Preparation of Controllable Cross-Linking Polyethylene Foaming Materials and Their Properties

In order to prepare the polyethylene materials with controlling properties,we developed two kinds of controllable cross-linking polyethylene foaming system.2,5-dimethyl-2,5-bis (tert-butyl peroxy) hexane was used as cross-linking agent and TEMPO as cross-linking inhibitor,azodicarbonamide (AC) was used as foaming agent and citric acid as foaming promoter.The density,expansion ratio,cellular structure and mechanical property of these two kinds of controllable materials were studied.Experimental results show that,properties of these two kinds of materials appear similar trend:cellular size and expansion ratio are enlarged with the amount of cross-linking inhibitor or foaming promoter increasing,while density and mechanical strength appear decreasing trend.Through comparing those two material systems’ properties,cross-linking polyethelene foaming system with citric acid as foaming promoter has better properties.

新型XPE健美操地垫特性分析及制备工艺影响研究

健美操在居家运动甚至高校课程中都被广泛关注,各项性能均衡的健美操地垫也随之被关注,人们生活工作中应用材料的环保性越来越得到重视,新型环保材料XPE在绿色领域具有很大的发展前景,因其特殊的泡孔结构和优异的吸音性、隔热性、缓冲性及耐化学腐蚀性等,被广泛应用于各个设施行业等领域,同时PE也是最早实现工业化批量生产和应用的发泡材料之一。XPE材料是用聚乙烯树脂加交联剂和发泡剂经过高温连续发泡而成,材料的化学性相对稳定,不容易发生分解,本文就健美操地垫的高强度XPE材料的性能优势及影响因素展开分析。

火焰复合层对化学交联聚乙烯发泡材料力学性能的影响

化学交联聚乙烯发泡材料（Cross-linked polyethylene,XPE）具有优异的物理、化学与力学性能,被广泛应用于工业领域。本文通过对不同层数的XPE发泡材料进行加载-卸载试验与压缩循环试验,得到不同层数XPE发泡材料的应力-应变曲线,获得了弹性区与平台区分界点的应力与应变、平台区与强化区应力的数量关系。通过计算得出应力-应变环的面积,发现其能量耗散能力随加载次数增加呈现下降趋势。结果表明,单层XPE发泡材料的弹性区与平台区弹性极限应变、临界应力强度和应力环面积等性质与多层材料相比差别显著,而多层材料间力学性能的差异微小。这些特征表明,火焰复合层自身具有较大的刚度并对发泡材料孔壁有较强的约束,改善了XPE发泡材料的刚度、弹性模量及耗能能力等。