Flyrock is one of the most hazardous events in blasting operation of surface mines. There are several empirical methods to predict flyrock. Low performance of such models is due to the complexity of flyrock analysis. ...Flyrock is one of the most hazardous events in blasting operation of surface mines. There are several empirical methods to predict flyrock. Low performance of such models is due to the complexity of flyrock analysis. Existence of various effective parameters and their unknown relationships are the main reasons for inaccuracy of the empirical models. Presently, the application of new approaches such as artificial intelligence is highly recommended. In this paper, an attempt has been made to predict flyrock in blasting operations of Soungun Copper Mine, Iran incorporating rock properties and blast design parameters using support vector machine (SVM) method. To investigate the suitability of this approach, the predictions by SVM have been compared with multivariate regression analysis (MVRA), too. Coefficient of determination (CoD) and mean absolute error (MAE) were taken as performance measures. It was found that CoD between measured and predicted flyrock was 0.948 and 0.440 by SVM and MVRA, respectively, whereas MAE between measured and predicted flyrock was 3.11 and 7.74 by SVM and MVRA, respectively.展开更多
Oxides with different crystal phases can have important effects on the configuration of surface atoms,which can further affect the distribution of hydrogenation sites and acidic sites as well as the competitions of th...Oxides with different crystal phases can have important effects on the configuration of surface atoms,which can further affect the distribution of hydrogenation sites and acidic sites as well as the competitions of these varied types of catalytic sites.This could be potentially used to tailor the distribution of the products.In this study,zirconium oxides with different crystal phases supported copper catalysts were prepared for the hydrogenation of the biomass-derived furfural,vanillin,etc.The results showed that both calcination temperature and Cu species affected the shift of zirconia from tetragonal phase to the monoclinic phase.Monoclinic zirconia supported copper catalyst can effectively catalyze the hydrogenation of furfural to furfuryl alcohol via hydrogenation route due to its low amount of Brønsted acidic sites,although the surface area and the exposed metallic Cu surface area were much lower than the tetragonal zirconia supported copper catalyst.Zirconia with tetragonal or tetragonal/monoclinic phases supported copper catalysts contain abundant acidic sites and especially the Br?nsted acidic sites,which catalyzed mainly the conversion of furfural via the acid-catalyzed routes such as the acetalization,rather than the hydrogenation.The acidic sites over the Cu/ZrO_(2)catalyst played more predominant roles than the hydrogenation sites in determining the conversion of the organics like furfural and vanillin.展开更多
文摘Flyrock is one of the most hazardous events in blasting operation of surface mines. There are several empirical methods to predict flyrock. Low performance of such models is due to the complexity of flyrock analysis. Existence of various effective parameters and their unknown relationships are the main reasons for inaccuracy of the empirical models. Presently, the application of new approaches such as artificial intelligence is highly recommended. In this paper, an attempt has been made to predict flyrock in blasting operations of Soungun Copper Mine, Iran incorporating rock properties and blast design parameters using support vector machine (SVM) method. To investigate the suitability of this approach, the predictions by SVM have been compared with multivariate regression analysis (MVRA), too. Coefficient of determination (CoD) and mean absolute error (MAE) were taken as performance measures. It was found that CoD between measured and predicted flyrock was 0.948 and 0.440 by SVM and MVRA, respectively, whereas MAE between measured and predicted flyrock was 3.11 and 7.74 by SVM and MVRA, respectively.
基金supported by the National Natural Science Foundation of China(No.51876080)the Program for Taishan Scholars of Shandong Province Government。
文摘Oxides with different crystal phases can have important effects on the configuration of surface atoms,which can further affect the distribution of hydrogenation sites and acidic sites as well as the competitions of these varied types of catalytic sites.This could be potentially used to tailor the distribution of the products.In this study,zirconium oxides with different crystal phases supported copper catalysts were prepared for the hydrogenation of the biomass-derived furfural,vanillin,etc.The results showed that both calcination temperature and Cu species affected the shift of zirconia from tetragonal phase to the monoclinic phase.Monoclinic zirconia supported copper catalyst can effectively catalyze the hydrogenation of furfural to furfuryl alcohol via hydrogenation route due to its low amount of Brønsted acidic sites,although the surface area and the exposed metallic Cu surface area were much lower than the tetragonal zirconia supported copper catalyst.Zirconia with tetragonal or tetragonal/monoclinic phases supported copper catalysts contain abundant acidic sites and especially the Br?nsted acidic sites,which catalyzed mainly the conversion of furfural via the acid-catalyzed routes such as the acetalization,rather than the hydrogenation.The acidic sites over the Cu/ZrO_(2)catalyst played more predominant roles than the hydrogenation sites in determining the conversion of the organics like furfural and vanillin.
