Two novel coordination compounds,1[Zn4（L1）4（NO3）2（H2O）2]（NO3）2·2H2O and 2[Mn2（L2）2（DMF）（H2O）3]（ClO4）2·DMF（HL1 = N＇-[（1E）-pyridine-2-ylmethylidene]pyrazine-2-carbohydrazide,H2L2 = 2-hydrox...Two novel coordination compounds,1[Zn4（L1）4（NO3）2（H2O）2]（NO3）2·2H2O and 2[Mn2（L2）2（DMF）（H2O）3]（ClO4）2·DMF（HL1 = N＇-[（1E）-pyridine-2-ylmethylidene]pyrazine-2-carbohydrazide,H2L2 = 2-hydroxy-3-methoxybenzaldehyde（pyrazin-2-ylcarbonyl）hydrazone）,based on the N-N bridged ligands were prepared and structurally characterized.Compound 1represents the[2＊2]molecular squares,in which both N atoms belonging to the N-N bridged ligands are connected to the Zn centers.The emission of compound 1 exhibits a blue shift,which can be assigned to strong electrostatic interaction between Zn^Ⅱ ions and the L1^-1.Compound 2represents a rare phenol-O bridged Mn2^Ⅱ complex.The magnetic investigation indicates weak antiferromagnetic interactions between the Mn^Ⅱ centers.展开更多
Multispeed transmissions can enhance the dynamics and economic performance of electric vehicles(EVs),but the coordinated control of the drive motor and gear shift mechanism during gear shifting is still a difficult ch...Multispeed transmissions can enhance the dynamics and economic performance of electric vehicles(EVs),but the coordinated control of the drive motor and gear shift mechanism during gear shifting is still a difficult challenge because gear shifting may cause discomfort to the occupants.To improve the swiftness of gear shifting,this paper proposes a coordinated shift control method based on the dynamic tooth alignment(DTA)algorithm for nonsynchronizer automated mechanical transmissions(NSAMTs)of EVs.After the speed difference between the sleeve(SL)and target dog gear is reduced to a certain value by speed synchronization,angle synchronization is adopted to synchronize the SL quickly to the target tooth slofs angular position predicted by the DTA.A two-speed planetary NS AMT is taken as an example to carry out comparative simulations and bench experiments.Results show that gear shifting duration and maximum jerk are reduced under the shift control with the proposed method,which proves the effectiveness of the proposed coordinated shift control method with DTA.展开更多
基金supported by the National Basic Research Program of China(973 Program2012CB821702)+1 种基金the National Natural Science Foundation of China(21233009 and 21173221)the State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences
文摘Two novel coordination compounds,1[Zn4（L1）4（NO3）2（H2O）2]（NO3）2·2H2O and 2[Mn2（L2）2（DMF）（H2O）3]（ClO4）2·DMF（HL1 = N＇-[（1E）-pyridine-2-ylmethylidene]pyrazine-2-carbohydrazide,H2L2 = 2-hydroxy-3-methoxybenzaldehyde（pyrazin-2-ylcarbonyl）hydrazone）,based on the N-N bridged ligands were prepared and structurally characterized.Compound 1represents the[2＊2]molecular squares,in which both N atoms belonging to the N-N bridged ligands are connected to the Zn centers.The emission of compound 1 exhibits a blue shift,which can be assigned to strong electrostatic interaction between Zn^Ⅱ ions and the L1^-1.Compound 2represents a rare phenol-O bridged Mn2^Ⅱ complex.The magnetic investigation indicates weak antiferromagnetic interactions between the Mn^Ⅱ centers.
基金This work was supported by the Science and Technology Planning Project of Guangdong Province,China(Grant Nos.2015B010119002 and 2016B010132001).
文摘Multispeed transmissions can enhance the dynamics and economic performance of electric vehicles(EVs),but the coordinated control of the drive motor and gear shift mechanism during gear shifting is still a difficult challenge because gear shifting may cause discomfort to the occupants.To improve the swiftness of gear shifting,this paper proposes a coordinated shift control method based on the dynamic tooth alignment(DTA)algorithm for nonsynchronizer automated mechanical transmissions(NSAMTs)of EVs.After the speed difference between the sleeve(SL)and target dog gear is reduced to a certain value by speed synchronization,angle synchronization is adopted to synchronize the SL quickly to the target tooth slofs angular position predicted by the DTA.A two-speed planetary NS AMT is taken as an example to carry out comparative simulations and bench experiments.Results show that gear shifting duration and maximum jerk are reduced under the shift control with the proposed method,which proves the effectiveness of the proposed coordinated shift control method with DTA.
