Core–Shell Microfiber Encapsulation Enables Glycerol‑Free Cryopreservation of RBCs with High Hematocrit

Cryopreservation of red blood cells(RBCs)provides great potential benefits for providing transfusion timely in emergencies.High concentrations of glycerol(20%or 40%)are used for RBC cryopreservation in current clinical practice,which results in cytotoxicity and osmotic injuries that must be carefully controlled.However,existing studies on the low-glycerol cryopreservation of RBCs still suffer from the bottleneck of low hematocrit levels,which require relatively large storage space and an extra concentration process before transfusion,making it inconvenient(time-consuming,and also may cause injury and sample lose)for clinical applications.To this end,we develop a novel method for the glycerol-free cryopreservation of human RBCs with a high final hematocrit by using trehalose as the sole cryoprotectant to dehydrate RBCs and using core–shell alginate hydrogel microfibers to enhance heat transfer during cryopreservation.Different from previous studies,we achieve the cryopreservation of human RBCs at high hematocrit(>40%)with high recovery(up to 95%).Additionally,the washed RBCs post-cryopreserved are proved to maintain their morphology,mechanics,and functional properties.This may provide a nontoxic,high-efficiency,and glycerol-free approach for RBC cryopreservation,along with potential clinical transfusion benefits.

Synthesis of Core-shell ZSM-5@ Ordered Mesoporous Silica by Tetradecylamine Surfactant

A core-shell composite consisting of ZSM-5 zeolite as the core and ordered mesoporous silica as the shell was prepared by a surfactant-controlled sol-gel process and using tetradecylamine(TDA) as the template and Tetraethylorthosilicate(TEOS) as the silica precursor.The pores of the silica shell were found to be ordered and perpendicular to the crystal faces of the zeolite core.The thickness of the shell in the coreshell structured composite can be adjusted in the range of 20-90 nm,while the surface morphology and the pore size distribution were modified by changing the mass ratio of TEOS to zeolite.The composite molecular sieves have higher surface area for capturing molecules than ZSM-5,and with the increase of mesoporous shell layer,the ZSM-5@SiO_(2)-x composites show stronger adsorption capacity of butyraldehyde.However,when the shell thickness exceeds 90 nm,the adsorption capacity of butyraldehyde decreases instead.The composites have a huge potential for environmental applications.

Core-Shell Semiconductor-Graphene Nanoarchitectures for Efficient Photocatalysis:State of the Art and Perspectives

Semiconductor photocatalysis holds great promise for renewable energy generation and environment remediation,but generally suffers from the serious drawbacks on light absorption,charge generation and transport,and structural stability that limit the performance.The core-shell semiconductorgraphene(CSSG)nanoarchitectures may address these issues due to their unique structures with exceptional physical and chemical properties.This review explores recent advances of the CSSG nanoarchitectures in the photocatalytic performance.It starts with the classification of the CSSG nanoarchitectures by the dimensionality.Then,the construction methods under internal and external driving forces were introduced and compared with each other.Afterward,the physicochemical properties and photocatalytic applications of these nanoarchitectures were discussed,with a focus on their role in photocatalysis.It ends with a summary and some perspectives on future development of the CSSG nanoarchitectures toward highly efficient photocatalysts with extensive application.By harnessing the synergistic capabilities of the CSSG architectures,we aim to address pressing environmental and energy challenges and drive scientific progress in these fields.

Recent advances in core-shell organic framework-based photocatalysts for energy conversion and environmental remediation

Direct conversion of solar energy into chemical energy in an environmentally friendly manner is one of the most promising strategies to deal with the environmental pollution and energy crisis.Among a variety of materials developed as photocatalysts,the core-shell metal/covalent-organic framework(MOF or COF)photocatalysts have garnered significant attention due to their highly porous structure and the adjustability in both structure and functionality.The existing reviews on core-shell organic framework photocatalytic materials have mainly focused on core-shell MOF materials.However,there is still a lack of indepth reviews specifically addressing the photocatalytic performance of core-shell COFs and MOFs@COFs.Simultaneously,there is an urgent need for a comprehensive review encompassing these three types of core-shell structures.Based on this,this review aims to provide a comprehensive understanding and useful guidelines for the exploration of suitable core-shell organic framework photocatalysts towards appropriate photocatalytic energy conversion and environmental governance.Firstly,the classification,synthesis,formation mechanisms,and reasonable regulation of core-shell organic framework were summarized.Then,the photocatalytic applications of these three kinds of core-shell structures in different areas,such as H_(2)evolution,CO_(2)reduction,and pollutants degradation are emphasized.Finally,the main challenges and development prospects of core-shell organic framework photocatalysts were introduced.This review aims to provide insights into the development of a novel generation of efficient and stable core-shell organic framework materials for energy conversion and environmental remediation.

Amorphous core-shell NiMoP@CuNWs rod-like structure with hydrophilicity feature for efficient hydrogen production in neutral media

Using interface engineering,a highly efficient catalyst with a shell@core structure was successfully synthesized by growing an amorphous material composed of Ni,Mo,and P on Cu nanowires(Ni-MoP@CuNWs).This catalyst only requires an overpotential of 35 mV to reach a current density of 10 mA cm^(-2).The exceptional hydrogen evolution reaction(HER)activity is attributed to the unique amorphous rod-like nature of NiMoP@CuNWs,which possesses a special hydrophilic feature,en-hances mass transfer,promotes effective contact between the electrode and electrolyte solution,and exposes more active sites during the catalytic process.Density functional theory revealed that the introduction of Mo weakens the binding strength of the Ni site on the catalyst surface with the H atom and promotes the desorption process of the H_(2) product significantly.Owing to its facile syn-thesis,low cost,and high catalytic performance,this electrocatalyst is a promising option for com-mercial applications as a water electrolysis catalyst.

A novel Ag/ZnO core-shell structure for efficient sterilization synergizing antibiotics and subsequently removing residuals

The massive use of antibiotics has led to the aggravation of bacterial resistance and also brought environmental pollution problems.This poses a great threat to human health.If the dosage of antibiotics is reduced by increasing its bactericidal performance,the emergence of drug resistance is certainly delayed,so that there's not enough time for developing drug resistance during treatment.Therefore,we selected typical representative materials of metal Ag and semiconductor ZnO nano-bactericides to design and synthesize Ag/ZnO hollow core-shell structures(AZ for short).Antibiotics are grafted on the surface of AZ through rational modification to form a composite sterilization system.The research results show that the antibacterial efficiency of the composite system is significantly increased,from the sum(34.7%+22.8%-57.5%)of the antibacterial efficiency of AZ and gentamicin to 80.2%,net synergizes 22.7%,which fully reflects the effect of 1+1>2.Therefore,the dosage of antibiotics can be drastically reduced in this way,which makes both the possibility of bacterial resistance and medical expenses remarkably decrease.Subsequently,residual antibiotics can be degraded under simple illumination using AZ-self as a photocatalyst,which cuts off the path of environmental pollution.In short,such an innovative route has guiding significance for drug resistance.

Exploring the Core-shell Structure of BaTiO3-based Dielectric Ceramics Using Machine Learning Models and Interpretability Analysis

A machine learning(ML)-based random forest(RF)classification model algorithm was employed to investigate the main factors affecting the formation of the core-shell structure of BaTiO_(3)-based ceramics and their interpretability was analyzed by using Shapley additive explanations(SHAP).An F1-score changed from 0.8795 to 0.9310,accuracy from 0.8450 to 0.9070,precision from 0.8714 to 0.9000,recall from 0.8929 to 0.9643,and ROC/AUC value of 0.97±0.03 was achieved by the RF classification with the optimal set of features containing only 5 features,demonstrating the high accuracy of our model and its high robustness.During the interpretability analysis of the model,it was found that the electronegativity,melting point,and sintering temperature of the dopant contribute highly to the formation of the core-shell structure,and based on these characteristics,specific ranges were delineated and twelve elements were finally obtained that met all the requirements,namely Si,Sc,Mn,Fe,Co,Ni,Pd,Er,Tm,Lu,Pa,and Cm.In the process of exploring the structure of the core-shell,the doping elements can be effectively localized to be selected by choosing the range of features.

Interfacial reinforcement of core-shell HMX@energetic polymer composites featuring enhanced thermal and safety performance

The weak interface interaction and solid-solid phase transition have long been a conundrum for 1,3,5,7-tetranitro-1,3,5,7-tetraazacyclooctane(HMX)-based polymer-bonded explosives(PBX).A two-step strategy that involves the pretreatment of HMX to endow—OH groups on the surface via polyalcohol bonding agent modification and in situ coating with nitrate ester-containing polymer,was proposed to address the problem.Two types of energetic polyether—glycidyl azide polymer(GAP)and nitrate modified GAP(GNP)were grafted onto HMX crystal based on isocyanate addition reaction bridged through neutral polymeric bonding agent(NPBA)layer.The morphology and structure of the HMX-based composites were characterized in detail and the core-shell structure was validated.The grafted polymers obviously enhanced the adhesion force between HMX crystals and fluoropolymer(F2314)binder.Due to the interfacial reinforcement among the components,the two HMX-based composites exhibited a remarkable increment of phase transition peak temperature by 10.2°C and 19.6°C with no more than 1.5%shell content,respectively.Furthermore,the impact and friction sensitivity of the composites decreased significantly as a result of the barrier produced by the grafted polymers.These findings will enhance the future prospects for the interface design of energetic composites aiming to solve the weak interface and safety concerns.

Core-shell mesoporous carbon hollow spheres as Se hosts for advanced Al-Se batteries

Incorporating a selenium(Se)positive electrode into aluminum(Al)-ion batteries is an effective strategy for improving the overall battery performance.However,the cycling stability of Se positive electrodes has challenges due to the dissolution of intermediate reaction products.In this work,we aim to harness the advantages of Se while reducing its limitations by preparing a core-shell mesoporous carbon hollow sphere with a titanium nitride(C@TiN)host to load 63.9wt%Se as the positive electrode material for Al-Se batteries.Using the physical and chemical confinement offered by the hollow mesoporous carbon and TiN,the obtained core-shell mesoporous carbon hollow spheres coated with Se(Se@C@TiN)display superior utilization of the active material and remarkable cycling stability.As a result,Al-Se batteries equipped with the as-prepared Se@C@TiN composite positive electrodes show an initial discharge specific capacity of 377 mAh·g^(-1)at a current density of 1000 mA·g^(-1)while maintaining a discharge specific capacity of 86.0 mAh·g^(-1)over 200 cycles.This improved cycling performance is ascribed to the high electrical conductivity of the core-shell mesoporous carbon hollow spheres and the unique three-dimensional hierarchical architecture of Se@C@TiN.

Fe-N_(x) sites coupled with core-shell FeS@C nanoparticles to boost the oxygen catalysis for rechargeable Zn-air batteries

The development of efficient single-atom catalysts(SACs) for the oxygen reduction reaction(ORR)remains a formidable challenge,primarily due to the symmetric charge distribution of metal singleatom sites(M-N_(4)).To address such issue,herein,Fe-N_(x) sites coupled synergistic catalysts fabrication strategy is presented to break the uniform electronic distribution,thus enhancing the intrinsic catalytic activity.Precisely,atomically dispersed Fe-N_(x) sites supported on N/S-doped mesoporous carbon(NSC)coupled with FeS@C core-shell nanoparticles(FAS-NSC@950) is synthesized by a facile hydrothermal reaction and subsequent pyrolysis.Due to the presence of an in situ-grown conductive graphitic layer(shell),the FeS nanoparticles(core) effectively adjust the electronic structure of single-atom Fe sites and facilitate the ORR kinetics via short/long-range coupling interactions.Consequently,FAS-NSC@950displays a more positive half-wave potential(E_(1/2)) of 0.871 V with a significantly boosted ORR kinetics(Tafel slope=52.2 mV dec^(-1)),outpacing the commercial Pt/C(E_(1/2)=0.84 V and Tafel slope=54.6 mV dec^(-1)).As a bifunctional electrocatalyst,it displays a smaller bifunctional activity parameter(ΔE) of 0.673 V,surpassing the Pt/C-RuO_(2) combination(ΔE=0.724 V).Besides,the FAS-NSC@950-based zincair battery(ZAB) displays superior power density,specific capacity,and long-term cycling performance to the Pt/C-Ir/C-based ZAB.This work significantly contributes to the field by offering a promising strategy to enhance the catalytic activity of SACs for ORR,with potential implications for energy conversion and storage technologies.

Synergistic Tuning of Nickel Cobalt Selenide@Nickel Telluride Core-Shell Heteroarchitectures for Boosting Overall Urea Electrooxidation and Electrochemical Supercapattery

Herein,we demonstrate the synthesis of bifunctional nickel cobalt selenide@nickel telluride(Ni_(x)Co_(12-x)Se@NiTe)core-shell heterostructures via an electrodeposition approach for overall urea electrolysis and supercapacitors.The 3D vertically orientated NiTe dendritic frameworks induce the homogeneous nucleation of 2D Ni_(x)Co_(12-x)Se nanosheet arrays along similar crystal directions and bring a strong interfacial binding between the integrated active components.In particular,the optimized Ni_(6)Co_(6)Se@NiTe with an interface coupling effect works in concert to tune the intrinsic activity.It only needs a low overpotential of 1.33 V to yield a current density of 10 mA cm^(-2)for alkaline urea electrolysis.Meanwhile,the full urea catalysis driven only by Ni_(6)Co_(6)Se@NiTe achieves 10 mA cm^(-2)at a potential of 1.38 V and can approach a constant level of the current response for 40 h.Besides,the integrated Ni_(6)Co_(6)Se@NiTe electrode delivers an enhanced specific capacity(223 mA h g^(-1)at 1 A g^(-1))with a high cycling stability.Consequently,a hybrid asymmetric supercapacitor(HASC)device based on Ni_(6)Co_(6)Se@NiTe exhibits a favorable rate capability and reaches a high energy density of 67.7 Wh kg^(-1)and a power density of 724.8 W kg^(-1)with an exceptional capacity retention of 92.4%after sequential 12000 cycles at 5 A g^(-1).

Fabrication of Core-Shell Hydrogel Bead Based on Sodium Alginate and Chitosan for Methylene Blue Adsorption

A novel core-shell hydrogel bead was fabricated for effective removal of methylene blue dye from aqueous solutions.The core,made of sodium alginate-g-polyacrylamide and attapulgite nanofibers,was cross-linked by Calcium ions(Ca^(2+)).The shell,composed of a chitosan/activated carbon mixture,was then coated onto the core.Fourier transform infrared spectroscopy confirmed the grafting polymerization of acrylamide onto sodium alginate.Scanning electron microscopy images showed the core-shell structure.The core exhibited a high water uptake ratio,facilitating the diffusion of methylene blue into the core.During the diffusion process,the methylene blue was first adsorbed by the shell and then further adsorbed by the core.Adsorption tests showed that the coreshell structure had a larger adsorption capacity than the core alone.The shell effectively enhanced the adsorption capacity to methylene blue compared to the single core.Methylene blue was adsorbed by activated carbon and chitosan in the shell,and the residual methylene blue diffused into the core and was further adsorbed.

TiO2/BiVO4, a Heterojuncted Microfiber with Enhanced Photocatalytic Performance for Methylene Blue under Visible Light Irradiation

Novel TiO2/BiVO4 microfiber heterojunctions were constructed using cotton as biomorphic templates. The as-synthesized samples were characterized by scanning electron microscope, X-ray diffraction, X-ray photoelectron spectroscopy, UV-Vis diffuse reflectance spectra and photocatalytic experiment. The morphology of the as-synthesized TiO2/BiVO4 composites was consisted of a large quantity of microfiber structures with diameter from 2.5 gm to 5 μm, and the surface of samples became more coarse and compact with the increase of weight ratio of TiO2. The TiO2/BiVO4 samples with proper content （10.00wt%） showed the highest pho- tocatalytic degradation activity for methylene blue （MB） degradation among all the samples under visible light, and 88.58%MB could be degraded within 150 min. The enhancement of photocatalytic activity was mainly attributed to the formation of n-n heterojunction at the contact interface of TiO2 and BiVO4, which not only narrowed the band gap of BiVO4 for extending the absorption range of visible light, but also promoted the transfer of charge carriers across interface. A possible photodegradation mechanism of MB in the presence of TiO2/BiVO4 microfibrous photocatalyst was proposed.

Surface treatment effect on the photocatalytic hydrogen generation of CdS/ZnS core-shell microstructures

CdS/ZnS core-shell microparticles were prepared by a simple two-step method combining ultrasonic spray pyrolysis and chemical bath deposition.The core-shell structures showed enhanced photocatalytic properties compared with those of CdS or ZnS spherical particles.CdS/ZnS photocatalysts with different amount of ZnS loaded as shells were prepared by adjusting the concentrations of Zn and S precursors during synthesis.The optical properties and photocatalytic activity for hydrogen production were investigated and the amount of ZnS loaded as shell was optimized.Thermal annealing and hydrothermal sulfurization treatments were applied to the core-shell structure and both treatments enhanced the material＇s photocatalytic activity and stability by eliminating crystalline defects and surface states.The result showed that thermal annealing treatment improved the bulk crystallinity and hydrothermal sulfurization improved the surface properties.The sample subjected to both treatments showed the highest photocatalytic activity.These results indicate that CdS/ZnS core-shell microspheres are a simple structure that can be used as efficient photocatalysts.The hydrothermal sulfurization treatment may also be a useful surface treatment for metal sulfide photocatalysts.The simple two-step method provides a promising approach to the large-scale synthesis of core-shell microsphere catalysts.

Thermodynamics analysis of Ni^(2+)-C_2H_8N_2- C_2O_4^(2-)-H_2O system and preparation of Ni microfiber

According to the principles of simultaneous equilibrium and mass equilibrium, the thermodynamics model of the precipitation-coordination equilibrium of Ni2＋-C2H8N2- 2-2 4C O -H2O system was established, and calculation for the relationships between concentration of each substance in solution and parameters was carried out, including pH value, concentrations of ethylenediamine and oxalate by MATLAB program. The results show that Ni exists as Ni2＋and [Ni（C2O4）n]2-2n mainly at pH〈1 and pH=1-6, respectively. When pH〉6, the complex between Ni2＋and ethylenediamine is predominant. The precursor of Ni microfiber was prepared by an oxalate precipitation process using ethylenediamine as a coordination agent, and the role of ethylenediamine in the growth of the precursor fiber was discussed. The Ni microfiber can be obtained by a thermal decomposition-reduction process of the precursor in N2 and H2 mixed atmosphere. The diameters and aspect ratios of the obtained Ni microfibers are 0.2-1 μm and 20-30, respectively.

Ni@Pd core-shell nanoparticles supported on a metal-organic framework as highly efficient catalysts for nitroarenes reduction

Ni@Pd core-shell nanoparticles with a mean particle size of 8–9 nm were prepared by solvothermal reduction of bivalent nickel and palladium in oleylamine and trioctylphosphine.Subsequently,the first-ever deposition of Ni@Pd core-shell nanoparticles having different compositions on a metal-organic framework（MIL-101）was accomplished by wet impregnation in n-hexane.The Ni@Pd/MIL-101 materials were characterized by powder X-ray diffraction,Fourier transform infrared spectroscopy,transmission electron microscopy,and energy-dispersive X-ray spectroscopy and also investigated as catalysts for the hydrogenation of nitrobenzene under mild reaction conditions.At 30 °C and 0.1 MPa of H2 pressure,the Ni@Pd/MIL-101 gives a TOF as high as 375 h–1 for the hydrogenation of nitrobenzene and is applicable to a wide range of substituted nitroarenes.The exceptional performance of this catalyst is believed to result from the significant Ni-Pd interaction in the core-shell structure,together with promotion of the conversions of aromatics by uncoordinated Lewis acidic Cr sites on the MIL-101 support.

Fabrication of Cu_2O@Cu_2O core-shell nanoparticles and conversion to Cu_2O@Cu core-shell nanoparticles in solution

Cu2O@Cu2O core-shell nanoparticles (NPs) were prepared by using solution phase strategy. It was found that Cu2O@Cu2O NPs were easily converted to Cu2O@Cu NPs with the help of polyvinylpyrrolidine (PVP) and excessive ascorbic acid (AA) in air at room temperature, which was an interesting phenomenon. The features of the two kinds of NPs were characterized by XRD, TEM and extinction spectra. Cu2O@Cu NPs with different shell thicknesses showed wide tunable optical properties for the localized surface plasmon (LSP) in metallic Cu. But Cu2O@Cu2O NPs did not indicate this feature. FTIR results reveal that Cu+ ions on the surface of Cu2O shell coordinate with N and O atoms in PVP and are further reduced to metallic Cu by excessive AA and then form a nucleation site on the surface of Cu2O nanocrystalline. PVP binds onto different sites to proceed with the reduction utill all the Cu sources in Cu2O shell are completely assumed.

Fabricating Core-Shell WC@C/Pt Structures and its Enhanced Performance for Methanol Electrooxidation

The spray-dried spheres within a W/Pt multi-separation can be used to prepare discrete core-shell WC@C/Pt catalysts through a typical carburization production mechanism at 800 ℃. In contrast with previous studies of the WC/Pt synthesis, the reaction observed here proceeds through an indirect annealing thereby resulting in core-shell structure, and mechanism at 600℃ wherein species diffuse, Pt nanoparticles were successfully dispersed in size/shape and randomly scattered across the in situ produced C spheres. Through direct carburization or at higher initial hydrochloroplatiuic acid concentrations, however, complete reaction with core-shell spheres was not observed. Indirect carburization reduces the strain felt by the bonds featuring the larger WC WC and Pt nanoparticles to be reserved, stability toward methanol oxidation. particles and allows the motion of carbon around influencing the eleetrocatalytic performance and

Preparation of TiO2/Bi2O3 Microfibers and Their Photocatalytic Activity

A series of TiO2/Bi2O3 heterojunction microfibers have been fabricated using cotton fibers as bio-templates, and characterized by XRD, SEM and UV-Vis techniques. Results reveal that Bi2O3 in the TiO2/Bi2O3 sample is assigned to monoclinic and tetragonal mix-crystal phase. Fibers lengths can reach several micrometers and diameters range from 0.5 μm to 3 μm. Compared with pure TiO2 and Bi2O3, TiO2/Bi2O3 samples display better absorption in visible light region. Photocatalytic activity was evaluated by degradation of MB under visible light irradiation. TiO2/Bi2O3 microfibers exhibite much higher activity than pure TiO2 and Bi2O3, and 22.84%TiO2/Bi2O3 can achieve the decomposition of about 95%MB, which is attributed to synergistic effects of the strong visible-light absorption of TiO2/Bi2O3 microfibers and the heterojunction formed between TiO2 and Bi2O3.

Preparation and characterization of ZnSe/CdSe core-shell microspheres

The preparation of Zn Se/Cd Se core-shell structure nanocomposites by using the re-prepared Zn Se microspheres as the template under the hydrothermal condition was presented. The influence of different mole ratios of ZnS e to Cd（NO3）2 on the morphology and structure of the final product was investigated. And the performances of ZnS e/Cd Se core-shell structure nanocomposites were characterized by the means of X-ray diffraction（XRD） analyses, scanning electron microscopy（SEM）, transmission electron microscopy（TEM） and photoluminescence（PL） spectroscopy. The results indicate that the core-shell structure product can be prepared, when the mole ratio of Zn Se to Cd（NO3）2 is larger than 1：1; and the product will be ball solid structure, when the mole ratio of Zn Se to Cd（NO3）2 is equal to 1：1. The photo luminescence results show that Zn Se/Cd Se core-shell structures have high photo luminescence emission properties, and the product with mole ratio of Zn Se to Cd（NO3）2 being 1：0.5 has the best luminescence properties.