Acrylic acid was grafted onto the surface of cotton fabric after being short time treated by corona-discharge inair in the presence of initiator.The means of gas-phaseSO<sub>2</sub> derivatization was used...Acrylic acid was grafted onto the surface of cotton fabric after being short time treated by corona-discharge inair in the presence of initiator.The means of gas-phaseSO<sub>2</sub> derivatization was used along with ESCA to deter-mine corona-discharge-induced-hydroperoxidegroups on the surface.The content of hydroperoxideshows a maxmium value at 15 sec.of corona-dischargetime.Effect of corona treatment time and various con-centration initlator on graft yield was studied.The addit-ion of initiator increases the graft yield.Acceleratedgraft with an increase in the concentration of Mohr’s saltshows that peroxide groups on the corona treated cottonfabric initiate graft copolymerization.展开更多
The novel perfluorinated vinyl ether containing sulfonimide functionality CF2 = CFORfSO2NHSO2CF3 was synthesized by multiple reaction steps. It could be copolymerized with tetraflu-oroethylene by radox initiator to gi...The novel perfluorinated vinyl ether containing sulfonimide functionality CF2 = CFORfSO2NHSO2CF3 was synthesized by multiple reaction steps. It could be copolymerized with tetraflu-oroethylene by radox initiator to give a novel perfluorinated ionomer polymer. Its physical and chemical properties were studied.展开更多
文摘Acrylic acid was grafted onto the surface of cotton fabric after being short time treated by corona-discharge inair in the presence of initiator.The means of gas-phaseSO<sub>2</sub> derivatization was used along with ESCA to deter-mine corona-discharge-induced-hydroperoxidegroups on the surface.The content of hydroperoxideshows a maxmium value at 15 sec.of corona-dischargetime.Effect of corona treatment time and various con-centration initlator on graft yield was studied.The addit-ion of initiator increases the graft yield.Acceleratedgraft with an increase in the concentration of Mohr’s saltshows that peroxide groups on the corona treated cottonfabric initiate graft copolymerization.
基金Project supported by the National Natural Science Foundation of China(Nos.20032010,20072049).
文摘The novel perfluorinated vinyl ether containing sulfonimide functionality CF2 = CFORfSO2NHSO2CF3 was synthesized by multiple reaction steps. It could be copolymerized with tetraflu-oroethylene by radox initiator to give a novel perfluorinated ionomer polymer. Its physical and chemical properties were studied.
