Cored wires for electric arc spraying of Al/Al 2 O 3 MMC coatings were developed, with Al 2 O 3 powder as the core material and commercial aluminium strip as the retaining sheath. The bond strength, ...Cored wires for electric arc spraying of Al/Al 2 O 3 MMC coatings were developed, with Al 2 O 3 powder as the core material and commercial aluminium strip as the retaining sheath. The bond strength, Al 2 O 3 content, microstructure, micro-hardness and wear resistance of coatings produced by arc spraying of the cored wires were experimentally investigated and were compared with those of pure aluminum coating.展开更多
In this paper, an artificial neural network method that can predict the chemical composition of deposited weld metal by CO 2 Shielded Flux Cored Wire Surfacing was studied. It is found that artificial neural networ...In this paper, an artificial neural network method that can predict the chemical composition of deposited weld metal by CO 2 Shielded Flux Cored Wire Surfacing was studied. It is found that artificial neural network is a good approach on studying welding metallurgy processes that cannot be described by conventional mathematical methods. In the same time we explored a new way to study the no equilibrium welding metallurgy processes.展开更多
A set of electromagnetic vibration powder feeding apparatus of the flux cored wire production line and its single chip controlling system have been designed in this paper. The parameters of the electromagnatic vibr...A set of electromagnetic vibration powder feeding apparatus of the flux cored wire production line and its single chip controlling system have been designed in this paper. The parameters of the electromagnatic vibration powder feeding apparatus have been tested, the functional relation between powder feeding velocity V L and current I has been made out so that the controlling system can not only automatically make out the quantity of the powder according to the width of the steel belt, powder density, production speed and filling ratio, but also adjust the powder feeding speed according to the real production speed, keeping a stable filling ratio.展开更多
According to the characteristics of electric arc spraying technology and abrasion of boiler piping,a flux cored wire SMD 45 for electric arc spraying is developed The experimental results show that the surface hardn...According to the characteristics of electric arc spraying technology and abrasion of boiler piping,a flux cored wire SMD 45 for electric arc spraying is developed The experimental results show that the surface hardness of the coating reaches 60~65 HR and the adhesive strength between the coating and base is 23~28 MPa The wearability of the coating sprayed by the wire is 5 times than that of ordinary steel pipe Applying the wire to the heated surface,the life of the economizer pipe is doubly increased No local desquamation,rust and abrasion can be examined during more than one year's service.展开更多
In this research, a vermicular graphite cast iron brake drum was produced by cored wire injection in a one-step method. Silica sand and low-density alumina-silicate ceramic were used as molding materials in order to i...In this research, a vermicular graphite cast iron brake drum was produced by cored wire injection in a one-step method. Silica sand and low-density alumina-silicate ceramic were used as molding materials in order to investigate the effect of cooling rate on percentage of vermicular graphite and mechanical properties of the brake drum casting. Several thermocouples were inserted into the casting in the desired positions to measure the temperature change. By means of one-step cored wire injection, the two residual concentrations of Mg and RE were effectively controlled in the ranges of 0.013%-0.017% and 0.019%-0.025%, respectively, which are crucial for the production of vermicular graphite cast iron and the formation of vermicular graphite. In addition, the cooling rate had a significant effect on the vermicular graphite percentage. In the case of the silica mold brake drum casting, there was an obvious difference in the cooling rate with the wall change, leading to a change in vermicular graphite percentage from 70.8% to 90%. In the low-density alumina-silicate ceramic mold casting, no obvious change in temperature was detected by the thermocouples and the percentage of the vermicular graphite was stable at 85%. Therefore, the vermicular graphite cast iron brake drum with a better combination of mechanical properties could be obtained.展开更多
The effect of Fe203 and Liz CO3 additives in flux core on the weld metal oxygen content and weld penetration in self-shielded flux cored arc welding were studied schematically. The result shows that the oxygen content...The effect of Fe203 and Liz CO3 additives in flux core on the weld metal oxygen content and weld penetration in self-shielded flux cored arc welding were studied schematically. The result shows that the oxygen content in the weld metal and weld penetration both increased with the Fe203 addition increased in the range of 5 wt. % to 20 wt. %. The oxygen content in the weld metal was increased with the Li2CO3 addition increased in the range of 1 wt. % to 8 wt. %. However, the weld penetration decreased when Li2CO3 addition exceeding 4 wt. %. High-speed photographic images show that when Fe2O3 addition influx core exceeding 15 wt. %, droplet became excessively large, so that spatters were frequently generated in large numbers. In this study, Fe203 and Li2 CO3 in the amount of 11 wt. % and 4 wt. %, respectively, jointly added in the flux core can achieve a deeper weld penetration with sound usability characteristics.展开更多
Effects of CeF3 on properties of self-shielded flux cored wire including welding process, inclusions in weld metal and mechanical properties are systematically studied. Welding smoke and spatter are reduced with the a...Effects of CeF3 on properties of self-shielded flux cored wire including welding process, inclusions in weld metal and mechanical properties are systematically studied. Welding smoke and spatter are reduced with the addition of CeF3. The main non-metallic inclusions in weld metal are AlN and Al2O3. CeF3 can refine non-metallic inclusions and reduce the amount of large size inclusions, which is attributed to the inclusion floating behavior during the solidification of weld metal. The low temperature impact toughness is improved by adding suitable amount of CeF3 in the flux.展开更多
Prevention of nitrogen porosity in weld metal deposited with self-shielded flux cored wire with CaF2-TiO2-MgO slag system can be accomplished by using a 'killing agent' such as titanium to react with nitrogen ...Prevention of nitrogen porosity in weld metal deposited with self-shielded flux cored wire with CaF2-TiO2-MgO slag system can be accomplished by using a 'killing agent' such as titanium to react with nitrogen dissolved in the weld metal. The amount of titanium needed to prevent porosity is calculated thermodynamically for various dissolved nitrogen levels. Experimental flux cored wires are used to verify the thermodynamic model. It is concluded that approximately 0.11 wt% titanium in the weld deposit is need to prevent nitrogen porosity when welding without externally applied shielding.展开更多
Metal transfer behavior of six kinds of self shielded flux cored wire(SSFCW) is studied using the apparatus of SSFCW high speed photography self made. Six kinds of metal transfer modes of SSFCW were obtained throu...Metal transfer behavior of six kinds of self shielded flux cored wire(SSFCW) is studied using the apparatus of SSFCW high speed photography self made. Six kinds of metal transfer modes of SSFCW were obtained through observation for high speed photograph film and analysis. It is believed that the research is of magnificent for improving operative performance and mechanical properties of SSFCW and dynamics characteristic of welding power.展开更多
Based on the advanced integrated technology of materials preparation and formation, a new pattern Zn-Al-Mg-RE anti-corrosion coating for steel structure sustainable design was manufactured by cored wires and high velo...Based on the advanced integrated technology of materials preparation and formation, a new pattern Zn-Al-Mg-RE anti-corrosion coating for steel structure sustainable design was manufactured by cored wires and high velocity arc spraying (HVAS) technologies. The developments of thermally sprayed coatings for steel structure protection were described. Based on Al, Zn, Zn-Al and Zn-Al-Mg coatings, the anti-corrosion properties of new-pattern Zn-Al-Mg-RE coating were evaluated through electrochemical methods including electrochemical polarization and electrochemical impedance spectroscopy (EIS) coupled with SEM and XRD. The models of Zn-Al-Mg-RE coating undergoing corrosion with the initial pinhole defect and the latter with accelerated products were also discussed. The results show that Zn-Al-Mg-RE coating exhibites excellent corrosion resistance for long-term immersion, which is helpful for the sustainable design of steel structure in aggressive corrosion conditions. And the corrosion products seem to possess certain self-sealing function.展开更多
A novel Ti cored wire containing Ti B2,Al60 V40 and Ti6 Al4 V mixed powders was developed for wirefeed arc deposition of Ti B/Ti composite coating,to enhance the hardness and wear resistance of Ti alloy.Results showed...A novel Ti cored wire containing Ti B2,Al60 V40 and Ti6 Al4 V mixed powders was developed for wirefeed arc deposition of Ti B/Ti composite coating,to enhance the hardness and wear resistance of Ti alloy.Results showed that after experiencing several chemical reactions,the wire was melted in the arc zone and turned into nonuniform droplets composed of Ti-Al-V-B melt and undecomposed Ti B2 particles.With the increase of welding current,the detachment time of droplet shortened while the transfer frequency accelerated,accompanied by the improvement in coating surface quality.The spatial distribution of Ti B whiskers in coating was governed by welding current.A uniform distribution could be achieved as welding current was sufficient at the expense of elevated dilution ratio,while increasing wire feeding speed could compensate the dilution loss of Ti B whisker to some extent.The decomposition process of Ti B_(2)particles and the microstructure evolution mechanism of coating was discussed in detail.The optimum coating possessed uniform microstructure,relatively low dilution ratio,and high hardness(639.1 HV_(0.5))as compared with Ti6 Al4 V substrate(326 HV_(0.5)).Indentation morphology analysis verified the excellent performance was ascribed to the load-sharing strengthening of Ti B whiskers.This study provides a high-efficiency fabrication method for the ever-developing titanium matrix composites(TMCs)coating.展开更多
The flux cored wires with different amounts of rare earth (RE) oxides additions for hardfacing (harden-face-welding) the workpieces of high chromium cast iron were studied in this work.The morphology of carbides i...The flux cored wires with different amounts of rare earth (RE) oxides additions for hardfacing (harden-face-welding) the workpieces of high chromium cast iron were studied in this work.The morphology of carbides in hardfacing metal was observed,and the type of the carbides was determined by optical microscopy,scanning electron microscopy (SEM),energy dispersive spectrometer (EDS) and X-ray diffraction (XRD).Based on the data of effect of RE on carbides morphology,the refined reason for carbide by RE oxide was discussed with the misfit theory.The results showed that,the microstructure of hardfacing metal was composed of martensite,residual austenite and M7C3 carbides.With the increasing amount of RE oxide additions,the volume fraction and roundness of the carbides were increased,however,the area and perimeter of carbides were decreased.It indicated that carbides in hardfacing metal could be refined and spheroidized by adding RE oxides in flux cored wires.展开更多
The flux cored wires with different rare earth oxide additions for hardfacing the workpieces of medium-high carbon steel were developed. The microstrucmre of the hardfacing layer was observed using the optical microsc...The flux cored wires with different rare earth oxide additions for hardfacing the workpieces of medium-high carbon steel were developed. The microstrucmre of the hardfacing layer was observed using the optical microscopy. The average dimension of primary austenite grains in hardfacing layer was measured by image analyzer. The primary austenite grain growth activation energy and index were calculated according to Sellars's mode and Beck formula, respectively. Moreover, the effect of rare earth oxide on the growth dynamics of primary aus- tenite grain was analyzed, and then discussed with the misfit theory. The experimental results showed that, by adding rare earth oxide, the av- erage dimension of primary austenite grains in hardfacing layer of medium-high carbon steel decreased, and it was the smallest when the ad- dition of rare earth oxide was 5.17 wt.%. Meanwhile, at this rare earth oxide addition, the primary austenite grain growth activating energy in hardfacing layer was the largest, while its index was the smallest. The calculated results indicated that the primary austenite grain could be refined because LaAlO3 as heterogeneous nuclei of γ-Fe was the most effective.展开更多
文摘Cored wires for electric arc spraying of Al/Al 2 O 3 MMC coatings were developed, with Al 2 O 3 powder as the core material and commercial aluminium strip as the retaining sheath. The bond strength, Al 2 O 3 content, microstructure, micro-hardness and wear resistance of coatings produced by arc spraying of the cored wires were experimentally investigated and were compared with those of pure aluminum coating.
文摘In this paper, an artificial neural network method that can predict the chemical composition of deposited weld metal by CO 2 Shielded Flux Cored Wire Surfacing was studied. It is found that artificial neural network is a good approach on studying welding metallurgy processes that cannot be described by conventional mathematical methods. In the same time we explored a new way to study the no equilibrium welding metallurgy processes.
文摘A set of electromagnetic vibration powder feeding apparatus of the flux cored wire production line and its single chip controlling system have been designed in this paper. The parameters of the electromagnatic vibration powder feeding apparatus have been tested, the functional relation between powder feeding velocity V L and current I has been made out so that the controlling system can not only automatically make out the quantity of the powder according to the width of the steel belt, powder density, production speed and filling ratio, but also adjust the powder feeding speed according to the real production speed, keeping a stable filling ratio.
文摘According to the characteristics of electric arc spraying technology and abrasion of boiler piping,a flux cored wire SMD 45 for electric arc spraying is developed The experimental results show that the surface hardness of the coating reaches 60~65 HR and the adhesive strength between the coating and base is 23~28 MPa The wearability of the coating sprayed by the wire is 5 times than that of ordinary steel pipe Applying the wire to the heated surface,the life of the economizer pipe is doubly increased No local desquamation,rust and abrasion can be examined during more than one year's service.
基金financially supported by the Foundation of Heilongjiang Educational Committee(Grant No.12531116)the Harbin Special Funds for Creative Talents in Science and Technology(Grant No.2013RFQXJ102)
文摘In this research, a vermicular graphite cast iron brake drum was produced by cored wire injection in a one-step method. Silica sand and low-density alumina-silicate ceramic were used as molding materials in order to investigate the effect of cooling rate on percentage of vermicular graphite and mechanical properties of the brake drum casting. Several thermocouples were inserted into the casting in the desired positions to measure the temperature change. By means of one-step cored wire injection, the two residual concentrations of Mg and RE were effectively controlled in the ranges of 0.013%-0.017% and 0.019%-0.025%, respectively, which are crucial for the production of vermicular graphite cast iron and the formation of vermicular graphite. In addition, the cooling rate had a significant effect on the vermicular graphite percentage. In the case of the silica mold brake drum casting, there was an obvious difference in the cooling rate with the wall change, leading to a change in vermicular graphite percentage from 70.8% to 90%. In the low-density alumina-silicate ceramic mold casting, no obvious change in temperature was detected by the thermocouples and the percentage of the vermicular graphite was stable at 85%. Therefore, the vermicular graphite cast iron brake drum with a better combination of mechanical properties could be obtained.
文摘The effect of Fe203 and Liz CO3 additives in flux core on the weld metal oxygen content and weld penetration in self-shielded flux cored arc welding were studied schematically. The result shows that the oxygen content in the weld metal and weld penetration both increased with the Fe203 addition increased in the range of 5 wt. % to 20 wt. %. The oxygen content in the weld metal was increased with the Li2CO3 addition increased in the range of 1 wt. % to 8 wt. %. However, the weld penetration decreased when Li2CO3 addition exceeding 4 wt. %. High-speed photographic images show that when Fe2O3 addition influx core exceeding 15 wt. %, droplet became excessively large, so that spatters were frequently generated in large numbers. In this study, Fe203 and Li2 CO3 in the amount of 11 wt. % and 4 wt. %, respectively, jointly added in the flux core can achieve a deeper weld penetration with sound usability characteristics.
文摘Effects of CeF3 on properties of self-shielded flux cored wire including welding process, inclusions in weld metal and mechanical properties are systematically studied. Welding smoke and spatter are reduced with the addition of CeF3. The main non-metallic inclusions in weld metal are AlN and Al2O3. CeF3 can refine non-metallic inclusions and reduce the amount of large size inclusions, which is attributed to the inclusion floating behavior during the solidification of weld metal. The low temperature impact toughness is improved by adding suitable amount of CeF3 in the flux.
文摘Prevention of nitrogen porosity in weld metal deposited with self-shielded flux cored wire with CaF2-TiO2-MgO slag system can be accomplished by using a 'killing agent' such as titanium to react with nitrogen dissolved in the weld metal. The amount of titanium needed to prevent porosity is calculated thermodynamically for various dissolved nitrogen levels. Experimental flux cored wires are used to verify the thermodynamic model. It is concluded that approximately 0.11 wt% titanium in the weld deposit is need to prevent nitrogen porosity when welding without externally applied shielding.
文摘Metal transfer behavior of six kinds of self shielded flux cored wire(SSFCW) is studied using the apparatus of SSFCW high speed photography self made. Six kinds of metal transfer modes of SSFCW were obtained through observation for high speed photograph film and analysis. It is believed that the research is of magnificent for improving operative performance and mechanical properties of SSFCW and dynamics characteristic of welding power.
文摘Based on the advanced integrated technology of materials preparation and formation, a new pattern Zn-Al-Mg-RE anti-corrosion coating for steel structure sustainable design was manufactured by cored wires and high velocity arc spraying (HVAS) technologies. The developments of thermally sprayed coatings for steel structure protection were described. Based on Al, Zn, Zn-Al and Zn-Al-Mg coatings, the anti-corrosion properties of new-pattern Zn-Al-Mg-RE coating were evaluated through electrochemical methods including electrochemical polarization and electrochemical impedance spectroscopy (EIS) coupled with SEM and XRD. The models of Zn-Al-Mg-RE coating undergoing corrosion with the initial pinhole defect and the latter with accelerated products were also discussed. The results show that Zn-Al-Mg-RE coating exhibites excellent corrosion resistance for long-term immersion, which is helpful for the sustainable design of steel structure in aggressive corrosion conditions. And the corrosion products seem to possess certain self-sealing function.
基金financially supported by Key-Area Research and Development Program of GuangDong Province(2019B010942001)National Key R&D Program of China(No.2017YFB0703100)+1 种基金the National Natural Science Foundation of China[grant numbers 51822103,51731009 and 51671068]the Fundamental Research Funds for the Central Universities[grant number HIT.BRETIV.201902]。
文摘A novel Ti cored wire containing Ti B2,Al60 V40 and Ti6 Al4 V mixed powders was developed for wirefeed arc deposition of Ti B/Ti composite coating,to enhance the hardness and wear resistance of Ti alloy.Results showed that after experiencing several chemical reactions,the wire was melted in the arc zone and turned into nonuniform droplets composed of Ti-Al-V-B melt and undecomposed Ti B2 particles.With the increase of welding current,the detachment time of droplet shortened while the transfer frequency accelerated,accompanied by the improvement in coating surface quality.The spatial distribution of Ti B whiskers in coating was governed by welding current.A uniform distribution could be achieved as welding current was sufficient at the expense of elevated dilution ratio,while increasing wire feeding speed could compensate the dilution loss of Ti B whisker to some extent.The decomposition process of Ti B_(2)particles and the microstructure evolution mechanism of coating was discussed in detail.The optimum coating possessed uniform microstructure,relatively low dilution ratio,and high hardness(639.1 HV_(0.5))as compared with Ti6 Al4 V substrate(326 HV_(0.5)).Indentation morphology analysis verified the excellent performance was ascribed to the load-sharing strengthening of Ti B whiskers.This study provides a high-efficiency fabrication method for the ever-developing titanium matrix composites(TMCs)coating.
基金Project supported by One Hundred Excellent Talents of Hebei Province of China and Key Project of Science and Technology of Hebei Province (09215106D)
文摘The flux cored wires with different amounts of rare earth (RE) oxides additions for hardfacing (harden-face-welding) the workpieces of high chromium cast iron were studied in this work.The morphology of carbides in hardfacing metal was observed,and the type of the carbides was determined by optical microscopy,scanning electron microscopy (SEM),energy dispersive spectrometer (EDS) and X-ray diffraction (XRD).Based on the data of effect of RE on carbides morphology,the refined reason for carbide by RE oxide was discussed with the misfit theory.The results showed that,the microstructure of hardfacing metal was composed of martensite,residual austenite and M7C3 carbides.With the increasing amount of RE oxide additions,the volume fraction and roundness of the carbides were increased,however,the area and perimeter of carbides were decreased.It indicated that carbides in hardfacing metal could be refined and spheroidized by adding RE oxides in flux cored wires.
基金Program supported by National Nature Science Foundation of China(51271163)Key Project of Science and Technology of Hebei Province(09215106D)
文摘The flux cored wires with different rare earth oxide additions for hardfacing the workpieces of medium-high carbon steel were developed. The microstrucmre of the hardfacing layer was observed using the optical microscopy. The average dimension of primary austenite grains in hardfacing layer was measured by image analyzer. The primary austenite grain growth activation energy and index were calculated according to Sellars's mode and Beck formula, respectively. Moreover, the effect of rare earth oxide on the growth dynamics of primary aus- tenite grain was analyzed, and then discussed with the misfit theory. The experimental results showed that, by adding rare earth oxide, the av- erage dimension of primary austenite grains in hardfacing layer of medium-high carbon steel decreased, and it was the smallest when the ad- dition of rare earth oxide was 5.17 wt.%. Meanwhile, at this rare earth oxide addition, the primary austenite grain growth activating energy in hardfacing layer was the largest, while its index was the smallest. The calculated results indicated that the primary austenite grain could be refined because LaAlO3 as heterogeneous nuclei of γ-Fe was the most effective.