Exploring the unusual orbital hybridization types of atoms and their new connection modes contributes to the development of chemical bond theory and can inspire compounds with unique molecular configurations.Dicoordin...Exploring the unusual orbital hybridization types of atoms and their new connection modes contributes to the development of chemical bond theory and can inspire compounds with unique molecular configurations.Dicoordinated sulfur(S)atoms(or anions)with sp3 hybridization in a bent-bridging mode are commonly observed in many inorganic and organic compounds.However,sp-hybridized S species have,thus far,been extremely rare,and the linearly bridging mode has only been“forcibly”achieved with the aid of metal–S multiple bonds and/or significant steric hindrance from the surrounding organic ligands.展开更多
基金support from the National Natural Science Foundation of China(nos.21671142,21875150,and 21720102006)the 111 Project(no.D20015)+2 种基金the Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD)Shanxi Natural Science Foundation(no.201901D111018)the OIT program of Shanxi Higher Education Institutions.
文摘Exploring the unusual orbital hybridization types of atoms and their new connection modes contributes to the development of chemical bond theory and can inspire compounds with unique molecular configurations.Dicoordinated sulfur(S)atoms(or anions)with sp3 hybridization in a bent-bridging mode are commonly observed in many inorganic and organic compounds.However,sp-hybridized S species have,thus far,been extremely rare,and the linearly bridging mode has only been“forcibly”achieved with the aid of metal–S multiple bonds and/or significant steric hindrance from the surrounding organic ligands.
