A generalized corresponding-state model based on two reference fluids was developed for the prediction of surface tensions for non-polar and weakly polar pure fluids and their binary mixtures. Four parameters, p_c, T_...A generalized corresponding-state model based on two reference fluids was developed for the prediction of surface tensions for non-polar and weakly polar pure fluids and their binary mixtures. Four parameters, p_c, T_c, V_c and ω, were used in this model, and the acentric factor ω was used as a scaling parameter. This model has been tested for 69 pure substances and 20 binary mixtures; the average absolute deviations are 0.28 and 0.20 mN/m, respectively. The results indicate that the predictions by means of this model were in good agreement with experimental data. In addition, the calculated deviation would increase with the excess surface tension rising, and if the excess surface tension is less than 3 mN/m, the prediction will be good and credible.展开更多
文摘A generalized corresponding-state model based on two reference fluids was developed for the prediction of surface tensions for non-polar and weakly polar pure fluids and their binary mixtures. Four parameters, p_c, T_c, V_c and ω, were used in this model, and the acentric factor ω was used as a scaling parameter. This model has been tested for 69 pure substances and 20 binary mixtures; the average absolute deviations are 0.28 and 0.20 mN/m, respectively. The results indicate that the predictions by means of this model were in good agreement with experimental data. In addition, the calculated deviation would increase with the excess surface tension rising, and if the excess surface tension is less than 3 mN/m, the prediction will be good and credible.
