Cascade utilization of full spectrum solar energy for achieving simultaneous hydrogen production and all-day thermoelectric conversion

Solar-driven photocatalytic water/seawater splitting holds great potential for green hydrogen production.However,the practical application is hindered by the relatively low conversion efficiency resulting from the inadequate utilization of solar spectrum with significant waste in the form of heat.Moreover,current equipment struggles to maintain all-day operation subjected to the lack of light during nighttime.Herein,a novel hybrid system integrating photothermal catalytic(PTC)reactor,thermoelectric generator(TEG),and phase change materials(PCM)was proposed and designed(named as PTC-TEG-PCM)to address these challenges and enable simultaneous overall seawater splitting and 24-hour power generation.The PTC system effectively maintains in an optimal temperature range to maximize photothermal-assisted photocatalytic hydrogen production.The TEG component recycles the low-grade waste heat for power generation,complementing the shortcoming of photocatalytic conversion and achieving cascade utilization of full-spectrum solar energy.Furthermore,exceptional thermal storage capability of PCM allow for the conversion of released heat into electricity during nighttime,contributing significantly to the overall power output and enabling PTC-TEG-PCM to operate for more than 12 h under the actual condition.Compared to traditional PTC system,the overall energy conversion efficiency of the PTC-TEG-PCM system can be increased by∼500%,while maintaining the solar-to-hydrogen efficiency.The advancement of this novel system demonstrated that recycling waste heat from the PTC system and utilizing heat absorption/release capability of PCM for thermoelectric application are effective strategies to improve solar energy conversion.With flexible parameter designing,PTC-TEG-PCM can be applied in various scenarios,offering high efficiency,stability,and sustainability.

Electricity as an Energy Vector: A Performance Comparison with Hydrogen and Biodiesel in Italy

This study presents a comparative analysis of electricity, hydrogen, and biodiesel as energy vectors, with a focus on powering an aluminum smelter in southern Italy. It evaluates these vectors in terms of efficiency, land requirements for carbon-neutral energy production, and capital expenditure, providing insights throughout the entire supply chain (upstream, midstream, and downstream) into their feasibility for industrial applications. The research reveals that biodiesel, despite being carbon neutral, is impractical due to extensive land requirements and lower efficiency if compared to other vectors. Hydrogen, downstream explored in two forms as thermal power generation and fuel cell technology, shows lower efficiency and higher capital expenditure compared to electricity. Additionally, green hydrogen production’s land requirements significantly exceed those of electricity-based systems. Electricity emerges as the most viable option, offering an overall higher efficiency, lower land requirements for its green production, and comparatively lower capital expenditure. The study’s findings highlight the importance of a holistic assessment of energy vectors, considering economic, environmental, and practical aspects along the entire energy supply chain, especially in industrial applications where the balance of these factors is crucial for long-term sustainability and feasibility. This comprehensive analysis provides valuable guidance for similar industrial applications, emphasizing the need for a balanced approach in the selection of energy vectors.

Meta-analysis of CO_(2) conversion,energy efficiency,and other performance data of plasma-catalysis reactors with the open access PIONEER database

This paper brings the comparison of performances of CO_(2)conversion by plasma and plasma-assisted catalysis based on the data collected from literature in this field,organised in an open access online database.This tool is open to all users to carry out their own analyses,but also to contributors who wish to add their data to the database in order to improve the relevance of the comparisons made,and ultimately to improve the efficiency of CO_(2)conversion by plasma-catalysis.The creation of this database and database user interface is motivated by the fact that plasma-catalysis is a fast-growing field for all CO_(2)conversion processes,be it methanation,dry reforming of methane,methanolisation,or others.As a result of this rapid increase,there is a need for a set of standard procedures to rigorously compare performances of different systems.However,this is currently not possible because the fundamental mechanisms of plasma-catalysis are still too poorly understood to define these standard procedures.Fortunately however,the accumulated data within the CO_(2)plasma-catalysis community has become large enough to warrant so-called“big data”studies more familiar in the fields of medicine and the social sciences.To enable comparisons between multiple data sets and make future research more effective,this work proposes the first database on CO_(2)conversion performances by plasma-catalysis open to the whole community.This database has been initiated in the framework of a H_(2)0_(2)0 European project and is called the“PIONEER Data Base”.The database gathers a large amount of CO_(2)conversion performance data such as conversion rate,energy efficiency,and selectivity for numerous plasma sources coupled with or without a catalyst.Each data set is associated with metadata describing the gas mixture,the plasma source,the nature of the catalyst,and the form of coupling with the plasma.Beyond the database itself,a data extraction tool with direct visualisation features or advanced filtering functionalities has been developed and is available online to the public.The simple and fast visualisation of the state of the art puts new results into context,identifies literal gaps in data,and consequently points towards promising research routes.More advanced data extraction illustrates the impact that the database can have in the understanding of plasma-catalyst coupling.Lessons learned from the review of a large amount of literature during the setup of the database lead to best practice advice to increase comparability between future CO_(2)plasma-catalytic studies.Finally,the community is strongly encouraged to contribute to the database not only to increase the visibility of their data but also the relevance of the comparisons allowed by this tool.

Research on Operation Optimization of Heating System Based on Electric Storage Coupled Solar Energy and Air Source Heat Pump

For heating systems based on electricity storage coupled with solar energy and an air source heat pump(ECSA),choosing the appropriate combination of heat sources according to local conditions is the key to improving economic efficiency.In this paper,four cities in three climatic regions in China were selected,namely Nanjing in the hot summer and cold winter region,Tianjin in the cold region,Shenyang and Harbin in the severe cold winter region.The levelized cost of heat(LCOH)was used as the economic evaluation index,and the energy consumption and emissions of different pollutants were analyzed.TRNSYS software was used to simulate and analyze the system performance.The Hooke-Jeeves optimization algorithm and GenOpt software were used to optimize the system parameters.The results showed that ECSA systemhad an excellent operation effect in cold region and hot summer and cold winter region.Compared with ECS system,the systemenergy consumption,and the emission of different pollutants of ECSA system can be reduced by a maximum of 1.37 times.In cold region,the initial investment in an air source heat pump is higher due to the lower ambient temperature,resulting in an increase in the LOCH value of ECSA system.After the LOCH value of ECSA system in each region was optimized,the heating cost of the system was reduced,but also resulted in an increase in energy consumption and the emission of different pollutant gases.

Designing high-efficiency light-to-thermal conversion materials for solar desalination and photothermal catalysis

Light-to-thermal conversion materials(LTCMs)have been of great interest to researchers due to their impressive energy conversion capacity and wide range of applications in biomedical,desalination,and synergistic catalysis.Given the limited advances in existing materials(metals,semiconductors,π-conjugates),researchers generally adopt the method of constructing complex systems and hybrid structures to optimize performance and achieve multifunctional integration.However,the development of LTCMs is still in its infancy as the physical mechanism of light-to-thermal conversion is unclear.In this review,we proposed design strategies for efficient LTCMs by analyzing the physical process of light-tothermal conversion.First,we analyze the nature of light absorption and heat generation to reveal the physical processes of light-to-thermal conversion.Then,we explain the light-to-thermal conversion mechanisms of metallic,semiconducting andπ-conjugated LCTMs,and propose new material design strategies and performance improvement methods.Finally,we summarize the challenges and prospects of LTCMs in emerging applications such as solar water evaporation and photothermal catalysis.

Reducing voltage hysteresis of metal oxide anodes to achieve high energy efficiency for Li-ion batteries

In the past two decades,a lot of high-capacity conversion-type metal oxides have been intensively studied as alternative anode materials for Li-ion batteries with higher energy density.Unfortunately,their large voltage hysteresis(0.8-1.2 V) within reversed conversion reactions results in huge round-trip inefficiencies and thus lower energy efficiency(50%-75%) in full cells than those with graphite anodes.This remains a long-term open question and has been the most serious drawback toward application of metal oxide anodes.Here we clarify the origins of voltage hysteresis in the typical SnO2anode and propose a universal strategy to minimize it.With the established in situ phosphating to generate metal phosphates during reversed conversion reactions in synergy with boosted reaction kinetics by the added P and Mo,the huge voltage hysteresis of 0.9 V in SnO_(2),SnO_(2)-Mo,and 0.6 V in SnO2-P anodes is minimized to 0.3 V in a ternary SnO_(2)-Mo-P(SOMP) composite,along with stable high capacity of 936 mA h g^(-1)after 800 cycles.The small voltage hysteresis can remain stable even the SOMP anode operated at high current rate of10 A g^(-1)and wide-range temperatures from 60 to 30℃,resulting in a high energy efficiency of88.5% in full cells.This effective strategy to minimize voltage hysteresis has also been demonstrated in Fe2O3,Co3O4-basded conversion-type anodes.This work provides important guidance to advance the high-capacity metal oxide anodes from laboratory to industrialization.

Solar energy conversion on g-C3N4 photocatalyst:Light harvesting,charge separation,and surface kinetics

Photocatalysis. which utilizes solar energy to trigger chemical reactions, is one of the most desirable solar-energy-conversion approaches. Graphitic carbon nitride （g-C3N4）. as an attractive metal-free photocatalyst, has drawn worldwide research interest in the area of solar energy conversion due to its easy synthesis, earth-abundant nature, physicochemical stability and visible-light-responsive properties. Over the past ten years, g-C3N4 based photocatalysts have experienced intensive exploration, and great progress has been achieved. However, the solar conversion efficiency is still far from industrial applications due to the wide bandgap, severe charge recombination, and lack of surface active sites. Many strategies have been proposed to enhance the light absorption, reduce the recombination of charge carriers and accelerate the surface kinetics. This work makes a crucial review about the main contributions of various strategies to the light harvesting, charge separation and surface kinetics of g-C3N4 photocatalyst. Furthermore, the evaluation measurements for the enhanced light harvesting, reduced charge recombination and accelerated surface kinetics will be discussed. In addition, this review proposes future trends to enhance the photocatalytic performance of g-C3N4 photocatalyst for the solar energy conversion.

Conversion of Solar Energy to Fuels by Inorganic Heterogeneous Systems

Over the last several years,the need to find clean and renewable energy sources has increased rapidly because current fossil fuels will not only eventually be depleted,but their continuous combustion leads to a dramatic increase in the carbon dioxide amount in atmosphere.Utilisation of the Sun's radiation can provide a solution to both problems.Hydrogen fuel can be generated by using solar energy to split water,and liquid fuels can be produced via direct CO2 photoreduction.This would create an essentially free carbon or at least carbon neutral energy cycle.In this tutorial review,the current progress in fuels' generation directly driven by solar energy is summarised.Fundamental mechanisms are discussed with suggestions for future research.

Managing System Losses to Improve Energy Efficiency within the Electricity Company of Ghana (ECG) Limited

The inability to achieve the target of universal access to electricity is influenced by several factors including funding limitations, the use of obsolete equipment, power theft, and system losses confronting the electricity distribution services of the Electricity Company of Ghana Limited (ECG). The study assessed the components of system losses within the ECG by determining and computing the percentage of system losses within ECG, examining the causes of both commercial and technical losses in ECG, and determining ways to improve energy efficiency by reducing system losses in the most cost-efficient manner. The study adopted deductive reasoning and a quantitative approach to guide data collection and analysis of the research output. A sample of 345 technical and non-technical staff of ECG in the Greater Accra Metropolis was selected from a population of 2500. Purposive, simple random, and cluster sampling techniques were used in identifying and accessing respondents for the study. Descriptive statistics were applied to measure central tendency and degrees of dispersion and the Relative Importance Index (RII) to predict criterion and predictor variables. The impact of low voltage network losses can adversely contribute to technical losses (20%) and reduce energy efficiency in power or electricity distribution companies. Non-technical losses are mainly caused by illegal connections, meter problems, and billing problems. Each of the non-technical losses contributes a maximum of 10% to system losses. Contributors to system losses at ECG are ranked first for power theft and least for lack of incentives. System losses at ECG include metering inaccuracies, bad workmanship, unmetered supply, and lengthy distribution lines, each recording a mean value of above 3.5. Measures to improve monitoring of the networks and systems at ECG and discourage power theft should include an extensive quantification, patrolling, and inspection of the entire network to assess the extent of the network and conditions relevant for the placement of systematically planned maintenance programmes.

A Study of Energy Conversion Efficiency Versus Plasma Density by Lower Hybrid Current Drive in HT-7 Tokamak

Ramp-up experiments by means of lower hybrid wave on HT-7 superconducting tokamak have been performed and analyzed. A ramp-up rate of over 300 kA/s is obtained and a conversion efficiency of over 1.0% has been achieved during the ramp-up phase. The study of the dependence of conversion efficiency on plasma density shows that the conversion efficiency is affected by the driven current, which is mainly dominated by the competition of impurity concentration with wave accessibility condition. In addition, the effect of current profile may play an important role in determining the conversion efficiency.

Industrial Electric Energy Efficiency and Influential Factors in China

As traditional single-factor electricity intensity can not reveal the real electricity consumption efficiency accurately, this study applies the data envelopment analysis (DEA) approach to calculale the total-factor electricity consumption efficiency of China’s 33 industrial sectors from year 1998 to 2007, and uses the Tobit model to analyze the influential factors of electric energy efficiency. The result shows that China’s industrial electricity efficiency is universally low. Further study shows that industrial structure and technological progress have positive influence on consumption efficiency, while industry concentration and electricity price have negative influence on consumption efficiency. The effect of property right structure is fluctuated. Therefore, to optimize industry structure, promote technological progress, maintain competition, and deepen the reform of electricity price are beneficial for the improvement of electric energy efficiency.

基于EnergyPlus和Jeplus+EA联合模拟的建筑围护结构及光储系统协同优化研究

建筑本体和可再生能源系统的协同作用对于降低建筑碳排放具有重要意义.以北京某办公建筑为例,基于NSGA-Ⅱ的优化算法,以运行阶段碳排放和生命周期成本为目标函数,以热舒适为约束条件,利用EnergyPlus和Jeplus+EA软件进行联合仿真,开展建筑围护结构和光储系统的协同优化研究.结果表明:配置光储系统可较大程度降低建筑电网购电量及运行阶段碳排放,虽然生命周期成本会略有增加,但其减碳效果,大于单纯依靠围护结构性能提升的传统做法;尽可能利用建筑空间配置光伏对减少碳排放及生命周期成本都是有利的;通过软件联合模拟可实现建筑围护结构和光储系统的协同优化,且较于各自独立优化,能取得更好的设计方案.

Rational design of natural leather-based water evaporator for electricity generation and functional applications

In recent years,water evaporation-induced electricity has attracted a great deal of attention as an emerging green and renewable energy harvesting technology.Although abundant materials have been developed to fabricate hydrovoltaic devices,the limitations of high costs,inconvenient storage and transport,low environmental benefits,and unadaptable shape have restricted their wide applications.Here,an electricity generator driven by water evaporation has been engineered based on natural biomass leather with inherent properties of good moisture permeability,excellent wettability,physicochemical stability,flexibility,and biocompatibility.Including numerous nano/microchannels together with rich oxygen-bearing functional groups,the natural leather-based water evaporator,Leather_(Emblic-NPs-SA/CB),could continuously produce electricity even staying outside,achieving a maximum output voltage of∼3 V with six-series connection.Furthermore,the leather-based water evaporator has enormous potential for use as a flexible self-powered electronic floor and seawater demineralizer due to its sensitive pressure sensing ability as well as its excellent photothermal conversion efficiency(96.3%)and thus fast water evaporation rate(2.65 kg m^(−2)h^(−1)).This work offers a new and functional material for the construction of hydrovoltaic devices to harvest the sustained green energy from water evaporation in arbitrary ambient environments,which shows great promise in their widespread applications.

Techno-Economic Optimization of Novel Stand-Alone Renewable Based Electric Vehicle Charging Station near Bahria Town Karachi,Sindh Pakistan

Electric vehicles (EVs) are the most interesting and innovative technology in the 21st century because of theirenormous advantages, both technically and economically. Their emissions rate compared to fuel-based vehicles isnegligible as they do not consume fuel and hence do not emit any harmful gases. However, their bulk production,adoption and lack of charging stations increase the stress of power stations due to modern-day lifestyles. If Electricvehicles demand increases drastically then conventional power stations will not bear their demand and if theygenerate electricity by conventional means it will be very costly and may further add greenhouse gases. Therefore,this research provides the techno-economic assessment of a stand-alone renewable-dependent electric vehiclecharging station, excluding any burden on electrical utility. The proposed study is carried out in Bahria Town,Karachi, a city in Pakistan. In this study, HOMER Pro software was utilized for techno-economic assessment. Ahybrid system comprising solar Photovoltaic/Wind Turbine/Fuel cells and battery storage is included in the model.Solar and wind resources were taken from NASA’s website, where charging stations will be integrated. The overallresults show promising in terms of total Net Present Cost and the Cost of Energy which are 2.72M $ and 0.237 $,respectively. The total system generation is 3,598 Megawatt hours per year, and the total energy consumption is 885Megawatt hours per year.

The Benefits of Solar Energy on the Provision of Sustainable Affordable Housing in Nigeria

Solar energy is the most abundant form of energy on Earth. Solar energy brings impactful benefits and products that are expected to make homes more reliable, sustainable, and affordable. Thanks to technological advancements like the solar cell, we can gather this energy and turn it into electricity. The construction industry has an exceptional chance of benefiting from this sustainable energy. Many recognised benefits have been spelled forth in the construction industry, such as providing homes with clean energy with no trace of ozone depleting material emission. There are many people in Nigeria who are not linked to the public electric grid, and the energy sector produces and generates less than 58% of the entire amount of energy required. As stated in the Nigeria’s National Energy General Plan, the Sustainable Energy programme aims to enhance the country’s use of solar electricity. This paper focuses on the role of solar energy in the provision of sustainable affordable housing in Nigeria. It considers the description, method, and utilisation of solar energy with a focus on residential and commercial buildings.

Energy Consumption Analysis and Optimization of Electric Submersible Pump System

Electric submersible pumps account for a considerable proportion in the development of the Bohai Oilfield. Improving the system efficiency of the electric submersible pump wells, ensuring that the units operate in the high-efficiency zone, is essential. Analysis shows that the efficiency of the electric submersible pump system depends on the wear and tear of each component of the submersible pump equipment, the setting of operational parameters, and more importantly, the production status and daily management level of the oil well. Therefore, improving the structural performance of the submersible pump product, optimizing the parameters setting of the oil well, strengthening daily management, establishing a scientific management system, and improving the production management process and system can effectively improve the production efficiency and economic benefits of the oil well, and further achieve the goal of energy saving and emission reduction. In addition, it is necessary to actively promote the concept and technology of energy saving and emission reduction, encourage oilfield enterprises to explore effective measures to reduce the energy consumption of the electric submersible pump system by strengthening the scientific management system, and achieve a green, low-carbon, and high-quality development of oilfield production to achieve the unity of economic benefits, social benefits, and environmental benefits. This article applies the above measures in the P oilfield to achieve energy optimization of submersible electric pump systems, reducing the daily power consumption of single well submersible electric pump systems by 371 kWh per day, increasing the submersible electric pump's lifespan by 200 days, generating considerable project benefits.

Boudouard reaction driven by thermal plasma for efficient CO2 conversion and energy storage

Conversion of CO2 into CO using plasma processing powered by renewable energy is a promising method to convert intermittent sustainable electricity into storable chemical energy.Despite extensive research efforts worldwide,there is currently no process that achieves economically viable values for both CO2 conversion fraction and energy recovery efficiency simultaneously.Here we demonstrate that a process that utilizes the Boudouard reaction,CO^2++C→2 CO,driven by a thermal plasma allows both 95%CO2 conversion to CO and energy recovery efficiency of 70%,values far higher than seen so far.By comparing the conversion process with and without CO2 excitation by a plasma and by using optical emission spectroscopy we show that the improved performance is due to a novel mode of operation where CO2 is pyrolyzed into an active mixture of CO,O and O2 by an arc discharge which is then introduced into a fixed bed to interact with carbon material.In this way,the free oxygen in the mixture combusts with carbon to form CO,and residual plasma excited CO2 is reduced by carbon.In the overall process,the endothermic Boudouard reaction is partially replaced by an exothermic reaction,and the excess electric energy to produce CO2 plasma is reused in the carbon bed.

Graphene Array-Based Anti-fouling Solar Vapour Gap Membrane Distillation with High Energy Efficiency

Photothermal membrane distillation(MD)is a promising technology for desalination and water purification.However,solar-thermal conversion suffers from low energy efficiency(a typical solar-water efficiency of ~50%),while complex modifications are needed to reduce membrane fouling.Here,we demonstrate a new concept of solar vapour gap membrane distillation(SVGMD)synergistically combining self-guided water transport,localized heating,and separation of membrane from feed solution.A free-standing,multifunctional light absorber based on graphene array is custom-designed to locally heat the thin water layer transporting through graphene nanochannels.The as-generated vapour passes through a gap and condenses,while salt/contaminants are rejected before reaching the membrane.The high solar-water efficiency(73.4% at 1 sun),clean water collection ratio(82.3%),excellent anti-fouling performance,and stable permeate flux in continuous operation over 72 h are simultaneously achieved.Meanwhile,SVGMD inherits the advantage of MD in microorganism removal and water collection,enabling the solar-water efficiency 3.5 times higher compared to state-of-the-art solar vapour systems.A scaled system to treat oil/seawater mixtures under natural sunlight is developed with a purified water yield of 92.8 kg m-2 day-1.Our results can be applied for diverse mixed-phase feeds,leading to the next-generation solar-driven MD technology.

Dynamic Properties and Energy Conversion Efficiency of A Floating Multi-Body Wave Energy Converter

The present study proposed a floating multi-body wave energy converter composed of a floating central platform,multiple oscillating bodies and multiple actuating arms. The relative motions between the oscillating bodies and the floating central platform capture multi-point wave energy simultaneously. The converter was simplified as a forced vibration system with three degrees of freedom, namely two heave motions and one rotational motion. The expressions of the amplitude-frequency response and the wave energy capture width were deduced from the motion equations of the converter. Based on the built mathematical model, the effects of the PTO damping coefficient, the PTO elastic coefficient, the connection length between the oscillating body and central platform, and the total number of oscillating bodies on the performance of the wave energy converter were investigated. Numerical results indicate that the dynamical properties and the energy conversion efficiency are related not only to the incident wave circle frequency but also to the converter’s physical parameters and interior PTO coefficients. By adjusting the connection length, higher wave energy absorption efficiencies can be obtained. More oscillating bodies installed result in more stable floating central platform and higher wave energy conversion efficiency.

Improving energy utilization efficiency of electrical discharge milling in titanium alloys machining

Electrical discharge milling(ED-milling) can be a good choice for titanium alloys machining and it was proven that its machining efficiency can be improved to compete with mechanical cutting. In order to improve energy utilization efficiency of ED-milling process, unstable arc discharge and stable arc discharge combined with normal discharge were implemented for material removal by adjusting servo control strategy. The influence of electrode rotating speed and dielectric flushing pressure on machining performance was investigated by experiments. It was found that the rotating of electrode could move the position of discharge plasma channel, and high pressure flushing could wash melted debris out the discharge gap effectively. Both electrode rotating motion and high pressure flushing are contributed to the improvement of machining efficiency.