Pitting corrosion behaviour of Monel-400 alloy in 3.5 wt pct NaCl sodium chloride solution has been investigated using the cyclic potentiodynamic anodic polarization technique. The effect of chloride ion concentration...Pitting corrosion behaviour of Monel-400 alloy in 3.5 wt pct NaCl sodium chloride solution has been investigated using the cyclic potentiodynamic anodic polarization technique. The effect of chloride ion concentration, pH values and difFerent temperatures on the pitting parameters were determined. The morphology of the pits produced after anodic polarization treatments was inspected by scanning electron microscope (SEM). The results indicated that, the increase in chloride ion concentration shifts Epit and Eprot of the alloy toward negative values and the pitting potential is much more dependent on pH value in the basic region. The breakdown of passivity with increasing temperature may be due to kinetic changes of passivating films and dissolution rate of the alloy in its passive展开更多
The transient current behaviour for Iron in 3.5%NaCl and 3.5%NaCl +1%NaNO2 solutions during corrosion fatigue (CF) process has been investigated at different given strain amplitudes and strain rates. The results show ...The transient current behaviour for Iron in 3.5%NaCl and 3.5%NaCl +1%NaNO2 solutions during corrosion fatigue (CF) process has been investigated at different given strain amplitudes and strain rates. The results show that elastic strain has little contribution to material dissolution. The elastic tension strain results in the decrease in the transient current, while the elastic compression strain increases the transient current. Compared to the elastic deformation, plastic deformation affects material dissolution evidently For iron in 3.5%NaCl solution, the strain amplitude plays a dominant role in the dissolution process accelerated by the plastic strain, while in 3.5%NaCl+1%NaNO2 solution, both the strain amplitude and strain rate play an important role in this process. In this paper, the effect of the elastic deformation on the material dissolution and the relation between the tension and compression current peak values under the plastic cycle deformation are展开更多
文摘Pitting corrosion behaviour of Monel-400 alloy in 3.5 wt pct NaCl sodium chloride solution has been investigated using the cyclic potentiodynamic anodic polarization technique. The effect of chloride ion concentration, pH values and difFerent temperatures on the pitting parameters were determined. The morphology of the pits produced after anodic polarization treatments was inspected by scanning electron microscope (SEM). The results indicated that, the increase in chloride ion concentration shifts Epit and Eprot of the alloy toward negative values and the pitting potential is much more dependent on pH value in the basic region. The breakdown of passivity with increasing temperature may be due to kinetic changes of passivating films and dissolution rate of the alloy in its passive
文摘The transient current behaviour for Iron in 3.5%NaCl and 3.5%NaCl +1%NaNO2 solutions during corrosion fatigue (CF) process has been investigated at different given strain amplitudes and strain rates. The results show that elastic strain has little contribution to material dissolution. The elastic tension strain results in the decrease in the transient current, while the elastic compression strain increases the transient current. Compared to the elastic deformation, plastic deformation affects material dissolution evidently For iron in 3.5%NaCl solution, the strain amplitude plays a dominant role in the dissolution process accelerated by the plastic strain, while in 3.5%NaCl+1%NaNO2 solution, both the strain amplitude and strain rate play an important role in this process. In this paper, the effect of the elastic deformation on the material dissolution and the relation between the tension and compression current peak values under the plastic cycle deformation are
