Bio-cementation for tidal erosion resistance improvement of foreshore slopes based on microbially induced magnesium and calcium precipitation

In most coastal and estuarine areas,tides easily cause surface erosion and even slope failure,resulting in severe land losses,deterioration of coastal infrastructure,and increased floods.The bio-cementation technique has been previously demonstrated to effectively improve the erosion resistance of slopes.Seawater contains magnesium ions(Mg^(2+))with a higher concentration than calcium ions(Ca^(2+));therefore,Mg^(2+)and Ca^(2+)were used together for bio-cementation in this study at various Mg^(2+)/Ca^(2+)ratios as the microbially induced magnesium and calcium precipitation(MIMCP)treatment.Slope angles,surface strengths,precipitation contents,major phases,and microscopic characteristics of precipitation were used to evaluate the treatment effects.Results showed that the MIMCP treatment markedly enhanced the erosion resistance of slopes.Decreased Mg^(2+)/Ca^(2+)ratios resulted in a smaller change in angles and fewer soil losses,especially the Mg^(2+)concentration below 0.2 M.The decreased Mg^(2+)/Ca^(2+)ratio achieved increased precipitation contents,which contributed to better erosion resistance and higher surface strengths.Additionally,the production of aragonite would benefit from elevated Mg^(2+)concentrations and a higher Ca^(2+)concentration led to more nesquehonite in magnesium precipitation crystals.The slopes with an initial angle of 53°had worse erosion resistance than the slopes with an initial angle of 35°,but the Mg^(2+)/Ca^(2+)ratios of 0.2:0.8,0.1:0.9,and 0:1.0 were effective for both slope stabilization and erosion mitigation to a great extent.The results are of great significance for the application of MIMCP to improve erosion resistance of foreshore slopes and the MIMCP technique has promising application potential in marine engineering.

Study on the Wind Erosion Resistance of Desert Soil Induced by Bacillus Megaterium

With the intensification of global climate change and the worsening of land degradation,desertification has emerged as a significant global issue threatening ecosystems and human activities.The technique of Microbial Induced Calcium Carbonate Precipitation(MICP)has been widely applied in soil stabilization and engineering geology in recent years.This study conducts experiments using Bacillus megaterium to solidify desert sand via MICP,aiming to explore its feasibility as a novel ecological method for desert protection.Experimental results indicate that desert sand treated with MICP exhibits a significant enhancement in wind erosion resistance,providing a potential solution for desert management and land restoration.

Effect of Al-deposition on erosion resistance of plasma sprayed thermal barrier coating

A columnar Al film was firstly deposited on the top of 7%Y2O3？stabilized zirconia （7YSZ） ceramic coating in thermal barrier coating （TBC） system by magnetron sputtering. A vacuum treatment was then carried out at 700 °C for 1 h and 900 °C for 5 h to improve the erosion resistance of Al-deposited TBC. Aα-Al2O3 layer was in situ synthesized on the top of 7YSZ coating via vacuum heat treatment. The microstructure evolution of Al-deposited TBC illustrated that a loose surface-layer and a dense sub-layer formed on the top of 7YSZ coating after vacuum treatment. The phase structures of the as-sprayed TBC and the Al-deposited TBC after vacuum heat treatment were characterized by X-ray diffraction （XRD） and transmission electron microscope （TEM） assisted with focused ion beam （FIB）. Particulate erosion resistances of the as-sprayed TBC and treated TBC were compared at room temperature. In addition, erosion mechanism and schematic diagram were proposed. The results show that the Al-deposited TBC after vacuum heat treatment has better particulate erosion resistance than the as-sprayed one.

Effect of La on arc erosion behaviors and oxidation resistance of Cu alloys

Cu with and without La addition was prepared and the effect of a trace amount of La on the arc erosion behaviors and oxidation resistance of Cu alloys was investigated. The results indicate that CuLa alloy exhibits superior oxidation resistance and arc erosion resistance. The contact resistance and temperature rise were obviously improved. The oxidation resistance of CuLa alloy mainly is due to the interface wrapping of La2O3 particles and CuLa alloy phase on Cu atoms. Thermodynamic calculation indicated that La2O3 could form preferentially in the CuLa alloy, which was beneficial for the protection of the Cu substrate. According to kinetics analysis, the activation energy of CuLa alloy was higher than that of pure Cu, indicating the better oxidation resistance of CuLa alloys.

Corrosion-erosion resistance of Zn-Al co-cementation coatings on carbon steels in aqueous media

A novel Zn Al co cementation coating was obtained by a pack cementation method. This coating possesses a two layered structure. The outer layer is mainly composed of Fe 2Al 5 and FeAl intermetallics with a small amount of Zn, and the inner layer consists of Zn, Fe and a small amount of Al. The corrosion erosion resistance of Zn Al co cementation coatings on carbon steel was studied by a rotary corrosion method in various NaCl and H 2S containing solutions and relevant SiO 2 containing media. The experimental results are compared with those of carbon steels and the sherardizing and aluminizing coatings, showing that the Zn Al co cementation coatings have excellent corrosion erosion resistance in various aqueous media.

Effect of Rare Earth Elements on Erosion Resistance of Nitrocarburized Layers of 38CrMoAl Steel

Effect of rare earth elements (RE) on erosion resistance of nitrocarburized layer of 38CrMoAl steel was investigated. The results indicate that significant improvement occurs in erosion resistance of nitrocarburized 38CrMoAl steel by introducing RE during nitrocarburizing processing as compared with conventional nitrocarburizing processing. Results of mechanical testing show that both hardness and impact toughness of RE-nitrocarburizing layer of 38CrMoAl steel increase as compared with the conventional one. Optical microscopy reveals that there is improvement in the nitrocarburized layer attributed to the introduction of RE, which results in improvement in erosion resistance. Surface morphology observation of tested samples reveals that predominantly furrow-like peelings from plastic deformation are observed for RE nitrocarburizied 38CrMoAl steel, while the furrow-like peeling with initial cross crack and large grinding peelings were observed for conventionally nitrocarburized samples.

Effects of Alloying Elements on Microstructure and Erosion Resistance of Fe-C-Cr Weld Surfacing Layer

Effects of alloying elements on microstructure and erosion resistance of Fe-C-Cr weld surfacing layer have been studied. The experimental results show that increasing C and Cr content favors improving the erosion resistance of the layer, and the excessive C and Cr result in decreasing the erosion resistance at 90 deg. erosion. That Mo, Nb or Ti improves the erosion resistance of Fe-C-Cr weld surfacing layer is mainly attributed to increasing the amount of M7C3 and forming fine NbC or TiC in austenite matrix, but the excessive Mo, Nb or Ti is unfavorable. The addition of Mo, Nb and Ti in proper combination possesses stronger effect on improving the erosion resistance and the erosion resistance (εA) of Fe-C-Cr weld surfacing layer with fine NbC, TiC and M7C3 distributing uniformly in austenite matrix obviously increases to 2.81 at 15 deg. erosion and 2.88 at 90 deg. erosion when the layer composition is 3.05C, 20.58Cr, 1.88Mo, 2.00Nb and 1.05Ti (in wt pct).

Study on Wave-influenced resistance to erosion of silty soil in Huanghe (Yellow) River Delta

Along with the reduction of sediment yield of the Huanghe （Yellow） River, the erosion of the Huanghe River Delta aggravates, which has becomes an important factor that threatens the coastal protection structures. Starting from the study of the erosion resistibility of the sediment, this paper explores the internal mechanism of erosion phenomenon. This paper takes Diaokou as the study area and takes soils as samples which are mixed with clay into reconstructed samples whose ratio of clay content are 5%, 10%, 15%, 20% respectively, then dynamic tri-axial apparatus is applied to simulate wave loads of different intensity; then the resistibility of soil to erosion is determined via concentrated flow test and the structural property is determined via the disintegration test. Finally, the resistibility to erosion and the structural property of the non-compressed soil samples are compared with the compressed data. The results indicates that liquefaction failure exerts significant influence on the resistibility to erosion and the structural property of the silty soil in the Huanghe River Delta. Therefore, in the future erosion studies, the liquefaction phenomenon shall be fully considered.

Microstructures and erosion resistance of plasma-sprayed WCp/NiCrBSi composite coatings

WCp/NiCrBSi composite coatings have been deposited by plasma spraying with the mixed powders of WC-12Ni and NiCrBSi. The coatings consist mainly of WC, γ-Ni, Ni3B, CrB, Cr2B, M7C3, M23C6 and W2C phases. The W2C content increases with increasing WC mass fraction in the powders. The porosity and microhardness of the coatings are related to the coating WC content. The excessive WC results in decreasing the microhardness due to increasing the porosity. The WCp/ NiCrBSi coating with 35 % WC mass fraction powder has more excellent erosion resistance. With an increase of impact angles from 15° to 90° the erosion rate of the coating increases, the erosion rate at 15° impact angle being approximately two times lower than that at 90° impact angle. Based on the wear morphology of the coatings at different impact angles, the wear mechanisms were discussed.

Structure of Micro-nano WC-10Co4Cr Coating and Cavitation Erosion Resistance in NaCl Solution

Cavitation erosion （CE） is the predominant cause for the failure of overflow components in fluid machinery. Advanced coatings have provided an effective solution to cavitation erosion due to the rapid development of surface engineering techniques. However, the influence of coating structures on CE resistance has not been sys- tematically studied. To better understand their relationship, micro-nano and conventional WC-10Co4Cr cermet coat- ings are deposited by high velocity oxygen fuel spray- ing（HVOF）, and their microstructures are analyzed by OM, SEM and XRD. Meanwhile, characterizations of mechan- ical and electrochemical properties of the coatings are carried out, as well as the coatings＇ resistance to CE in 3.5 wt % NaC1 solution, and the cavitation mechanisms are explored. Results show that micro-nano WC-10Co4Cr coating possesses dense microstructure, excellent mechanical and electrochemical properties, with very low porosity of 0.26 4-0.07% and extraordinary fracture toughness of 5.58 4-0.51 MPa.m1/2. Moreover, the CE resistance of micro-nano coating is enhanced above 50% than conventional coating at the steady CE period in 3.5 wt % NaC1 solution. The superior CE resistance of micro- nano WC-10Co4Cr coating may originate from the unique micro-nano structure and properties, which can effectively obstruct the formation and propagation of CE crack. Thus,a new method is proposed to enhance the CE resistance of WC-10Co4Cr coating by manipulating the microstructure.

Influence of vegetation restoration on matrix structure and erosion resistance of iron tailings sites in eastern Hebei, China

The effects of vegetation restoration on matrix structure and erosion resistance of iron tailings were studied at dump sites in Malanzhuang, Qian'an, Hebei province, China. The restoration process involved soil spray sowing restoration model with Rhus typhina, soil and iron tailings admixture spray sowing restoration model with Amorpha fruticosa Linn. and six-hole brick restoration model with Pinus tabulaeformis Carriere.–Amorpha fruticosa Linn. mixed-forest, and direct restoration model with Hippophae rhamnoides and Sabina vulgaris. Results show that the composition and distribution of particles and aggregates were closely related to erosion resistance(P < 0.05), indicating that matrix structure of iron tailings play an important role in erosion resistance. The improvement in matrix structure of iron tailings by the different restoration models was in the order of R. typhina soil spray sowing > A. fruticosa soil and iron tailings admixture spray sowing > mixed-forest six-hole brick >H. rhamnoides direct restoration > S. vulgaris direct restoration. The R. typhina soil spray sowing restorationmodel resulted in the greatest improvement in matrix structure of iron tailings, increasing the clay(10.6%) and large particle aggregates(18.7%) contents significantly(P < 0.01). Simultaneously, particle population, grading conditions(Cu= 28.86, Cs= 1.65), and aggregate stability(6.02) were significantly improved. The A. fruticosa soil and iron tailings admixture spray sowing restoration model,which effectively improved particle distribution(Cu-= 8.51, Cs= 1.07), increased the number of large aggregates considerably(9.6%), thereby increasing aggregate stability(6.2). The six-hole brick model significantly increased the number of large aggregates(4.0%) and improved the stability of aggregates(6.2). H. rhamnoides direct restoration improved the stability of aggregates(5.1)but showed no other significant improvements. The effect of S. vulgaris direct restoration on matrix structure of iron tailings was not significant. Due to its dependence on matrix structure of iron tailings, the erosion resistance of R.typhina soil spray sowing restoration model was the greatest, while that of S. vulgaris direct restoration was the weakest. There was no significant difference in the erosion resistance of the other models. Overall, vegetation restoration supplemented by soil spray sowing restoration and engineering measures is superior to in situ direct vegetation restoration in the short-term. In-situ direct restoration has long-term ecological significance because of its advanced concept of near-natural restoration and the advantages of low cost, easy operation, and low secondary damage.

Mechanical properties and plasma erosion resistance of BN_p/Al_2O_3-SiO_2 composite ceramics

BNp/Al2O3-SiO2 system ceramic matrix composites with different volume fractions （10%-60%） of hexagonal BN particulates （BNp） were prepared by hot-press sintering technique. Phase components, microstructure, mechanical properties and plasma erosion resistance were also investigated. With the increase of h-BNp content, relative density and Vickers＇ hardness of the composite ceramics decrease, while the flexural strength, elastic modulus and fracture toughness increase and then decrease. The plasma erosion resistance linearly deteriorated with the increase of BNp content which is mainly determined by the density, crystal structure and atomic number of the elements.

Erosion resistance of Fe-C-Cr weld surfacing layers

Fe C Cr weld surfacing layers with different compositions and microstructures can be obtained by submerged arc welding with welding wire of the low carbon steel and high alloy bonded flux. With the increase of Cr and C in the layers the microstructures are changed from hypoeutectoid steel, hypereutectoid steel to hypoeutectic iron and hypereutectic iron. When the weld surfacing layers belong to the alloyed cast irons the erosion resistance can be raised with the eutectic increase and the austenite decrease. Good erosion resistance can be obtained when the proportion of the primary carbides is within 10 %. The experimental results lay a foundation to make double metal percussive plates by surfacing wear resistant layers on the substrates of the low carbon steels.

Structure and erosion resistance of Ni60A/SiC coatting by laser cladding

The Ni60A and Ni60A/SiC coatings were obtained by laser cladding on 0.45% C steel. The microstructure and hardness of the coatings were studied by SEM and XRD. The erosion resistances of Ni60A and Ni60A/SiC coatings were also investigated. The results show that the structure of different coatings is up to the temperature gradient and solidifying velocity in metal-melting region during laser cladding process. The coatings consist of a cladding layer, in which dendritic crystal and bulky cell-like crystal exist mainly, and a thermo-affected layer. Ni60A/SiC coating has higher microhardness than that of Ni60A coating, which is mainly caused by SiC and complicated phases formed by Ni, Cr, Fe, C and Si. It is obvious from the erosion test that the Ni60A/SiC coating has high erosion resistance.

Erosion Resistance Behaviours of H13 Steel to Molten ADC12 Alloy

H13 hot work steel samples and surface water vapor oxidized H13 samples were immersed into molten ADC 12 alloy under static resting or dynamic rotating conditions. Weigh-losing method was used to discover the influences of temperature, time and surface conditions on the erosion resistance of H13 steel. The interfaces between the steel and the molten alloy were studied with optical microscopy to compare the different erosion resistance behaviours. The results show that the composite layer outside of the compounds layers changes obviously with increasing temperature, lasting time or sample movement. The better erosion resistance of H13 steel can be endowed with the oxide films, which would gradually decrease along with the dissolve of the films.

Thermal Shock Resistance and Erosion Resistance of TiB_2 Multiphase Ceramic Composites

The thermal shock resistance and anti- aluminum erosion of TiB2 - BN multiphase ceramics composites were studied. The experimental results show that the TiB2-BN multiphase ceramic possesses a good thermal shock resistance at high temperatures （ 1000, 1200, 1400, 1500 ℃ ）, with the increasing in thermal shocking temperature, the electro-conductivity of TiB2-BN ceramics increases. The metal aluminum has a great influence on the properties of TiB2 - BN ceramics and the main reason is that the aluminum reacts seriously with BN. It is suggested that the content of BN should be reduced to the greatest extent.

Erosion Resistance of CaO-Al_2O_3-SiO_2 System Glass-Ceramics

The erosion resistance tests were used to research the erosion wear behavior of CaO-Al-2O-3-SiO-2 system glass-ceramic. With the orthogonal test method, the factors that affect the erosion wear of CaO-Al-2O-3-SiO-2 system glass-ceramic such as particles property, impact angle, impact time, size of particles were discussed.The results show that erosion rate rises along a straight line at the early period of erosion wear.With the impact time increased,the erosion rate deviates from original staight line,tendency of the erosion rate increases.With the size of paricle increased,it will have more kinetic energy,the erosion rate of the surface of glass-ceramics ploate rises.

Contact Resistance and Arc Erosion of Tungsten-copper Contacts in Direct Currents

The arc erosion under medium direct currents in the argon flow was tested on tungsten-copper（W-Cu） contacts which were processed by hot extrusion and heat treatment. The scanning electron microscopy（SEM） and transmission electron microscopy（TEM） were used to study the microstructure of the W-Cu powders and compacts. The contact resistance, arcing energy, and arcing time were continuously measured by JF04C contact materials test system. Changes in tungsten-copper contact surface were observed by SEM. The test results showed that the arcing time and arcing energy all increase with current and voltage, but the changes of average contact resistance are more complicated. For a short arcing time, the average contact resistance decreases with increasing current due to the vaporization of Cu. However, for a longer arcing time, it slightly increases due to the formation of high resistant films, compound copper tungsten. The formation of compound copper tungsten was confirmed by the increased Rc kept in the range from 1.1 to 1.6 mΩ. The compound copper tungsten is first exposed with a tungsten and copper-rich surface, and then totally exposed due to evaporation of copper from the surface. At last a stabilized surface is created and the crystals decrease from 8 μm to 2 μm caused by the arc erosion.

Effect of ion implantation upon erosion resistance of polyimide films in space environment

The atomic oxygen (AO) resistance of Si ion implanted polyimide films in the ground-based AO simulation facility was investigated by scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS) and Auger electron spectroscopy (AES). The results show that at the initial stage of AO exposure the implanted sample has a small mass change, and then is stabilized. The erosion yield of the implanted polyimide film decreases by about two orders of magnitude compared with that of the polyimide film. The analysis through XPS and AES indicates that a continuous high-quality protective oxide-based (SiO2) surface layer is formed on the implanted polyimide films after the AO exposure. It can provide high-quality erosion protection for these materials. The implanted polyimide fully restores its original color and the carbonization effect disappears on the whole after AO exposure. Thermal-optical properties and surface morphology of the implanted polyimide materials are not altered. The modified materials have a markedly increased erosion resistance in AO environment.

The Kirkendall effect on erosion resistance of chrome-coated 25Cr3Mo2WNiV and 30SiMn2MoV gun barrel steels

This study aimed to investigate the erosion behavior and mechanism of a newly developed 25Cr3Mo2WNiV steel with a chrome coating using promoted ignition combustion tests.The erosion threshold pressure and temperature of the chrome-coated 25Cr3Mo2WNiV steel were determined to be 0.2 MPa and 254.3 K higher than those of traditional chrome-coated 30SiMn2MoV steel.Furthermore,Kirkendall voids and inter-diffusion between the Cr coating and matrix were first observed before ero-sion.The improved erosion resistance of the chrome-coated 25Cr3Mo2WNiV steel was attributed to the suppression of the Kirkendall effect,which minimized heat generation at the Cr/matrix interface by pre-venting oxygen diffusion and reducing oxygen affinity.