Two depositional processes controlled the muddy sediments in the South China Sea Basin. Bathyal sediments depositional rate was 7.66 cm/la in the northern continental slope of the Basin where turbidity current was alm...Two depositional processes controlled the muddy sediments in the South China Sea Basin. Bathyal sediments depositional rate was 7.66 cm/la in the northern continental slope of the Basin where turbidity current was almost nonexistent. In the northern margin of the Basin, abyssal sediment depositional rate was 5.05cm/ka and turbidity current occurrence averaged 0.22 per 1000 years. Turbidite was found in the middle of the Basin. Over half of the muddy sediments in the deep sea basin were deposited by turbidity currents, and had typically graded bedding, and contents of organic matter, calcareous material and micropaleontologic species inconsistent with the environment.展开更多
The capacity fade of spinel lithium manganese oxide in lithium-ion batteries is a bottleneck challenge for the large-scale application.The traditional opinion is that Mn（Ⅱ） ions in the anode are reduced to the meta...The capacity fade of spinel lithium manganese oxide in lithium-ion batteries is a bottleneck challenge for the large-scale application.The traditional opinion is that Mn（Ⅱ） ions in the anode are reduced to the metallic manganese that helps for catalyzing electrolyte decomposition.This could poison and damage the solid electrolyte interface（SEI） film,leading to the the capacity fade in Li-ion batteries.We propose a new mechanism that Mn（Ⅱ） deposites at the anode hinders and/or blocks the intercalation/de-intercalation of lithium ions,which leads to the capacity fade in Li-ion batteries.Based on the new mechanism assumption,a kind of new structure with core-shell characteristic is designed to inhabit manganese ion dissolution,thus improving electrochemical cycle performance of the cell.By the way,this mechanism hypothesis is also supported by the results of these experiments.The LiMn2-xTixO4 shell layer enhances cathode resistance to corrosion attack and effectively suppresses dissolution of Mn,then improves battery cycle performance with LiMn_2O_4 cathode,even at high rate and elevated temperature.展开更多
In this study, a novel core-shell structure of ZSM-5@Mg(Al)O(abbreviated as Z@MA) was designed by using the sol-gel method, and the influence of different weight ratios of Mg(Al)O/ZSM-5 on the structure and catalytic ...In this study, a novel core-shell structure of ZSM-5@Mg(Al)O(abbreviated as Z@MA) was designed by using the sol-gel method, and the influence of different weight ratios of Mg(Al)O/ZSM-5 on the structure and catalytic performance was investigated. The as-obtained materials were characterized by XRD, N_2-physisorption, SEM, FT-IR, NH_3-TPD and XPS analyses. The results showed that, with the increase of the weight ratio of Mg(Al)O/ZSM-5, the thickness of Mg(Al)O shell was improved, and the pore structure and physiochemical properties of core-shell materials were directly modified. After introduction of Mg(Al)O, the acidity properties of different materials were significantly suppressed. Meanwhile, more Sn oxide species in Z@MA could facilitate the anchoring of Pt on the support. By effectively employing these modifications, the capacity of the catalysts to accommodate coke was significanty improved and the carbon deposits were migrated from active metal to the carrier. When the weight ratio was equal to 3, the catalyst PtSnNa/Z@MA showed a highest conversion and high selectivity in propane dehydrogenation.展开更多
Recent petro-structural investigations on the Faboula gold deposit located in the Bougouni-Kékoro basin, in southern Mali, north-west of the Leo-Man Shield, have provided new data on the nature and spatial organi...Recent petro-structural investigations on the Faboula gold deposit located in the Bougouni-Kékoro basin, in southern Mali, north-west of the Leo-Man Shield, have provided new data on the nature and spatial organization of the lithostratigraphic units as well as their deformation style. The deposit is covered by a thick lateritic layer and is hosted by a metavolcano-sedimentary sequence of Paleoproterozoic age intersected by intrusive bodies and filled fractures of various shape</span></span><span><span><span style="font-family:"">s</span></span></span><span><span><span style="font-family:""> and type</span></span></span><span><span><span style="font-family:"">s</span></span></span><span><span><span style="font-family:"">. The lithostratigraphic units consist of metagreywackes, metasiltstones, meta-argillites, slates and schists. Metagreywackes and metasiltstones are generally feldspathic, both may contain biotite and locally amphibole, just as slates may contain andalusite which is locally stretched. Plutonic units most often occur as stocks or as dikes on the drill core, up to 1 m. The metavolcano-sedimentary rocks are schistose and deformed under greenschist facies conditions, </span></span></span><span><span><span style="font-family:"">and </span></span></span><span><span><span style="font-family:"">locally they reach the epidote-amphibolite facies. The structural study revealed that the deposit is affected by several stages of deformation evolving from a ductile type to a brittle type via a ductile-brittle type. The dominant ductile and brittle-ductile de<span>formations show a combination of isoclinal folding and strike-slip faults.</span> <span>Both the isoclinal folding and the strike-slip faults whose sigmoidal en-echelon</span> tension gashes indicate a dextral movement in the NNE-SSW direction are the result of the same ENE-WSW regional shortening. Consequently, they highlight a transpressive deformation. This deformation noted here D<sub>2Fb</sub>, could be equivalent to the regional D<sub>2</sub> or D<sub>3</sub> deformations identified at the scale of the Leo-Man Shield if we refer to the style of deformation. There is an abundance of quartz veins networks. Their relation within the structural features indicate</span></span></span><span><span><span style="font-family:"">s</span></span></span><span><span><span style="font-family:""> that the mineralization is structurally controlled during a hydrothermal event linked certainly to the circulations of fluids during the transpressive event D<sub>2Fb</sub>.展开更多
文摘Two depositional processes controlled the muddy sediments in the South China Sea Basin. Bathyal sediments depositional rate was 7.66 cm/la in the northern continental slope of the Basin where turbidity current was almost nonexistent. In the northern margin of the Basin, abyssal sediment depositional rate was 5.05cm/ka and turbidity current occurrence averaged 0.22 per 1000 years. Turbidite was found in the middle of the Basin. Over half of the muddy sediments in the deep sea basin were deposited by turbidity currents, and had typically graded bedding, and contents of organic matter, calcareous material and micropaleontologic species inconsistent with the environment.
基金Funded by the National Natural Science Foundation of China(Nos.21561016,21661015)Jiangxi Provincial Science&Technology Program(Nos.20133BBE50010,20142BDH80020,and 20161BBE50052)Science&Technology Program of Jiangxi Provincial Education Bureau(No.GJJ150775)
文摘The capacity fade of spinel lithium manganese oxide in lithium-ion batteries is a bottleneck challenge for the large-scale application.The traditional opinion is that Mn（Ⅱ） ions in the anode are reduced to the metallic manganese that helps for catalyzing electrolyte decomposition.This could poison and damage the solid electrolyte interface（SEI） film,leading to the the capacity fade in Li-ion batteries.We propose a new mechanism that Mn（Ⅱ） deposites at the anode hinders and/or blocks the intercalation/de-intercalation of lithium ions,which leads to the capacity fade in Li-ion batteries.Based on the new mechanism assumption,a kind of new structure with core-shell characteristic is designed to inhabit manganese ion dissolution,thus improving electrochemical cycle performance of the cell.By the way,this mechanism hypothesis is also supported by the results of these experiments.The LiMn2-xTixO4 shell layer enhances cathode resistance to corrosion attack and effectively suppresses dissolution of Mn,then improves battery cycle performance with LiMn_2O_4 cathode,even at high rate and elevated temperature.
文摘In this study, a novel core-shell structure of ZSM-5@Mg(Al)O(abbreviated as Z@MA) was designed by using the sol-gel method, and the influence of different weight ratios of Mg(Al)O/ZSM-5 on the structure and catalytic performance was investigated. The as-obtained materials were characterized by XRD, N_2-physisorption, SEM, FT-IR, NH_3-TPD and XPS analyses. The results showed that, with the increase of the weight ratio of Mg(Al)O/ZSM-5, the thickness of Mg(Al)O shell was improved, and the pore structure and physiochemical properties of core-shell materials were directly modified. After introduction of Mg(Al)O, the acidity properties of different materials were significantly suppressed. Meanwhile, more Sn oxide species in Z@MA could facilitate the anchoring of Pt on the support. By effectively employing these modifications, the capacity of the catalysts to accommodate coke was significanty improved and the carbon deposits were migrated from active metal to the carrier. When the weight ratio was equal to 3, the catalyst PtSnNa/Z@MA showed a highest conversion and high selectivity in propane dehydrogenation.
文摘Recent petro-structural investigations on the Faboula gold deposit located in the Bougouni-Kékoro basin, in southern Mali, north-west of the Leo-Man Shield, have provided new data on the nature and spatial organization of the lithostratigraphic units as well as their deformation style. The deposit is covered by a thick lateritic layer and is hosted by a metavolcano-sedimentary sequence of Paleoproterozoic age intersected by intrusive bodies and filled fractures of various shape</span></span><span><span><span style="font-family:"">s</span></span></span><span><span><span style="font-family:""> and type</span></span></span><span><span><span style="font-family:"">s</span></span></span><span><span><span style="font-family:"">. The lithostratigraphic units consist of metagreywackes, metasiltstones, meta-argillites, slates and schists. Metagreywackes and metasiltstones are generally feldspathic, both may contain biotite and locally amphibole, just as slates may contain andalusite which is locally stretched. Plutonic units most often occur as stocks or as dikes on the drill core, up to 1 m. The metavolcano-sedimentary rocks are schistose and deformed under greenschist facies conditions, </span></span></span><span><span><span style="font-family:"">and </span></span></span><span><span><span style="font-family:"">locally they reach the epidote-amphibolite facies. The structural study revealed that the deposit is affected by several stages of deformation evolving from a ductile type to a brittle type via a ductile-brittle type. The dominant ductile and brittle-ductile de<span>formations show a combination of isoclinal folding and strike-slip faults.</span> <span>Both the isoclinal folding and the strike-slip faults whose sigmoidal en-echelon</span> tension gashes indicate a dextral movement in the NNE-SSW direction are the result of the same ENE-WSW regional shortening. Consequently, they highlight a transpressive deformation. This deformation noted here D<sub>2Fb</sub>, could be equivalent to the regional D<sub>2</sub> or D<sub>3</sub> deformations identified at the scale of the Leo-Man Shield if we refer to the style of deformation. There is an abundance of quartz veins networks. Their relation within the structural features indicate</span></span></span><span><span><span style="font-family:"">s</span></span></span><span><span><span style="font-family:""> that the mineralization is structurally controlled during a hydrothermal event linked certainly to the circulations of fluids during the transpressive event D<sub>2Fb</sub>.
