Types, Metallogenic Environments and Characteristics of Temporal and Spatial Distribution of Copper Deposits in China

Based upon a comprehensive study of 123 copper deposits in China. this paper reaches the following conclusions: 1. The crust in China was solidified pretty late; with the accretion of the plate, the copper mineralization moved towards its margin in space and became successively younger in age. 2. The major copper ore types ever found in the world have mostly been discovered in China, in which the porphyry type seems to be the most important and the massive sulfide type in the transitional bed between marine clastic and carbonate rocks is clearly defined. 3. Carbonate strata are widespread in China and their deposition lasted for a long geological period, so the proportion of copper deposits occurring in them is large as compared with other parts of the world. 4. Seven metallogenic epochs can be recognized, in which the Mesozoic one plays the leading role and the middle(late) Palaeozoic and Cenozoic ones are next in importance. Mineralization was comparatively simple in the early geological period. and became diversified later on. In the early epochs copper deposits related to basaltic magmatism and metamorphosed marine sediments predominated, whereas in the later epochs those related to granitic magmatism and continental sedimentation were dominant. 5. There exist in China thirteen metallogenic provinces, of which the Lower Yangtze downwarping belt, Sanjiang fold system, Jiangnan axis and Xikang-Yunnan axis are of greater significance. 6. The crustal mobility in China was rather pronounced, the polycyclic evolution of the crust has resulted in such obvious phenomena as the inheritance of mineralization, the coexistence of various types and the superposition of different genetic types.

Geochemistry Characteristics of Granodiorite Porphyry in the Degongniuchang Copper Deposit, Muli, Sichuan Province, China

1 Introduction 1The Sanjiang region in SE Tibet Plateau and NW Yunnan is known to have formed by amalgamation of Gongwanaderived continental blocks and arc terranes as a result of oceanic subduction followed by continental

Geochemical Characteristics and Zonation of Primary Halos of Pulang Porphyry Copper Deposit,Northwestern Yunnan Province,Southwestern China

The Pulang （普朗） porphyry copper deposit, located in the southern segment of the Yidun-Zhongdian （义敦-中甸） island arc ore-forming belt of the Tethys-Himalaya ore-forming domain, is a recently discovered large copper deposit. Compared with the composition of granodiorite in China, the porphyry rocks in this area are enriched in W, Mo, Cu, Au, As, Sb, F, V, and Na2O （K1≥1.2）. Compared with the composition of fresh porphyry rocks in this district, the mineralized rocks are enriched in Cu, Au, Ag, Mo, Pb, Zn, W, As, Sb, and K2O （K2≥1.2）. Some elements show clear anomalies, such as Zn, Ag, Cu, Au, W, and Mo, and can be regarded as pathfinders for prospecting new ore bodies in depth. It has been inferred from factor analysis that the Pulang porphyry copper deposit may have undergone the multiple stages of alteration and mineralization： （a） Cu-Au mineralization; （b） W-Mo mineralization; and （c） silicification and potassic metasomatism in the whole ore-forming process. A detailed zonation sequence of indicator elements is obtained using the variability index of indicator elements as follows： Zn→Ag→Cu→Au→W→Mo. According to this zonation, an index such as （Ag＊Zn）D/（Mo×W）D can be constructed and regarded as a significant criterion for predicting the Cu potential at a particular depth.

Geological and Geochemical Characteristics and Genesis of the Shaxi Porphyry Copper (Gold) Deposits, Anhui Province

The Shaxi porphyry copper (gold) deposits are a typical example of porphyry copper deposits associated with diorite in eastern China. Quartz diorite, which hosts the deposits, has a Rb-Sr isochron age of 127.9 ± 1.6 Ma. Geochemically, the rock is rich in alkalis (especially sodium), light rare earth elements (LREE) and large-ion lithophile elements (LILE), and has a relatively low initial strontium isotopic ratio (Isr=0.7058); thus it is the product of differentiation of crust-mantle mixing source magma. The model of alteration and mineralization zoning is similar to the Hollister (1974) diorite model. The ore fluids have a relatively high salinity and contain significant amounts of CO2, Ca2+, Na+ and ***CI?. The homogenization temperatures of fluid inclusions for the main mineralization stage range from 280 to 420°C, the δ18O values of the ore fluids vary from 3.51 to 5.52 %, the δD values are in the range between ?82.4 and ?59.8 %, the δ34S values of sulphides vary from ?0.3 to 2.49 %, and the δ13C values of CO2 in inclusions range between ?2.66 and ?6.53 %. Isotope data indicate that the hydrothermal ore fluids and ore substances of the Shaxi porphyry copper (gold) deposits were mainly derived from magmatic systems.

The Mechanism of Structural Control of Ore Formation and Geochemical Characteristics in the Massive Sulfide Deposits of the Wushan Copper Ore Field,Jiangxi

The ore-controlling mechanism of the bedding fault system in the massive sulfide deposits of the Wushancopper orefield may be generalized as the control of ore deposition by optimum surface in an ore-formingstructural trap. The mechanism has three major features: (1) timing of mineralization; (2) positioning of hostformation; and (3) dependence of ore-controlling structure on properties of rocks. The 'optimum surface' is adivisional structural plane which marks obvious difference in physical, chemical and mechanical properties andis favorable for mineralization. It is also a unity of structures. lithofacies and orebodies. The structural and geochemical characteristics of the ore deposits indicate the migration trend of the ma-jor characteristic clements in the ore-controlling fault belt: elements with a small radius (Si, Fe, Mg and Al)moved towards and concentrated at the center of the belt while large-radius ones (Ca, K and Na) were remotefrom the center.

Geological Characteristics and Its Metallogenesis of Daolundaba Copper Polymetallic Deposits,Inner Mongolia

1 Geology Daolundaba copper polymetallic deposit occurs in West Ujimqin Banner,the Xilin Gol League of Inner Mongolia,along the west side of South part of Daxinganling ore belt,whose tectonic position just lies at the junction of Siberian Block in the south part,North China Block in the north and Songliao block in the east.The Daolundaba copper polymetallic deposit is hosted by the Lower Proterozoic Baoyintu group of biotite-plagioclase gneiss(Pt1by),upper Permian Linxi formation of sandy slate(P2l),and the Hercynian Qianjinchang pluton of biotite granite.

Rock-forming mechanism of Qingshanjiao intrusion in Dongguashan copper(gold) deposit, Tongling area, Anhui province, China

Dongguashan deposit is a large porphyry-skarn copper（gold） deposit in Tongling ore district. The Qingshanjiao intermediate acid intrusion of Yanshanian had a direct genetic relationship with mineralization. The magma origin, rock-forming dynamic background and rock-forming process were studied, and the rock-forming mechanism of Qingshanjiao intrusion was discussed, based on geological characteristics, detailed observation of petrography and systematic investigation of petrochemistry, trace elements and REE geochemistry characteristics of Qingshanjiao intrusion. The results show that Qingshanjiao rock body belongs to high-K calc-alkaline series with higher LREE elements, Th, Rb and Sr abundance, but depleted in HREE elements, Ba, Nb and Ta. The primary magma originated from the mantle-crust mixtures which were caused by basaltic magma of mantle mixing with syenite magma of partial melting of the lower crust, and the formation environment of Qingshanjiao intrusion was emplaced in the transitional environment from compression to extension. The Harker diagram and hybrid structures of plagioclase and potassium feldspar indicate that the fractional crystallization occurred in the process of magmatic evolution. The petrochemistry, trace elements and REE geochemistry characteristics indicate that the magma was contaminated by crustal material during the rock-forming. These results suggested that the Qingshanjiao intrusion was formed by fractional crystallization and assimilation and hybridization of mantle-crust magma in the transitional environment from compression to extensional.

Metallogeny of Shoshonite-Hosted Copper-Gold Deposits in Middle-South Parts of Tancheng-Lujiang Deep Fault Zone and Its Vicinity, Eastern China

The middle south parts of Tancheng Lujiang deep fault zone and its vicinity are an important locality of Cu Au deposits related to Mesozoic volcanic subvolcanic magmatism in eastern China. According to their metallogenic features and ore forming conditions, copper gold deposits in this district are ascribed to two groups: the epithermal group which can be further divided into tellurium gold type, quartz adularia type and quartz manganoansiderite type; the magmatic hydrothermal group which includes porphyry Cu Au deposit, breccia pipe porphyry type Au Cu deposit and skarn type Au Cu deposit. In this paper, characteristics of six typical shoshonite hosted Cu Au deposits are outlined. Additionally, the factors that control the metallogenesis and distribution of these Cu Au deposits are discussed preliminarily.

Diagenesis-Mineralization and Ore Prospecting of the Yangla Copper Deposit, Yunnan Province, Southwest China

The large-scale Yangla copper deposit, located in the central part of the Sanjiang Tethys polymetallic belt, is structurally controlled by the Jinsha River Fault and Yangla Fault. This deposit consists of seven ore blocks, including the Beiwu, Nilv, Jiangbian, Linong, Lunong, Tongjige and Jiaren. The Cu metal prospective reserves of the Yangla deposit are above 1 million tons. There are widely distributed Indosinian granodiorite and also many gabbro-diabase dikes and few quartz porphyries exposed in the Yangla ore district. The ore-hosting rocks are diopsode-garnet skarn, sericitie sandy slate and metamorphic quartz sandstone of the first member of the Devonian Linong Formation. Ore bodies occur as layered, stratoid, lenticular and veined shapes, and are strictly controlled by rocks, strata and structures.

Geochemistry of Subvolcanic-Type Copper-Silver Deposits in Eastern China

The metallogenesis of subvolcanic deposits is controlled by subvolcanic activities. The copper polymetallic deposits are genetically related to intermediate-acid rocks, and the silver polymetallic deposits are more closely related to acid rocks. The abundance of Cu is relatively high in the intermediate-acid rocks and subvolcanic rocks, whereas the abundances of Pb, An and Ag are high in acid rocks, indicating rich ore-forming elements in original magmas. The study of REEs shows that the magmatic type related to copper deposits is the syntectic type, and that related to silver polymetallic deposits is mainly the re-melting type. The deposits were formed under medium-low temperatures and low salinity. The metallogenic times were the late stage of the early Yanshanian or the late Yanshanian, dating 78–147 Ma.

Geology and mineralization of the Pulang supergiant porphyry copper deposit(5.11 Mt)in Shangri-la,Yunnan Province,China:A review

The porphyry copper belt in the Geza island arc in southwestern China is the only Indosinian porphyry copper metallogenic belt that has been discovered and evaluated so far.The Pulang porphyry copper deposit(also referred to as the Pulang deposit)in this area has proven copper reserves of 5.11×106 t.This deposit has been exploited on a large scale using advanced mining methods,exhibiting substantial economic benefit.Based on many research results of previous researchers and the authors’team,this study proposed the following key insights.(1)The Geza island arc was once regarded as an immature island arc with only andesites and quartz diorite porphyrites occurring.This understanding was overturned in this study.Acidic endmember components such as quartz monzonite porphyries and quartz monzonite porphyries have been identified in the Geza island arc,and the mineralization is mainly related to the magmatism of quartz monzonite porphyries.(2)Complete porphyry orebodies and large vein orebodies have developed in the Pulang deposit.Main orebody KT1 occurs in the transition area between the potassium silicate alteration zone of quartz monzonite porphyries and the sericite-quartz alteration zone.Most of them have developed in the potassium silicate alteration zone.The main orebody occurs as large lenses at the top of the hanging wall of rock bodies,with an engineering-controlled length of 1920 m and thickness of 32.5‒630.29 m(average:187.07 m).It has a copper grade of 0.21%-1.56%(average:0.42%)and proven copper resources of 5.11×10^(6) t,which are associated with 113 t of gold,1459 t of silver,and 170×10^(3) t of molybdenum.(3)Many studies on diagenetic and metallogenic chronology,isotopes,and fluid inclusions have been carried out for the Pulang deposit,including K-Ar/Ar-Ar dating of monominerals(e.g.,potassium feldspars,biotites,and amphiboles),zircon U-Pb dating,and molybdenite Re-Os dating.The results show that the porphyries in the Pulang deposit are composite plutons and can be classified into pre-mineralization quartz diorite porphyrites,quartz monzonite porphyries formed during the mineralization,and post-mineralization granite porphyries,which were formed at 223±3.7 Ma,218±4 Ma,and 207±3.9 Ma,respectively.The metallogenic age of the Pulang deposit is 213‒216 Ma.(4)The petrogeochemical characteristics show that the Pulang deposit has the characteristics of volcanic arc granites.The calculation results of trace element contents in zircons show that quartz monzonite porphyries and granite porphyries have higher oxygen fugacity.The isotopic tracing results show that the diagenetic and metallogenic materials were derived from mixed crust-and mantle-derived magmas.

Magmatic Hydrothermal Origin of the Wenyu Copper Polymetallic Deposit, Southern Lancangjiang Zone, SW China

The Wenyu copper polymetallic deposit, with proven reserves of about 0.23 Mt Cu, 394 t Ag and 0.04 Mt Pb, is located in the central part of the Lancangjiang volcanic rock belt （Fig. l a）, which is one of the most potential copper polymetallic exploration areas in SW China.

Post-ore Modification and Preservation of the Indosinian Porphyry Copper Deposit in Geza Arc, Yunnan, SW China

Objective The post-ore modification and preservation of porphyry copper deposits is controlled and influenced by various geological processes, and the regional uplift and denudation is the most important factors. This study used biotite mineral geobarometer and Apatite Fission Track （AFT） to restore the uplift evolution of the granitic porphyries in the Geza arc and to obtain quantitative data of rock erosion degree and denudation rate.

Re-Os Dating of Chalcopyrite from the Lala IOCG Deposit in the Kangdian Copper Belt,China

This study focused on the typical Precambrian copper- iron-gold-uranium deposits in the southwestern margin of the Yangtze block, such as the Lala in Huili, Dahongshan in Xinping, Yinachang in Wuding, and Chahe in Yuanjiang. Through systematically sampling of rocks, mineral and single mineral samples, this study discussed the continental geodynamics, age of magmatic rocks and metallogenic epoch, coupling relationship between polymetallic elements and ore-forming fluid, and the coupling relationship between magma evolution and polymetallic mineralization based on the latest metallogenic theory and modern analytical techniques.

REE Characteristics of a New Uranium Mineral from the Xianshi Uranium Deposit, South China

Objective Galuskin et al. （2011） firstly discovered that vorlanite （CaU^6＋/4＋）04 is a rare Ca-rich mineral with a fluorite-type structure, which is isostructural with uraninite （U^4＋O2）. Previous studies of the Xianshi granite-related uranium deposit reported that uraninite and pyrite are the major ore minerals whereas galena, clausthalite （PbSe）, and pyrite are minor phases in the ores. A more detailed petrographic and geochronological study of the uranium minerals from the Xianshi deposit showed that there are three distinct types of uraninite-bearing assemblages which formed at three mineralization episodes （Fig. la; Luo et al., 2015）.

3D electrical structure of porphyry copper deposit:A case study of Shaxi copper deposit

Located in Lu-Zong ore concentration area, middle-lower Yangtze metallogenic belt, ShaXi porphyry copper deposit is a typical hydrothermal deposit. To investigate the distribution of deep ore bodies and spatial characteristics of host structures, an AMT survey was conducted in mining area. Eighteen pseudo-2D resistivity sections were constructed through careful processing and inversion. These sections clearly show resistivity difference between the Silurian sandstones formation and quartz diorite porphyry and this porphyry copper formation was controlled by the highly resistive anticlines. Using 3D block Kxiging interpolation method and 3D visualization techniques, we constructed a detailed 3D resistivity model of quartz diorite porphyry which shows the shape and spatial distribution of deep ore bodies. This case study can serve as a good example for future ore prospecting in and around this mining area.

Grade and Tonnage Model of Contact Metasomatic Copper Deposit in China

Grade-tonnage model is one of the research frontiers of systematical exploration theory. Based on the “Reserve Database of Mineral Resources in China (1997)”, this paper establishes the geological model, grade model, tonnage model, grade-tonnage model and tonnage-sequence model of contact metasomatic copper deposits in China. The mathematical properties of these models are described in detail.

Features and significance of the Yudai porphyry copper deposit in the Kalatag district,eastern Tianshan,NW China

1 Introduction The eastern Tianshan region covers around 60000 km2in area and is located in the eastern part of Xinjiang.The district contains various types mineral commodities including Cu,Ni,Au,Fe,Pb and Zn(Wang et al.,2006).The Dannanhu belt in eastern part of the area is interpreted as a volcanic arc and forms an important mineralized zone bordered by the Turpan-Hami Basin to the north and Kanggur back-arc basin to the south.

Geological Setting of the Porphyry Copper Deposit Series of China

In accordance with the terms global minerogenic series, regional metallogenic series and ore depositsystem which are put forward here, metallogenic environments at different levels are discussed for theporphyry copper deposit series in China. It is considered that the porphyry copper deposits in China arecontrolled not only by the boundaries of convergent plates but, more importantly, by the boundaries ofintraplate divergent mobile belts and those between continental blocks. Besides, the emplacement ofhypabyssal and supper-hypabyssal calc-alkaline magmas and the temporal-spatial distribution of China'sporphyry copper deposits are governed by the superimposition of fracture systems of the pre-Alpine base-ments. Meso-Cenozoic cover and continental-margin new-born crust. Such a superimposition has also re-sulted in the polycyclicity of the mineralization.

Studies on Characteristics of Fracture Lithofaciesin Wenxipo W-Cs-Rb Polymetallic Deposit,Hainan Province,China

1 Introduction Wenxipo W-Cs-Rb polymetallic depositis located in Fengshou rubidium-cesium polymetallic prospecting area in Danzhou City,Hainan Province,China.The hornstone facies,a thermal metamorphic facies,