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Optimization Design of Superluminescent Diodes with RWG Structure for High Efficiency Coupling with SMFs
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作者 钟馨 黄翊东 +2 位作者 赵涵 张巍 彭江得 《Journal of Semiconductors》 EI CAS CSCD 北大核心 2006年第4期683-687,共5页
With the aim of achieving high coupling power of RWG SLDs into SMFs,the structure dependences of the output power and the near field pattern are investigated. The thicknesses of the layers between the active region an... With the aim of achieving high coupling power of RWG SLDs into SMFs,the structure dependences of the output power and the near field pattern are investigated. The thicknesses of the layers between the active region and the ridge waveguide are optimized by taking into account the injected carrier distribution and local material gain in the SLD cross section. 展开更多
关键词 superluminescent diode coupling efficiency injection efficiency
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An Efficient Three-Dimensional Coupled Normal Mode Model and Its Application to Internal Solitary Wave Problems 被引量:1
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作者 Ze-Zhong Zhang Wen-Yu Luo Ren-He Zhang 《Chinese Physics Letters》 SCIE CAS CSCD 2018年第8期36-39,共4页
We present an efficient three-dimensional coupled-mode model based on the Fourier synthesis technique. In principle, this model is a one-way model, and hence provides satisfactory accuracy for problems where the forwa... We present an efficient three-dimensional coupled-mode model based on the Fourier synthesis technique. In principle, this model is a one-way model, and hence provides satisfactory accuracy for problems where the forward scattering dominates. At the same time, this model provides an efficiency gain of an order of magnitude or more over two-way coupled-mode models. This model can be applied to three-dimensional range-dependent problems with a slowly varying bathymetry or internal waves. A numerical example of the latter is demonstrated in this work. Comparisons of both accuracy and efficiency between the present model and a benchmark model are also provided. 展开更多
关键词 An efficient Three-Dimensional Coupled Normal Mode Model and Its Application to Internal Solitary Wave Problems
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Compact and high-efficient wavelength demultiplexing coupler based on high-index dielectric nanoantennas
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作者 Jingfeng Tan Hua Pang +1 位作者 Fengkai Meng and Jin Jiang 《Chinese Physics B》 SCIE EI CAS CSCD 2018年第9期327-332,共6页
Wavelength demultiplexing waveguide couplers have important applications in integrated nanophotonic devices. Two of the most important indicators of the quality of a wavelength demultiplexing coupler are coupling effi... Wavelength demultiplexing waveguide couplers have important applications in integrated nanophotonic devices. Two of the most important indicators of the quality of a wavelength demultiplexing coupler are coupling efficiency and splitting ratio. In this study, we utilize two asymmetric high-index dielectric nanoantennas directly positioned on top of a silicon-on insulator waveguide to realize a compact wavelength demultiplexing coupler in a communication band, which is based on the interference of the waveguide modes coupled by the two nanoantennas. We add a Au substrate for further increasing the coupling efficiency. This has constructive and destructive influences on the antenna's in-coupling efficiency owing to the Fabry-Perot(FP) resonance in the SiO2 layer. Therefore, we can realize a wavelength demultiplexing coupler with compact size and high coupling efficiency. This coupler has widespread applications in the areas of wavelength filters,on-chip signal processing, and integrated nanophotonic circuits. 展开更多
关键词 wavelength demultiplexing coupler high-index dielectric nanoantenna coupling efficiency Fabry-Perot(FP) resonance
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Design of coupling system in fiber optic sensing measurement
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作者 YANG Rui-feng GAI Ting +2 位作者 GUO Chen-xia HU Chen-hao LANG Guo-wei 《Journal of Measurement Science and Instrumentation》 CAS CSCD 2019年第1期76-80,共5页
According to the principle of choosing the light source in the fiber optic sensing measurement,semiconductor laser is used as the light source of fiber optic sensor and single-mode fiber is used as the tail fiber of l... According to the principle of choosing the light source in the fiber optic sensing measurement,semiconductor laser is used as the light source of fiber optic sensor and single-mode fiber is used as the tail fiber of light source. Based on optical design software Zemax’s pure non-sequential components,a coupling system of semiconductor laser and single-mode fiber is designed. By analyzing the beam characteristics of the semiconductor laser and the coupled mode theory of semiconductor laser and single-mode fiber,the combined lens consists of a ball lens and a collimating lens for the purpose of improving the coupling efficiency and adjusting tolerance. The simulation results show that the coupling efficiency can reach about 78% by using one million ray traces on non-sequential components,while the experimental test result is 69.11%,accordingly,the reasons for the difference between the experiment and the simulation results are analyzed. 展开更多
关键词 semiconductor laser fiber couple ZEMAX coupling efficiency
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Calculation of coupling efficiency for rectangular waveguide CO_2 laser by fresnel approximation
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作者 Hussain Badran 田兆硕 王骐 《Journal of Harbin Institute of Technology(New Series)》 EI CAS 2003年第3期335-337,共3页
Theoretical analyses have been performed to describe the coupling losses for a plane mirror in rectangular waveguide resonator for an arbitrary waveguide mode as a function of the Fresnel number for several values of ... Theoretical analyses have been performed to describe the coupling losses for a plane mirror in rectangular waveguide resonator for an arbitrary waveguide mode as a function of the Fresnel number for several values of the aspect ratio by using Fresnel approximation. 展开更多
关键词 rectangular waveguide RESONATOR coupling efficiency
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High Coupling Efficiency of the Fiber-Coupled Module Based on Photonic-Band-Crystal Laser Diodes
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作者 陈洋 王宇飞 +6 位作者 渠红伟 张玉芳 刘云 马晓龙 郭小杰 赵鹏超 郑婉华 《Chinese Physics Letters》 SCIE CAS CSCD 2017年第7期92-95,共4页
The coupling efficiency of the beam combination and the fiber-coupled module is limited due to the large vertical divergent angle of conventional semiconductor laser diodes. We present a high coupling efficiency modul... The coupling efficiency of the beam combination and the fiber-coupled module is limited due to the large vertical divergent angle of conventional semiconductor laser diodes. We present a high coupling efficiency module using photonic-band-crystal (PBC) laser diodes with narrow vertical divergent angles. Three PBC single-emitter laser diodes are combined into a fiber with core diameter of 105μm and numerical aperture of 0.22. A high coupling efficiency of 94.4% is achieved and the brightness is calculated to be 1.T MW/(cm2.sr) with the injection current of 8A. 展开更多
关键词 PBC High coupling Efficiency of the Fiber-Coupled Module Based on Photonic-Band-Crystal Laser Diodes
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Radiation Temperature Scaling Law for Gold Hohlraum Heated with Lasers at 0.35 mm Wavelength 被引量:4
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作者 江少恩 孙可煦 +3 位作者 丁永坤 黄天晅 崔延莉 陈久森 《Chinese Physics Letters》 SCIE CAS CSCD 2005年第9期2328-2331,共4页
We have carried out the hohlraum experiments about radiation temperature scaling on the Shenguang-Ⅱ (SG- Ⅱ) laser facility with eight laser beams of 0.35#m, pulse duration of about 1.0ns and total energy of 2000J.... We have carried out the hohlraum experiments about radiation temperature scaling on the Shenguang-Ⅱ (SG- Ⅱ) laser facility with eight laser beams of 0.35#m, pulse duration of about 1.0ns and total energy of 2000J. The reradiated x-ray flux through the laser entrance hole was measured using a soft x-ray spectrometer. The measured peak radiation temperature was 170eV for the standard hohlraum and 150 eV for the 1.5-scaled one. We have derived the radiation temperature scaling law, in which the laser hohlraum coupling efficiency is included. With an appropriate coupling efficiency, the coincidences between experimental and scaling hohlraum radiation temperatures are rather good. 展开更多
关键词 INERTIAL CONFINEMENT FUSION INDIRECT-DRIVE TARGETS X-RAY CONFINEMENT coupling EFFICIENCY PHYSICS BASIS ENERGY-LOSS NOVA LASER FACILITY LIGHT IGNITION
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Progress in octahedral spherical hohlraum study 被引量:5
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作者 Ke Lan Jie Liu +36 位作者 Zhichao Li Xufei Xie Wenyi Huo Yaohua Chen Guoli Ren Chunyang Zheng Dong Yang Sanwei Li Zhiwen Yang Liang Guo Shu Li Mingyu Zhang Xiaoying Han Chuanlei Zhai Lifei Hou Yukun Li Keli Deng Zheng Yuan Xiayu Zhan Feng Wang Guanghui Yuan Haijun Zhang Bobin Jiang Lizhen Huang Wei Zhang Kai Du Runchang Zhao Ping Li Wei Wang Jingqin Su Xuewei Deng Dongxia Hu Wei Zhou Huaiting Jia Yongkun Ding Wanguo Zheng Xiantu He 《Matter and Radiation at Extremes》 SCIE EI CAS 2016年第1期8-27,共20页
In this paper,we give a review of our theoretical and experimental progress in octahedral spherical hohlraum study.From our theoretical study,the octahedral spherical hohlraums with 6 Laser Entrance Holes(LEHs)of octa... In this paper,we give a review of our theoretical and experimental progress in octahedral spherical hohlraum study.From our theoretical study,the octahedral spherical hohlraums with 6 Laser Entrance Holes(LEHs)of octahedral symmetry have robust high symmetry during the capsule implosion at hohlraum-to-capsule radius ratio larger than 3.7.In addition,the octahedral spherical hohlraums also have potential superiority on low backscattering without supplementary technology.We studied the laser arrangement and constraints of the octahedral spherical hohlraums,and gave a design on the laser arrangement for ignition octahedral hohlraums.As a result,the injection angle of laser beams of 50°-60°was proposed as the optimum candidate range for the octahedral spherical hohlraums.We proposed a novel octahedral spherical hohlraum with cylindrical LEHs and LEH shields,in order to increase the laser coupling efficiency and improve the capsule symmetry and to mitigate the influence of the wall blowoff on laser transport.We studied on the sensitivity of the octahedral spherical hohlraums to random errors and compared the sensitivity among the octahedral spherical hohlraums,the rugby hohlraums and the cylindrical hohlraums,and the results show that the octahedral spherical hohlraums are robust to these random errors while the cylindrical hohlraums are the most sensitive.Up till to now,we have carried out three experiments on the spherical hohlraum with 2 LEHs on Shenguang(SG)laser facilities,including demonstration of improving laser transport by using the cylindrical LEHs in the spherical hohlraums,spherical hohlraum energetics on the SGIII prototype laser facility,and comparisons of laser plasma instabilities between the spherical hohlraums and the cylindrical hohlraums on the SGIII laser facility. 展开更多
关键词 Indirect-drive inertial confinement fusion Novel spherical hohlraum with 6 LEHs High and robust radiation symmetry High energy coupling efficiency Theoretical study Experiments
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High efficiency and broad bandwidth grating coupler between nanophotonic waveguide and fibre 被引量:2
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作者 朱宇 徐学俊 +5 位作者 李智勇 周亮 韩伟华 樊中朝 俞育德 余金中 《Chinese Physics B》 SCIE EI CAS CSCD 2010年第1期393-397,共5页
A high efficiency and broad bandwidth grating coupler between a silicon-on-insulator (SOI) nanophotonic waveguide and fibre is designed and fabricated. Coupling efficiencies of 46% and 25% at a wavelength of 1.55um ... A high efficiency and broad bandwidth grating coupler between a silicon-on-insulator (SOI) nanophotonic waveguide and fibre is designed and fabricated. Coupling efficiencies of 46% and 25% at a wavelength of 1.55um are achieved by simulation and experiment, respectively. An optical 3 dB bandwidth of 45 mn from 1530 nm to 1575 nm is also obtained in experin, ent. Numerical calculation shows that a tolerance to fabrication error of 10 nm in etch depth is achievable. The measurement results indicate that the alignment error of 112 um results in less than 1 dB additional coupling loss. 展开更多
关键词 grating coupler SILICON-ON-INSULATOR coupling efficiency BANDWIDTH
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Influence of positioning errors of optical shaping components for single emitter laser diode on beam shaping effects 被引量:2
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作者 YAN Yi-xiong ZHENG Yu DUAN Ji-an 《Journal of Central South University》 SCIE EI CAS CSCD 2019年第10期2814-2821,共8页
Beam shaping is required for semiconductor lasers to achieve high optical fiber coupling efficiency in many applications.But the positioning errors on optics may reduce beam shaping effects,and then lead to low optica... Beam shaping is required for semiconductor lasers to achieve high optical fiber coupling efficiency in many applications.But the positioning errors on optics may reduce beam shaping effects,and then lead to low optical fiber coupling efficiency.In this work,the positioning errors models for the single emitter laser diode beam shaping system are established.Moreover,the relationships between the errors and the beam shaping effect of each shapers are analysed.Subsequently,the relationship between the errors and the optical fiber coupling efficiency is analysed.The result shows that position errors in the Z axis direction on the fast axis collimator have the greatest influence on the shaping effect,followed by the position errors in the Z axis direction on the converging lens,which should be strictly suppressed in actual operation.Besides,the position errors have a significant influence on the optical fiber coupling efficiency and need to be avoided. 展开更多
关键词 single emitter laser diode beam shaping positioning error coupling efficiency
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Design of a barcode-like waveguide nanostructure for efficient chip-fiber coupling 被引量:4
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作者 Xiang Wen Ke Xu Qinghai Song 《Photonics Research》 SCIE EI 2016年第6期209-213,共5页
A barcode-like waveguide nanostructure with discretized multilevel pixel lines is designed and optimized by a nonlinear search algorithm. We obtain the design of a one-dimensional multilevel nanostructure with-1.04 d ... A barcode-like waveguide nanostructure with discretized multilevel pixel lines is designed and optimized by a nonlinear search algorithm. We obtain the design of a one-dimensional multilevel nanostructure with-1.04 d B efficiency for surface normal coupling to a standard single-mode fiber. Another design is achieved from the automatic optimization process, which enables polarization-independent coupling to a single-mode fiber. The optimum coupling efficiency is simulated to be-2.83 dB for TE and-3.49 for TM polarization centered near the 1550 nm wavelength. Polarization-dependent loss of less than 1 dB over 45.3 nm is achieved. 展开更多
关键词 TE TM Design of a barcode-like waveguide nanostructure for efficient chip-fiber coupling
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Analysis on Mode Field Distribution of Waveguide Grating Coupler by the Scalar FDTD 被引量:2
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作者 HUANGChong-qing LIUJing +3 位作者 LUOWen-hua ANWei-ke YUANXiu-hua HUANGDe-xiu 《Semiconductor Photonics and Technology》 CAS 2003年第3期166-169,177,共5页
The scalar two-dimensional finite difference time domain (FDTD) method is applied to simulate the mode field distribution of TE 0 of the waveguide grating coupler. Computer simulation shows that the same stable mode f... The scalar two-dimensional finite difference time domain (FDTD) method is applied to simulate the mode field distribution of TE 0 of the waveguide grating coupler. Computer simulation shows that the same stable mode field distribution pattern is obtained through the different kinds of driving sources. It is found that the optical field mode is determined by waveguide structure and optical wavelength other than the driving source.According to the mode field distribution, the optimum coupling efficiency can be predicted. Compared with another numerical methods,the CPU-time and memory elements of computer used by FDTD are much less. 展开更多
关键词 Waveguide grating couplers Light fields coupling efficiency FDTD
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Silicon micromirrors with three-dimensional curvature enabling lensless efficient coupling of free-space light 被引量:1
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作者 Yasser M Sabry Bassam Saadany +1 位作者 Diaa Khalil Tarik Bourouina 《Light(Science & Applications)》 SCIE EI CAS 2013年第1期98-106,共9页
Miniaturized optical benches process free-space light propagating in-plane with respect to the substrate and have a large variety of applications,including the coupling of light through an optical fiber.High coupling ... Miniaturized optical benches process free-space light propagating in-plane with respect to the substrate and have a large variety of applications,including the coupling of light through an optical fiber.High coupling efficiency is usually obtained using assembled micro-optical parts,which considerably increase the system cost and integration effort.In this work,we report a high coupling efficiency,monolithically integrated silicon micromirror with controlled three-dimensional(3D)curvature that is capable of manipulating optical beams propagating in the plane of the silicon substrate.Based on our theoretical modeling,a spherical micromirror with a microscale radius of curvature as small as twice the Gaussian beam Rayleigh range provides a 100%coupling efficiency over a relatively long optical path range.Introducing dimensionless parameters facilitates the elucidation of the role of key design parameters,including the mirror’s radii of curvature,independent of the wavelength.A micromachining method is presented for fabricating the 3D micromirror using fluorinated gas plasmas.The measured coupling efficiency was greater than 50%over a 200-mm optical path,compared to less than 10%afforded by a conventional flat micromirror,which was in good agreement with the model.Using the 3D micromirror,an optical cavity was formed with a round-trip diffraction loss of less than 0.4%,resulting in one order of magnitude enhancement in the measured quality factor.A nearly 100%coupling was also estimated when matching the sagittal and tangential radii of curvature of the presented micromirror’s surface.The reported class of 3D micromirrors may be an advantageous replacement for the optical lenses usually assembled in silicon photonics and optical benches by transforming them into real 3D monolithic systems while achieving wideband high coupling efficiency over submillimeter distances. 展开更多
关键词 coupling efficiency Gaussian beam coupling MICRO-OPTICS monolithic chip optical cavity optical fabrication optical benches silicon photonics
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High-sensitivity methane monitoring based on quasi-fundamental mode matched continuous-wave cavity ring-down spectroscopy 被引量:1
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作者 Zhe Li Shuang Yang +6 位作者 Zhirong Zhang Hua Xia Tao Pang Bian Wu Pengshuai Sun Huadong Wang Runqing Yu 《Chinese Physics B》 SCIE EI CAS CSCD 2022年第9期326-332,共7页
Continuous-wave cavity ring-down spectroscopy(CW-CRDS)is an important technical means to monitor greenhouse gases in atmospheric environment.In this paper,a CW-CRDS system is built to meet the needs of atmospheric met... Continuous-wave cavity ring-down spectroscopy(CW-CRDS)is an important technical means to monitor greenhouse gases in atmospheric environment.In this paper,a CW-CRDS system is built to meet the needs of atmospheric methane monitoring.The problem of mode matching is explained from the perspective of transverse mode and longitudinal mode,and the influence of laser injection efficiency on measurement precision is further analyzed.The results of cavity ring-down time measurement show that the measurement precision is higher when the laser is coupled with the fundamental mode.In the experiment,DFB laser is used to calibrate the system with standard methane concentration,and the measurement residual is less than±4×10^(-4)μs^(-1).The methane concentration in the air is monitored in real time for two days.The results show the consistency of the concentration changes over the two days,which further demonstrates the reliability of the system for the measurement of trace methane.By analyzing the influence of mode matching,it not only assists the adjustment of the optical path,but also further improves the sensitivity of the system measurement. 展开更多
关键词 continuous-wave cavity ring-down spectroscopy(CW-CRDS) cavity modes coupling efficiency mode matching greenhouse gas
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Coupled resonator-induced transparency on a three-ring resonator 被引量:1
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作者 Xinquan Jiao Haobo Yu +2 位作者 Miao Yu Chenyang Xue Yongfeng Ren 《Chinese Physics B》 SCIE EI CAS CSCD 2018年第7期371-375,共5页
The coupled resonator-induced transparency (CRIT) phenomenon, which is analogous to electromagnetically induced transparency in atomic systems, can occur in an original integrated optical resonator system due to the... The coupled resonator-induced transparency (CRIT) phenomenon, which is analogous to electromagnetically induced transparency in atomic systems, can occur in an original integrated optical resonator system due to the coherent interference of the coupled optical resonators. The system was composed of three ring resonators on silicon, each with the same cavity size, and the optical coupling to the input and output ports was achieved using grating with a power coupling efficiency of 36%. A CRIT resonance whose spectrum shows a narrow transparency peak with a low group velocity was demonstrated. The quality factor of the ring resonator can attain a value up to 6x 104, and the harmonic wavelength can be controlled by adjusting the temperature. The through and drop transmission spectra of the resonator are reconciled well with each other and also consistent well with the theoretical analysis. 展开更多
关键词 coupled resonator-induced transparency three-ring resonator coupling efficiency transmission spectra quality factor
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Wavelength dependent loss of splice of single-mode fibers 被引量:1
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作者 YANG Bo DUAN Ji-an +1 位作者 XIE Zheng XIAO Hong-feng 《Journal of Central South University》 SCIE EI CAS 2013年第7期1832-1837,共6页
After reviewing three different definitions of mode field diameter of single-mode fibers, coupled efficiency calculation methods associated with lateral offset, longitude separation and wavelength, the effects produce... After reviewing three different definitions of mode field diameter of single-mode fibers, coupled efficiency calculation methods associated with lateral offset, longitude separation and wavelength, the effects produced by them, and the influences of splicing defects were discussed in detail. The regularities of the effects were studied according to the first order derivation of couple efficiency formula, and a simplified formula for couple efficiency calculation was presented under the circumstance of slight misalignment, with respect to wavelength, 2, and in a good agreement with the theoretical model. The simplified formula provides a new but simple approach to evaluate wavelength dependent couple efficiency of single-mode fibers. Theoretical analyses and numerical calculations show that, when those defects exist, the wavelength produces additional effects on the couple loss that growth of wavelength causes an increase on the couple efficiency for the lateral offset or longitude separation whereas lessens the couple efficiency due to angular misalignment or mode fields mismatching, and that the wavelength degrades the couple efficiency distinctly when λ≥2.5 μm whereas it distorts the couple slightly in range of λ≤2λ≤2 μm. 展开更多
关键词 wavelength dependent loss couple efficiency single-mode fiber cut-offwavelength
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In situ Synthesis of Oligonucleotides on Plasma Treated Polypropylene Microporous Membrane
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作者 NongYueHE JianXinTANG +2 位作者 SongLI HongCHEN AnCunZHOU 《Chinese Chemical Letters》 SCIE CAS CSCD 2005年第3期397-400,共4页
Polypropylene microporous membranes were treated with plasma in a mixture of N2 and H2 (1:2 in volume). Attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FT1R), X-ray photoelectron spectroscopy... Polypropylene microporous membranes were treated with plasma in a mixture of N2 and H2 (1:2 in volume). Attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FT1R), X-ray photoelectron spectroscopy (XPS) and ultra-violet (UV) spectra demonstrated the success of grafting amino groups. The density of the polar amino groups on the membrane surface is about 0.59 μmol/cm2. The as-treated membranes were successively applied to the in situ synthesis of oligonucleotides and an average coupling yield was more than 98%. The surface feature of the treated membrane is suggested to be responsible for its advantage over a glass slide. 展开更多
关键词 PLASMA grafting. amino group in situ synthesis of oligonucleotides coupling efficiency polypropylene microporous membrane.
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Apodized grating coupler using fully-etched nanostructures
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作者 武华 李冲 +1 位作者 李智勇 郭霞 《Chinese Physics B》 SCIE EI CAS CSCD 2016年第8期211-215,共5页
A two-dimensional apodized grating coupler for interfacing between single-mode fiber and photonic circuit is demonstrated in order to bridge the mode gap between the grating coupler and optical fiber. The grating groo... A two-dimensional apodized grating coupler for interfacing between single-mode fiber and photonic circuit is demonstrated in order to bridge the mode gap between the grating coupler and optical fiber. The grating grooves of the grating couplers are realized by columns of fully etched nanostructures, which are utilized to digitally tailor the effective refractive index of each groove in order to obtain the Gaussian-like output diffractive mode and then enhance the coupling efficiency.Compared with that of the uniform grating coupler, the coupling efficiency of the apodized grating coupler is increased by 4.3% and 5.7%, respectively, for the nanoholes and nanorectangles as refractive index tunes layer. 展开更多
关键词 grating couplers equivalent refractive index mode matching coupling efficiency
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A Novel Substrate for in situ Synthesis of Oligonucleotides: Hydrolyzed Microporous Polyamide-6 Membrane
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作者 SongLI JianXinTANG MeiJuJI PengHOU PengFengXIAO NongYueHE 《Chinese Chemical Letters》 SCIE CAS CSCD 2004年第7期837-840,共4页
A novel substrate for in situ synthesis of oligonucleotide was prepared by hydrolyzing microporous polyamide-6 membranes in a 0.01mol/L NaOH/(H2O-CH3OH) mixture medium. The formation of amines (NH2) on the surface was... A novel substrate for in situ synthesis of oligonucleotide was prepared by hydrolyzing microporous polyamide-6 membranes in a 0.01mol/L NaOH/(H2O-CH3OH) mixture medium. The formation of amines (NH2) on the surface was proved by attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR). The treated membrane was applied for in situ synthesis of oligonucleotide and a single step coupling efficiency determined by ultraviolet (UV) spectra was above 98 %. 展开更多
关键词 Catalyzed hydrolysis in situ synthesis of oligonucleotides coupling efficiency poly-amide-6 membrane.
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Ambient electrocatalytic synthesis of urea by co-reduction of NO_(3)^(-) and CO_(2) over graphene-supported In_(2)O_(3)
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作者 Yini Mao Yong Jiang +4 位作者 Hao Liu Yimin Jiang Ming Li Wei Su Rongxing He 《Chinese Chemical Letters》 SCIE CAS CSCD 2024年第3期538-543,共6页
Urea plays a vital role in the sustainable development of mankind as it is one of the most important nitrogen fertilizers.Conventional synthesis of urea is accompanied by a high level of energy consumption while elect... Urea plays a vital role in the sustainable development of mankind as it is one of the most important nitrogen fertilizers.Conventional synthesis of urea is accompanied by a high level of energy consumption while electrocatalytic methods suffer from low yields and poor selectivity.Our work achieves efficient synthesis of urea by designing the graphene-In_(2)O_(3)electrocatalysts for the co-activated reduction of nitrate and carbon dioxide,where the formation rate of urea,Faraday efficiency(FE)and carbon selectivity at-0.35 V vs.RHE can reach 357.47μg mg^(-1)h^(-1),10.46%and~100%,respectively.Herein,the key intermediates in the C–N coupling reaction are demonstrated to be*NH_(2)and*CO_(2),which is of novelty compared to previous reports.This work may provide inspiration for subsequent studies on the reaction mechanism of the electrochemical synthesis of urea,as well as theoretical guidance for the sustainable synthesis of some other important chemical substances. 展开更多
关键词 Graphene-supported In_(2)O_(3) Dispersion effect efficient C-N coupling Key intermediate UREA
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