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Effect of Organic Materials on Speciation of Copper inSoil Solution 被引量:6
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作者 WANG GUO CHEN JIANBIN +1 位作者 GU XUNGANG GAO SHAN and CAI HAIYANG(Department of Land and Environmental Science, Fujian Agricultural University, Fuzhou 350002 (Chica)) 《Pedosphere》 SCIE CAS CSCD 1999年第2期139-146,共8页
Incubation of two soils, a red soil derived from granodiorte and a fluvo-aquic soil from alluvial deposit,with rice straw, Chinese milk vetch and pig manure under submerged condition were conducted to study thespecies... Incubation of two soils, a red soil derived from granodiorte and a fluvo-aquic soil from alluvial deposit,with rice straw, Chinese milk vetch and pig manure under submerged condition were conducted to study thespecies of Cu in soil solutions as affected by the organic materials. The organic materials increased totalsoluble Cu by raising dissolved organic carbon (DOC) in soil solution when the solution pH values were belowthe range in which Cu deposited quickly. When the solution pH rose to this range, the increase of DOCdid not raise total soluble Cu. Total soluble Cu in all the treatments dropped with incubation time. Afteradding organic materials labile Cu dropped with incubation time and decreased sharply in the pH range ofCu precipitation. Addition of organic materials enhanced slowly labile Cu but depressed the ratio of labileCu to total soluble Cu. Slowly labile Cu decreased with incubation time. Stepwise multiple linear regressionanalysis showed that total soluble Cu was positively correlated with Eh and DOC (P=0.0025), labile Cuwas negatively correlated with pH (P=0.011 8), and slowly labile Cu was positively correlated with Eh andDOC (P=0.002 2). Both the labile and slowly labile Cu were correlated with total soluble Cu at extremelysignificant levels. 展开更多
关键词 coppert dissolved organic carbon organic material SPECIATION
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用双波长分光光度法测定锡铜锌合金镀液中铜、锌的含量 被引量:1
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作者 罗序燕 朱传华 成荣超 《材料保护》 CAS CSCD 北大核心 2008年第8期69-71,共3页
锡铜锌合金镀层已广泛应用于电子和机械产品的防护,为此,以5-Br-2-吡啶偶氮-5-二乙氨基酚(5-Br—PADAP)为显色剂,采用双波长分光光度法对新型环保锡铜锌合金镀液中的铜、锌含量进行同时测定。Cu^2+的测量波长是555nm,参比波长是5... 锡铜锌合金镀层已广泛应用于电子和机械产品的防护,为此,以5-Br-2-吡啶偶氮-5-二乙氨基酚(5-Br—PADAP)为显色剂,采用双波长分光光度法对新型环保锡铜锌合金镀液中的铜、锌含量进行同时测定。Cu^2+的测量波长是555nm,参比波长是561nm;Zn^2+的测量波长是538nm,参比波长是568nm。试验考察了酸度、甘油用量、显色剂用量、OP乳化剂用量以及干扰离子对测定的影响。结果表明:铜、锌含量在0-20μg/25mL范围内均服从郎伯-比尔定律,样品加标回收率为98%以上。该方法简便、快速,准确度高,不经分离可直接对锡铜锌合金镀液中的铜、锌进行快速测定,结果令人满意。 展开更多
关键词 测定 锡铜锌合金镀液 5-Br—PADAP 双波长分光光度法
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