Two novel coordination polymers with molecular structures(2MI)+[Zn(2MI)Cl3]-(1) and(2MI)+NO3-(2) based on ligand 2-methylimidazole(2MI) were synthesized under solution method. Compound 1 crystallizes in ...Two novel coordination polymers with molecular structures(2MI)+[Zn(2MI)Cl3]-(1) and(2MI)+NO3-(2) based on ligand 2-methylimidazole(2MI) were synthesized under solution method. Compound 1 crystallizes in the monoclinic system, space group Cc with a=7.489(2), b=13.448(4), c=13.983(4) , β=98.402(2)°, Z=4 and V=102.246(2) 3. Compound 2 crystallizes in the orthorhombic system, space group pnma with a=14.296(3), b=6.3180(12), c=7.3862(13) , β=90°, Z=4 and V=667.1(2) 3. Dielectric measurements show compounds 1 and 2 have reversible dielectric anomalous behaviors with variation frequencies at different temperature.展开更多
In this paper,using the fractional Fourier law,we obtain the fractional heat conduction equation with a time-fractional derivative in the spherical coordinate system.The method of variable separation is used to solve ...In this paper,using the fractional Fourier law,we obtain the fractional heat conduction equation with a time-fractional derivative in the spherical coordinate system.The method of variable separation is used to solve the timefractional heat conduction equation.The Caputo fractional derivative of the order 0 〈 α≤ 1 is used.The solution is presented in terms of the Mittag-Leffler functions.Numerical results are illustrated graphically for various values of fractional derivative.展开更多
基金Supported by the National Natural Science Foundation of China(No.21201087 and 21671084)NSF of Jiangsu Province(BK20131244 and BK20130460)+1 种基金the Foundation of Jiangsu Educational Committee(16KJB430011)the Qing Lan Project of Jiangsu Province and Jiangsu Overseas Research&Training Program for University Prominent Young&Middle-aged Teacher and Presidents,Six talent peaks project in Jiangsu Province(2014-XCL-008)
文摘Two novel coordination polymers with molecular structures(2MI)+[Zn(2MI)Cl3]-(1) and(2MI)+NO3-(2) based on ligand 2-methylimidazole(2MI) were synthesized under solution method. Compound 1 crystallizes in the monoclinic system, space group Cc with a=7.489(2), b=13.448(4), c=13.983(4) , β=98.402(2)°, Z=4 and V=102.246(2) 3. Compound 2 crystallizes in the orthorhombic system, space group pnma with a=14.296(3), b=6.3180(12), c=7.3862(13) , β=90°, Z=4 and V=667.1(2) 3. Dielectric measurements show compounds 1 and 2 have reversible dielectric anomalous behaviors with variation frequencies at different temperature.
基金supported by the National Natural Science Foundation of China(11072134 and 11102102)
文摘In this paper,using the fractional Fourier law,we obtain the fractional heat conduction equation with a time-fractional derivative in the spherical coordinate system.The method of variable separation is used to solve the timefractional heat conduction equation.The Caputo fractional derivative of the order 0 〈 α≤ 1 is used.The solution is presented in terms of the Mittag-Leffler functions.Numerical results are illustrated graphically for various values of fractional derivative.