculture. Several CRFs made with special coating technology were used for testing the fertilizer effects in yield and environment through pot experiment and field trial. The result indicated that the CRFs had higher N use efficiency, thus reducing N loss through leaching and volatilization while keeping higher yields. Comparing with imported standard CRFs, the test on CRFs showed similar fertilizer effect but with much lower cost. CRFs application is becoming a new approach for minimizing non-point contamination in agriculture.

Studies on the Mechanism of Single Basal Application of Controlled-Release Fertilizers for Increasing Yield of Rice (Oryza sativa L.)

This paper was to explore the mechanism of single basal application of controlled-release fertilizers for increasing yield of rice （Oryza sativa L.）. Pot trials and cylinder trials were carried out from 2002 to 2005 to study the influences of single basal application of 3 controlled-release fertilizers on the changes of soil available N, root development, senescence and lodging resistance at late growth stages. Results showed that at 30 days after fertilization, single basal application of controlled-release fertilizers coated with vegetal-substance （CRF1） and polymer materials （CRF3） increased soil available N to 12.0 and 147.9%, respectively, in comparison to split fertilization of rice-specific fertilizer （RSF1）. Treatments of the two CRFs obviously benefited the development of root system, resulting in greater rice root weights with extensive distribution and higher root activity. In addition, the two CRF treatments, in comparison to RSF1, enhanced chlorophyll consents of the flag leaves to 9.5 and 15.5%, and soluble protein up to 89.7 and 108.0% respectively. Application of the two CRFs also made the base of rice stems strong and large, declined the proportion of shoot and root, increased root depth index. Though relatively low K rate, single basal application of the CRF3 coated with NH4MgPO4 could also promote the development of root system, enhance root activity and some physiological functions of flag leaves. Based on these results, it was concluded that major mechanisms for increasing rice yield by single basal application of the CRFs should be attributed to grater soil available N supply, superior development of root systems, better nutrient absorption capacity, slower senescence and enhancement of lodging resistance at late stages.

Shifts in soil bacterial communities induced by the controlled-release fertilizer coatings

Coated controlled-release fertilizers （CRFs） have been widely applied in agriculture due to their increased efficiency. However, the widespread and a lot of coated CRFs application may leave undesired coating residues in the soil due to their slow degradation. Limited information is available on the effects of substantial residual coatings on the soil bacterial community. By adding 0, 5, 10, 20, and 50 times quantities of residual coating from conventional application amount of resin and water-soluble coated CRFs, we studied the responses of soil properties and bacterial community composition to these two residual coatings in black soil. The results showed that the resin and water-soluble coatings did not essentially alter the properties of black soil or cause dramatic changes to bacterial diversity within the test concentration range. The residual resin and water-soluble coatings also did not distinctly alter the relative abundance of the top ten bacteria at phylum level. Heatmap results suggested that the treatments were basically clustered into two groups by concentration rather than types of coating material. Pearson correlation analysis showed that the Simpson＇s diversity index of the bacterial community was significantly correlated with microbial biomass carbon （MBC, r=0.394, P〈0.05）, and the richness index abundance-based coverage estimator （ACE） of the bacterial community was significantly correlated with microbial biomass nitrogen （MBN, t=0.407, P〈0.05）. Overall, results of this study suggested that substantial residual resin and water-soluble coatings with 0-50 times quantities of residual coating from conventional application amount of coated CRFs did not generate obviously negative impacts on the bacterial community in black soil.

Effects of different types of slow-and controlled-release fertilizers on rice yield

This experiment explored the effects of single application of seven types of slow-and controlled-release fertilizers on rice yield and various population characteristics.Based on a study of the nitrogen(N)release characteristics of these fertilizers,pot experiments were conducted in 2018 and 2019 with split fertilization(CK,urea applied split equally at basal and panicle initiation stages,respectively)as control,which assessed the effects on SPAD value,yield and yield components,dynamic changes of rice tillers and dry matter accumulation.The results showed that the N release characteristics of different types of slow-and controlled-release fertilizers were significantly different.Polymer-coated urea(PCU)showed a controlledrelease mode and provided sustained release throughout the whole growth stages.Sulfur-coated urea(SCU)exhibited a slow-release mode,providing insufficient release at the middle and late stages.Urease inhibitor urea(AHA)and ureaformaldehyde(UF)yielded a rapid-release mode,with an explosive N release at the early stage and no release at the middle and late stages.These results showed that PCU delayed the peak seedling stage.Compared with CK,dry matter accumulation and SPAD showed no significant differences,and due to the continuous release of N throughout the growth stages,rice yield,spikelets per panicle,seed setting rate,and 1000-grain weight were all increased.Owing to the lack of N supply at the late stage and the low number of spikelets,SCU led to a reduction of rice yield,which is nevertheless not statistically significant.AHA and UF were susceptible to environmental factors and had varying effects on rice yield.The results of this experiment indicated that given a fixed amount of N applied in a pot,the stronger the N supply capacity and the longer the effective duration time of the fertilizer,the higher the dry matter accumulation at the late growth stage,and the higher the rice yield.

Physiological Basis of Photosynthetic Function and Senescence of Rice Leaves as Regulated by Controlled-Release Nitrogen Fertilizer

The physiological mechanism of photosynthetic function and senescence of rice leaves was studied by using early rice variety Baliangyou 100 and late rice variety Weiyou 46, treated with controlled-release nitrogen fertilizer （CRNF）, urea and no nitrogen fertilizer. CRNF showed obvious effects on delaying the senescence and prolonging photosynthetic function duration of rice leaves. Compared with urea, CRNF could significantly increase the chlorophyll content of functional leaves in both early and late rice varieties, and this difference between the treatments became larger as rice growth progressed; CRNF increased the activities of active oxygen scavenging enzymes super oxide dismutase （SOD） and peroxidase （POD）, and decreased the accumulation amount of malondialdehyde （MDA） in functional leaves during leaf aging; Photosynthetic rate of functional leaves in CRNF treatment was significantly higher than that in urea treatment. The result also indicated that CRNF could effectively regulate the contents of indole-3-acetic acid （IAA） and abscisic acid （ABA） in functional leaves; IAA content was higher and ABA content was lower in CRNF treatment than those in urea treatment. Therefore, application of CRNF could increase the rice yield significantly due to these physiological changes in the functional leaves.

Preparation and characterization of controlled-release fertilizers coated with marine polysaccharide derivatives

Encapsulation of water-soluble nitrogen fertilizers by membranes can be used to control the release of nutrients to maximize the fertilization ef fect and reduce environmental pollution.In this research,we formulated a new double-coated controlled-release fertilizer(CRF)by using food-grade microcrystalline wax(MW)and marine polysaccharide derivatives(calcium alginate and chitosan-glutaraldehyde copolymer).The pellets of water-soluble nitrogen fertilizer were coated with the marine polysaccharide derivatives and MW.A convenient and eco-friendly method was used to prepare the CRF.Scanning electron microscopy(SEM)and Fourier transform infrared spectroscopy(FTIR)were used to characterize the morphology and composition of the products.The nitrogen-release properties were determined in water using UV-Vis spectrophotometry.The controlled-release properties of the fertilizer were improved dramatically after coating with MW and the marine polysaccharide derivatives.The results show that the double-coated CRFs can release nitrogen in a controlled manner,have excellent controlled-release features,and meet the European Standard for CRFs.

Effects of Controlled-Release Fertilizers and Their Application Methods on Germination and Seedling Growth of Dent and Sweet Corns

Effects of controlled-release fertilizers (CRFs) (C-AS, polyolefin coated ammonium sulfate, 50-day-type; Dd-LP, polyolefincoated urea with dicyandiamide, 40-day-type; C-ANP, polyolefin coated ammonium nitrate phosphate, 40-day-type; andC-DAP, polyolefin coated diammonium acid phosphate, 40-day-type), ammonium sulphate and no fertilizer control, andtheir application methods (spot, band, surface and mixed) on germination and seedling development of sweet corn (Zeamays L.var. saccharata Sturt.) and dent corn (Zea mays L.var. indentata Sturt.) were investigated in a greenhouse. Underco-situs application (band and spot) of CRFs, there were no obvious differences in the germination speed and rate for bothdent corn and sweet corn relative to control. Mortality rates of sweet corn seedlings under co-situs application were highin experiment 1, but were very low in experiment 2, because the environmental conditions were different in the twoexperiments. That is, under lower temperature and weaker sunlight, young seedlings easily die due to high soil nutrientconcentration and slow growth speed of corn. Shoot weight of both dent and sweet corn did not greatly decrease inexperiment 1. In experiment 2, there were no significant differences in shoot and root weight of both corns between co-situs and surface or mixed application methods. However, with spot and band application of ammonium sulfate, shoot androot weight were significantly reduced. Soil EC and pH were considerably affected by co-situs application, especially atthe fertilizer application site. For both dent and sweet corn, EC in the 0-3 cm soil was significantly higher under co-situsapplication and surface application than that under mixed application, whereas in the 3-6 cm soil depth the situation wasreversed. Compared with control, mixed application of CRFs decreased soil pH slightly (0-3 cm depth) or greatly (3-6 cmdepth).

Quantitative Evaluation on the Comprehensive Benefit of Controlled-Release Fertilizer in Typically Middle-Low Yield Rice Field

Quantitative evaluation and analysis was made to the soil nutrients,rice yield,rice and fertilizer utilization rate,and economic and ecological benefits of the slow controlled release fertilizer in typical rice fields with middle-low yield by comparing the one-time application and split applications of slow-or controlledrelease fertilizer（ CRF） with farmers fertilizer practice as the control,with the aim to explore the effect of CRF. Results showed that compared with the control,the application of CRF could meet balance nutrients required for rice growth,and the effective panicles and seed-setting rate were higher in the treatment groups of FVOL,SVOL,LADVOLwhich applied CRF. As for soil nutrients,soil pH maintained balance in FVOL,FCAI,SVOL,LADVOL. In addition,differences in soil nutrient reduction amount reached the extremely significant level between FVOLand SXNK.SVOLwhich applied CRF provided reasonable regulation of N,P and K release rate,which showed advantages over blending fertilization and farmers fertilizer practice. Comprehensive analysis found that the application of CRF could make rice tillering growth and decline leveled off,which effectively improved the quality of rice population,and it also had higher input-output ratio than that of the control and good economic benefits. In general,CRF suits to be used widely on rice crop in the regions with medium-low yield.

Subsurface banding of blended controlled-release urea can optimize rice yields while minimizing yield-scaled greenhouse gas emissions

Controlled-release urea(CRU)is widely reported to supply crop nitrogen(N)demand with one basal application,thus effectively replacing split applications of urea without diminishing grain yield and N use efficiency(NUE).However,its use for replacement for high-yield split applications of urea(CK)for rice is untested.In addition,the degree to which greenhouse gas(GHG)emissions in rice systems are affected when CRU is substituted for CK remains unclear.During 2017 and 2018,we sampled plant growth and gas emissions in a rice paddy field treated with three CRU types(sulfur-coated urea[SCU],polymer-coated urea[PCU],and bulk blended CRU[BBU])applied via two methods(surface broadcasting on the soil and subsurface banding at 5 cm depth),with CK as a control.The three CRUs led to different soil NH_(4)^(+)-N dynamics,and the N supply pattern under BBU was more beneficial for rice seedling establishment than under SCU and PCU,resulting in grain yield and NUE comparable to those under CK.CRU type showed no significant effect on either CH_(4) emissions or N_(2)O emissions,and broadcast CRUs exhibited significantly higher total GHG emissions than CK.However,banded CRUs significantly reduced the total GHG emissions in comparison with broadcast CRUs,by 9.2%averaged across the two years.Reduced CH_(4) emissions,particularly during the period prior to the middle drainage,contributed largely to the GHG difference.With comparably high grain yield and low total GHG emissions,banded BBU showed a low yield-scaled GHG(GHG emissions divided by grain yield)comparable to that under CK in both years.Overall,our study suggested that N management synchronized with rice demand and contributing to a high NUE tended to minimize yield-scaled GHG.Broadcast CRU can hardly substitute for CK in terms of either grain yield or GHG emissions,but banded BBU is a promising N management strategy for sustaining rice production while minimizing environmental impacts.

Advances in controlled-release fertilizer encapsulated by organic-inorganic composite membranes

Heavy use of conventional fertilizers can lead to negative environmental concerns.Controlled-release fertilizers(CRFs)can effectively reduce the amounts of fertilizers used,improve the availability of fer-tilizers,and which is conducive to the protection of the ecological environment and sustainable devel-opment of agriculture.Therefore,it is imperative to develop and use CRFs as an alternative to traditional fertilizers.This review aims to present the classification,raw material composition,benefits,release process,release mode,and manufacturing methods of fertilizers coated with organic-inorganic com-posite membranes(OICMs)in order to provide an overall update and summarize CRFs encapsulated by OICMs and provide an insight for future trends in the field of fertilizers.It is expected that utilizing CRFs encapsulated by OICMs and their characteristics for agricultural applications can provide innovative ideas and suggestions for developing novel CRFs suitable for modern and sustainable agriculture.

Biochar-compost-based controlled-release nitrogen fertilizer intended for an active microbial community

Nitrogen(N) fertilizers in agriculture suffer losses by volatilization of N to the air, surface runoff and leaching into the soil, resulting in low N use efficiency(NUE)( 50%) and raising severe environmental pollutions. Controlledrelease nitrogen fertilizers(CRNFs) can control the release of N nutrients to NUE in crop production. Different methods were used to develop new CRNFs.However, different CRNF technologies are still underdeveloped due to inadequate controlling on N releasing time and/or unsustainable diffusion. The study on the influences of CRNF processing parameters on microbial conditions are lacking when the CRNFs composed of various bio-ingredients such as biochar, composts, and biowaste. The complexity of processing methods, material biodegradability, and other physical properties make current CRNFs of questionable value in agricultural production. This research aims to develop a novel biochar-compost-based controlled-release urea fertilizer(BCRUF) to preserve microbial properties carried by the compost. The BCRUF was synthesized by pelletizing the 50:50(dry, wt/wt) mixture of biochar and compost. BCRUF was loaded with urea and then spray-coated with polylactic acid(PLA). The releasing time of two types of BCRUFs, coated and uncoated with PLA, for 80% of N release in water was up to 6 h at three different temperatures(4, 23, and 40 °C), compared to conventional urea fertilizer and commercial environmentally smart N(ESN) fertilizer. The releasing time of coated BCRUF for 80% N release in soil was up to 192 h(8 days). Fourier-transform infrared spectroscopy(FTIR) analysis revealed that no new functional groups were found in the release solution, indicating no new chemical hazards generated. The differential scanning calorimetry(DSC)tests also verified that its thermal stability could be up to 160 °C. The microbe populations in the BCRUF pellets were reduced after the pelleting and drying processes in BCRUF fabrication, but a few bacteria can endure in the air-drying process. BCRUF pellets soaked in water for 4 days retained some bacteria. The BCRUF showed very promising characteristics to improve NUE and sustainability in agricultural production.

One-time application of controlled-release bulk blending fertilizer enhances yield,quality and photosynthetic efficiency in late japonica rice

Controlled-release urea(CRU)releases nitrogen(N)at the same pace that rice takes it up,which can effectively improve N use efficiency,increase rice yield and improve rice quality.However,few studies have described the effects of CRU application on the photosynthetic rate and endogenous enzyme activities of rice.Accordingly,a twoyear field trial was conducted with a total of seven treatments:CK,no N fertilizer;BBF,regular blended fertilizer;RBBF,20%N-reduced regular blended fertilizer;CRF1,70%CRU+30%regular urea one-time base application;CRF2,60%CRU+40%regular urea one-time base application;RCRF1,CRF1 treatment with 20%N reduction;and RCRF2,CRF2 treatment with 20%N reduction.Each treatment was conducted in triplicate.The results showed that the N recovery efficiency(NRE)of the controlled-release bulk blending fertilizer(CRBBF)treatments was significantly greater over the two years.There were significant yield increases of 4.1–5.9%under the CRF1treatment and 5.6–7.6%under the CRF2 treatment compared to the BBF treatment,but the differences between the reduced-N treatments RBBF and RCRF2 were not significant.Photosynthetic rates under the CRF1 and CRF2treatments were significantly higher than under the other treatments,and they had significantly greater RuBPCase,RuBisCO,glutamate synthase(GOGAT)and glutamine synthetase(GS)enzyme activities.Additionally,the soil NH_(4)^(+)-N and NO_(3)^(–)-N contents under the CRBBF treatments were significantly higher at the late growth stage of rice,which was more in-line with the fertilizer requirements of rice throughout the reproductive period.CRBBF also led to some improvement in rice quality.Compared with the BBF and RBBF treatments,the protein contents under the CRBBF treatments were reduced but the milling,appearance,eating and cooking qualities of the rice were improved.These results showed that the application of CRBBF can improve the NRE,photosynthetic rate and endogenous enzyme activities of rice,ensuring sufficient N nutrition and photosynthetic material production during rice growth and thereby achieving improved rice yield and quality.

Study on the Rapid Method to Predict Longevity of Controlled Release Fertilizer Coated by Water Soluble Resin

The study discussed the rapid method to test and predict the longevity of controlled release fertilizers （CRFs） coated by water soluble resin by using the short-term leaching under higher temperature. Pure water dissolving incubation and higher temperature leaching were used to study the patterns of the nutrient release of the CRFs. The correlation analysis between the days at 25℃ and the hours at 80℃ of Trincote 1 and Trincote 2 for the same cumulative release rates were conducted. Patterns of cumulative nutrient release curve followed one factor quadratic regression equation at each given temperatures, and each of relative coefficient was bigger than 0.995. As the temperature increased, nutrients release of the CRFs increased. The longevity of resin coated CRFs were predicted by use of both the cumulative nutrients release equation at 80℃ and the regression equation of release time needed for the same cumulative release rates between 25 and 80℃. There were only 0.3-6.9% relative errors between the tested longevity and predicted one. In conclusion, the longevity of resin coated CRFs could be predicted more quickly and precisely by use of the higher temperature short-term leaching method than that of the traditional differential release rate. The longevity of resin coated CRF could be rapidly and precisely predicted in a few hours by application of the higher temperature shortterm leaching method.

基于ERNIE-BiLSTM-CRF模型的土壤肥力命名实体识别研究

为充分利用安徽省土壤肥力指标数据,解决现有土壤肥力命名实体识别方法普遍存在的效率低、迁移能力较差以及长文本处理影响效果等问题,文中提出了一种基于ERNIE-BiLSTM-CRF模型的土壤肥力命名实体识别方法,并构建了一套安徽省土壤肥力知识问答系统。首先将土壤肥力数据集中的长文本处理为短文本,对土壤肥力信息使用ERNIE模型编码,得到保留语义关联的词表示形式,再利用BiLSTM模型进行特征提取,对一切可能的标签序列评分并输出给CRF模型,最后使用CRF模型解码获取分数最高的标签序列,生成实体标签序列。结果表明,与HMM模型、CRF模型、BiLSTM模型、BiLSTM-CRF模型相比较,本文使用的基于ERNIE-BiLSTM-CRF模型的土壤肥力命名实体识别方法,准确率P达到92.85%、召回率R达到92.00%、F1值达到92.59%,取得了相对较好的识别效果。

Effects of a controlled-release fertilizer on yield, nutrient uptake, and fertilizer usage efficiency in early ripening rapeseed(Brassica napus L.)

Background： Nitrogen（N）, phosphorous（P）, and potassium（K） are critical nutrient elements necessary for crop plant growth and development. However, excessive inputs will lead to inefficient usage and cause excessive nutrient losses in the field environment, and also adversely affect the soil, water and air quality, human health, and biodiversity. Methods： Field experiments were conducted to study the effects of controlled-release fertilizer（CRF） on seed yield, plant growth, nutrient uptake, and fertilizer usage efficiency for early ripening rapeseed（Xiangzayou 1613） in the red-yellow soil of southern China during 2011–2013. It was grown using a soluble fertilizer（SF） and the same amounts of CRF, such as SF1/CRF1（3750 kg/hm^2）, SF2/CRF2（3000 kg/hm^2）, SF3/CRF3（2250 kg/hm^2）, SF4/CRF4（1500 kg/hm^2）, SF5/CRF5（750 kg/hm^2）, and also using no fertilizer（CK）. Results： CRF gave higher seed yields than SF in both seasons by 14.51%. CRF4 and SF3 in each group achieved maximum seed yield（2066.97 and 1844.50 kg/hm^2, respectively）, followed by CRF3（1929.97 kg/hm^2） and SF4（1839.40 kg/hm^2）. There were no significant differences in seed yield among CK, SF1, and CRF1（P0.05）. CRF4 had the highest profit（7126.4 CNY/hm2） and showed an increase of 12.37% in seed yield, and it decreased by 11.01% in unit fertilizer rate compared with SF4. The branch number, pod number, and dry matter weight compared with SF increased significantly under the fertilization of CRF（P0.05）. The pod number per plant was the major contributor to seed yield. On the other hand, the N, P, and K uptakes increased at first and then decreased with increasing the fertilizer rate at maturity, and the N, P, and K usage efficiency decreased with increasing the fertilizer rate. The N, P, and K uptakes and usage efficiencies of the CRF were significantly higher than those of SF（P0.05）. The N accumulation and N usage efficiency of CRF increased by an average of 13.66% and 9.74 percentage points, respectively, compared to SF. In conclusion, CRF significantly promoted the growth of rapeseed with using total N as the base fertilizer, by providing sufficient N in the later growth stages, and last by reducing the residual N in the soil and increasing the N accumulation and N usage efficiency.

Nitrogen release characteristics of polyethylene-coated controlled-release fertilizers and their dependence on membrane pore structure

In this study, controlled-release fertilizers （CRFs） with five different nitrogen release periods were pre- pared by coating large urea particles with polyethylene （PE） membranes under various experimental conditions. The preliminary and differential solubility rates, release periods, and membrane pore sizes of the obtained CRFs were measured using water immersion, scanning electron microscopy, and mercury porosimetry. For all CRF samples, the median pore diameters of the membranes were equal to 4.5-5.3 nm and pores with sizes smaller than 10 nm accounted for 86-96% of the total pore surface area. The obtained pore diameter distributions differed for the five studied types of CRF, having release periods of 1,2, 4, 6, and 8 months. Thus, for the CRFs with a 1-month release period, the maximum pore diameter reached a magnitude of 4000 nm, while this value did not exceed 30 nm for the CRFs with a release period of 8 months. Hence, we have established a relationship between the release period of CRFs and their effective maximum pore sizes.

Highly degradable chitosan-montmorillonite (MMT) nanocomposite hydrogel for controlled fertilizer release

Fertilizer consumption is increasing drastically along with the rapid expansion of farming in response to the ever-growing population. However, a significant portion of the nutrients in traditional fertilizers is lost during leaching and runoff causing economic loss and environmental threats. Polymer-modified controlled-release fertilizers provide an opportunity for mitigating adverse environmental effects and increasing the profitability of crop production. Here, we present a cheap and easy-to-fabricate controlled-release fertilizer excipient based on hydrogels scaffolded by safe and biodegradable chitosan and montmorillonite (MMT) nanoclays. By introducing elastic and flexible physical crosslinking induced by 2-dimensional (2D) MMT nanoflakes into the chitosan hydrogel, highly swellable and degradable chitosan-MMT nanocomposites were fabricated. The addition of MMT into the chitosan hydrogels enhanced the total release of phosphorous (P) and potassium (K), from 22.0 % to 94.9 % and 9.6% to 31.4 %, respectively, compared to the pure chitosan gel. The chitosan-MMT nanocomposite hydrogel achieved a well-controlled overall fertilizer release in soil. A total of 55.3 % of loaded fertilizer was released over 15 d with a daily release of 2.8 %. For the traditional fertilizer podwer, 89.2 % of the fertilizer was washed out during the first irrigation under the same setup. In the meantime, the nanocomposites improved the water retention of the soil, thanks to its excellent water absorbency. Moreover, the chitosan-MMT nanocomposite hydrogels exhibited high degradation of 57 % after swelling in water for 20 d. Such highly degradable fertilizer excipient poses minimal threat to the long-term fertility of the soil. The engineered Chitosan-MMT biopolymer scaffold as a controlled-release fertilizer excipient provides a promising opportunity for advancing sustainable agriculture.

热固性树脂包膜控释肥料肥效期的快速预测方法

采用静水溶出率的方法,在25℃、40℃、60℃、70℃、80℃和100℃条件下,探讨了控释肥料中养分累积释放率与温度的变化规律,以期建立控释肥料肥效期或养分释放期的快速预测方法.结果表明,从低温到高温的各种温度处理下,Scotta公司的Osmocote热固性树脂包膜控释肥料养分累积释放曲线都呈二次曲线,相关指数R2均大于0.996.温度与包膜控释肥料肥效期间呈极显著的负相关,并符合一元二次方程,相关指数R2大于0.993.在高温下培养3或8 h建立的预测预报回归方程,可以快速而准确地预测预报包膜控释肥料在常温下（25℃）的肥效期,预测值与实测值只相差2.4 d;而习惯上的微分溶出率法却相差29～42 d.表明用高温下的肥效期预测预报回归法可以在数小时内准确、迅速地预测控释肥料的肥效期.同时该方法可作为控释肥料在线生产质量控制和市场上控释肥料质量检验的候选方法.

水溶性树脂包膜控释肥料肥效期快速检测方法研究

【目的】探索和建立80℃高温下的快速检测方法(高温短期淋洗法),预测水溶性树脂包膜控释肥料在25℃常温下的肥效期。【方法】采用常温静水溶出试验和高温淋洗的方法,并对常温25℃与高温80℃下供试肥料达到相同养分释放率所需时间进行相关分析。【结果】树脂包膜控释肥料累积释放曲线都呈二次曲线,相关系数r均大于0.995。随着温度的升高供试控释肥料养分释放加快。利用常温25℃与高温80℃高温短期淋洗达到相同养分释放率所需时间的回归方程,并结合80℃的释放曲线方程,可以快速而准确地预测这种包膜控释肥料在常温下养分释放率达到75%所需要的时间,即肥效期。两种树脂包膜控释肥料Trincote1和Trincote2肥效期的预测值与实测值相对误差只有0.3%～6.9%。【结论】采用高温短期淋洗法可以在数小时内比较准确、迅速地预测控释肥料的肥效期,与传统的静水溶出率法或土柱淋溶法相比,结果更准确,而且大大缩短了检测时间。该方法可作为树脂包膜控释肥料肥效期或养分释放期的快速检测方法。