3,3′-Dimethyl-dibenzo-18-crown-6 was synthesized and characterized by elemental analysis, FT-IR, ^1H NMR, UV, MS spectra and X-ray single-crystal diffraction. It belongs to orthorhombic, space group Pna21 with a = 8....3,3′-Dimethyl-dibenzo-18-crown-6 was synthesized and characterized by elemental analysis, FT-IR, ^1H NMR, UV, MS spectra and X-ray single-crystal diffraction. It belongs to orthorhombic, space group Pna21 with a = 8.0790(18), b = 16.780(4), c = 15.222(3) .A, Z= 4, V= 2063.6(8) A3 Dc = 1.250 g/cm^3,μ = 0.090 mm^-1, F(000) = 832, R = 0.0474 and wR = 0.1103. According to structural analysis, the title compound possesses a boat-like configuration.展开更多
基金This project was supported by the Natural Science Foundation of Shandong Province (No.Y2003 D01)
文摘3,3′-Dimethyl-dibenzo-18-crown-6 was synthesized and characterized by elemental analysis, FT-IR, ^1H NMR, UV, MS spectra and X-ray single-crystal diffraction. It belongs to orthorhombic, space group Pna21 with a = 8.0790(18), b = 16.780(4), c = 15.222(3) .A, Z= 4, V= 2063.6(8) A3 Dc = 1.250 g/cm^3,μ = 0.090 mm^-1, F(000) = 832, R = 0.0474 and wR = 0.1103. According to structural analysis, the title compound possesses a boat-like configuration.