The effect of microwave irradiation on the intermolecular and intramolecular Friedel-Crafts acylation of aromatic compounds was investigated. Microwave irradiation had no effect on the intermolecular reaction but had ...The effect of microwave irradiation on the intermolecular and intramolecular Friedel-Crafts acylation of aromatic compounds was investigated. Microwave irradiation had no effect on the intermolecular reaction but had an accelerating effect on the intramolecular reaction. This enhanced intramolecular reactivity that was attributed to the high probability of close proximity between the reaction sites.展开更多
The reaction between diphenylmethanols and substituted benzenes is useful to yield triarylmethane derivatives which are important skeletons in various functional materials and biologically relevant substances. The Rea...The reaction between diphenylmethanols and substituted benzenes is useful to yield triarylmethane derivatives which are important skeletons in various functional materials and biologically relevant substances. The Reactions were carried out under microwave irradiation as environmentally-friendly method. In cyclohexane, the reaction was accelerated under microwave irradiation as compared to under conventional heating. Also, when more than 0.8 equivalents of iron(III) chloride were used, the acceleration was observed. Notably, when iron(III) chloride and arenes were combined, the temperature of the reaction solution rose to 40°C. It is considered that a chemical species was formed upon coordination of iron(III) chloride to the diphenylmethanols or arenes.展开更多
Based on the research, simulation and experimental investigation of Basilisk Lizard running on the water surface, and similar experimental investigation of the craft models and practical crafts running on the water su...Based on the research, simulation and experimental investigation of Basilisk Lizard running on the water surface, and similar experimental investigation of the craft models and practical crafts running on the water surface for about 30 years. The Bionic Lizard Flying Wheel Planing Craft was created and invented. This paper describes the evolution, experimental investigation, test results, design features, advantages, applications, and prospect of the innovation, which denotes the craft with excellent speed performance （high speed, extra STOL （short take-off and landing distance） and VTOL（vertical take-off and landing） characteristics, good transverse and longitudinal stability, super shallow water draft, high propulsion efficiency at high speed without cavitations obstacle, low external field noise, small dimension, simple configuration and structure, good economy, nice transportation efficiency, and possibly is first of these kinds in the HPMV （High Performance Marine Vessels） family around the world.展开更多
The optimum coating composition of alkali Fe powder welding rods was designed by orthogonal experiment with mix rates. A new kind of effective RE-Fe powder welding rod was prepared which could be used at the condition...The optimum coating composition of alkali Fe powder welding rods was designed by orthogonal experiment with mix rates. A new kind of effective RE-Fe powder welding rod was prepared which could be used at the condition of direct and indirect current. The arc characteristics and stabilities of effective Fe powder welding rods containing RE were analyzed by HANNOVER analyzer. The efficiency of Fe powder welding rods was tested by weighting method. It was found that the stability of Fe powder welding rods was improved when it was added with rare earths. The results of impact experiment at low temperatures and SEM analysis on impact break showed that the grain was refined, the welding joint was cleaned, and the mechanical properties of joint was enhanced with proper RE content. It was provided with good processing property for this effective RE-Fe powder welding rod, and its efficiency could arrive at 180%.展开更多
文摘The effect of microwave irradiation on the intermolecular and intramolecular Friedel-Crafts acylation of aromatic compounds was investigated. Microwave irradiation had no effect on the intermolecular reaction but had an accelerating effect on the intramolecular reaction. This enhanced intramolecular reactivity that was attributed to the high probability of close proximity between the reaction sites.
文摘The reaction between diphenylmethanols and substituted benzenes is useful to yield triarylmethane derivatives which are important skeletons in various functional materials and biologically relevant substances. The Reactions were carried out under microwave irradiation as environmentally-friendly method. In cyclohexane, the reaction was accelerated under microwave irradiation as compared to under conventional heating. Also, when more than 0.8 equivalents of iron(III) chloride were used, the acceleration was observed. Notably, when iron(III) chloride and arenes were combined, the temperature of the reaction solution rose to 40°C. It is considered that a chemical species was formed upon coordination of iron(III) chloride to the diphenylmethanols or arenes.
文摘Based on the research, simulation and experimental investigation of Basilisk Lizard running on the water surface, and similar experimental investigation of the craft models and practical crafts running on the water surface for about 30 years. The Bionic Lizard Flying Wheel Planing Craft was created and invented. This paper describes the evolution, experimental investigation, test results, design features, advantages, applications, and prospect of the innovation, which denotes the craft with excellent speed performance （high speed, extra STOL （short take-off and landing distance） and VTOL（vertical take-off and landing） characteristics, good transverse and longitudinal stability, super shallow water draft, high propulsion efficiency at high speed without cavitations obstacle, low external field noise, small dimension, simple configuration and structure, good economy, nice transportation efficiency, and possibly is first of these kinds in the HPMV （High Performance Marine Vessels） family around the world.
文摘The optimum coating composition of alkali Fe powder welding rods was designed by orthogonal experiment with mix rates. A new kind of effective RE-Fe powder welding rod was prepared which could be used at the condition of direct and indirect current. The arc characteristics and stabilities of effective Fe powder welding rods containing RE were analyzed by HANNOVER analyzer. The efficiency of Fe powder welding rods was tested by weighting method. It was found that the stability of Fe powder welding rods was improved when it was added with rare earths. The results of impact experiment at low temperatures and SEM analysis on impact break showed that the grain was refined, the welding joint was cleaned, and the mechanical properties of joint was enhanced with proper RE content. It was provided with good processing property for this effective RE-Fe powder welding rod, and its efficiency could arrive at 180%.
